CN105949834A - Thermal-resistant chemical-resistance coating for exhaust equipment - Google Patents
Thermal-resistant chemical-resistance coating for exhaust equipment Download PDFInfo
- Publication number
- CN105949834A CN105949834A CN201610180745.XA CN201610180745A CN105949834A CN 105949834 A CN105949834 A CN 105949834A CN 201610180745 A CN201610180745 A CN 201610180745A CN 105949834 A CN105949834 A CN 105949834A
- Authority
- CN
- China
- Prior art keywords
- resistance
- coating
- add
- powder
- exhaust equipment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/103—Anti-corrosive paints containing metal dust containing Al
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a thermal-resistant chemical-resistance coating for exhaust equipment. The coating is made from the following raw materials: coal ash, aluminium powder, a glycerol alkyd resin, a melamine-formaldehyde resin, precipitated barium sulphate, a curing agent, sodium tripolyphosphate, an acrylates leveling agent, butyl acetate, sepiolite powder, styrene, azodiisobutyronitrile, glycidyl methacrylate, dihydroxy polydimethylsiloxane, magnesium tungstate, sodium methylenebisnaphthalenesulphonate, aluminium nitride, molasses, dilinoleic acid and a proper amount of deionized water and absolute ethanol. The coating has preferable fouling resistance, oil resistance, water resistance and aging resistance, and good thermal resistance, corrosion resistance and chemical corrosion resistance. The defect of a conventional wear-resistant coating is overcome, the service life of mechanical equipment is prolonged, and the coating has high practical value.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of heat-resisting chemicals-resistant coating of exhaust equipment.
Background technology
The surface of shell of exhaust equipment can be brushed different pigment and guarantee that housing is without damage, the use longevity of extension device
Life.Aluminum pigment is widely used in traditional solvent based coating and oil due to its special metallic luster and " changeable colors along with angle " effect
Mo Zhong.It is big that it has excellent metallic effect demand, and flake aluminum has good reflection light and the energy of reflective thermal radiation
Power, forms continuous print metal film in coating, can reflect visible ray, ultraviolet and infrared ray.Reflection to visible light full spectrum
It is silvery white in color so that it is there is good decoration performance, ultrared reflection is made it have the heat-insulating property of reflective thermal radiation, and
To the reflection of ultraviolet then can protective coating not by ultraviolet damage, extend the life-span of coating.Due to the performance of pure aluminum own
Vivaciously, aluminium powder specific surface area is big, and the most surface treated aluminium powder is easy to reunite, and aluminium powder occurs chemistry anti-with other media
Should easily lose original performance.Common aluminium powder pigment easily reacts with water, therefore can not directly use, with acid in water paint again
Property or alkaline medium contact time be easily corroded, corrosion can make the glossiness of aluminium powder pigment decline, and color is gloomy, the hydrogen of release
The biggest pressure is formed, consequently, it is possible to there is the danger of blast in container.Therefore to adapt to different application demands, improve aluminum
The weatherability of powder, widens application, needs aluminium powder is carried out surface modification, makes powder body in preparation process and last handling process
In be in high degree of dispersion state, be current aluminium powder pigment research important topic.
Having carried out the research of styrene polymerization cladding aluminium powder in " research of styrene polymerization cladding flake aluminum ", author adopts
Being coated with aluminium powder under the system of dehydrated alcohol with refined styrene, result shows along with the increase of monomer consumption, slow
Releasing efficiency to be gradually increased, conversion ratio, clad ratio, coating efficiency are had the biggest by the quality of the quality of monomer, consumption and aluminium powder
Impact, the quality stability of product is the highest, and the corrosion resistant effect played in coating also needs to improve.The thing that flyash is good
Reason, chemical characteristic make it have and well apply potential quality, add flyash and be not only able to strengthen the mobility of coating in coating,
The pore structure of system can also be improved, improve the function of coating.The present invention utilizes aluminium powder and flyash to be mixed with high-alumina fly
Coal ash microsphere, corrosion-resistant, impact strength, the erosion-wear-resisting performance that play in coating can play the biggest raising, but
It is that to be directly added into the compatibility the highest, the combination property of material can be substantially reduced.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of exhaust equipment is coated with heat-resisting chemicals-resistant
Material.
