CN105948717A - 一种陶瓷用纳米负离子功能材料及其制备方法 - Google Patents

一种陶瓷用纳米负离子功能材料及其制备方法 Download PDF

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CN105948717A
CN105948717A CN201610312078.6A CN201610312078A CN105948717A CN 105948717 A CN105948717 A CN 105948717A CN 201610312078 A CN201610312078 A CN 201610312078A CN 105948717 A CN105948717 A CN 105948717A
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Abstract

本发明公开了一种陶瓷用纳米负离子功能材料及其制备方法，其由以下重量份的原料制成：添寿石33‑41、水镁石18‑27、膨润土14‑26、堇青石10‑20、活性氧化铝5‑10、海鸥石24‑36、锆英石12‑18、柱沸石27‑39、斑马石19‑28、多孔硅酸钙8‑14。本发明以添寿石、海鸥石、斑马石等材料为基础，利用其所具有的释放负离子功能，并加入吸附能力强的膨润土、柱沸石等材料，通过配方优化，制备出一种陶瓷用纳米负离子功能材料，其负离子产生能力强，吸附性能优异，可以在静止状态下激发释放高浓度负离子，有降低水质氧化还原电位、消毒、杀菌、中和PH值、快速高效除去环境中苯、甲醛、硫化物、氨和臭味等有毒、有害气体。

