CN105967642B - Net porcelain of a kind of feature work and preparation method thereof - Google Patents

Net porcelain of a kind of feature work and preparation method thereof Download PDF

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CN105967642B
CN105967642B CN201610265911.6A CN201610265911A CN105967642B CN 105967642 B CN105967642 B CN 105967642B CN 201610265911 A CN201610265911 A CN 201610265911A CN 105967642 B CN105967642 B CN 105967642B
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陈源浩
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/131—Inorganic additives
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/30—Treatment of water, waste water, or sewage by irradiation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3481—Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Toxicology (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The present invention relates to net porcelain of a kind of feature work and preparation method thereof, the net porcelain billet material of the feature work is made up of following components in percentage by weight：Quartz 13% 15%, albite 6% 8%, potassium feldspar 3% 5%, medical stone 5% 6%, rare earth element 5.9% 7%, borax 2% 3%, clay 47% 59%, barium carbonate 1.5% 2.5%, spinelle 2.1% 3.2%, cordierite 2.5% 3%；The net glaze of the feature work is made up of following components in percentage by weight：Nano Silver 4% 5%, tourmaline 4% 4.8%, medical stone 7% 8%, limonite 5.5% 6.5%, anion 11% 13%, germanium powder 2% 3%, borax 2.3% 3%, clay 56% 65%.The beneficial effects of the present invention are, net porcelain of a kind of feature work and its preparation method and application is provided, net ceramic material living can play a part of purifying water, applied to container can be played a part of in ceramic after can also purify water, so as to reach the effect of promoting health.