The present invention is achieved by the following technical solutions:
A kind of exhaust equipment, with heat-resisting chemicals-resistant coating, is made up of the raw material of following weight portion: flyash 18-22, aluminum
Powder 7-9, glyptal 50-55, melamine resin 40-45, blanc fixe 3-4, firming agent 1-1.3, trimerization
Sodium phosphate 0.4-0.7, esters of acrylic acid levelling agent 0.3-0.7, butyl acetate 15-18, sepiolite powder 2.5-3, styrene 12-
14, azodiisobutyronitrile 1.2-1.4, glycidyl methacrylate 0.2-0.25, dialkyl polydimethylsiloxane 0.12-
0.15, magnesium tungstate 0.8-1.2, sodium metnylene bis-naphthalene sulfonate 0.2-0.24, aluminium nitride 1.2-1.5, molasses 0.4-0.6, dimerization Asia
Oleic acid 0.2-0.3, deionized water are appropriate, dehydrated alcohol is appropriate.
2, according to claim 1 a kind of exhaust equipment with heat-resisting chemicals-resistant coating, it is characterised in that by following tool
Body step is made:
(1) being hydrofluoric acid dips 8-10h of 35-40% by flyash 2-3 times amount mass concentration, taking-up is washed with deionized
It is neutrality to filtrate, dried 200-300 mesh sieve, then by magnesium tungstate, sodium metnylene bis-naphthalene sulfonate, aluminium nitride, molasses and appropriate
Deionized water mixing, be sprayed on flyash surface, after spray drying add material gross weight 0.3-0.6% titanate esters coupling
Agent;
(2) aluminum paste that mass concentration is 40-45% is made in the making beating of aluminium powder dehydrated alcohol, add dihydroxy polydimethyl
Siloxanes, dimerized linoleic acid and the aluminum sulfate of slip weight 6-8%, ultrasonic disperse final vacuum is dried, after cooling and methacrylic acid
Product mix and blend prepared by ethylene oxidic ester, step (1), then calcines 0.5-1h, natural cooling at 100-120 DEG C;
(3) in equipped with the flask of agitator add step (2) prepare product, dehydrated alcohol, styrene, in the protection of nitrogen
Under, start agitator heat make bottle in temperature control, at 70 DEG C, to be slowly added dropwise initiator azo two at this temperature
Isopropyl cyanide, then constant temperature keeps this temperature to continue reaction 3-3.5h, and reaction cools down after terminating, reactant mixture methanol extraction,
Filtering, filter cake is placed in that to dry, pulverize 300-400 mesh sieve in 50 DEG C of vacuum drying ovens standby;
(4) be sequentially added into glyptal in high-speed stirred dispersion machine, prepared by melamine resin, step (3)
Product and butyl acetate first stir 10-12min with 200r/min, add sodium tripolyphosphate and stir 12-with 800r/min
14min, is eventually adding esters of acrylic acid levelling agent and surplus materials thereof and stirs 10-15min with 600-800r/min, and stirring completes
Rear standing 4-6min.
The invention have the advantage that the present invention uses Fluohydric acid., as caustic, flyash surface is carried out corrosion treatmentCorrosion Science, table
Face becomes the active site that coarse formation is new, then activates heat-resisting, heat conduction and the fire resistance improving flyash, and profit with activator
Improve hydrophobicity and the reactivity of flyash by coupling agent treatment, aluminium powder is also modified process and improves water-fast by the present invention
Property, the performance such as moisture resistance and insulation, and and modified coal ash mixing also solve aluminium powder and be easily generated in matrix resin is coated with
Between trace, unordered polymerization aluminium powder, the problem of cross-linkable adhesive, improves the dispersibility in coating and the compatibility;The present invention's is resistance to
Hot chemicals-resistant coating, not only has preferable anti-fouling performance, oil resistant resistance to water, ageing-resistant performance, also has the strongest resistance to
Hot anticorrosion and chemicals-resistant corrosive nature, breach the defect of tradition abrasion-resistant coating, add the service life of plant equipment, tool
There is the strongest practical value.
Detailed description of the invention
A kind of exhaust equipment, with heat-resisting chemicals-resistant coating, is made up of the raw material of following weight portion (kilogram): fine coal
Ash 18, aluminium powder 7, glyptal 50, melamine resin 40, blanc fixe 3, firming agent 1, sodium tripolyphosphate
0.4, esters of acrylic acid levelling agent 0.3, butyl acetate 15, sepiolite powder 2.5, styrene 12, azodiisobutyronitrile 1.2, methyl
Glycidyl acrylate 0.2, dialkyl polydimethylsiloxane 0.12, magnesium tungstate 0.8, sodium metnylene bis-naphthalene sulfonate 0.2, nitrogen
Change aluminum 1.2, molasses 0.4, dimerized linoleic acid 0.2, deionized water is appropriate, dehydrated alcohol is appropriate.
