CN105964693A - Planetary rolling production technology of nickel-based high-temperature alloy tube - Google Patents

Planetary rolling production technology of nickel-based high-temperature alloy tube Download PDF

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Publication number
CN105964693A
CN105964693A CN201610017233.1A CN201610017233A CN105964693A CN 105964693 A CN105964693 A CN 105964693A CN 201610017233 A CN201610017233 A CN 201610017233A CN 105964693 A CN105964693 A CN 105964693A
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China
Prior art keywords
pipe
planetary rolling
nickel
production technology
base
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CN201610017233.1A
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Chinese (zh)
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CN105964693B (en
Inventor
周向东
浦益龙
王颜臣
江生
吕斌
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Jiangsu Longda Super Alloy Co.,Ltd.
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Jiangsu Longda Superalloy Aviation Materials Co Ltd
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B19/00Tube-rolling by rollers arranged outside the work and having their axes not perpendicular to the axis of the work
    • B21B19/02Tube-rolling by rollers arranged outside the work and having their axes not perpendicular to the axis of the work the axes of the rollers being arranged essentially diagonally to the axis of the work, e.g. "cross" tube-rolling ; Diescher mills, Stiefel disc piercers or Stiefel rotary piercers
    • B21B19/06Rolling hollow basic material, e.g. Assel mills
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/46Roll speed or drive motor control
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/48Tension control; Compression control
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/74Temperature control, e.g. by cooling or heating the rolls or the product
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/78Control of tube rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/02Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
    • B21B45/0203Cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B9/00Measures for carrying out rolling operations under special conditions, e.g. in vacuum or inert atmosphere to prevent oxidation of work; Special measures for removing fumes from rolling mills
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B13/00Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories
    • B21B13/18Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories for step-by-step or planetary rolling; pendulum mills

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Metal Rolling (AREA)

Abstract

The invention relates to a planetary rolling production technology of a nickel-based high-temperature alloy tube, and the technology comprises the steps of inspecting the quality of the surface of a planetary mill upper tool roll and a core rod; adjusting a dog drift angle of 8.6-8.9 DEG; then unlatching an auxiliary system and a main motor of the planetary mill, preheating the auxiliary motor, and filling nitrogen in the planetary mill; sending a parison tube in an induction heater for preheating at the speed of 0.4-0.8m/min and at the temperature of 300-600 DEG C; and finally conducting rolling in the planetary mill. The production technology is simple; a horizontal continuous casting hollow ingot of a nickel-based high-temperature alloy tube is processed by planetary rolling continuously to produce the parison tube; the rolling yield and the efficiency are high; the dog drift angle is adjusted, and a suitable parison tube sending speed and a heating temperature are selected in the parison tube preheating step, therefore, the rolling force can be reduced by 20%-40%, and the parison tube can be sent through the roller and the core rod stably; the power of the main motor is raised in the parison tube hot rolling process, therefore the rolled tube has fine equiaxed grains and good drawable performance.