Description

Net porcelain of a kind of feature work and preparation method thereof
Technical field
The invention belongs to ceramic technology field, is related to net porcelain of a kind of feature work and preparation method thereof.
Background technology
Ceramic product is more and more applied in daily life now, is also provided in addition to as traditional decoration certain Storage effect, but for ceramic product essence, it is to provide the carrier held, a platform, and can not provide More beneficial effects, how to be improved from the ceramic material of itself turns into the class of research to provide more beneficial effects Topic and main flow direction.
The content of the invention
It is an object of the present invention to provide a kind of net porcelain of feature work, to solve the above problems.
Another object of the present invention is to, there is provided the preparation method of the net porcelain of above-mentioned feature work.
Third object of the present invention is, there is provided the application of the net porcelain of above-mentioned feature work.
The present invention is accomplished by the following way：
A kind of net porcelain of feature work, the net porcelain billet material of the feature work are made up of following components in percentage by weight：Quartz Stone 13%-15%, albite 6%-8%, potassium feldspar 3%-5%, tourmaline 4%-5%, medical stone 5%-6%, rare earth element 5.9%-7%, borax 2%-3%, clay 47%-59%, barium carbonate 1.5%-2.5%, spinelle 2.1%-3.2%, violet are blue or green Stone 2.5%-3%；The net glaze of the feature work is made up of following components in percentage by weight：Nano Silver 4%-5%, electrically Stone 4%-4.8%, medical stone 7%-8%, limonite 5.5%-6.5%, anion 11%-13%, germanium powder 2%-3%, borax 2.3%-3%, clay 52%-60%.
Further, the net porcelain billet material of the feature work is made up of following components in percentage by weight：Quartz 14%, Albite 7%, potassium feldspar 4%, tourmaline 4.5%, medical stone 5.5%, rare earth element 6.5%, borax 2.5%, clay 48.4%th, barium carbonate 2%, spinelle 2.8%, cordierite 2.8%；The feature lives net glaze by following percentage by weight Component be made：Nano Silver 4.5%, tourmaline 4.5%, medical stone 7.5%, limonite 6%, anion 12%, germanium powder 2.5%th, borax 2.6%, clay 60.4%.
The preparation method of the net porcelain of above-mentioned feature work comprises the following steps：
S1. pre-treatment of raw material：
S11. albite, potassium feldspar are calcined 5.5 hours at 1020 DEG C respectively, and are ground after being cooled to normal temperature, Cross 120 mesh sieves.
S12. quartz, medical stone, spinelle, cordierite, limonite are calcined 8.5 hours at 870 DEG C respectively, and Ground after being cooled to normal temperature, cross 120 mesh sieves.
S13. clay is calcined 10 hours at 600 DEG C, and ground after being cooled to normal temperature, cross 120 mesh sieves.
S2. prepared by blank
By weight percentage, quartz 14%, albite 7%, potassium feldspar 4%, tourmaline 4.5%, medical stone are taken 5.5%th, rare earth element 6.5%, borax 2.5%, clay 48.4%, barium carbonate 2%, spinelle 2.8%, cordierite 2.8% are made For blank stock, ball mill is knocked down, adds 80~100% water of blank stock gross weight, is ground 24 hours, then it is quiet Put 40 hours, remove water float thing, then cleaned using magnet, then except hydraulic pressure mud, pugging to pug wet weight percentage For 19~25%, blank is made；
S3. prepared by glaze
By weight percentage, Nano Silver 4.5%, tourmaline 4.5%, medical stone 7.5%, limonite 6%, anion are taken 12%th, germanium powder 2.5%, borax 2.6%, clay 60.4% are used as glaze raw material, knock down ball mill, add enamel raw material gross weight 80~100% water, it is ground 24 hours, then stands 40 hours, remove water float thing, then cleaned using magnet, then Except hydraulic pressure mud, pugging to pug wet weight percentage are 19~25%, glaze is made；
S4. the S2 blanks prepared are molded by traditional ceramics production method, dried, then biscuiting 7 is small at 900 DEG C When, and normal temperature is naturally cooled to, obtain biscuiting product；
S5. traditional ceramics production method is pressed, glazing is carried out to biscuiting product prepared by S4 using glaze prepared by S3, then It is placed in kiln and is burnt till, obtains the net porcelain of the feature work.
The net porcelain of feature work that above-mentioned preparation method is prepared.
Application of the net porcelain of above-mentioned feature work in ceramic is prepared.
Application of the net porcelain of above-mentioned feature work in drinking water treatment equipment is prepared.
The core content of the present invention is adding germanium powder and anion in raw material, and by the rational proportion of raw material, Germanium powder and anion is enabled to play maximum catharsis, finished product can be container or the thing for providing purification function Product.
Product made of the present invention has following net work energy living：
Examined through " Beijing public health drinking water research institute ", bacteriostasis rate reaches 75.76%.
Examined through " Beijing public health drinking water research institute ", free chlorine residual clearance reaches 24.3%.
Through " country is infrared and industrial electroheat product quality supervision and inspection " center " is examined, and product infra red energy density is 9.22x102W/m2。
The invention has the advantages that net ceramic material living can play a part of purifying water, applied in ceramic It can play a part of purifying water after container, so as to reach the effect of promoting health.
Embodiment
A kind of preparation method of the net porcelain of feature work：
S1. pre-treatment of raw material：
S11. albite, potassium feldspar are calcined 5.5 hours at 1020 DEG C respectively, and are ground after being cooled to normal temperature, Cross 120 mesh sieves.
S12. quartz, medical stone, spinelle, cordierite, limonite are calcined 8.5 hours at 870 DEG C respectively, and Ground after being cooled to normal temperature, cross 120 mesh sieves.
S13. clay is calcined 10 hours at 600 DEG C, and ground after being cooled to normal temperature, cross 120 mesh sieves.
S2. prepared by blank
By weight percentage, quartz 13%-15%, albite 6%-8%, potassium feldspar 3%-5%, medical stone are taken 5%-6%, rare earth element 5.9%-7%, borax 2%-3%, clay 47%-59%, barium carbonate 1.5%-2.5%, spinelle 2.1%-3.2%, cordierite 2.5%-3% knock down ball mill as blank stock, add blank stock gross weight 80~ 100% water, it is ground 24 hours, then stands 40 hours, remove water float thing, then cleaned using magnet, is then removed water It is 19~25% to press mud, pugging to pug wet weight percentage, and blank is made；
S3. prepared by glaze
By weight percentage, Nano Silver 4%-5%, tourmaline 4%-4.8%, medical stone 7%-8%, limonite are taken 5.5%-6.5%, anion 11%-13%, germanium powder 2%-3%, borax 2.3%-3%, clay 56%-65% are former as glaze Material, knocks down ball mill, adds 80~100% water of enamel raw material gross weight, be ground 24 hours, then stands 40 hours, removes Water float thing is removed, then is cleaned using magnet, then except hydraulic pressure mud, pugging to pug wet weight percentage are 19~25%, Glaze is made；
S4. the S2 blanks prepared are molded by traditional ceramics production method, dried, then biscuiting 7 is small at 900 DEG C When, and normal temperature is naturally cooled to, obtain biscuiting product；
S5. traditional ceramics production method is pressed, glazing is carried out to biscuiting product prepared by S4 using glaze prepared by S3, then It is placed in kiln and is burnt till, obtains the net porcelain of the feature work.
Optimum implementation：
S1. pre-treatment of raw material：
S11. albite, potassium feldspar are calcined 5.5 hours at 1020 DEG C respectively, and are ground after being cooled to normal temperature, Cross 120 mesh sieves.
S12. quartz, medical stone, spinelle, cordierite, limonite are calcined 8.5 hours at 870 DEG C respectively, and Ground after being cooled to normal temperature, cross 120 mesh sieves.
S13. clay is calcined 10 hours at 600 DEG C, and ground after being cooled to normal temperature, cross 120 mesh sieves.
S2. prepared by blank
By weight percentage, quartz 14%, albite 7%, potassium feldspar 4%, medical stone 5.5%, rare earth element are taken 6.5%th, borax 2.5%, clay 52.9%, barium carbonate 2%, spinelle 2.8%, cordierite 2.8% are used as blank stock, throw Enter ball mill, add 80~100% water of blank stock gross weight, be ground 24 hours, be stirred simultaneously, then it is quiet Put 40 hours, remove water float thing, then cleaned using magnet, then except hydraulic pressure mud, pugging to pug wet weight percentage For 19~25%, blank is made；
S3. prepared by glaze
By weight percentage, Nano Silver 4.5%, tourmaline 4.4%, medical stone 7.5%, limonite 6%, anion are taken 12%th, germanium powder 2.5%, borax 2.6%, clay 60.5% are used as glaze raw material, knock down ball mill, add enamel raw material gross weight 80~100% water, it is ground 24 hours, then stands 40 hours, remove water float thing, then cleaned using magnet, then Except hydraulic pressure mud, pugging to pug wet weight percentage are 19~25%, glaze is made；
S4. the S2 blanks prepared are molded by traditional ceramics production method, dried, then biscuiting 7 is small at 900 DEG C When, and normal temperature is naturally cooled to, obtain biscuiting product；
S5. traditional ceramics production method is pressed, glazing is carried out to biscuiting product prepared by S4 using glaze prepared by S3, then It is placed in kiln and is burnt till, obtains the net porcelain of the feature work.
Presently preferred embodiments of the present invention is the foregoing is only, is not used for limiting the practical range of the present invention；That is Fan Yiben The equivalents that the right of invention is done, it is that scope of the presently claimed invention is covered.

