CN105967266A - Efficient sewage treatment agent and preparation method thereof - Google Patents

Efficient sewage treatment agent and preparation method thereof Download PDF

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Publication number
CN105967266A
CN105967266A CN201610571993.7A CN201610571993A CN105967266A CN 105967266 A CN105967266 A CN 105967266A CN 201610571993 A CN201610571993 A CN 201610571993A CN 105967266 A CN105967266 A CN 105967266A
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China
Prior art keywords
parts
treating agent
high efficiency
sewage treating
sodium
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Pending
Application number
CN201610571993.7A
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Chinese (zh)
Inventor
储仲芳
郑有飞
史丹炜
袁月
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Nanjing University of Information Science and Technology
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Nanjing University of Information Science and Technology
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Priority to CN201610571993.7A priority Critical patent/CN105967266A/en
Publication of CN105967266A publication Critical patent/CN105967266A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses an efficient sewage treatment agent and a preparation method thereof. The efficient sewage treatment agent is prepared from the following raw materials in parts by weight: 30-40 parts of kieselguhr, 30-40 parts of sodium chloride, 10-15 parts of lithopone, 5-10 parts of polyethyleneimine, 5-10 parts of citric acid, 8-10 parts of zinc oxide, 4-6 parts of activated carbon, 5-10 parts of polymerized ferric sulphate, 5-10 parts of sodium dodecyl benzene sulfonate, 20-30 parts of a composite synergist, 8-10 parts of sepiolite powder and 50-100 parts of deionized water. The efficient sewage treatment agent is wide in pollutant disposal range, good in effect, wide in raw material source and low in cost, thus being a comprehensive sewage treatment agent with very stable performance.