Description

The planetary rolling production technology of nickel base superalloy pipe
Technical field
The present invention relates to the planetary rolling production technology of a kind of nickel base superalloy pipe, belong to nickel-based alloy pipe technology of preparing Field.
Background technology
Nickel base superalloy, because having the performance such as high-temp and high-strength, excellent corrosion resistance, is widely used in chemical industry, oil, sea Ocean industry. wait key areas.
The production technology that nickel base superalloy pipe is traditional at present is: vacuum casting-strip off the skin-bore a hole-extrude--reconditioning-and repeatedly Cold rolling, heat treatment-finish rolling to finished product-arrangement-flaw detection, pressure test-annealing detection warehouse-in, this production technology is Ф to external diameter The production technology of the nickel base superalloy pipe of more than 30mm is more ripe, but the pipe production then rolling for below Ф 30mm (is drawn Pull out) number of channels is many, heat treatment often, at rolling external diameter Ф 20mm, because of the tiny appearance of plug core bar during the following specification of especially Ф 12mm Easily breaking, and rolling yield is the lowest, if using cold-drawn, being needed sawing to take the lead head because the factor such as length, speed of pulling a cart limits And lumber recovery is low, simultaneously need to the drawing of multi-pass and inefficiency, cost is high.And patent " dish of monel metal pipe draws life Production. art-201410059315.3 " then use the extruded method drawn with dish of big extruder, for below Ф 20mm Monel metal pipe has significantly improved lumber recovery and production efficiency, but the input cost of big extruder is high, only extrudes perforation The lumber recovery of operation is 60~about 80%.
Summary of the invention
The invention aims to solve the nickel base superalloy pipe prepared of traditional processing technology less at rolling external diameter Easily break because plug core bar is tiny during specification, and the problem that rolling yield is the lowest, it is provided that a kind of knot preparation method is simple The planetary rolling production technology of nickel base superalloy pipe, the nickel base superalloy pipe lumber recovery prepared is high, efficiency is high.
The present invention adopts the following technical scheme that the planetary rolling production technology of a kind of nickel base superalloy pipe, including as follows Step:
(1) checking that on planetary rolling, tool and mould roll and mandrel surface quality guarantee to install correct, fastening, adjusting dog drift angle is 8.6~8.9 °;
(2) geared parts is lubricated by the aid system Lubricating-oil Station opening planetary rolling, opens hydraulic power unit and prepares to run liquid Pressure system;
(3) start mair motor, first make at a slow speed main frame deep bid to rotate, restart auxiliary motor and progressively rise to 800~1000r/min, Then raise speed 1000r/min by mair motor, empty machine operating 8min;
(4) before planet mill milling 15min in planetary rolling cover, sensing heater, directed cavity in be filled with nitrogen as guarantor Protecting device, nitrogen flow is 100~200L/min, nitrogen gas purity more than 99.99%;
(5) with horizontal casting nickel-base high-temperature corrosion resistant alloy hollow cast ingot for base pipe, select the plug matched with base pipe, open sense Answer heater and base pipe to be sent into motor, preheat sending base pipe to enter in sensing heater by the speed of 0.4~0.8m/min, sense The temperature answering heater is 300~600 DEG C, and pressure is 160~190V;
(6) the base pipe after preheating rolls after being nipped by planetary rolling mill roller after the directed cavity by 0.8m length, progressively adjusts Whole feeding motor thrust, adjusts thrust according to auxiliary motor size of current, and it is 400~500A that subsidiary engine electric current controls, the merit of mair motor Rate is 1400~1600KW;
(7) lengthening coefficient of the pipe shut out is 8~16, produces the biggest deformation energy in rolling, the temperature of pipe be 720~ 920 DEG C, water spray chilling makes the pipe shut out have tiny equi-axed crystal, good drawability and excellent wall thickness public affairs subsequently Difference;
(8) pipe is curled into coil pipe base on coiling system and is used for following process.
Further, in described step (5), horizontal casting nickel-base high-temperature corrosion resistant alloy hollow cast ingot is through milling face, described milling Surface thickness x-xmm is removed in face.
Further, in described step (7) during water spray chilling water temperature be 35 DEG C (write as form x of scope~x DEG C) with Under, pressure 2kg(is write as form x~the x kg of scope) more than, spray flow 50~100m3/h.
Further, by the one end of pipe introducing prebending machine before pipe curling in described step (8), by pipe around Tighten with adhesive plaster after prebending machine one circle, then pre-bending machine is adjusted and be crimped to suitable pre-bending position.
Further, in described step (6), mair motor speed is 1400~2000r/min, deep bid rotating speed be 500~ 580rpm。
The production technology of the present invention is simple, and nickel base superalloy pipe hollow ingot horizontally and continuously cast is used planetary rolling Continuous Heat Shut out pipe draw for the cold rolling i.e. dish of subsequent handling, cold drawn, its lumber recovery is high, efficiency is high, and adjusting dog drift angle is 8.6~8.9 °, Make to increase roll in the operation of rolling to the gmatjpdumamics of base pipe and feeding force, alleviate the power of rolling, at the preheating steps of base pipe Base pipe feed rate that middle selection is suitable for and heating-up temperature, it is possible to reduce roll power 20~40%, beneficially base pipe stable by rolling Roller and plug, improve the power of mair motor in the course of hot rolling of base pipe, can be made the tubing shut out by regulation auxiliary motor rotating speed Do not rotate, by during milling train under the effect of aximal deformation value and deformation speed, the pipe rolled out has tiny equiax crystal Grain, good drawability and excellent wall thickness tolerance.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated.
Embodiment one:
The nickel base superalloy trade mark is NCu30, and wherein the mass percent of main component is: Ni >=63%, Cu:28-34%, Fe≤ 2.5%, Mn≤2%. horizontal casting hollow ingot pipe specifications are Φ 85*20.
Planetary rolling production craft step is as follows:
(1) checking that on planetary rolling, tool and mould roll and mandrel surface quality guarantee to install correct, fastening, adjusting dog drift angle is 8.7°;
(2) geared parts is lubricated by the aid system Lubricating-oil Station opening planetary rolling, opens hydraulic power unit and prepares to run liquid Pressure system;
