CN105919158A - Cigarette filter stick capable of reducing harmful ingredients in cigarette - Google Patents
Cigarette filter stick capable of reducing harmful ingredients in cigarette Download PDFInfo
- Publication number
- CN105919158A CN105919158A CN201610361813.2A CN201610361813A CN105919158A CN 105919158 A CN105919158 A CN 105919158A CN 201610361813 A CN201610361813 A CN 201610361813A CN 105919158 A CN105919158 A CN 105919158A
- Authority
- CN
- China
- Prior art keywords
- cigarette
- parts
- cigarette filter
- drying
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
- A24D3/163—Carbon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a cigarette filter stick capable of reducing harmful ingredients in a cigarette. The cigarette filter stick is prepared from raw materials in parts by weight as follows: 4.8-5.5 parts of calcium stearate, 83-90 parts of polypropylene resin, 1.1-1.5 parts of polyvinyl alcohol, 0.6-1 part of dibenzylidene sorbitol, 5.5-6 parts of silica gel, 2.2-3 parts of activated carbon, 13-16 parts of oyster shells, 0.4-0.5 parts of carboxymethyl chitosan and an appropriate amount of deionized water. The waste oyster shells are recycled and taken as a carrier for carrying perfume and are safe and environment-friendly, repeated utilization of resources is realized, and the cigarette filter stick has a good function on reducing tar and the harmful ingredients and is low in production cost, simple to operate and worth popularization.
Description
Technical field
The present invention relates to cigarette filter rod technical field, particularly relate to a kind of cigarette filter rod reducing Medicated cigarette harmful components.
Background technology
The harmful substance that cigarette combustion produces, such as the N-nitrosamine in tar, benzopyrene, free radical etc., serious harm cigarette
The people's is healthy, and Chinese smoker is numerous, and Smoking is harmful to your health, must improve the safety of Medicated cigarette under existing conditions,
Inevitably cause the loss of fragrance matter, perfuming research to be carried out while reducing harmful substance, improve Medicated cigarette
Local flavor, meets consumer demand.Filter tip can with the harmful substance in effectively catching cigarette smoke, the most novel filter tip material
For reducing, cigarette smoke is coal-tar middle oil and other harmful components tool has very important significance in research.Adsorption technology subtracts at perfuming cigarette
Evil has important application, is added in filter tip after adsorbent essence, the requirement of perfuming can be met;Additionally add at filter tip
Add the adsorbent of suitable high absorption property, the CO in flue gas can be adsorbed.
In " application in perfuming cigarette harm reduction CO of the modified porous material " literary composition, author proposes to select delicate fragrance type spice two
Hydrogen actinidia lactone and geranyl acetone are applied research object, have selected aluminium silicate, montmorillonite and MCM-C41 for absorption storage perfume
Material, for presently, there are the fragrance material problem that release efficiency is the highest from these porous materials, by load glucose again
The method of high temperature cabonization is modified, and test result indicate that the adsorbent after carbonizing and modifying, and the acidic-group on its surface all increases,
Basic group all reduces, and the Desorption Activation Energy of Carbon on dihydroactinidiolide and geranyl acetone adsorbent after modification reduces,
Show that this method of modifying can effectively weaken adsorbent and show the adhesion with fragrance material, contribute to the slow release of fragrance material;
Reducing CO part, preparing the adsorbent of activated carbon supported copper the most respectively by different Cu source, testing and show to prepare
Two kinds of adsorbents all have preferably reduction CO effect.Although author is pretty good in perfuming harm reduction each side effect, but comprehensively real
Border effect and cost consideration, process is loaded down with trivial details, does not possess actual application, is unfavorable for large-scale promotion, and the present invention is from reality
Occurring, the filter stick material understanding China's tobacco business use is mainly cellulose diacetate and polypropylene fibre, diacetate fiber
Element fall Jiaozhuo is used substantially, comfortable taste, but its raw material sources are limited, and price is high, and complex manufacturing is seriously polluted, polypropylene
Fiber is cheap, and chemical stability is good, but owing to the polarity of this material is little, smooth surface, to the nicotine in flue gas and tar
Absorbability poor diacetate fiber so that it is only used in low-grade medicated cigarette, and polypropylene fibre is modified by the present invention,
Make fiber surface coarse, introduce functional group, strengthen its absorption and retain the performance of harmful ingredients in flue gas, reduce cost, economize on resources,
Invention is made to possess good Social benefit and economic benefit.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of Medicated cigarette filter reducing Medicated cigarette harmful components
Rod.
The present invention is achieved by the following technical solutions:
A kind of cigarette filter rod reducing Medicated cigarette harmful components, is made up of the raw material of following weight portion: calcium stearate 4.8-
5.5, acrylic resin 83-90, polyvinyl alcohol 1.1-1.5, dibenzal sorbitol 0.6-1, silica gel 5.5-6, activated carbon 2.2-3,
Ke shell 13-16, carboxymethyl chitosan 0.4-0.5, deionized water are appropriate.
