CN105924275A - Slow release fertilizer used for sandy soil and matrix cultivation - Google Patents

Slow release fertilizer used for sandy soil and matrix cultivation Download PDF

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Publication number
CN105924275A
CN105924275A CN201610268065.3A CN201610268065A CN105924275A CN 105924275 A CN105924275 A CN 105924275A CN 201610268065 A CN201610268065 A CN 201610268065A CN 105924275 A CN105924275 A CN 105924275A
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CN
China
Prior art keywords
fertilizer
starch
parts
resin foam
slow
Prior art date
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Pending
Application number
CN201610268065.3A
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Chinese (zh)
Inventor
冯汝龙
冯锡鸿
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SHANDONG SHANGDAO BIOTECH CO Ltd
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SHANDONG SHANGDAO BIOTECH CO Ltd
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Priority to CN201610268065.3A priority Critical patent/CN105924275A/en
Publication of CN105924275A publication Critical patent/CN105924275A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00Growth substrates; Culture media; Apparatus or methods therefor
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)

Abstract

Raw materials of a slow release fertilizer used for sandy soil and matrix cultivation comprise starch resin foam particles, and a nitrogen fertilizer, a phosphorus fertilizer, a potassium fertilizer, a calcium fertilizer, a magnesium fertilizer and an iron fertilizer which are wrapped in the starch resin foam particles. Water and the nitrogen fertilizer, the phosphorus fertilizer, the potassium fertilizer, the calcium fertilizer, the magnesium fertilizer and the iron fertilizer are be well kept in the starch resin foam particles, and can be continuously supplied to plant roots and absorbed by the plant roots with the degradation of the starch resin, so the water and fertilizer utilization rate is improved.

