CN105951120A - Process unit for glutathione - Google Patents
Process unit for glutathione Download PDFInfo
- Publication number
- CN105951120A CN105951120A CN201610337318.8A CN201610337318A CN105951120A CN 105951120 A CN105951120 A CN 105951120A CN 201610337318 A CN201610337318 A CN 201610337318A CN 105951120 A CN105951120 A CN 105951120A
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- CN
- China
- Prior art keywords
- basin
- process unit
- electrolysis bath
- glutathion
- rod
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The invention relates to a process unit for glutathione. The process unit comprises an electrolytic cell (1), a cathode (4), an anode (5), a power source (6) and a diaphragm (14). The diaphragm (14) is located in the middle of the electrolytic cell (1) to divide the electrolytic cell (1) into a negative electrolytic cell body (2) and a positive electrolytic cell body (3). The cathode (4) is arranged in the negative electrolytic cell body (2). The anode (5) is arranged in the positive electrolytic cell body (3). A negative electrode of the power source is connected with the cathode (4), and a positive electrode of the power source is connected with the anode (5). The process unit further comprises a cathode liquor storage tank (9), an alkali liquor storage tank (10) and a neutral salt solution storage tank (11). The cathode liquor storage tank (9), the alkali liquor storage tank (10) and the neutral salt solution storage tank (11) are connected with the negative electrolytic cell through pipelines. The process unit further comprises an acid liquor storage tank (12) and an anode liquor storage tank (13). The acid liquor storage tank (12) and the anode liquor storage tank (13) are connected with the positive electrolytic cell body (3) through pipelines. The process unit is suitable for preparing glutathione.
Description
Technical field
The present invention relates to chemical process device, particularly prepare the process unit of glutathion.
Background technology
Glutathion (glutathione, GSH) is a kind of containing γ-amido link with the tripeptides of sulfydryl, is made up of glutamic acid, cysteine and glycine.It is present in each cell of almost health.Gluathione Toplink assists in keeping normal immune function, and there is antioxidation and integrate Detoxication, sulfydryl on cysteine is its active group (therefore being often abbreviated as G-SH), glutathion raw material production is almost by Japan's consonance (KYOWA) fermentation monopolization, and therefore glutathion price remains high always.Domestic shortage mass production capabilities, the most also only has the production of raw medicine producer of 2 state approvals.The industrialization promptly developing and realize producing glutathion is respectively provided with great Social benefit and economic benefit to China's medical industry, clinical medicine and food industry.
GSH mainly uses fermentative Production at present, post processing mainly uses mantoquita method, i.e. forms mantoquita precipitation with Red copper oxide with GSH in fermentation liquid, then carries out reduction with hydrogen sulfide and obtain GSH, the method environmental pollution is relatively big, forces the production technology that manufacturing enterprise's exploitation is more environmentally friendly..
Summary of the invention
Goal of the invention: in order to overcome above-mentioned deficiency, the present invention provides a kind of environmental protection, the easy-operating process system preparing glutathion.
Technical scheme: the process unit of a kind of glutathion, including electrolysis bath (1), negative electrode (4), anode (5), power supply (6), barrier film (14), this barrier film (14) is positioned at the centre of described electrolysis bath (1), this electrolysis bath (1) is separated into cloudy electrolysis bath (2), sun electrolysis bath (3), described negative electrode (4) is placed in this moon electrolysis bath (2), described anode (5) is placed in described sun electrolysis bath (3), and the negative pole of described power supply, positive pole are connected with described negative electrode (4), anode (5) respectively；Also including catholyte basin (9), alkali liquor basin (10), neutral salt solution basin (11), described catholyte basin (9), alkali liquor basin (10), neutral salt solution basin (11) are connected by pipeline with described cloudy electrolysis bath respectively；Also including acid solution basin (12), anolyte basin (13), this acid solution basin (12), anolyte basin (13) are connected by pipeline with described sun electrolysis bath (3) respectively.
