CN105923932A - Electrolysis combined biomass charcoal floating bed and application thereof - Google Patents

Electrolysis combined biomass charcoal floating bed and application thereof Download PDF

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Publication number
CN105923932A
CN105923932A CN201610550837.2A CN201610550837A CN105923932A CN 105923932 A CN105923932 A CN 105923932A CN 201610550837 A CN201610550837 A CN 201610550837A CN 105923932 A CN105923932 A CN 105923932A
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China
Prior art keywords
floating bed
electrolysis
biomass carbon
floating
biomass charcoal
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Pending
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CN201610550837.2A
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Chinese (zh)
Inventor
杨柳燕
高燕
张文
张瑄文
张燕
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Nanjing University
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Nanjing University
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Priority to CN201610550837.2A priority Critical patent/CN105923932A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/14NH3-N
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/16Total nitrogen (tkN-N)
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/18PO4-P
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses an electrolysis combined biomass charcoal floating bed. The electrolysis combined biomass charcoal floating bed comprises at least two floating bed units, every floating bed unit comprises a floating bridge frame body, a planting tank is arranged in the floating bridge frame body, and a floating bridge cavity is arranged under the planting tank; and floating bed plants are planted in the planting tank, the floating bed cavity is filled with biomass charcoal, and electrode plates are vertically arranged in the biomass charcoal. The invention also discloses an application of the electrolysis combined biomass charcoal floating bed in the water purifying field. The electrolysis combined biomass charcoal floating bed disclosed in the invention, adopting biomass charcoal surface microorganism and water plant root dual biological purification, has a better removal effect on nutritional salts in water than floating beds in the prior art. Adsorption filler and electrolysis effect dual physical and chemical purification mode combination is adopted to enhance removal of pollutants from water. The electrolysis combined biomass charcoal floating bed can stably run in four seasons, is efficient and fast, occupies a smaller area than traditional floating beds, and realizes removal of pollutants from water and recycling.

