CN105941435A - Compound insecticidal composition containing Lepimectin and spinosad and application thereof - Google Patents
Compound insecticidal composition containing Lepimectin and spinosad and application thereof Download PDFInfo
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- CN105941435A CN105941435A CN201610454866.9A CN201610454866A CN105941435A CN 105941435 A CN105941435 A CN 105941435A CN 201610454866 A CN201610454866 A CN 201610454866A CN 105941435 A CN105941435 A CN 105941435A
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- pleocidin
- lepimectin
- pesticide compositions
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a compound insecticidal composition containing Lepimectin and spinosad and application thereof. In the insecticidal composition, Lepimectin and spinosad are insecticidal active ingredients, wherein the weight ratio of the Lepimectin to spinosad is (0.1-80):(0.5-80). The insecticidal composition can generate a relatively strong synergistic effect, and can be used for overcoming and delaying the pest resistance to insecticide, realizing high insecticidal speed and long duration and reducing the application cost while the control effect is obviously better than that of single dosage. The compound insecticidal composition disclosed by the invention can control the lepidoptera pests on crops and particularly can be used for controlling helicoverpa armigera and borer while the effect is obviously better than that of single dosage.
Description
Technical field
The invention belongs to the field of agricultural pesticide containing heterocyclic compound, concrete body relates to a kind of compound pesticide compositions.
Background technology
Lepimectin, is the derivant being total to mibemycin (milbemycin) A3/A4 that company finds by Japan three, in
Within 2006, use in Japan's registration.As novel pesticide for the vegetable such as Caulis et Folium Brassicae capitatae, Fructus Lycopersici esculenti, Citrus, Fructus Fragariae Ananssae and Fructus Vitis viniferae and
Fruit, the main preventing and treating insect such as Lepidoptera and Semiptera.This medical instrument has insecticidal activity high, and dosage is few, to person poultry safety,
Free from environmental pollution, specificity is strong, does not injure natural enemy, is not easy to produce the features such as resistance, can take turns with avermectins
Change use, in case avilamycin produces resistance.Therefore it is referred to as the most promising wide spectrum, no interactions efficient, novel at present
One of insecticide of resistance.Its mechanism of action is the permeability that can increase polypide nerve synapse caudacoria to C1-, thus blocks god
Through the transmission of signal, insecticide neural paralysis is finally made to cause insect death.
Pleocidin has another name called multiple killing teichomycin (Spinosad), molecular formula: C41H65NO10.It is to sting sugared many born of the same parents bacterium
A kind of Macrolide Nuisanceless high-efficient biological insecticides extracted in (Saccharopolyspora spinosa) fermentation liquid.Structure
Formula:
Insect is had and quickly tags and stomach poison function, blade is had stronger osmosis, subepidermal insect can be killed,
The longevity of residure is longer, some insects is had certain ovicidal action, without systemic action.Can effectively preventing Lepidoptera, dipteron
Mesh and Thysanoptera, also can well prevent and treat in coleoptera and Orthoptera some pest species taking food blade in a large number, to thorn
The prevention effect of suction insect and demodicid mite class is poor.Safer to predatory natural enemy insect, because insecticidal action mechanism is unique, mesh
Before not yet find with other insecticides there is mutual drug-fast report.It is suitable on vegetable, fruit tree, gardening, crops making
With, insecticidal effect is affected less by raining.
Insecticide variety containing single component often existing defects in pesticide Pest control: use easily produces drug resistance continuously
Property, insecticidal spectrum is narrow, it is impossible to provide comprehensively protection for crop, and peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of containing Lepimectin with the compound pesticide compositions of pleocidin, this Insecticidal combinations
Thing is the multifunctional insecticide compositions of preventing and treating lepidoptera pest.
It is a further object of the present invention to provide this Pesticidal combination to prevent and treat on the insecticidal materials of resistance lepidoptera pest in preparation
Application, the particularly application on the insecticidal materials of preparation preventing and treating bollworm or snout moths larva.