Description

一种陶瓷用纳米负离子功能材料及其制备方法
技术领域
本发明涉及一种负离子功能材料及其制备方法，具体涉及一种陶瓷用纳米负离子功能材料及其制备方法。
背景技术
随着空气电离理论的深入研究，人们对空气负离子发生的原理和应用引起了极大的兴趣。众所周知，空气是由多种气体组成的气体混合物，在某些能量场的作用下，气体分子中某些原子的外层电子会离开轨道，成为自由电子，而游离的自由电子又会与其它中性的分子相结合，使得到多余电子的气体分子呈负电极性，被称为“空气负离子”。自然界的负离子产生的原因，主要是宇宙射线、矿物放射线、电晕放电、水流瀑布和森林植物的光合作用。也就是说，负离子产生于某些物质内部潜在能量和大自然气象活动产生能量的激发。
负离子材料，是人类利用自然界产生负离子的原理，人工合成或者配比的一种复合矿物，因为其具有热电性和压电性，因此在有温度和压力变化的情况下(即使微小的变化)即能引起成分晶体之间的电势差，这静电高达100万电子伏特，从而使空气发生电离，被击中的电子附着于邻近的水和氧气分子并使它转化为空气负离子，即负氧离子。负氧离子具有以下功能：①可加速水分子运动，使普通水变成活性水，从而使水的渗透力、扩散力、溶解力、代谢力增强，并产生水保护膜。②对于循环***，可起到扩张毛细血管，增强血液循环，促进新陈代谢，增强淋巴循环的作用；对于细胞组织，可使细胞活化，使老死细胞***或赋予再生能力，可增强细胞能量，增强细胞的功能和活力等作用，改善哮喘等呼吸***疾病，改善情绪波动、抑郁心情、慢性疲劳，缓解精神紧张状况等，对人们的健康、情绪、精力大有裨益，③除粉尘，除浮毛，除异味，除烟，杀菌，净化空气，消除室内异味和各种有害气体。
随着负离子材料的功能不断地为人们所认识，对负离子产品的研究也日益受到重视。负离子功能材料对于开发高档功能性陶瓷具有重要的作用，近年来成为市场竞争的焦点，应用前景可观。但是，目前国内对于陶瓷用负离子功能材料的研究较少，这就对开发负离子陶瓷带来了一定的困难。因此，开发一种陶瓷用负离子功能材料具有重要的价值与意义。
发明内容
本发明的目的在于提供一种陶瓷用纳米负离子功能材料及其制备方法。本发明制得的纳米负离子功能材料负离子产生能力强，吸附性能优异。
为实现上述目的，本发明采用如下的技术方案：
一种陶瓷用纳米负离子功能材料，由以下重量份的原料制成：添寿石33-41、水镁石18-27、膨润土14-26、堇青石10-20、活性氧化铝5-10、海鸥石24-36、锆英石12-18、柱沸石27-39、斑马石19-28、多孔硅酸钙8-14。
一种陶瓷用纳米负离子功能材料的制备方法，包括以下步骤：
(1)将添寿石、水镁石、膨润土、堇青石、海鸥石、锆英石、柱沸石、斑马石混合，在470-530℃下煅烧2-4h，冷却至室温，粉碎成粒径为40-70μm的颗粒，加入适量的水搅拌制成浓度为50-60％的悬浮液，然后用浓度为15％的氢氧化钠溶液调节悬浮液pH至8.5-9.5，微波处理2-3h，微波功率为200-300W，磁力振荡2-3h，振荡频率为200-300Hz，再用浓度为20％的盐酸溶液调节悬浮液pH至5.5-6.5，微波处理1-2h，微波功率为350-450W，超声振荡1-2h，振荡频率为35-45KHz，最后用浓度为15％碳酸钠溶液中和至中性，在3000-5000r/min的转速下离心5-15min，静置10-20h，过滤，干燥去除水分至含水率≤2％；
(2)将步骤(1)制得的矿物原料进行二次煅烧，煅烧温度为660-690℃，煅烧时间为0.5-1h，冷却至室温，然后在6000-8000r/min的转速下球磨至颗粒粒径为30-50μm；
(3)将步骤(2)制得的矿物原料与活性氧化铝、多孔硅酸钙等原料混合，然后在7000-9000r/min的转速下球磨至颗粒粒径为600-800nm，即得成品。
本发明的有益效果：
本发明以添寿石、海鸥石、斑马石等材料为基础，利用其所具有的释放负离子功能，并加入吸附能力强的膨润土、柱沸石等材料，通过配方优化，制备出一种陶瓷用纳米负离子功能材料，其负离子产生能力强，吸附性能优异，可以在静止状态下激发释放高浓度负离子，有降低水质氧化还原电位、消毒、杀菌、中和PH值、快速高效除去环境中苯、甲醛、硫化物、氨和臭味等有毒、有害气体。
具体实施方式
实施例1
一种陶瓷用纳米负离子功能材料，由以下重量(kg)的原料制成：添寿石33、水镁石18、膨润土14、堇青石10、活性氧化铝5、海鸥石24、锆英石12、柱沸石27、斑马石19、多孔硅酸钙8。
一种陶瓷用纳米负离子功能材料的制备方法，包括以下步骤：
(1)将添寿石、水镁石、膨润土、堇青石、海鸥石、锆英石、柱沸石、斑马石混合，在470℃下煅烧4h，冷却至室温，粉碎成粒径为40μm的颗粒，加入适量的水搅拌制成浓度为50％的悬浮液，然后用浓度为15％的氢氧化钠溶液调节悬浮液pH至8.5，微波处理2h，微波功率为300W，磁力振荡2h，振荡频率为300Hz，再用浓度为20％的盐酸溶液调节悬浮液pH至5.5，微波处理1h，微波功率为450W，超声振荡1h，振荡频率为45KHz，最后用浓度为15％碳酸钠溶液中和至中性，在3000r/min的转速下离心15min，静置10h，过滤，干燥去除水分至含水率≤2％；
(2)将步骤(1)制得的矿物原料进行二次煅烧，煅烧温度为660℃，煅烧时间为1h，冷却至室温，然后在6000r/min的转速下球磨至颗粒粒径为30μm；
(3)将步骤(2)制得的矿物原料与活性氧化铝、多孔硅酸钙等原料混合，然后在7000r/min的转速下球磨至颗粒粒径为600nm，即得成品。
实施例2
一种陶瓷用纳米负离子功能材料，由以下重量(kg)的原料制成：添寿石38、水镁石23、膨润土21、堇青石15、活性氧化铝7、海鸥石32、锆英石15、柱沸石34、斑马石23、多孔硅酸钙10。
一种陶瓷用纳米负离子功能材料的制备方法，包括以下步骤：
(1)将添寿石、水镁石、膨润土、堇青石、海鸥石、锆英石、柱沸石、斑马石混合，在500℃下煅烧3h，冷却至室温，粉碎成粒径为50μm的颗粒，加入适量的水搅拌制成浓度为55％的悬浮液，然后用浓度为15％的氢氧化钠溶液调节悬浮液pH至9，微波处理2.5h，微波功率为250W，磁力振荡2.5h，振荡频率为250Hz，再用浓度为20％的盐酸溶液调节悬浮液pH至6，微波处理1.5h，微波功率为400W，超声振荡1.5h，振荡频率为40KHz，最后用浓度为15％碳酸钠溶液中和至中性，在4000r/min的转速下离心10min，静置15h，过滤，干燥去除水分至含水率≤2％；
(2)将步骤(1)制得的矿物原料进行二次煅烧，煅烧温度为670℃，煅烧时间为0.5h，冷却至室温，然后在7000r/min的转速下球磨至颗粒粒径为40μm；
(3)将步骤(2)制得的矿物原料与活性氧化铝、多孔硅酸钙等原料混合，然后在8000r/min的转速下球磨至颗粒粒径为700nm，即得成品。
实施例3
一种陶瓷用纳米负离子功能材料，由以下重量(kg)的原料制成：添寿石41、水镁石27、膨润土26、堇青石20、活性氧化铝10、海鸥石36、锆英石18、柱沸石39、斑马石28、多孔硅酸钙14。
一种陶瓷用纳米负离子功能材料的制备方法，包括以下步骤：
(1)将添寿石、水镁石、膨润土、堇青石、海鸥石、锆英石、柱沸石、斑马石混合，在530℃下煅烧2h，冷却至室温，粉碎成粒径为70μm的颗粒，加入适量的水搅拌制成浓度为60％的悬浮液，然后用浓度为15％的氢氧化钠溶液调节悬浮液pH至9.5，微波处理3h，微波功率为200W，磁力振荡3h，振荡频率为200Hz，再用浓度为20％的盐酸溶液调节悬浮液pH至6.5，微波处理2h，微波功率为350W，超声振荡2h，振荡频率为35KHz，最后用浓度为15％碳酸钠溶液中和至中性，在5000r/min的转速下离心5min，静置20h，过滤，干燥去除水分至含水率≤2％；
(2)将步骤(1)制得的矿物原料进行二次煅烧，煅烧温度为690℃，煅烧时间为0.5h，冷却至室温，然后在8000r/min的转速下球磨至颗粒粒径为50μm；
(3)将步骤(2)制得的矿物原料与活性氧化铝、多孔硅酸钙等原料混合，然后在9000r/min的转速下球磨至颗粒粒径为800nm，即得成品。
取500g本发明制得的纳米负离子功能材料置于密封箱中，均匀摊开，密闭24h，用日本日本安天世空气负离子浓度测试仪ITC-201A每隔1小时检测一次，每次取20个数据，求得各数据的平均值作为最终检测结果，测试结果见表1。
表1负离子浓度测试数据表
负离子浓度(个/cm3)
实施例1 18568
实施例2 19432
实施例3 19087