Described a kind of cigarette filter rod reducing Medicated cigarette harmful components, is made up of step in detail below:
(1) Ke shell is ground into powder, uses 0.4mol/L copper citrate solution equi-volume impregnating that it is processed, the time
For 30-50min, take out post-drying, at 500-600 DEG C, be then pyrolyzed carbonization 1-2h, after cooling, be added to 0.05mol/L carboxymethyl
In chitosan solution, it is added in vacuum drying oven after soaking 2-3h dry;
(2) calcium stearate is added in the Oleum Terebinthinae of 15-18 times amount, is evenly stirred until dissolving, be subsequently adding the polypropylene tree of 40%
Fat mixes, and heated and stirred is completely dissolved to polypropylene, adds polyvinyl alcohol and two benzal Pyrusussuriensiss when temperature is cooled to 40-55 DEG C
Alcohol, ultrasonic disperse is uniform, is then added to pelletize in double screw extruder and makes master batch, by washing with alcohol post-drying for several times and residue
Acrylic resin blending and modifying to make modified polypropene standby;
(3) modified polypropene prepared by silica gel, activated carbon and step (2) is respectively placed in baking oven drying, drains moisture, cooling
After modified polypropene is cut into granule, the melt blending 20min in banbury by modified polypropylene particles and activated carbon granule, so
Rear addition silica gel continues 30min is blended, and cuts into the granule of uniform particle sizes after taking out cooling, be placed on capillary rheometer
In, make mixing precursor, precursor is clamped on fixture, add in hot tank at the environment of 170-180 DEG C, with the speed of 10mm/min
Uniform Tension makes fiber;
(4) load essence on product step (1) prepared, be coated in modification prepared by step (3) by binding agent compound poly-
On tacryl, after drying, conventionally make cigarette filter rod.
The invention have the advantage that the present invention pollutes for the reduction that economizes on resources, select polypropylene fibre to replace two acetic acid fine
Tie up as cigarette filter rod, use calcium stearate etc. to polypropylene modification to improve the shortcoming of polypropylene fibre so that it is surface goes out
Existing hole, crack and groove increase its specific surface area, and also use porous and poromerics silica gel, activated carbon to change polypropylene
Property so that it is become capillary polypropylene material, improve its adsorptivity further, and the means using solid phase to stretch make fiber,
Avoid the impact on polypropylene fibre absorption property of the electrostatic spinning intermediate ion liquid, improve safety, and in medicated cigarette
Harmful substance plays good crown_interception, and the present invention, also by by Ke shell powder modified load copper ion, reduces in flue gas harmful
Material, improves smoking safety, then loading chitosan, and biological adsorption is good, safety non-toxic, carries fragrant effective, it is possible to improve
Suction quality, the present invention utilizes the regeneration of garbage Ke shell, as the carrier of carried perfume, safety and environmental protection, it is achieved resource
Huge profit use, and there is the effect of good reducing tar and reducing harm, production cost is low, simple to operate, is worthy to be popularized.
Detailed description of the invention
A kind of cigarette filter rod reducing Medicated cigarette harmful components, is made up of the raw material of following weight portion (kilogram): stearic
Acid calcium 4.8, acrylic resin 83, polyvinyl alcohol 1.1, dibenzal sorbitol 0.6, silica gel 5.5, activated carbon 2.2, Ke shell 13, carboxylic
Methyl chitosan 0.4, deionized water are appropriate.
Described a kind of cigarette filter rod reducing Medicated cigarette harmful components, is made up of step in detail below:
(1) Ke shell is ground into powder, uses 0.4mol/L copper citrate solution equi-volume impregnating that it is processed, the time
For 30min, take out post-drying, at 500 DEG C, be then pyrolyzed carbonization 1h, be added to 0.05mol/L carboxymethyl chitosan after cooling molten
In liquid, it is added in vacuum drying oven after soaking 2h dry;
(2) calcium stearate is added in the Oleum Terebinthinae of 15 times amount, is evenly stirred until dissolving, be subsequently adding the acrylic resin of 40%
Mixing, heated and stirred is completely dissolved to polypropylene, adds polyvinyl alcohol and dibenzal sorbitol when temperature is cooled to 40 DEG C, super
Sound is uniformly dispersed, and is then added to pelletize in double screw extruder and makes master batch, by washing with alcohol post-drying for several times and remaining poly-
It is standby that allyl resin blending and modifying makes modified polypropene;
(3) modified polypropene prepared by silica gel, activated carbon and step (2) is respectively placed in baking oven drying, drains moisture, cooling
After modified polypropene is cut into granule, the melt blending 20min in banbury by modified polypropylene particles and activated carbon granule, so
Rear addition silica gel continues 30min is blended, and cuts into the granule of uniform particle sizes after taking out cooling, be placed on capillary rheometer
In, to make mixing precursor, precursor is clamped on fixture, add in hot tank at the environment of 170 DEG C, the speed with 10mm/min is uniform
Fiber is made in stretching;
(4) load essence on product step (1) prepared, be coated in modification prepared by step (3) by binding agent compound poly-
On tacryl, after drying, conventionally make cigarette filter rod.