Described a kind of exhaust equipment with heat-resisting chemicals-resistant coating, is made up of step in detail below:
(1) be hydrofluoric acid dips 8h of 35% by flyash by 2 times amount mass concentrations, take out be washed with deionized to filtrate in
Neutrality, dried 200 mesh sieves, then magnesium tungstate, sodium metnylene bis-naphthalene sulfonate, aluminium nitride, molasses and appropriate deionized water was mixed
Close, be sprayed on flyash surface, after spray drying, add the titanate coupling agent of material gross weight 0.3%;
(2) aluminum paste that mass concentration is 40% is made in the making beating of aluminium powder dehydrated alcohol, add dihydroxy polydimethyl silica
Alkane, dimerized linoleic acid and the aluminum sulfate of slip weight 6%, ultrasonic disperse final vacuum is dried, sweet with Glycidyl methacrylate after cooling
Product mix and blend prepared by grease, step (1), then calcines 0.5h, natural cooling at 100 DEG C;
(3) in equipped with the flask of agitator add step (2) prepare product, dehydrated alcohol, styrene, in the protection of nitrogen
Under, start agitator heat make bottle in temperature control, at 70 DEG C, to be slowly added dropwise initiator azo two at this temperature
Isopropyl cyanide, then constant temperature keeps this temperature to continue reaction 3h, and reaction cools down after terminating, and reactant mixture methanol extraction filters,
Filter cake is placed in that to dry, pulverize 300 mesh sieves in 50 DEG C of vacuum drying ovens standby;
(4) be sequentially added into glyptal in high-speed stirred dispersion machine, prepared by melamine resin, step (3)
Product and butyl acetate first stir 10min with 200r/min, add sodium tripolyphosphate and stir 12min with 800r/min, finally
Add esters of acrylic acid levelling agent and surplus materials stirs 10min with 600r/min, after having stirred, stand 4min.
This coating artificial ageing resistance 4800 hours, pliability > 2mm, resistance to impact > 55cm, resistance to 30% sulfuric acid solution >
180d, resistance to 30% sodium hydroxide solution > 180d, resistance to 3% sodium chloride solution > 180d, thermostability (heating 80h at 500 DEG C) is without becoming
Change, fire resistance >=4 grade.
Claims (2)
1. an exhaust equipment is with heat-resisting chemicals-resistant coating, it is characterised in that be made up of the raw material of following weight portion: powder
Coal ash 18-22, aluminium powder 7-9, glyptal 50-55, melamine resin 40-45, blanc fixe 3-4, solidification
Agent 1-1.3, sodium tripolyphosphate 0.4-0.7, esters of acrylic acid levelling agent 0.3-0.7, butyl acetate 15-18, sepiolite powder 2.5-
3, styrene 12-14, azodiisobutyronitrile 1.2-1.4, glycidyl methacrylate 0.2-0.25, dihydroxy polydimethyl
Siloxanes 0.12-0.15, magnesium tungstate 0.8-1.2, sodium metnylene bis-naphthalene sulfonate 0.2-0.24, aluminium nitride 1.2-1.5, molasses 0.4-
0.6, dimerized linoleic acid 0.2-0.3, deionized water is appropriate, dehydrated alcohol is appropriate.