Description

For sand ground and the slow-release fertilizer of substrate culture
Technical field:
The present invention relates to technical field of fertilizers, particularly to a kind of for sand ground with the slow-release fertilizer of substrate culture.
Background technology:
Slow-release fertilizer is also referred to as Controlled Release Fertilizer, it is simply that the hydrophobic substance the thinnest at chemical fertilizer granule surface bag last layer makes bag Membranization is fertile, and moisture can enter the semipermeable membrane of porous, and the nutrient of dissolving, to film external diffusion, is continuing to supply crop, I.e. fertilizer nutrient rate of release is adjusted, according to crop demand Releasing nutrient, reaches element fertilizer providing intensity Dynamic equilibrium with plant physiology demand.Coating urea on market, polymer-coated urea, long-term efficiency bicarbonate ammonium, CA, CR fertilizer is exactly a type of slow-release fertilizer.
Slow-release fertilizer has the advantage that
1. fertilizer amount reduces, and utilization rate improves.Slow-release fertilizer fertilizer efficiency is longer more than 30 days than general non-peplos, Leaching volatilization loss reduces, and fertilizer amount can reduce 10 20% than conventional fertilizer application, reaches cost-effective Purpose.
2. use conveniently, saving of labor's safety.Can coordinate with quick-acting fertilizer and make base manure and disposably use, fertilising is used Work reduces about 1/3rd, and uses safety, anti-fertilizer damage.
3. increasing both production and income.After using show fertilizer efficiency the longest, the later stage does not take off power, disease-resistant anti-fall, volume increase 5% with On.
In the area of China's length and breadth of land, there are large-area desert, area, semidesert in the northwestward, utilizes the modern times These areas are opened up wasteland by agricultural technology, and except water resources problem to be solved, it is also critically important problem that fertilizer keeps, Owing to sand ground hole is big, after watering, the fertilizer major part being dissolved in water can run off along hole, causes fertilizer Utilization rate is low, and proportion of crop planting cost is high, therefore needs a kind of slow-release fertilizer that can keep fertilizer efficiency badly.
The rise of soilless culture in recent years makes the use of substrate get more and more, many big owing to being mixed with in substrate The perlite of granule, Vermiculitum, therefore it is similar to sand ground to the holding of fertilizer.
Starch-resin has the strongest water absorbing capacity, can absorb sole mass tens times or even the water of thousand of times, This is that conventional any absorbent material is incomparable, and water holding capacity is the highest, after water suction, no matter applies Great pressure is not dehydrated, and be therefore otherwise known as high water-retaining agent, and meanwhile, starch-resin can in the short time certainly So degraded, is the material of a kind of environmental protection.As the main component of starch-resin, starch source extensively, Cheap, be suitable for large-scale processing.
Summary of the invention:
In consideration of it, be necessary to design a kind of with starch-resin as matrix for sand ground and the slow release of substrate culture Fertile.
A kind of for sand ground with the slow-release fertilizer of substrate culture, its raw material includes: starch-resin foam particle and shallow lake The nitrogenous fertilizer of parcel, phosphate fertilizer, potash fertilizer, calcareous fertilisers, fertiliser containing magnesium, iron fertilizer in powder resin foam particle.
Preferably, its raw material includes: starch-resin foam particle, potassium dihydrogen phosphate, calcium nitrate, magnesium nitrate, Ferrum oxide.
Preferably, the matter of starch-resin foam particle, potassium dihydrogen phosphate, calcium nitrate, magnesium nitrate, ferrum oxide Amount ratio is 110:(8~21): (2~6): (2~6): (4~10).
A kind of for sand ground with the production method of the slow-release fertilizer of substrate culture, comprise the following steps:
(1) take 200~300 parts of Polyethylene Glycol and 180~240 parts of glycerol, 9~11 parts of methanesulfonic acids add with In the oil bath interlayer retort of condensation reflux unit, heat and start agitating device, being heated to 155~165 DEG C, Add 40~80 parts of starch, stirring reaction 40~50min, be cooled to 20~35 DEG C, send into centrifuge, centrifugal Remove solid catalyst, obtain starch liquefacation product;
(2) above-mentioned starch liquefacation product being sent into retort 80 parts, add 1 part of water simultaneously, 0.2~0.4 part double The kicker of the dibutyl tin laurate composition of dimethylaminoethyl ether and 0.1 part, 7 parts of silicone oil L580, Starting agitating device, add 120~150 part 4 at 10 DEG C, 4`-methyl diphenylene diisocyanate, at 7000r/min Lower stirring 10S, pours in mould and adds 7~19 parts of potassium dihydrogen phosphates, 2~5 parts of calcium nitrates, 2~5 parts of nitre Acid magnesium, the powder of 3~9 parts of ferrum oxides, stir, and solidification, the demoulding afterwards obtains starch-resin foam;
(3) by foam comminutor, the starch-resin foam that previous step obtains is fabricated to particle diameter be more than or equal to 1mm and the starch-resin foam particle less than or equal to 5mm.
The present invention can be by moisture and the nitrogenous fertilizer being dissolved in moisture, phosphate fertilizer, potash fertilizer, calcareous fertilisers, fertiliser containing magnesium, iron fertilizer Well it is maintained in starch-resin foam particle, and provides continuously along with the degraded of starch-resin Absorb to plant root, improve the utilization rate of moisture and fertilizer.
Detailed description of the invention:
A kind of for sand ground with the slow-release fertilizer of substrate culture, its raw material includes: starch-resin foam particle and shallow lake The nitrogenous fertilizer of parcel, phosphate fertilizer, potash fertilizer, calcareous fertilisers, fertiliser containing magnesium, iron fertilizer in powder resin foam particle.
In the present embodiment, its raw material includes: starch-resin foam particle, potassium dihydrogen phosphate, calcium nitrate, Magnesium nitrate, ferrum oxide.
In the present embodiment, starch-resin foam particle, potassium dihydrogen phosphate, calcium nitrate, magnesium nitrate, oxygen The mass ratio changing ferrum is 110:(8~21): (2~6): (2~6): (4~10).
A kind of for sand ground with the production method of the slow-release fertilizer of substrate culture, comprise the following steps:
(1) take 200~300 parts of Polyethylene Glycol and 180~240 parts of glycerol, 9~11 parts of methanesulfonic acids add with In the oil bath interlayer retort of condensation reflux unit, heat and start agitating device, being heated to 155~165 DEG C, Add 40~80 parts of starch, stirring reaction 40~50min, be cooled to 20~35 DEG C, send into centrifuge, centrifugal Remove solid catalyst, obtain starch liquefacation product;
(2) above-mentioned starch liquefacation product being sent into retort 80 parts, add 1 part of water simultaneously, 0.2~0.4 part double The kicker of the dibutyl tin laurate composition of dimethylaminoethyl ether and 0.1 part, 7 parts of silicone oil L580, Starting agitating device, add 120~150 part 4 at 10 DEG C, 4`-methyl diphenylene diisocyanate, at 7000r/min Lower stirring 10S, pours in mould and adds 7~19 parts of potassium dihydrogen phosphates, 2~5 parts of calcium nitrates, 2~5 parts of nitre Acid magnesium, the powder of 3~9 parts of ferrum oxides, stir, and solidification, the demoulding afterwards obtains starch-resin foam;
(3) by foam comminutor, the starch-resin foam that previous step obtains is fabricated to particle diameter be more than or equal to 1mm and the starch-resin foam particle less than or equal to 5mm.