Claims (2)

1.一种陶瓷用纳米负离子功能材料，其特征在于，由以下重量份的原料制成：添寿石33-41、水镁石18-27、膨润土14-26、堇青石10-20、活性氧化铝5-10、海鸥石24-36、锆英石12-18、柱沸石27-39、斑马石19-28、多孔硅酸钙8-14。
2.一种如权利要求1所述的陶瓷用纳米负离子功能材料的制备方法，其特征在于，包括以下步骤：
(1)将添寿石、水镁石、膨润土、堇青石、海鸥石、锆英石、柱沸石、斑马石混合，在470-530℃下煅烧2-4h，冷却至室温，粉碎成粒径为40-70μm的颗粒，加入适量的水搅拌制成浓度为50-60％的悬浮液，然后用浓度为15％的氢氧化钠溶液调节悬浮液pH至8.5-9.5，微波处理2-3h，微波功率为200-300W，磁力振荡2-3h，振荡频率为200-300Hz，再用浓度为20％的盐酸溶液调节悬浮液pH至5.5-6.5，微波处理1-2h，微波功率为350-450W，超声振荡1-2h，振荡频率为35-45KHz，最后用浓度为15％碳酸钠溶液中和至中性，在3000-5000r/min的转速下离心5-15min，静置10-20h，过滤，干燥去除水分至含水率≤2％；
(2)将步骤(1)制得的矿物原料进行二次煅烧，煅烧温度为660-690℃，煅烧时间为0.5-1h，冷却至室温，然后在6000-8000r/min的转速下球磨至颗粒粒径为30-50μm；
(3)将步骤(2)制得的矿物原料与活性氧化铝、多孔硅酸钙等原料混合，然后在7000-9000r/min的转速下球磨至颗粒粒径为600-800nm，即得成品。
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107218662A (zh) * 2017-07-07 2017-09-29 谢夏霖 一种大气污染的新风***及制造方法
CN107651951A (zh) * 2017-09-11 2018-02-02 佛山市高明区新粤丰建材有限公司 一种环保绿色负离子瓷砖及其生产方法
CN115353124A (zh) * 2022-09-14 2022-11-18 山东岱岳制盐有限公司 一种原卤硫化物绿色氧化祛除工艺

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103203179A (zh) * 2013-03-19 2013-07-17 王映璋 一种多微孔负离子远红外电场生物亲和填料的制备方法
CN103396167A (zh) * 2013-08-05 2013-11-20 李涛 可调湿减害并能释放负离子的多孔建筑装饰材料
CN103799761A (zh) * 2014-03-07 2014-05-21 浙江建中竹业科技有限公司 一种功能性坐垫

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103203179A (zh) * 2013-03-19 2013-07-17 王映璋 一种多微孔负离子远红外电场生物亲和填料的制备方法
CN103396167A (zh) * 2013-08-05 2013-11-20 李涛 可调湿减害并能释放负离子的多孔建筑装饰材料
CN103799761A (zh) * 2014-03-07 2014-05-21 浙江建中竹业科技有限公司 一种功能性坐垫

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107218662A (zh) * 2017-07-07 2017-09-29 谢夏霖 一种大气污染的新风***及制造方法
CN107651951A (zh) * 2017-09-11 2018-02-02 佛山市高明区新粤丰建材有限公司 一种环保绿色负离子瓷砖及其生产方法
CN115353124A (zh) * 2022-09-14 2022-11-18 山东岱岳制盐有限公司 一种原卤硫化物绿色氧化祛除工艺
CN115353124B (zh) * 2022-09-14 2024-04-09 山东岱岳制盐有限公司 一种原卤硫化物绿色氧化祛除工艺

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