Claims (4)

  1. The preparation method of net porcelain 1. a kind of feature is lived, it is characterised in that comprise the following steps：
    S1. pre-treatment of raw material；
    S11. albite, potassium feldspar are calcined 5.5 hours at 1020 DEG C respectively, and are ground after being cooled to normal temperature, cross 120 Mesh sieve；
    S12. quartz, medical stone, spinelle, cordierite, limonite are calcined 8.5 hours at 870 DEG C respectively, and are cooled to Ground after normal temperature, cross 120 mesh sieves；
    S13. clay is calcined 10 hours at 600 DEG C, and ground after being cooled to normal temperature, cross 120 mesh sieves；
    S2. prepared by blank；
    By weight percentage, take quartz 14%, albite 7%, potassium feldspar 4%, tourmaline 4.5%, medical stone 5.5%, Rare earth element 6.5%, borax 2.5%, clay 48.4%, barium carbonate 2%, spinelle 2.8%, cordierite 2.8% are used as blank Raw material, ball mill is knocked down, adds 80~100% water of blank stock gross weight, be ground 24 hours, then stand 40 hours, Remove water float thing, then cleaned using magnet, then except hydraulic pressure mud, pugging to pug wet weight percentage be 19~ 25%, blank is made；
    S3. prepared by glaze；
    By weight percentage, Nano Silver 4.5%, tourmaline 4.5%, medical stone 7.5%, limonite 6%, anion are taken 12%th, germanium powder 2.5%, borax 2.6%, clay 60.4% are used as glaze raw material, knock down ball mill, add enamel raw material gross weight 80~100% water, it is ground 24 hours, then stands 40 hours, remove water float thing, then cleaned using magnet, then Except hydraulic pressure mud, pugging to pug wet weight percentage are 19~25%, glaze is made；
    S4. the S2 blanks prepared are molded by traditional ceramics production method, dried, then biscuiting 7 hours at 900 DEG C, and Normal temperature is naturally cooled to, obtains biscuiting product；
    S5. traditional ceramics production method is pressed, glazing is carried out to biscuiting product prepared by S4 using glaze prepared by S3, is subsequently placed in Burnt till in kiln, obtain the net porcelain of the feature work.
  2. The net porcelain 2. a kind of feature is lived, it is characterised in that the feature being prepared using preparation method described in claim 1 is lived Net porcelain.
  3. The net porcelain 3. a kind of feature according to claim 2 is lived, it is characterised in that the functional activity ceramics are used to make Standby ceramic.
  4. The net porcelain 4. a kind of feature according to claim 2 is lived, it is characterised in that the functional activity ceramics are used to make Standby drinking water treatment equipment.
CN201610265911.6A 2016-04-27 2016-04-27 Net porcelain of a kind of feature work and preparation method thereof Active CN105967642B (en)

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CN106630629B (en) * 2016-10-20 2018-12-14 淄博百康经贸有限公司 The preparation method of the ceramics and ceramics of ceramic glaze, preparation method with water activating function and its preparation
CN108675766A (en) * 2018-06-05 2018-10-19 浙江纳巍负离子科技有限公司 A kind of graphene anion bone shellfish porcelain tea set and preparation method thereof
CN108640514A (en) * 2018-06-25 2018-10-12 浙江东度文化创意有限公司 Secret color glaze layer of celadon of sustained-release antibacterial and preparation method thereof
CN108675767A (en) * 2018-08-07 2018-10-19 张维亮 A kind of health porcelain and preparation method thereof
CN112110651B (en) * 2020-09-14 2022-07-29 九牧厨卫股份有限公司 Preparation method of ultra-smooth sanitary ceramic antibacterial glaze
CN115433002A (en) * 2022-08-23 2022-12-06 秦皇岛日福陶瓷有限公司 Medical stone ceramic product and preparation method thereof

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