Description

A kind of high efficiency sewage treating agent and preparation method thereof
Technical field
The present invention relates to technical field of sewage, a kind of high efficiency sewage treating agent and preparation method thereof.
Background technology
At present, along with industrialized development, subsidiary production waste also gets more and more, environment can be made a very bad impression by arbitrarily discharge, for improving environment, sewage disposal technology arises at the historic moment, sewage disposal refers to as making sewage reach a certain water body of draining or the water quality requirement reused, and the process that it is purified, sewage disposal is widely used in building, agricultural, the every field such as traffic, the energy, petrochemical industry, environmental protection, urban look, medical treatment, food and drink, come into the daily life of common people the most more and more;High efficiency sewage treating agent, become the important component part of sewage disposal, some high efficiency sewage treating agents such as ferrous sulfate, aluminium polychlorid, PAMC, PAMA etc., using effect is bad, the inorganic agent of good sewage processing effect, cost is high.Therefore, prior art also needs to develop further and improve.
Summary of the invention
It is an object of the invention to for above-mentioned deficiency of the prior art, it is provided that a kind of Pollutant Treatment scope is wide, respond well, raw material sources wide, the high efficiency sewage treating agent of low cost.
It is a further object of the present invention to provide that a kind of Pollutant Treatment scope is wide, respond well, raw material sources wide, the high efficiency sewage treating agent preparation method of low cost.
It is an object of the invention to be achieved through the following technical solutions:
A kind of high efficiency sewage treating agent, is made up of the raw material of following weight portion: kieselguhr 30-40 part, sodium chloride 30-40 part, lithopone 10-15 part, polymine 5-10 part, citric acid 5-10 part, zinc oxide 8-10 part, activated carbon 4-6 part, bodied ferric sulfate 5-10 part, dodecylbenzene sodium sulfonate 5-10 part, composite synergist 20-30 part, sepiolite powder 8-10 part and deionized water 50-100 part.
Further in design, above-mentioned composite synergist is one or more in iron chloride, sodium lignin sulfonate, aluminium polychlorid and sodium acetate.
The preparation method of a kind of high efficiency sewage treating agent, comprises the following steps:
1) take kieselguhr 30-40 part, zinc oxide 8-10 part and activated carbon 4-6 part and put into blender, and add deionized water 50-100 part;
2) citric acid 5-10 part is added in blender, stir and uniformly pour into, until stirring;
3) stir in bodied ferric sulfate 5-10 part, dodecylbenzene sodium sulfonate 5-10 part and polymine 5-10 part are added blender, stir and uniformly pour into, until stirring;
4) putting into sepiolite powder 8-10 part at ambient pressure, control maximum temperature and be less than 80 DEG C, when reaction temperature rises very fast, slow down charging rate, until charging terminates, whole course of reaction completed in 30 minutes;
5) sodium chloride 30-40 part and lithopone 10-15 part are put at ambient pressure, control maximum temperature less than 80 DEG C, when reaction temperature rises very fast, slow down charging rate, until charging terminates, whole course of reaction completed in 30 minutes, and pH controls between 3 and 6, stop blender, obtain stirring thing;
6) stirring thing step 5) obtained is dried at 80 DEG C-150 DEG C, obtains the mix products of moisture content≤8% after cooling;
7) mix products step 6) obtained mixes pulverizing with composite synergist 20-30 part, obtains the high efficiency sewage treating agent that granular size is 200-400 mesh.
Further in design, above-mentioned composite synergist is one or more in iron chloride, sodium lignin sulfonate, aluminium polychlorid and sodium acetate.
The present invention has a beneficial effect highlighted below:
The high efficiency sewage treating agent of the present invention, Pollutant Treatment scope is wide, respond well, raw material sources are wide, low cost, is the highly stable comprehensive sewage treatment drug of a kind of performance.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1
A kind of high efficiency sewage treating agent, including the raw material of following weight portion: 30 parts of kieselguhr, 30 parts of sodium chloride, 10 parts of lithopone, polymine 5 parts, citric acid 5 parts, zinc oxide 8 parts, activated carbon 4 parts, bodied ferric sulfate 5 parts, dodecylbenzene sodium sulfonate 5 parts, 20 parts of composite synergist iron chloride, sepiolite powder 8 parts and deionized water 50 parts.
The method using above-mentioned raw materials to manufacture high efficiency sewage treating agent comprises the following steps:
1) take 30 parts of kieselguhr, zinc oxide 8 parts and activated carbon 4 parts and put into blender, and add deionized water 50 parts;
2) by 5 parts of addition blenders of citric acid, stir and uniformly pour into, until stirring;
3) by stirring in bodied ferric sulfate 5 parts, dodecylbenzene sodium sulfonate 5 parts and 5 parts of addition blenders of polymine, stir and uniformly pour into, until stirring;