Description

A kind of electrolysis associating biomass carbon floating bed and application thereof
Technical field
The invention belongs to water body in-situ recovery technique field, be specifically related to a kind of electrolysis associating biomass carbon floating bed and answer With.
Background technology
Artificial floating bed technology utilizes the buoyancy support water plant of self, makes water plant raw in a fixing region Long, water plant makes water body be purified by the polluter in Root Absorption water body.Utilize water plant recovery technique The advantages such as economical good, energy resource consumption is few, administration fee is low, sustainable performance pollution treatment effect, in numerous rivers of getting dirty Existing more application in road regulation, and become one of technical measures administering eutrophication water.
But owing to its water body purification mode is single, and root system of plant and the absorption to the pollutant in water body of the root district effect Limited with detergent power, and the treatment effect of this technology affected relatively big by temperature, when plant is in low temperature autumn and winter season, along with Weakening of vitality, its water body purification ability also can weaken;Meanwhile, some invasive species is planted irrelevantly in some areas Water plant also result in the excessive multiplication of plant and cover the water surface, not only hinder river course flood and shipping safety, and And cause new ecocatas-trophe.Therefore, the supplementary means that artificial floating bed is often repaired only as water ecology, for existing There is the artificial floating bed weak point at water body purification, researched and developed a kind of water body purification ability strong, and can stablize in the four seasons The electrolysis associating biomass carbon floating bed technology run.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of electrolysis associating biomass carbon floating bed, to solve prior art existence The problem of poor effect.
The present invention also to solve the technical problem that the application being to provide above-mentioned electrolysis associating biomass carbon floating bed.
For solving above-mentioned technical problem, the technical solution used in the present invention is as follows:
A kind of electrolysis associating biomass carbon floating bed, it includes at least two floating bed unit, floating bed unit include floating bed cavity with It is positioned at the planting groove on floating bed cavity, plants in planting groove and be implanted with floating bed plant, in floating bed cavity, be filled with biomass carbon, raw It is vertically installed with battery lead plate in material charcoal.
It is characterized in that, floating bed cavity is positioned at below the water surface, and planting groove is positioned at above the water surface.
Wherein, described floating bed cavity is polyamide mesh bag, and mesh number is 60~100 mesh, and bag mouth is fixed on bottom planting groove.
Wherein, described floating bed plant is circle coin grass, water peanut, Phyllostachys congesta or Siberian iris, preferably justifies coin grass;Kind Density in planting is 48~80 strains/m2
Wherein, described biomass carbon is bamboo charcoal, Pericarppium arachidis hypogaeae charcoal or Oryza sativa L. charcoal, and particle diameter is 1~3mm.
Wherein, in two adjacent floating bed unit, it is respectively provided with anode electrode plate and cathode electrode plate, between two battery lead plates mutually Parallel, it is connected with D.C. regulated power supply by wire;Wherein, anode electrode plate is magnesium-aluminum alloy plate, cathode electrode plate For graphite cake or graphite fibre felt.
Wherein, the ratio of the effective volume of the effective volume of battery lead plate and biomass carbon is 0.0005~0.004:1;Wherein, electricity The effective volume of pole plate is for being distributed in the intramatrical volume of biomass carbon, and the effective volume of biomass carbon is in polyamide mesh bag It is positioned at the volume of the biomass carbon of below staying water horizontal plane.
The above-mentioned electrolysis associating biomass carbon floating bed application in water body purification field is also within protection scope of the present invention.
Wherein, the effective volume of biomass carbon is 1:10~50 with the volume ratio of water body to be clean.
Wherein, described water body purification refers to remove the nitrogen in water body and phosphorus.
Operationally, electric power system being opened generation unidirectional current, anode produces the magnesium ion of trace during electrolysis, For producing precipitation with the phosphate in water body, magnesium ion generates birds droppings with ammonium radical ion and phosphate ion simultaneously Stone, aluminium ion generates precipitation with phosphate simultaneously.Magnesium ion can play modified biomass charcoal after being adsorbed by biomass carbon Effect, beneficially biomass carbon absorption nitrate and phosphatic ability;Meanwhile, negative electrode produces during electrolysis The hydrogen of trace, can be for the microorganism on biomass carbon surface as the energy of autotrophic denitrification microorganism.Dirt in water body Dye thing is adsorbed by the biomass carbon in planting groove, and cell reaction and root system of plant absorb to be removed, thus reaches purification of water quality Effect.Floating bed main body uses high density polyethylene (HDPE) material, inner hollow, and its buoyancy provided is enough to ensure that whole floating bed body System bubbles through the water column;Planting groove is positioned in floating bed agent structure, uses the polyamide material of 60 mesh, its internal filling biomass Charcoal, biomass carbon is planted and has water plant circle coin grass, and plant root growth is in biomass carbon, and the stipes on top extends Floating bed surface, planting density is 48~80 strains/m2;Biomass carbon in planting groove is the bamboo charcoal of particle diameter 1~3mm, thickness It is 20~30cm;Single floating bed is connected by junction button, and the center of the planting groove of two corresponding floating beds is respectively perpendicular cloth Put anode and negative electrode, negative electrode and anode to be connected with power supply by waterproof copper cash.