It is an object of the invention to be achieved through the following technical solutions:
A kind of containing Lepimectin with the compound pesticide compositions of pleocidin, this compound pesticide compositions is with Lepimectin
Being principle active component with pleocidin, wherein, the weight ratio of Lepimectin and pleocidin is 0.1～80:0.5～80.
In this compound pesticide compositions, the weight ratio of Lepimectin (A) and pleocidin (B) is preferably 1～60:1～60,
More preferably 1～40:1～40, most preferably 1～30:1～30.
In some preferred technical schemes: Lepimectin and pleocidin can 1:30,1:29,1:28,1:27,1:26,
1:25、1:24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、
1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、
8:1、9:1、10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、
23:1、24:1、25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、2:5、
These ratios of 5:3,3:5,5:4,4:5 select.
This compound pesticide compositions can comprise only active component Lepimectin and pleocidin, it is possible to when using or prepare
Adding other components in active component, the active ingredient in this Pesticidal combination can be present in compositions with enhancing effective amount
In.
In compound pesticide compositions of the present invention, Lepimectin and both pleocidin weight in this compound pesticide compositions
Amount percentage composition is 3%～80%.It is preferably 5%～55%, most preferably 10%～40%.
Compound pesticide compositions of the present invention is with Lepimectin and pleocidin as active component or principle active component, and agriculture
Medicine auxiliary agent and excipient become any one dosage form allowed on pesticide, the preferred cream of described dosage form, suspending agent, wettable
Property powder, aqueous emulsion, microemulsion or water dispersion granule.
The insecticides adjuvant of the aforementioned present invention of can be applicable to is not particularly limited, and includes, but are not limited to DBSA
Calcium, 600#, polyoxyethylene polyoxy propylene block compound are (such as agriculture breast 33#), NPE etc., aforementioned can
The excipient being applied to the present invention is also not particularly limited, and includes, but are not limited to solvent naphtha, water, antifreezing agent (such as the third two
Alcohol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Compound pesticide compositions of the present invention easily produces multiple Semiptera and the lepidoptera pest of resistance to planthopper and snout moths larva etc.
There is good preventive effect；And suppress insect that the Drug resistance of unitary agent (Lepimectin or pleocidin are arbitrary) is produced
Raw.
Above-mentioned compound pesticide compositions prevents and treats the application on resistance lepidoptera pest insecticidal materials in preparation, especially anti-in preparation
Control the application effect on bollworm or snout moths larva insecticidal materials notable.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism lepidoptera pest is such as
Bollworm, snout moths larva etc. have obvious synergistic function, overcome and delayed pest resistance to insecticide, and expanding prevention is composed, parasite killing speed
Hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) hold concurrently
Have immediate effect and long-acting；(5) with Lepimectin compared with pleocidin single dose, produce and use cost reduces；(6) press down
The resistance of pesticide is strengthened by lepidoptera pest processed, and its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but limits the present invention never in any form.
Embodiment 1:
Weigh 80gLepimectin, 2g pleocidin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The Lepimectin pleocidin cream dividing weight percentage to be 82%.
Embodiment 2:
Weigh 2gLepimectin, 80g pleocidin, lignin 10g, Negel 2g, add to 100g with Kaolin,
Being mixed in super micron mill by above raw material, forming principle active component weight percentage is 82%
Lepimectin pleocidin wettable powder.
Embodiment 3:
Weigh 60gLepimectin, 2g pleocidin, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g,
Dimethylbenzene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed main effective
Ingredients Weight percentage composition is the Lepimectin pleocidin cream of 62%.
Embodiment 4:
Weigh 2gLepimectin, 60g pleocidin, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, positive fourth
The dimethylbenzene of alcohol 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g with water, n-butyl alcohol and
Water dissolution forms aqueous phase, and remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase under cutter effect,
And continue to shear 10～30 minutes, form the Lepimectin pleocidin that principle active component weight percentage is 62%
Aqueous emulsion.