4) putting into sepiolite powder 8 parts at ambient pressure, control maximum temperature and be less than 80 DEG C, when reaction temperature rises very fast, slow down charging rate, until charging terminates, whole course of reaction completed in 30 minutes;
5) put into 30 parts of sodium chloride and 10 parts of lithopone at ambient pressure, control maximum temperature and be less than 80 DEG C, when reaction temperature rises very fast, slowing down charging rate, until charging terminates, whole course of reaction completed in 30 minutes, pH controls between 3, stops blender;
6) above-mentioned stirring thing is dried at 80 DEG C, after cooling, obtain the mix products of moisture content≤8%;
7) mix products and composite synergist 20 parts is mixed pulverizing, obtain the sewage-treating agent that granular size is 200 mesh.
Embodiment 2
A kind of high efficiency sewage treating agent, including the raw material of following weight portion: 40 parts of kieselguhr, 40 parts of sodium chloride, 15 parts of lithopone, polymine 10 parts, citric acid 10 parts, zinc oxide 10 parts, activated carbon 6 parts, bodied ferric sulfate 10 parts, dodecylbenzene sodium sulfonate 10 parts, composite synergist sodium lignin sulfonate 30 parts, sepiolite powder 10 parts and deionized water 100 parts.
The method using above-mentioned raw materials to manufacture high efficiency sewage treating agent comprises the following steps:
1) take 40 parts of kieselguhr, zinc oxide 10 parts and activated carbon 6 parts and put into blender, and add deionized water 100 parts;
2) by 10 parts of addition blenders of citric acid, stir and uniformly pour into, until stirring;
3) by stirring in bodied ferric sulfate 10 parts, dodecylbenzene sodium sulfonate 10 parts and 10 parts of addition blenders of polymine, stir and uniformly pour into, until stirring;
4) putting into sepiolite powder 10 parts at ambient pressure, control maximum temperature and be less than 80 DEG C, when reaction temperature rises very fast, slow down charging rate, until charging terminates, whole course of reaction completed in 30 minutes;
5) put into 40 parts of sodium chloride and 15 parts of lithopone at ambient pressure, control maximum temperature and be less than 80 DEG C, when reaction temperature rises very fast, slowing down charging rate, until charging terminates, whole course of reaction completed in 30 minutes, pH controls between 6, stops blender;
6) above-mentioned stirring thing is dried at 150 DEG C, after cooling, obtain the mix products of moisture content≤8%;
7) mix products and composite synergist 30 parts is mixed pulverizing, obtain the sewage-treating agent that granular size is 400 mesh.
Case study on implementation 3
A kind of high efficiency sewage treating agent, including the raw material of following weight portion: 35 parts of kieselguhr, 35 parts of sodium chloride, 12 parts of lithopone, polymine 7 parts, citric acid 7 parts, zinc oxide 9 parts, activated carbon 5 parts, bodied ferric sulfate 7 parts, dodecylbenzene sodium sulfonate 7 parts, composite synergist aluminium polychlorid and sodium acetate 25 parts, sepiolite powder 9 parts and deionized water 75 parts.
The method using above-mentioned raw materials to manufacture high efficiency sewage treating agent comprises the following steps:
1) take 35 parts of kieselguhr, zinc oxide 9 parts and activated carbon 5 parts and put into blender, and add deionized water 75 parts;
2) by 7 parts of addition blenders of citric acid, stir and uniformly pour into, until stirring;
3) by stirring in bodied ferric sulfate 7 parts, dodecylbenzene sodium sulfonate 7 parts and 7 parts of addition blenders of polymine, stir and uniformly pour into, until stirring;
4) putting into sepiolite powder 9 parts at ambient pressure, control maximum temperature and be less than 80 DEG C, when reaction temperature rises very fast, slow down charging rate, until charging terminates, whole course of reaction completed in 30 minutes;
5) put into 35 parts of sodium chloride and 12 parts of lithopone at ambient pressure, control maximum temperature and be less than 80 DEG C, when reaction temperature rises very fast, slowing down charging rate, until charging terminates, whole course of reaction completed in 30 minutes, pH controls between 4, stops blender;
6) above-mentioned stirring thing is dried at 115 DEG C, after cooling, obtain the mix products of moisture content≤8%;
7) mix products and composite synergist 25 parts is mixed pulverizing, obtain the sewage-treating agent that granular size is 300 mesh.
Experiment case study:
Be respectively adopted the high efficiency sewage treating agent of the present invention with existing sewage-treating agent PAMC on the market to process the sanitary sewage in the sewer of somewhere, Chaohu, first according to The addition of 1.5kg/m3 adds, and is stirred for or aeration makes high efficiency sewage treating agent be sufficiently mixed with sewage;After standing 1 hour, sampling detection, result such as following table.
As can be known from the above table, using the high efficiency sewage treating agent of above-mentioned case study on implementation 1-3 to carry out Treating Municipal Sewage, its effluent quality is substantially better than existing sewage-treating agent, and effect is notable.
It is above presently preferred embodiments of the present invention, all changes made according to technical solution of the present invention, when produced function is without departing from the scope of technical solution of the present invention, belong to protection scope of the present invention.