As preferably, described catholyte basin (9) is sulfosalicylic acid basin.
As preferably, described alkali liquor basin (10) is the one in NaOH basin, KOH basin, carbonate basin, bicarbonate basin.
As preferably, described neutral salt solution basin (11) is Na2SO4Basin, NaCl basin, K2SO4One in basin, KCl basin.
As preferably, described sour basin (12) is mineral acid basin or organic acid basin.
As preferably, described anolyte basin (13) is sulfosalicylic acid basin.
As preferably, described anelectrode (3) is the one in platinum rod, platinized titanium rod, lead rod, metal rod, titanium dioxide lead rod, titanium dioxide rod.
As preferably, described negative electrode (2) is the one in platinum rod, zinc bar, lead rod, carbon-point.
Beneficial effect: compared with fermentation method, the present invention uses electrolytic method to prepare glutathion, and in whole production process, quantity of three wastes is few, and post processing avoids using mantoquita method, environmentally friendly, is the environment-protective process preparing glutathion.Use catholyte basin, anolyte basin etc., the anion of loss, cation in electrolysis bath can be supplemented the most in time, it is ensured that whole electrolytic process is stable, lasting, so that it is guaranteed that the quality of product.
Accompanying drawing explanation
Fig. 1 is the structural representation of the present invention.
Specific embodiment
Below in conjunction with specific embodiment, the present invention is expanded on further.Should be understood that these embodiments are merely to illustrate the present invention rather than limit the scope of the present invention.
Such as Fig. 1, a kind of process unit of glutathion, including electrolysis bath 1, negative electrode 4, anode 5, power supply 6, barrier film 14, this barrier film 14 is positioned at the centre of described electrolysis bath 1, this electrolysis bath 1 is separated into cloudy electrolysis bath 2, sun electrolysis bath 3, described negative electrode 4 is placed in this moon electrolysis bath 2, and described anode 5 is placed in described sun electrolysis bath 3, and the negative pole of described power supply, positive pole are connected with described negative electrode 4, anode 5 respectively；Also including catholyte basin 9, alkali liquor basin 10, neutral salt solution basin 11, described catholyte basin 9, alkali liquor basin 10, neutral salt solution basin 11 are connected by pipeline with described cloudy electrolysis bath respectively；Also including acid solution basin 12, anolyte basin 13, this acid solution basin 12, anolyte basin 13 are connected by pipeline with described sun electrolysis bath 3 respectively.
In the present embodiment, described catholyte basin 9 is sulfosalicylic acid basin；Described alkali liquor basin 10 is the one in NaOH basin, KOH basin, carbonate basin, bicarbonate basin；Described neutral salt solution basin 11 is Na2SO4Basin, NaCl basin, K2SO4One in basin, KCl basin；Described sour basin 12 is mineral acid basin or organic acid basin；Described anolyte basin 13 is sulfosalicylic acid basin；Described anelectrode 3 is the one in platinum rod, platinized titanium rod, lead rod, metal rod, titanium dioxide lead rod, titanium dioxide rod；Described negative electrode 2 is the one in platinum rod, zinc bar, lead rod, carbon-point.
Compared with fermentation method, the present invention uses electrolytic method to prepare glutathion, and in whole production process, quantity of three wastes is few, and post processing avoids using mantoquita method, environmentally friendly, is the environment-protective process preparing glutathion.Use catholyte basin, anolyte basin etc., the anion of loss, cation in electrolysis bath can be supplemented the most in time, it is ensured that whole electrolytic process is stable, lasting, so that it is guaranteed that the quality of product.