Cigarette sample is prepared, with the Medicated cigarette only adding polypropylene fibre as compareing, with reference to ISO's and GB according to embodiment
Method detects, and test result is as follows:
Comparison Medicated cigarette:
Puff number (mouth /): 8.1;TPM (mg/ props up): 14.45;Nicotine (mg/ props up): 1.15;Tar (mg/ props up):
9.5;Cd reduction rate (%): 14.5;Pb reduction rate (%): 14.6;CO(mg/ props up): 11.5;
Test Medicated cigarette:
Puff number (mouth /): 7.9;TPM (mg/ props up): 12.04;Nicotine (mg/ props up): 1.03;Tar (mg/ props up):
8.8;Cd reduction rate (%): 20.2;Pb reduction rate (%): 19.8;CO(mg/ props up): 10.2.
Claims (2)
1. the cigarette filter rod reducing Medicated cigarette harmful components, it is characterised in that be made up of the raw material of following weight portion: hard
Fat acid calcium 4.8-5.5, acrylic resin 83-90, polyvinyl alcohol 1.1-1.5, dibenzal sorbitol 0.6-1, silica gel 5.5-6, work
Property charcoal 2.2-3, Ke shell 13-16, carboxymethyl chitosan 0.4-0.5, deionized water are appropriate.
A kind of cigarette filter rod reducing Medicated cigarette harmful components, it is characterised in that by walking in detail below
Suddenly make:
(1) Ke shell is ground into powder, uses 0.4mol/L copper citrate solution equi-volume impregnating that it is processed, the time
For 30-50min, take out post-drying, at 500-600 DEG C, be then pyrolyzed carbonization 1-2h, after cooling, be added to 0.05mol/L carboxymethyl
In chitosan solution, it is added in vacuum drying oven after soaking 2-3h dry;
(2) calcium stearate is added in the Oleum Terebinthinae of 15-18 times amount, is evenly stirred until dissolving, be subsequently adding the polypropylene tree of 40%
Fat mixes, and heated and stirred is completely dissolved to polypropylene, adds polyvinyl alcohol and two benzal Pyrusussuriensiss when temperature is cooled to 40-55 DEG C
Alcohol, ultrasonic disperse is uniform, is then added to pelletize in double screw extruder and makes master batch, by washing with alcohol post-drying for several times and residue
Acrylic resin blending and modifying to make modified polypropene standby;
(3) modified polypropene prepared by silica gel, activated carbon and step (2) is respectively placed in baking oven drying, drains moisture, cooling
After modified polypropene is cut into granule, the melt blending 20min in banbury by modified polypropylene particles and activated carbon granule, so
Rear addition silica gel continues 30min is blended, and cuts into the granule of uniform particle sizes after taking out cooling, be placed on capillary rheometer
In, make mixing precursor, precursor is clamped on fixture, add in hot tank at the environment of 170-180 DEG C, with the speed of 10mm/min
Uniform Tension makes fiber;
(4) load essence on product step (1) prepared, be coated in modification prepared by step (3) by binding agent compound poly-
On tacryl, after drying, conventionally make cigarette filter rod.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610361813.2A CN105919158A (en) | 2016-05-27 | 2016-05-27 | Cigarette filter stick capable of reducing harmful ingredients in cigarette |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610361813.2A CN105919158A (en) | 2016-05-27 | 2016-05-27 | Cigarette filter stick capable of reducing harmful ingredients in cigarette |
Publications (1)
Publication Number | Publication Date |
---|---|
CN105919158A true CN105919158A (en) | 2016-09-07 |
Family
ID=56842299
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610361813.2A Pending CN105919158A (en) | 2016-05-27 | 2016-05-27 | Cigarette filter stick capable of reducing harmful ingredients in cigarette |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105919158A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110742302A (en) * | 2019-11-08 | 2020-02-04 | 广东中烟工业有限责任公司 | Cigarette capable of reducing free radical content in smoke and preparation method thereof |
CN113558292A (en) * | 2021-08-27 | 2021-10-29 | 上海烟草集团有限责任公司 | Method for reducing acetic acid in cigarette smoke |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101940364A (en) * | 2009-07-06 | 2011-01-12 | 周细才 | Application of oyster in tobacco micro filter tip and tobacco thereof |