Claims (4)

1. a high efficiency sewage treating agent, it is characterized in that, be made up of the raw material of following weight portion: kieselguhr 30-40 part, sodium chloride 30-40 part, lithopone 10-15 part, polymine 5-10 part, citric acid 5-10 part, zinc oxide 8-10 part, activated carbon 4-6 part, bodied ferric sulfate 5-10 part, dodecylbenzene sodium sulfonate 5-10 part, composite synergist 20-30 part, sepiolite powder 8-10 part and deionized water 50-100 part.
High efficiency sewage treating agent the most according to claim 1, it is characterised in that described composite synergist is one or more in iron chloride, sodium lignin sulfonate, aluminium polychlorid and sodium acetate.
3. the preparation method of the high efficiency sewage treating agent described in claim 1, it is characterised in that comprise the following steps:
1) take kieselguhr 30-40 part, zinc oxide 8-10 part and activated carbon 4-6 part and put into blender, and add deionized water 50-100 part;
2) citric acid 5-10 part is added in blender, stir and uniformly pour into, until stirring;
3) stir in bodied ferric sulfate 5-10 part, dodecylbenzene sodium sulfonate 5-10 part and polymine 5-10 part are added blender, stir and uniformly pour into, until stirring;
4) putting into sepiolite powder 8-10 part at ambient pressure, control maximum temperature and be less than 80 DEG C, when reaction temperature rises very fast, slow down charging rate, until charging terminates, whole course of reaction completed in 30 minutes;
5) sodium chloride 30-40 part and lithopone 10-15 part are put at ambient pressure, control maximum temperature less than 80 DEG C, when reaction temperature rises very fast, slow down charging rate, until charging terminates, whole course of reaction completed in 30 minutes, and pH controls between 3 and 6, stop blender, obtain stirring thing;
6) stirring thing step 5) obtained is dried at 80 DEG C-150 DEG C, obtains the mix products of moisture content≤8% after cooling;
7) mix products step 6) obtained mixes pulverizing with composite synergist 20-30 part, obtains the high efficiency sewage treating agent that granular size is 200-400 mesh.
The preparation method of high efficiency sewage treating agent the most according to claim 3, it is characterised in that described composite synergist is one or more in iron chloride, sodium lignin sulfonate, aluminium polychlorid and sodium acetate.
CN201610571993.7A 2016-07-20 2016-07-20 Efficient sewage treatment agent and preparation method thereof Pending CN105967266A (en)

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106380059A (en) * 2016-11-23 2017-02-08 郑州源冉生物技术有限公司 High-efficiency sludge treating agent and preparation method thereof
CN106395936A (en) * 2016-11-23 2017-02-15 郑州源冉生物技术有限公司 Chemical wastewater efficient treatment agent and preparation method and application thereof
CN106495251A (en) * 2016-12-06 2017-03-15 南京九致信息科技有限公司 A kind of inorganic agent for agricultural effluent and preparation method thereof
CN106517377A (en) * 2016-11-23 2017-03-22 郑州源冉生物技术有限公司 Chemical wastewater treatment agent as well as preparation method and application thereof
CN106587192A (en) * 2016-12-14 2017-04-26 桐乡市搏腾贸易有限公司 Efficient sewage treatment agent
CN106745595A (en) * 2016-12-14 2017-05-31 桐乡市搏腾贸易有限公司 Special coagulant of a kind of trade effluent and preparation method thereof
CN106745633A (en) * 2016-12-27 2017-05-31 郑州源冉生物技术有限公司 A kind of heavy metal-polluted water treatment agent and preparation method thereof
CN106745377A (en) * 2016-12-14 2017-05-31 桐乡市搏腾贸易有限公司 A kind of waste water control medicament and preparation method thereof
CN106745378A (en) * 2016-12-14 2017-05-31 桐乡市搏腾贸易有限公司 A kind of sewage containing copper treatment agent and preparation method thereof
CN106745612A (en) * 2016-12-30 2017-05-31 余姚市哈特馒餐饮有限公司 Special coagulant of a kind of paper waste and preparation method thereof
CN106746393A (en) * 2016-11-23 2017-05-31 郑州源冉生物技术有限公司 A kind of Treatment of Sludge medicament and preparation method thereof
CN107129016A (en) * 2017-04-28 2017-09-05 防城港市质量技术监督局 A kind of sewage-treating agent and preparation method thereof
CN107176629A (en) * 2017-06-06 2017-09-19 杨志益 A kind of new-type sewage-treating agent
CN107235520A (en) * 2017-07-03 2017-10-10 安徽国能亿盛环保科技有限公司 A kind of sewage purification additive
CN109534473A (en) * 2018-11-09 2019-03-29 天津天绿健科技有限公司 A kind of water treatment agent and preparation method thereof handling acid trade effluent
CN117700025A (en) * 2023-12-26 2024-03-15 爱土工程环境科技有限公司 Composite filler for antimony-containing sewage treatment and preparation method thereof
CN117700025B (en) * 2023-12-26 2024-06-04 爱土工程环境科技有限公司 Composite filler for antimony-containing sewage treatment and preparation method thereof