Claims (8)
1. the process unit of a glutathion, it is characterized in that: include electrolysis bath (1), negative electrode (4), anode (5), power supply (6), barrier film (14), this barrier film (14) is positioned at the centre of described electrolysis bath (1), this electrolysis bath (1) is separated into cloudy electrolysis bath (2), sun electrolysis bath (3), described negative electrode (4) is placed in this moon electrolysis bath (2), described anode (5) is placed in described sun electrolysis bath (3), and the negative pole of described power supply, positive pole are connected with described negative electrode (4), anode (5) respectively；Also including catholyte basin (9), alkali liquor basin (10), neutral salt solution basin (11), described catholyte basin (9), alkali liquor basin (10), neutral salt solution basin (11) are connected by pipeline with described cloudy electrolysis bath respectively；Also including acid solution basin (12), anolyte basin (13), this acid solution basin (12), anolyte basin (13) are connected by pipeline with described sun electrolysis bath (3) respectively.
The process unit of glutathion the most according to claim 1, it is characterised in that: described catholyte basin (9) is sulfosalicylic acid basin.
The process unit of glutathion the most according to claim 1, it is characterised in that: described alkali liquor basin (10) is the one in NaOH basin, KOH basin, carbonate basin, bicarbonate basin.
The process unit of glutathion the most according to claim 1, it is characterised in that: described neutral salt solution basin (11) is Na2SO4Basin, NaCl basin, K2SO4One in basin, KCl basin.
The process unit of glutathion the most according to claim 1, it is characterised in that: described sour basin (12) is mineral acid basin or organic acid basin.
The process unit of glutathion the most according to claim 1, it is characterised in that: described anolyte basin (13) is sulfosalicylic acid basin.
The process unit of glutathion the most according to claim 1, it is characterised in that: described anelectrode (3) is the one in platinum rod, platinized titanium rod, lead rod, metal rod, titanium dioxide lead rod, titanium dioxide rod.
The process unit of glutathion the most according to claim 1, it is characterised in that: described negative electrode (2) is the one in platinum rod, zinc bar, lead rod, carbon-point.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610337318.8A CN105951120A (en) | 2016-05-21 | 2016-05-21 | Process unit for glutathione |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610337318.8A CN105951120A (en) | 2016-05-21 | 2016-05-21 | Process unit for glutathione |
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| Publication Number | Publication Date |
|---|---|
| CN105951120A true CN105951120A (en) | 2016-09-21 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201610337318.8A Pending CN105951120A (en) | 2016-05-21 | 2016-05-21 | Process unit for glutathione |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201762455U (en) * | 2010-07-14 | 2011-03-16 | 中国科学院青海盐湖研究所 | Continuous preparation device of sodium dichromate crystalline liquid |
| CN202072769U (en) * | 2011-04-29 | 2011-12-14 | 郑州大学 | Double-membrane electrolytic device for preparing tetramethylammonium hydroxide |
| CN103459409A (en) * | 2011-04-06 | 2013-12-18 | 协和发酵生化株式会社 | Process for producing reduced glutathione |
| CN205635797U (en) * | 2016-05-21 | 2016-10-12 | 江苏诚信药业有限公司 | Glutathione's process units |
-
2016
- 2016-05-21 CN CN201610337318.8A patent/CN105951120A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201762455U (en) * | 2010-07-14 | 2011-03-16 | 中国科学院青海盐湖研究所 | Continuous preparation device of sodium dichromate crystalline liquid |
| CN103459409A (en) * | 2011-04-06 | 2013-12-18 | 协和发酵生化株式会社 | Process for producing reduced glutathione |
| CN202072769U (en) * | 2011-04-29 | 2011-12-14 | 郑州大学 | Double-membrane electrolytic device for preparing tetramethylammonium hydroxide |
| CN205635797U (en) * | 2016-05-21 | 2016-10-12 | 江苏诚信药业有限公司 | Glutathione's process units |
Non-Patent Citations (1)
| Title |
|---|
| 潘长华: "电解锰", 《实用小化工生产大全 第一卷 无机化工产品•复混肥料•农药•兽药》 * |
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Application publication date: 20160921 |