Embodiment 5:
Weigh 40gLepimectin, 2g pleocidin, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g,
The solvent xylene of 30g and the ketopyrrolidine of 15g, remaining complements to 100g, former medicine, solvent, emulsifying agent, hydrotropy with water
Agent mix and blend forms homogeneous phase transparent solution, is then slowly added into water and stirs formation clear solution, being principle active component
Weight percentage is the Lepimectin pleocidin microemulsion of 42%.
Embodiment 6:
Weigh 2gLepimectin, 40g pleocidin, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed and the most effectively becomes
The Lepimectin pleocidin cream dividing weight percentage to be 42%.
Embodiment 7:
Weigh 20gLepimectin, 2g pleocidin, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphuric acid thereof
Salt 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at sand
The effect of grinding machine is lower forms the Lepimectin pleocidin suspension that principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2gLepimectin, 20g pleocidin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The Lepimectin pleocidin cream dividing weight percentage to be 22%.
Embodiment 9:
Weigh 10gLepimectin, 2g pleocidin, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate
5g, polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, formed above raw material by the method for water dispersion granule and mainly have
Effect Ingredients Weight percentage composition is the Lepimectin pleocidin water dispersible granules of 12%.
Embodiment 10:
Weigh 10gLepimectin, 5g pleocidin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The Lepimectin pleocidin cream dividing weight percentage to be 15%.
Embodiment 11:
Weigh 10gLepimectin, 10g pleocidin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The Lepimectin pleocidin cream dividing weight percentage to be 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh Lepimectin and pleocidin 30g, calcium dodecyl benzene sulfonate 4g altogether, phenethyl phenol polyethenoxy ether 4g,
Vegetable oil is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is configured to main effective
Ingredients Weight percentage composition is the Lepimectin pleocidin cream of 30%.Wherein Lepimectin and the tool of pleocidin
Body ratio is shown in Table 1 and 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection resistant bollworm is target pest, often processes repetition 3
Secondary, every concentration process 60, with probability value method calculate each medicament antagonism bollworm toxicity regression equation and lethal in dense
Degree LC50, use LC50Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 1:
Table 1 Lepimectin, pleocidin and the toxicity test of compounding sample antagonism bollworm thereof and co-toxicity coefficient
In table, data show, after Lepimectin and pleocidin mixture, antagonism bollworm are had potentiation, institute in table
The proportioning co-toxicity coefficient of row is both greater than 120, and therefore Lepimectin and pleocidin mixture have significant synergies.
Weigh Lepimectin, pleocidin uses conventional formulation method to be configured to principle active component weight hundred by different proportion
The Lepimectin pleocidin cream dividing content to be 30%.Concrete ratio is shown in Table 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection rice-stem borer is target pest, often processes repetition
3 times, calculate toxicity regression equation and lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method50, use LC50
Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 2:
Table 2 Lepimectin, pleocidin and compounding sample thereof to striped rice borer toxicity test and co-toxicity coefficient
In table, data show, have potentiation after Lepimectin and pleocidin mixture to rice-stem borer, listed in table
Proportioning co-toxicity coefficient be all much larger than 120, therefore Lepimectin and pleocidin mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field bollworm, comparison medicament is 40% pleocidin EC
With 10%LepimectinEC (cream), it is diluted according to the extension rate in form 3, after medicine, looks into 3 days, 7 days,
The result of 14 days, result is shown in Table 3:
The field test results of table 3 Lepimectin-pleocidin compound antagonism bollworm
Example has fabulous quick-acting to antagonism bollworm as can be seen from Table 3, and the lasting period is long, in field
Performance is good, is the outstanding medicament preventing and treating antagonism bollworm.