(3) start mair motor, first make at a slow speed main frame deep bid to rotate, restart auxiliary motor and progressively rise to 900r/min, then will Mair motor raises speed 1000r/min, empty machine operating 8min;
(4) before planet mill milling 15min in planetary rolling cover, sensing heater, directed cavity in be filled with nitrogen as guarantor Protecting device, nitrogen flow is 100~200L/min, nitrogen gas purity more than 99.99%;
(5) with horizontal casting nickel-base high-temperature corrosion resistant alloy hollow cast ingot for base pipe, select the plug matched with base pipe, open sense Answering heater and base pipe to be sent into motor, preheat sending base pipe to enter in sensing heater by the speed of 0.5m/min, sensing adds The temperature of hot device is 520 DEG C, and pressure is 160V;
(6) the base pipe after preheating rolls after being nipped by planetary rolling mill roller after the directed cavity by 0.8m length, progressively adjusts Whole feeding motor thrust, adjusts thrust according to auxiliary motor size of current, and it is 400~500A that subsidiary engine electric current controls, the merit of mair motor Rate is 1500KW;
(7) the pipe specification shut out is Φ 48*2.6, and lengthening coefficient reaches 11, produces the biggest deformation energy in rolling, pipe Temperature is 870 DEG C, and water spray chilling makes the pipe shut out have tiny equi-axed crystal, good drawability and excellent wall subsequently Thick tolerance, during water spray chilling, water temperature is less than 35 DEG C, more than pressure 2kg, spray flow 50~100m3/h;
(8) hold up tube head to introduce prebending machine, with easy-to-draw that adhesive plaster is tightened after a circle, in case tube head blocks, cambering roll is transferred to Suitably pre-bending position;Pipe is coiled into by coiling system the dish of diameter 3200mm in case following process.
Embodiment two:
The nickel base superalloy trade mark is the planetary rolling of NCu28-1-1, and wherein the mass percent of main component is: Ni is remaining Amount, Cu:28-32%, Fe:1-1.4%, Mn:1-1.4%. horizontal casting hollow ingot pipe specification is Φ 90*23, and step is as follows:
(1) checking that on planetary rolling, tool and mould roll and mandrel surface quality guarantee to install correct, fastening, adjusting dog drift angle is 8.6°;
(2) geared parts is lubricated by the aid system Lubricating-oil Station opening planetary rolling, opens hydraulic power unit and prepares to run liquid Pressure system;
(3) start mair motor, first make at a slow speed main frame deep bid to rotate, restart auxiliary motor and progressively rise to 800r/min, then will Mair motor raises speed 1000r/min, empty machine operating 8min;
(4) before planet mill milling 15min in planetary rolling cover, sensing heater, directed cavity in be filled with nitrogen as guarantor Protecting device, nitrogen flow is 100~200L/min, nitrogen gas purity more than 99.99%;
(5) with horizontal casting nickel-base high-temperature corrosion resistant alloy hollow cast ingot for base pipe, select the plug matched with base pipe, open sense Answering heater and base pipe to be sent into motor, preheat sending base pipe to enter in sensing heater by the speed of 0.5m/min, sensing adds The temperature of hot device is 530 DEG C, and pressure is 175V;
(6) the base pipe after preheating rolls after being nipped by planetary rolling mill roller after the directed cavity by 0.8m length, progressively adjusts Whole feeding motor thrust, adjusts thrust according to auxiliary motor size of current, and it is 400~500A that subsidiary engine electric current controls, the merit of mair motor Rate is 1500KW;
(7) the pipe specification shut out is Φ 48*2.8, and lengthening coefficient reaches 12, produces the biggest deformation energy in rolling, pipe Temperature is 890 DEG C, and water spray chilling makes the pipe shut out have tiny equi-axed crystal, good drawability and excellent wall subsequently Thick tolerance, during water spray chilling, water temperature is less than 35 DEG C, more than pressure 2kg, spray flow 50~100m3/h;
(8) hold up tube head to introduce prebending machine, with easy-to-draw that adhesive plaster is tightened after a circle, in case tube head blocks, cambering roll is transferred to Suitably pre-bending position;Pipe is coiled into by coiling system the dish of diameter 3200mm in case following process.
Embodiment three:
The nickel base superalloy trade mark is the planetary rolling of NCu28-2.5-1.5, and wherein the mass percent of main component is, and: Ni is Surplus, Cu:27-29%, Fe:2-3%, Mn:1.2-1.8%. horizontal casting hollow ingot pipe specification is Φ 90*23, and step is as follows:
(1) checking that on planetary rolling, tool and mould roll and mandrel surface quality guarantee to install correct, fastening, adjusting dog drift angle is 8.9°;
(2) geared parts is lubricated by the aid system Lubricating-oil Station opening planetary rolling, opens hydraulic power unit and prepares to run liquid Pressure system;
(3) start mair motor, first make at a slow speed main frame deep bid to rotate, restart auxiliary motor and progressively rise to 900r/min, then will Mair motor raises speed 1000r/min, empty machine operating 8min;
(4) before planet mill milling 15min in planetary rolling cover, sensing heater, directed cavity in be filled with nitrogen as guarantor Protecting device, nitrogen flow is 100~200L/min, nitrogen gas purity more than 99.99%;
(5) with horizontal casting nickel-base high-temperature corrosion resistant alloy hollow cast ingot for base pipe, select the plug matched with base pipe, open sense Answering heater and base pipe to be sent into motor, preheat sending base pipe to enter in sensing heater by the speed of 0.5m/min, sensing adds The temperature of hot device is 560 DEG C, and pressure is 190V;
(6) the base pipe after preheating rolls after being nipped by planetary rolling mill roller after the directed cavity by 0.8m length, progressively adjusts Whole feeding motor thrust, adjusts thrust according to auxiliary motor size of current, and it is 400~500A that subsidiary engine electric current controls, the merit of mair motor Rate is 1500KW;
(7) the pipe specification shut out is Φ 48*3, and lengthening coefficient reaches 12, produces the biggest deformation energy in rolling, the temperature of pipe Degree is 900 DEG C, and water spray chilling makes the pipe shut out have tiny equi-axed crystal, good drawability and excellent wall thickness subsequently Tolerance, during water spray chilling, water temperature is less than 35 DEG C, more than pressure 2kg, spray flow 50~100m3/h;
(8) hold up tube head to introduce prebending machine, with easy-to-draw that adhesive plaster is tightened after a circle, in case tube head blocks, cambering roll is transferred to Suitably pre-bending position;Pipe is coiled into by coiling system the dish of diameter 3200mm in case following process.