CN102090716A (en) * | 2011-03-03 | 2011-06-15 | 中国海洋大学 | Novel cadmium-removal filter tip |
CN104188090A (en) * | 2014-09-12 | 2014-12-10 | 湖北中烟工业有限责任公司 | Method for reducing carbonic oxide emission of paper-making reconstituted tobacco |
-
2016
- 2016-05-27 CN CN201610361813.2A patent/CN105919158A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101940364A (en) * | 2009-07-06 | 2011-01-12 | 周细才 | Application of oyster in tobacco micro filter tip and tobacco thereof |
CN102090716A (en) * | 2011-03-03 | 2011-06-15 | 中国海洋大学 | Novel cadmium-removal filter tip |
CN104188090A (en) * | 2014-09-12 | 2014-12-10 | 湖北中烟工业有限责任公司 | Method for reducing carbonic oxide emission of paper-making reconstituted tobacco |
Non-Patent Citations (5)
Title |
---|
曹远虑: "提高烟用聚丙烯纤维丝束吸附性能的研究", 《中国优秀硕士学位论文全文数据库(工程科技Ⅰ辑)》 * |
沈凯 等: "活性炭吸附剂的制备及其在选择性降低卷烟主流烟气中氰化氢的应用", 《工业催化》 * |
王凯 等: "应用活性炭-壳聚糖复合材料选择性吸附主流烟气中挥发性醛酮", 《理化检验(化学分册)》 * |
王志亮 等: "聚丙烯微孔材料的制备", 《合成树脂及塑料》 * |
胡学寅 等: "贝壳吸附材料的制备与表征", 《应用科技》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110742302A (en) * | 2019-11-08 | 2020-02-04 | 广东中烟工业有限责任公司 | Cigarette capable of reducing free radical content in smoke and preparation method thereof |
CN110742302B (en) * | 2019-11-08 | 2020-09-22 | 广东中烟工业有限责任公司 | Cigarette capable of reducing free radical content in smoke and preparation method thereof |
CN113558292A (en) * | 2021-08-27 | 2021-10-29 | 上海烟草集团有限责任公司 | Method for reducing acetic acid in cigarette smoke |
CN113558292B (en) * | 2021-08-27 | 2023-10-20 | 上海烟草集团有限责任公司 | Method for reducing acetic acid in cigarette smoke |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102342389B (en) | Preparation method of carcinogen-free food smoking solution | |
CN103355743A (en) | Preparation and application of crop waste cigarette filter additive carrier materials | |
CN105919160A (en) | Composite cigarette filter stick containing graphene material | |
CN103932394B (en) | A kind of multistage composite cigarette filter stick and preparation method thereof and the application of turgid plant granule | |
CN110419777B (en) | Preparation method of activated carbon granules for cigarettes | |
CN109938399B (en) | Low-temperature non-combustible cigarette tobacco tar carrier | |
CN105996122A (en) | Cigarette filter stick for reducing cigarette aldehyde substances | |
CN106617287A (en) | Preparation method of aerogel particle with smoke reducing function and its application in cigarette filter tip | |
CN103876286A (en) | Filter rod particle additive with coffee or cocoa flavor and preparation method and application thereof | |
CN105919158A (en) | Cigarette filter stick capable of reducing harmful ingredients in cigarette | |
CN101433373B (en) | Granule and preparation method thereof | |
CN105901764A (en) | Cigarette filter stick for improving cigarette smoking quality | |
CN105996124A (en) | Cigarette filter stick with tar reduction and aroma enhancement performance | |
CN105962413A (en) | Cigarette filter stick achieving stable aroma | |
CN110124626A (en) | A kind of preparation method of filter-tip material | |
CN105919157A (en) | Cigarette filter stick capable of reducing content of ammonia in cigarette smoke | |
CN105919159A (en) | Cigarette filter stick capable of removing heavy metals in cigarette smoke | |
CN109757768B (en) | Cigarette filter tip and preparation process thereof | |
CN106037001A (en) | Cigarette filter stick having good adsorption property | |
CN115644491A (en) | Tea flavor particle for cigarette filter stick and preparation method thereof | |
CN105996123A (en) | Cigarette filter stick for reducing release quantity of crotonaldehyde in smoke gas | |
CN104905409A (en) | Healthcare cigarette filter tip composite adsorbent with functions of relieving cough and reducing sputum and preparation method thereof | |
CN106037000A (en) | Cigarette filter stick containing alginate fibers | |
CN105996125A (en) | Cigarette filter stick with magnetic adsorption function | |
CN106046533A (en) | Cigarette filter rod capable of improving cigarette quality |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160907 |
|
RJ01 | Rejection of invention patent application after publication |