Claims (4)

1. one kind is used for sand ground and the slow-release fertilizer of substrate culture, it is characterised in that: its raw material includes: starch-resin steeps The nitrogenous fertilizer of parcel, phosphate fertilizer, potash fertilizer, calcareous fertilisers, fertiliser containing magnesium, iron fertilizer in foam particle and starch-resin foam particle.
2. as claimed in claim 1 for sand ground and the slow-release fertilizer of substrate culture, it is characterised in that: its raw material bag Include: starch-resin foam particle, potassium dihydrogen phosphate, calcium nitrate, magnesium nitrate, ferrum oxide.
3. as claimed in claim 2 for sand ground and the slow-release fertilizer of substrate culture, it is characterised in that: starch-resin Foam particle, potassium dihydrogen phosphate, calcium nitrate, magnesium nitrate, the mass ratio of ferrum oxide are 110:(8~21): (2~6): (2~6): (4~10).
4. the production method of the slow-release fertilizer being used for sand ground and substrate culture, it is characterised in that: comprise the following steps:
(1) take 200~300 parts of Polyethylene Glycol and 180~240 parts of glycerol, 9~11 parts of methanesulfonic acids add with In the oil bath interlayer retort of condensation reflux unit, heat and start agitating device, being heated to 155~165 DEG C, Add 40~80 parts of starch, stirring reaction 40~50min, be cooled to 20~35 DEG C, send into centrifuge, centrifugal Remove solid catalyst, obtain starch liquefacation product;
(2) above-mentioned starch liquefacation product being sent into retort 80 parts, add 1 part of water simultaneously, 0.2~0.4 part double The kicker of the dibutyl tin laurate composition of dimethylaminoethyl ether and 0.1 part, 7 parts of silicone oil L580, Starting agitating device, add 120~150 part 4 at 10 DEG C, 4`-methyl diphenylene diisocyanate, at 7000r/min Lower stirring 10S, pours in mould and adds 7~19 parts of potassium dihydrogen phosphates, 2~5 parts of calcium nitrates, 2~5 parts of nitre Acid magnesium, the powder of 3~9 parts of ferrum oxides, stir, and solidification, the demoulding afterwards obtains starch-resin foam;
(3) by foam comminutor, the starch-resin foam that previous step obtains is fabricated to particle diameter be more than Equal to 1mm and the starch-resin foam particle less than or equal to 5mm.
CN201610268065.3A 2016-04-26 2016-04-26 Slow release fertilizer used for sandy soil and matrix cultivation Pending CN105924275A (en)

Priority Applications (1)

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CN201610268065.3A CN105924275A (en) 2016-04-26 2016-04-26 Slow release fertilizer used for sandy soil and matrix cultivation

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108219145A (en) * 2017-12-31 2018-06-29 湖南斯洛柯有机硅有限公司 A kind of organic-silicon-modified starch type slow-release material and preparation method thereof
CN110130308A (en) * 2019-05-29 2019-08-16 西南民族大学 Slow-release fertilizer sand brick and the sand-protecting barrier that fixes the sand

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1948395A (en) * 2006-10-11 2007-04-18 武汉理工大学 Water retaining fertilizer retaining multifunction polymer composite material and its preparation method
CN104262019A (en) * 2014-10-11 2015-01-07 辽宁芦田肥业有限公司 Coated degradation type slow release potassium fertilizer
CN105175681A (en) * 2015-09-13 2015-12-23 长春工业大学 Preparation method of starch-base rigid polyurethane foam thermal insulation material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1948395A (en) * 2006-10-11 2007-04-18 武汉理工大学 Water retaining fertilizer retaining multifunction polymer composite material and its preparation method
CN104262019A (en) * 2014-10-11 2015-01-07 辽宁芦田肥业有限公司 Coated degradation type slow release potassium fertilizer
CN105175681A (en) * 2015-09-13 2015-12-23 长春工业大学 Preparation method of starch-base rigid polyurethane foam thermal insulation material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
陈清 等主编: "《果类蔬菜养分管理》", 31 May 2015, 中国农业大学出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108219145A (en) * 2017-12-31 2018-06-29 湖南斯洛柯有机硅有限公司 A kind of organic-silicon-modified starch type slow-release material and preparation method thereof
CN110130308A (en) * 2019-05-29 2019-08-16 西南民族大学 Slow-release fertilizer sand brick and the sand-protecting barrier that fixes the sand

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