Claims (5)

1. the planetary rolling production technology of a nickel base superalloy pipe, it is characterised in that: comprise the steps:
(1) checking that on planetary rolling, tool and mould roll and mandrel surface quality guarantee to install correct, fastening, adjusting dog drift angle is 8.6~8.9 °;
(2) geared parts is lubricated by the aid system Lubricating-oil Station opening planetary rolling, opens hydraulic power unit and prepares to run liquid Pressure system;
(3) start mair motor, first make at a slow speed main frame deep bid to rotate, restart auxiliary motor and progressively rise to 800~1000r/min, Then mair motor is raised speed to 800~1000r/min, empty machine operating 8~10min;
(4) before planet mill milling 10~15min in planetary rolling cover, be filled with nitrogen in sensing heater, directed cavity and make For protector, nitrogen flow is 100~200L/min, nitrogen gas purity more than 99.99%;
(5) with horizontal casting nickel-base high-temperature corrosion resistant alloy hollow cast ingot for base pipe, select the plug matched with base pipe, open sense Answer heater and base pipe to be sent into motor, preheat sending base pipe to enter in sensing heater by the speed of 0.4~0.8m/min, sense The temperature answering heater is 300~600 DEG C, and pressure is 160~190V;
(6) the base pipe after preheating rolls after being nipped by planetary rolling mill roller after the directed cavity by 0.8m length, progressively adjusts Whole feeding motor thrust, adjusts thrust according to auxiliary motor size of current, and it is 400~500A that subsidiary engine electric current controls, the merit of mair motor Rate is 1400~1600KW;
(7) lengthening coefficient of the pipe shut out is 8~16, produces the biggest deformation energy in rolling, the temperature of pipe be 720~ 920 DEG C, water spray chilling makes the pipe shut out have tiny equi-axed crystal, good drawability and excellent wall thickness public affairs subsequently Difference;
(8) pipe is curled into coil pipe base on coiling system and is used for following process.
2. the planetary rolling production technology of nickel base superalloy pipe as claimed in claim 1, it is characterised in that: described step (5) in, horizontal casting nickel-base high-temperature corrosion resistant alloy hollow cast ingot is through milling face, and surface thickness 0.3~1mm is removed in described milling face.
3. the planetary rolling production technology of nickel base superalloy pipe as claimed in claim 1, it is characterised in that: described step (7) in, during water spray chilling, water temperature is less than 35 DEG C, pressure 1.5~4kg, spray flow 50~100m3/h。
4. the planetary rolling production technology of nickel base superalloy pipe as claimed in claim 1, it is characterised in that: described step (8) before pipe crimps, the one end of pipe is introduced prebending machine in, tighten with adhesive plaster after pipe is enclosed around prebending machine one, so After pre-bending machine adjusted be crimped to suitable pre-bending position.
5. the planetary rolling production technology of nickel base superalloy pipe as claimed in claim 1, it is characterised in that: described step (6) in, mair motor speed is 1400~2000r/min, and deep bid rotating speed is 500~580rpm.
CN201610017233.1A 2016-01-12 2016-01-12 The planetary rolling production technology of nickel base superalloy pipe Active CN105964693B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108517478A (en) * 2018-04-04 2018-09-11 浙江久立特材科技股份有限公司 A kind of manufacturing process of the small-bore accurate pipe of 718 alloy
CN109016449A (en) * 2018-08-30 2018-12-18 华南理工大学 The super high molecular weight polymer method for rolling and molding and equipment to be extended based on dynamic
CN110743914A (en) * 2019-10-14 2020-02-04 武汉科技大学 Method for determining technological parameters of three-roller planetary rolling bismuth-containing stainless steel bar