Measure through indoor synergism test and show: with pleocidin compound agent, bollworm and rice-stem borer are had by Lepimectin
Significantly synergistic insecticidal action；Field control effectiveness test also indicates that all of built agent of the present invention is equal to bollworm insecticidal effect equally
It is significantly higher than the effect of corresponding single dose pesticide.
Claims (10)
1. containing Lepimectin and a compound pesticide compositions for pleocidin, it is characterized in that this compound pesticide compositions with
Lepimectin and pleocidin are active insecticidal components, and wherein, the weight ratio of Lepimectin and pleocidin is
0.1～80:0.5～80.
The most according to claim 1 containing Lepimectin with the compound pesticide compositions of pleocidin, it is characterized in that institute
The Lepimectin stated and the weight ratio of pleocidin are 1～60:1～60.
The most according to claim 2 containing Lepimectin with the compound pesticide compositions of pleocidin, it is characterized in that institute
The Lepimectin stated and the weight ratio of pleocidin are 1～40:1～40.
The most according to claim 3 containing Lepimectin with the compound pesticide compositions of pleocidin, it is characterized in that institute
The Lepimectin stated and the weight ratio of pleocidin are 1～30:1～30.
The most according to claim 1 containing Lepimectin with the compound pesticide compositions of pleocidin, it is characterized in that
Lepimectin and both pleocidin weight percentage in this compound pesticide compositions are 3%～80%.
The most according to claim 5 containing Lepimectin with the compound pesticide compositions of pleocidin, it is characterized in that
Lepimectin and both pleocidin weight percentage in this compound pesticide compositions are 5%～55%.
The most according to claim 1 containing Lepimectin with the compound pesticide compositions of pleocidin, it is characterized in that this
With Lepimectin, as active insecticidal components and insecticides adjuvant is configured on pesticide to allow compound pesticide compositions with pleocidin
Dosage form.
The most according to claim 7 containing Lepimectin with the compound pesticide compositions of pleocidin, it is characterized in that institute
Stating dosage form is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions containing Lepimectin and pleocidin described in claim 1 prevents and treats resistance squama in preparation
Application on the insecticidal materials of wing mesh insect.
Compound pesticide compositions containing Lepimectin and pleocidin the most according to claim 9 is in preparation preventing and treating
Application on the insecticidal materials of bollworm or snout moths larva.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610454866.9A CN105941435A (en) | 2016-06-21 | 2016-06-21 | Compound insecticidal composition containing Lepimectin and spinosad and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610454866.9A CN105941435A (en) | 2016-06-21 | 2016-06-21 | Compound insecticidal composition containing Lepimectin and spinosad and application thereof |
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| CN105941435A true CN105941435A (en) | 2016-09-21 |
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| CN201610454866.9A Pending CN105941435A (en) | 2016-06-21 | 2016-06-21 | Compound insecticidal composition containing Lepimectin and spinosad and application thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1547433A (en) * | 2001-09-17 | 2004-11-17 | Pesticidal formulation | |
| WO2009030238A1 (en) * | 2007-09-06 | 2009-03-12 | Cheminova A/S | Pesticidal compositions |
| CN102696636A (en) * | 2011-03-27 | 2012-10-03 | 山东海利尔化工有限公司 | Insecticidal composition containing biological pesticide |
-
2016
- 2016-06-21 CN CN201610454866.9A patent/CN105941435A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1547433A (en) * | 2001-09-17 | 2004-11-17 | Pesticidal formulation | |
| WO2009030238A1 (en) * | 2007-09-06 | 2009-03-12 | Cheminova A/S | Pesticidal compositions |
| CN102696636A (en) * | 2011-03-27 | 2012-10-03 | 山东海利尔化工有限公司 | Insecticidal composition containing biological pesticide |
Non-Patent Citations (1)
| Title |
|---|
| 梁延坡 等: "小菜蛾对阿维菌素的抗性风险评估及交互抗性的室内测定", 《热带生物学报》 * |
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