Beneficial effect: compared with prior art, the present invention has the advantage that
1, biomass carbon surface microorganism and the dual biological cleaning mode of water plant root system, to the nutritive salt in water body There is preferable removal effect.
2, adsorption stuffing and the dual physics and chemistry purification style of electrolysis, enhance the pollutant removal in water body.
3, the four seasons are stable, the quickest, floor space is few compared with traditional floating bed and achieve water pollutant removes With recycling double goal.
Accompanying drawing explanation
Fig. 1 is the structural representation of the present invention;
Wherein, 1-1 is floating bed framework, and 1-2 is planting groove, and 1-3 is floating bed cavity, and 1-4 is floating bed plant, and 2-1 is D.C. regulated power supply, 2-2 is wire, and 2-3 is anode electrode plate, and 2-4 is cathode electrode plate;
Fig. 2 is that electrolysis biological matter charcoal floats TP variation diagram;
Fig. 3 is that electrolysis biological matter charcoal floats PO4 3--P variation diagram;
Fig. 4 is that electrolysis biological matter charcoal floats TN variation diagram;
Fig. 5 is that electrolysis biological matter charcoal floats NH3-N variation diagram.
Detailed description of the invention
According to following embodiment, the present invention be may be better understood.But, as it will be easily appreciated by one skilled in the art that reality Execute the content described by example and be merely to illustrate the present invention, and should be also without limitation on not described in detail in claims The present invention.
Embodiment 1
Electrolysis associating biomass carbon floating bed as shown in Figure 1, it includes two floating bed unit, by even between floating bed unit Connect button to couple together.
Each floating bed unit all includes floating bed framework 1-1, and material is high density polyethylene (HDPE) material, dimensions for long × Width x thickness=250mm × 250mm × 55mm, its buoyancy provided is enough to ensure that whole electrolysis biological matter charcoal floating bed floats on water Face.
Being planting groove 1-2 in the middle of floating bed framework 1-1, the cross section of planting groove 1-2 is prototype, a diameter of 100mm.Kind The lower section planting groove 1-2 is provided with pontoon bridge cavity 1-3, the cylindrical polyamide mesh bag of i.e. 60 mesh, a diameter of 120cm.Polyamides The bag mouth of amine mesh bag is fixed in floating bed framework 1-1 around planting groove 1-2 so that it is can catch planting groove 1-2 completely. Fill, in pontoon bridge cavity 1-3, the bamboo charcoal that particle diameter is 1~3mm, until bamboo charcoal height is less than planting groove from planting groove 1-2 1-2 notch 1~2cm.Meanwhile, plantation circle coin grass on the bamboo charcoal in planting groove, planting density is 48 strains/m2
It is respectively perpendicular in the planting groove 1-2 of two pontoon bridge unit and inserts cathode electrode plate 2-4 and anode electrode plate 2-3, two Between battery lead plate parallel to each other, and be connected with D.C. regulated power supply 2-1 by wire 2-2.Wherein, electrolytic process makes Voltage at 15V, wherein, cathode electrode plate 2-4 is graphite cake, and thickness is 2mm, long 25cm, wide 1cm, Being positioned at the intramatrical effective depth of biomass carbon is 23cm;Anode electrode plate 2-3 is magnesium-aluminum alloy plate, and thickness is 3mm, Long 25cm, wide 1cm, being positioned at the intramatrical effective depth of biomass carbon is 23cm.
Embodiment 2
Biomass carbon floating bed is combined in electrolysis in embodiment 1 and is arranged in depth of water 0.4m, area 0.053m2Human configuration Simulation sewage in, pollutant are mainly based on the nitrogen phosphorus of low concentration, its PO4 3-The concentration of-P is 3mg/L, with phosphoric acid Potassium dihydrogen configures, NH3The concentration of-N is 7mg/L, configures with ammonium chloride.Arrange sewage matched group, sewage adds biomass It is process group that charcoal floating bed group, sewage add electrolysis biomass carbon group.Wherein, sewage add electrolysis biomass carbon group used by floating bed be Electrolysis associating biomass carbon floating bed in embodiment 1, the voltage used in electrolytic process is 15V, and electrolysis time is 9h/d. Sewage adds floating bed used by biomass carbon floating bed group with embodiment 1, except that, be not provided with in floating bed any battery lead plate, Wire and power supply.In two floating beds, the effective volume of biomass carbon and the volume ratio for the treatment of sewage are 1:10.
In the present embodiment, the physical and chemical index of water body uses YSI6600 to measure, and the concentration of ammonia nitrogen measures and uses nessler reagent Photometry (GB7479-87) measures;Nitrate nitrogen uses the standard test in ultraviolet spectrophotometry;Total nitrogen uses alkali Property alkaline potassium per-sulfate digestion ultraviolet spectrophotometry (GB11894-89);Orthophosphate uses molybdenum-antimony anti-spectrophotometric method (GB11893-89);Nitrite nitrogen uses N-(1-naphthyl) ethylenediamine photometry (GB7493-87);See " water With effluent monitoring analyze method (fourth edition) " in standard.Each sample uses ultraviolet spectrometry after processing through standardization program Photometry (V1800, SHIMADZU) is analyzed and is measured.Continuous processing compares after 15 days matched group electrolysis biological matter The water quality of charcoal floating bed group is obviously improved, and Fig. 2, Fig. 3, Fig. 4, Fig. 5 respectively use the water quality monitoring knot that this enforcement runs; Wherein, CK1 is sewage matched group, and CK2 is that sewage adds biomass carbon floating bed group, T1 be sewage add electrolysis biomass float Bed charcoal group.