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4876870A (en) * 1987-03-26 1989-10-31 Outokumpu Oy Method for manufacturing tubes
CN1390655A (en) * 2002-07-24 2003-01-15 江苏兴荣高新科技股份有限公司 Warm machining method for macking carbon steel pipe or alloy steel pipe
CN1390678A (en) * 2002-07-24 2003-01-15 江苏兴荣高新科技股份有限公司 Warm machining method for making titanium or Ti-alloy pipe
CN2569933Y (en) * 2002-07-24 2003-09-03 江苏兴荣高新科技股份有限公司 Multi-roller planetary tube grimper
JP5765191B2 (en) * 2011-11-01 2015-08-19 新日鐵住金株式会社 Method for producing seamless pipe made of high Cr-high Ni base alloy

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4876870A (en) * 1987-03-26 1989-10-31 Outokumpu Oy Method for manufacturing tubes
CN1390655A (en) * 2002-07-24 2003-01-15 江苏兴荣高新科技股份有限公司 Warm machining method for macking carbon steel pipe or alloy steel pipe
CN1390678A (en) * 2002-07-24 2003-01-15 江苏兴荣高新科技股份有限公司 Warm machining method for making titanium or Ti-alloy pipe
CN2569933Y (en) * 2002-07-24 2003-09-03 江苏兴荣高新科技股份有限公司 Multi-roller planetary tube grimper
JP5765191B2 (en) * 2011-11-01 2015-08-19 新日鐵住金株式会社 Method for producing seamless pipe made of high Cr-high Ni base alloy

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108517478A (en) * 2018-04-04 2018-09-11 浙江久立特材科技股份有限公司 A kind of manufacturing process of the small-bore accurate pipe of 718 alloy
CN108517478B (en) * 2018-04-04 2019-10-29 浙江久立特材科技股份有限公司 A kind of manufacturing process of the small-bore accurate pipe of 718 alloy
CN109016449A (en) * 2018-08-30 2018-12-18 华南理工大学 The super high molecular weight polymer method for rolling and molding and equipment to be extended based on dynamic
CN109016449B (en) * 2018-08-30 2023-11-24 华南理工大学 Method and equipment for rolling and forming ultrahigh molecular weight polymer based on dynamic extension
CN110743914A (en) * 2019-10-14 2020-02-04 武汉科技大学 Method for determining technological parameters of three-roller planetary rolling bismuth-containing stainless steel bar

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Address after: 214105 Anan village, anzhen street, Xishan District, Wuxi City, Jiangsu Province

Patentee after: Aviation Company Limited Jiangsu Longda super alloy

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Address after: 214105 No. 18 Xiangyun Road, Anzhen Street, Xishan District, Wuxi City, Jiangsu Province (Development Zone)

Patentee after: Wuxi Longda Metal Material Co., Ltd.

Address before: 214105 Annan Village, Anzhen Street, Xishan District, Wuxi City, Jiangsu Province

Patentee before: Aviation Company Limited Jiangsu Longda super alloy

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Address after: 214105 No.18 Xiangyun Road, anzhen street, Xishan District, Wuxi City, Jiangsu Province

Patentee after: Jiangsu Longda Super Alloy Co.,Ltd.

Address before: 214105 No. 18 Xiangyun Road, Anzhen Street, Xishan District, Wuxi City, Jiangsu Province (Development Zone)

Patentee before: WUXI LONGDA METAL MATERIALS Co.,Ltd.

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