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CN103663579A (en) * 2013-12-19 2014-03-26 栾晓健 Industrial wastewater treating agent
CN104192922A (en) * 2014-09-19 2014-12-10 山东华亚环保科技有限公司 Papermaking sewage treatment agent
CN105060367A (en) * 2015-08-06 2015-11-18 马鞍山市顺达环保设备有限公司 Sewage processing agent

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN103663579A (en) * 2013-12-19 2014-03-26 栾晓健 Industrial wastewater treating agent
CN104192922A (en) * 2014-09-19 2014-12-10 山东华亚环保科技有限公司 Papermaking sewage treatment agent
CN105060367A (en) * 2015-08-06 2015-11-18 马鞍山市顺达环保设备有限公司 Sewage processing agent

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106380059A (en) * 2016-11-23 2017-02-08 郑州源冉生物技术有限公司 High-efficiency sludge treating agent and preparation method thereof
CN106395936A (en) * 2016-11-23 2017-02-15 郑州源冉生物技术有限公司 Chemical wastewater efficient treatment agent and preparation method and application thereof
CN106517377A (en) * 2016-11-23 2017-03-22 郑州源冉生物技术有限公司 Chemical wastewater treatment agent as well as preparation method and application thereof
CN106746393A (en) * 2016-11-23 2017-05-31 郑州源冉生物技术有限公司 A kind of Treatment of Sludge medicament and preparation method thereof
CN106495251A (en) * 2016-12-06 2017-03-15 南京九致信息科技有限公司 A kind of inorganic agent for agricultural effluent and preparation method thereof
CN106745378A (en) * 2016-12-14 2017-05-31 桐乡市搏腾贸易有限公司 A kind of sewage containing copper treatment agent and preparation method thereof
CN106745377A (en) * 2016-12-14 2017-05-31 桐乡市搏腾贸易有限公司 A kind of waste water control medicament and preparation method thereof
CN106745595A (en) * 2016-12-14 2017-05-31 桐乡市搏腾贸易有限公司 Special coagulant of a kind of trade effluent and preparation method thereof
CN106587192A (en) * 2016-12-14 2017-04-26 桐乡市搏腾贸易有限公司 Efficient sewage treatment agent
CN106745633A (en) * 2016-12-27 2017-05-31 郑州源冉生物技术有限公司 A kind of heavy metal-polluted water treatment agent and preparation method thereof
CN106745612A (en) * 2016-12-30 2017-05-31 余姚市哈特馒餐饮有限公司 Special coagulant of a kind of paper waste and preparation method thereof
CN107129016A (en) * 2017-04-28 2017-09-05 防城港市质量技术监督局 A kind of sewage-treating agent and preparation method thereof
CN107129016B (en) * 2017-04-28 2020-10-30 马鞍山绿色大陇农业科技有限公司 Sewage treatment agent and preparation method thereof
CN107176629A (en) * 2017-06-06 2017-09-19 杨志益 A kind of new-type sewage-treating agent
CN107235520A (en) * 2017-07-03 2017-10-10 安徽国能亿盛环保科技有限公司 A kind of sewage purification additive
CN109534473A (en) * 2018-11-09 2019-03-29 天津天绿健科技有限公司 A kind of water treatment agent and preparation method thereof handling acid trade effluent
CN117700025A (en) * 2023-12-26 2024-03-15 爱土工程环境科技有限公司 Composite filler for antimony-containing sewage treatment and preparation method thereof
CN117700025B (en) * 2023-12-26 2024-06-04 爱土工程环境科技有限公司 Composite filler for antimony-containing sewage treatment and preparation method thereof

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Application publication date: 20160928