Claims (10)

1. an electrolysis associating biomass carbon floating bed, it includes at least two floating bed unit, it is characterised in that floating bed list Unit includes pontoon bridge framework (1-1), is planting groove (1-2) in pontoon bridge framework (1-1), and planting groove (1-2) lower section is provided with Pontoon bridge cavity (1-3);Plant in planting groove (1-2) and be implanted with floating bed plant (1-4), be filled with in floating bed cavity (1-1) Biomass carbon (1-3), is vertically installed with battery lead plate in biomass carbon (1-3).
Electrolysis associating biomass carbon floating bed the most according to claim 1, it is characterised in that floating bed cavity (1-1) Being positioned at below the water surface, planting groove (1-2) is positioned at above the water surface.
Electrolysis associating biomass carbon floating bed the most according to claim 1, it is characterised in that described floating bed cavity (1-1) being polyamide mesh bag, mesh number is 60~100 mesh, and bag mouth is fixed on bottom planting groove.
Electrolysis associating biomass carbon floating bed the most according to claim 1, it is characterised in that described floating bed plant (1-4) for circle coin grass, water peanut, Phyllostachys congesta or Siberian iris, planting density is 48~80 strains/m2
Electrolysis associating biomass carbon floating bed the most according to claim 1, it is characterised in that described biomass carbon Particle diameter be 1~3mm.
Electrolysis associating biomass carbon floating bed the most according to claim 1, it is characterised in that two adjacent floating beds Anode electrode plate (2-3) and cathode electrode plate (2-4) it is respectively provided with in unit, parallel to each other between two battery lead plates, pass through Wire (2-2) is connected with D.C. regulated power supply (2-1);Wherein, anode electrode plate (2-3) is magnesium-aluminum alloy plate, cloudy Pole battery lead plate (2-4) is graphite cake or graphite fibre felt.
Electrolysis associating biomass carbon floating bed the most according to claim 1, it is characterised in that effective body of battery lead plate Long-pending and the effective volume of biomass carbon ratio is 0.0005~0.004:1.
8. the electrolysis associating biomass carbon floating bed application in water body purification field described in claim 1.
Application the most according to claim 8, it is characterised in that the effective volume of biomass carbon and water body to be clean Volume ratio be 1:10~50.
Application the most according to claim 8, it is characterised in that described water body purification refers to remove in water body Nitrogen and phosphorus.
CN201610550837.2A 2016-07-13 2016-07-13 Electrolysis combined biomass charcoal floating bed and application thereof Pending CN105923932A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106882857A (en) * 2017-03-24 2017-06-23 陕西科技大学 A kind of system and method for water plant-electrolysis combined purifying azo dye wastewater
CN108249548A (en) * 2018-01-31 2018-07-06 南京大学 A kind of electrolysis modified biomass charcoal system and its application
CN109399803A (en) * 2018-12-29 2019-03-01 博域环保技术研究院(南京)有限公司 A kind of aeration reinforcing electrochemical couple is biological floating bed
CN110651704A (en) * 2019-10-28 2020-01-07 南京大学 Biofilm planting device and method suitable for growth of submerged plants in black and odorous water body

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106882857A (en) * 2017-03-24 2017-06-23 陕西科技大学 A kind of system and method for water plant-electrolysis combined purifying azo dye wastewater
CN108249548A (en) * 2018-01-31 2018-07-06 南京大学 A kind of electrolysis modified biomass charcoal system and its application
CN109399803A (en) * 2018-12-29 2019-03-01 博域环保技术研究院(南京)有限公司 A kind of aeration reinforcing electrochemical couple is biological floating bed
CN110651704A (en) * 2019-10-28 2020-01-07 南京大学 Biofilm planting device and method suitable for growth of submerged plants in black and odorous water body

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