The most according to claim 1, a kind of exhaust equipment is with heat-resisting chemicals-resistant coating, it is characterised in that by walking in detail below
Suddenly make:
(1) being hydrofluoric acid dips 8-10h of 35-40% by flyash 2-3 times amount mass concentration, taking-up is washed with deionized
It is neutrality to filtrate, dried 200-300 mesh sieve, then by magnesium tungstate, sodium metnylene bis-naphthalene sulfonate, aluminium nitride, molasses and appropriate
Deionized water mixing, be sprayed on flyash surface, after spray drying add material gross weight 0.3-0.6% titanate esters coupling
Agent;
(2) aluminum paste that mass concentration is 40-45% is made in the making beating of aluminium powder dehydrated alcohol, add dihydroxy polydimethyl
Siloxanes, dimerized linoleic acid and the aluminum sulfate of slip weight 6-8%, ultrasonic disperse final vacuum is dried, after cooling and methacrylic acid
Product mix and blend prepared by ethylene oxidic ester, step (1), then calcines 0.5-1h, natural cooling at 100-120 DEG C;
(3) in equipped with the flask of agitator add step (2) prepare product, dehydrated alcohol, styrene, in the protection of nitrogen
Under, start agitator heat make bottle in temperature control, at 70 DEG C, to be slowly added dropwise initiator azo two at this temperature
Isopropyl cyanide, then constant temperature keeps this temperature to continue reaction 3-3.5h, and reaction cools down after terminating, reactant mixture methanol extraction,
Filtering, filter cake is placed in that to dry, pulverize 300-400 mesh sieve in 50 DEG C of vacuum drying ovens standby;
(4) be sequentially added into glyptal in high-speed stirred dispersion machine, prepared by melamine resin, step (3)
Product and butyl acetate first stir 10-12min with 200r/min, add sodium tripolyphosphate and stir 12-with 800r/min
14min, is eventually adding esters of acrylic acid levelling agent and surplus materials thereof and stirs 10-15min with 600-800r/min, and stirring completes
Rear standing 4-6min.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610180745.XA CN105949834A (en) | 2016-03-28 | 2016-03-28 | Thermal-resistant chemical-resistance coating for exhaust equipment |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610180745.XA CN105949834A (en) | 2016-03-28 | 2016-03-28 | Thermal-resistant chemical-resistance coating for exhaust equipment |
Publications (1)
Publication Number | Publication Date |
---|---|
CN105949834A true CN105949834A (en) | 2016-09-21 |
Family
ID=56917342
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610180745.XA Pending CN105949834A (en) | 2016-03-28 | 2016-03-28 | Thermal-resistant chemical-resistance coating for exhaust equipment |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105949834A (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1152012A (en) * | 1995-12-15 | 1997-06-18 | 中国人民解放军海军后勤技术装备研究所 | Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint |
CN104356901A (en) * | 2014-10-23 | 2015-02-18 | 安徽省金盾涂料有限责任公司 | Easily-cured flame-retardant corrosion-resistant coating |
-
2016
- 2016-03-28 CN CN201610180745.XA patent/CN105949834A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1152012A (en) * | 1995-12-15 | 1997-06-18 | 中国人民解放军海军后勤技术装备研究所 | Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint |
CN104356901A (en) * | 2014-10-23 | 2015-02-18 | 安徽省金盾涂料有限责任公司 | Easily-cured flame-retardant corrosion-resistant coating |
Non-Patent Citations (1)
Title |
---|
陈子路: "苯乙烯聚合包覆片状铝粉的研究", 《中国优秀硕士学位论文全文数据库,工程科技第Ⅰ辑》 * |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN108485419A (en) | A kind of external wall special-purpose thermal insulation insulating moulding coating and preparation method thereof | |
CN105820602A (en) | Preparing method of nanometer titanium oxide modified hollow glass beads | |
CN109705646A (en) | A kind of titanium dioxide compounded mix and preparation method thereof, reflective heat-insulation paint | |
CN105295635A (en) | Epoxy-modified styrene-acrylate emulsion paint and preparation method thereof | |
CN102391757A (en) | Water-borne acrylic thermal insulating coating and preparation method thereof | |
CN110229007A (en) | A kind of high emissivity heat insulation coating | |
CN106675287A (en) | Modified styrene-acrylic exterior wall latex paint and preparation method thereof | |
CN105949896A (en) | Freezing-tolerant crack-resistant coating for exhaust equipment | |
CN106146755A (en) | A kind of preparation method of high solids content silicone acrylic emulsion | |
CN102796230A (en) | Method for preparing silicone acrylic emulsion with high solid content and high silicon content | |
CN109207066A (en) | A kind of aquosity heat insulating heat preserving paint and preparation method thereof | |
CN105949835A (en) | High-wear-resistant coating for exhaust equipment | |
CN101092532B (en) | Preparation method of waterproofing agent of acrylic ester coat | |
CN102382239B (en) | Hollow polymer emulsion and preparation method thereof | |
CN105949963A (en) | Ultra-heat-resistant high-temperature-resistant coating for exhaust equipment | |
CN105949834A (en) | Thermal-resistant chemical-resistance coating for exhaust equipment | |
CN105949939A (en) | Acid-and-alkali-resistant coating for exhaust equipment | |
CN106147513A (en) | A kind of exhaust equipment coatings | |
CN105802306A (en) | Preparation method of building fireproof coating | |
CN108504225A (en) | Insulating moulding coating | |
CN107353755A (en) | A kind of heat-insulated uvioresistant exterior coating | |
CN105949997A (en) | High-anti-fouling coating for exhaust equipment | |
CN105949937A (en) | Waterproof coating for exhaust equipment | |
CN105949897A (en) | Corrosion-resistant coating used for surface of exhaust equipment | |
CN114854264A (en) | Compression-resistant waterproof environment-friendly coating |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160921 |
|
RJ01 | Rejection of invention patent application after publication |