CN105907484A - Detergent as stain removal pen and preparation method of detergent - Google Patents
Detergent as stain removal pen and preparation method of detergent Download PDFInfo
- Publication number
- CN105907484A CN105907484A CN201610352318.5A CN201610352318A CN105907484A CN 105907484 A CN105907484 A CN 105907484A CN 201610352318 A CN201610352318 A CN 201610352318A CN 105907484 A CN105907484 A CN 105907484A
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- Prior art keywords
- detergent
- fatty acid
- stain
- lipase
- amylase
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a detergent as a stain removal pen and a preparation method of the detergent. The detergent comprises the following components in percentage by mass: 1-2.5% of alkyl glycoside, 3-8% of ethoxylation fatty acid methyl ester, 2-4% of coconut oil fatty acid diethanol amide, 2-5% of sorbitol polyoxyethylene ether, 15-30% of polyethylene glycol 400, 0.5-1% of lipase, 0.2-0.5% of protease, 0.2-0.4% of amylase, 0.1-0.3% of cellulase, 0.05-0.2% of anhydrous citric acid and the balance of deionized water. The detergent is prepared from a gentle and non-irritant nonionic surfactant together with bio-enzyme preparations, so that the activity of the bio-enzyme can be maintained stably and efficiently for a long time; under dual stain removal action of the surfactant and the bio-enzyme preparations, stain can be removed relatively thoroughly, bloodstain, milk stain, sweat stain, ball-point pen stain, ink stain and the like on clothes can be easily and effectively removed; moreover, due to the easily degradable and environment-friendly constituting components, the stain can be rapidly decomposed, clothes are not damaged, and the environment is not polluted.
Description
Technical field
The present invention relates to a kind of decontamination formulation, more particularly relate to a kind of detergent as portable soil release pen and
Its preparation method.
Background technology
Various precipitate situation it is frequently encountered annoying, as gone out, gathering in people's productive life
Meeting, travelling way are often infected with various spots have little time cleaning and clean, these spots the or affect mood of people, or remain
Clothing is formed secondary spot be difficult to clean, bring inconvenience to the trip of people.
At present, the portable stain removal pen on market mainly uses two kinds of decontamination modes, and one is that the alkalescence containing bleaching agent is gone
Dirt, two is the fast decontaminating containing organic solvent.Put into practice use to show: the oxidation characteristic exclusive because of bleaching agent often damages
Clothes fiber, makes clothing variable color or hardening.There is the oil stain on the detergent energy rapid cleaning clothing of agent solvent, but to charcoal
The decontamination of black spot and protide spot is inconspicuous.Some products are had to use biology enzyme and volatile organic solvent in recent years
The method of compound decontamination, the reason not tolerated organic solvent due to biology enzyme so that biology enzyme loses activity, so not reaching
Preferably clean effect.
Summary of the invention
The technical problem to be solved is to overcome above-mentioned the deficiencies in the prior art, it is provided that a kind of as soil release
Detergent of pen and preparation method thereof.
The present invention solves above-mentioned technical problem and the technical scheme is that a kind of detergent as soil release pen, bag
Include following by each component of mass fraction proportioning:
APG 1-2.5%
Ethoxylated fatty-acid methyl ester 3-8%
Cocoanut fatty acid diethanolamide 2-4%
Sorbitan fatty acid APEO 2-5%
PEG400 15-30%
Lipase 0.5-1%
Proteinase-10 .2-0.5%
Amylase 0.2-0.4%
Cellulase 0.1-0.3%
Anhydrous citric acid 0.05-0.2%
Deionized water surplus.
The preparation method of a kind of detergent as soil release pen, comprises the steps:
Step A, adds deionized water in a mixing bowl, opens stirring and adds ethoxylated fatty-acid methyl ester and sorbitan fatty acid
APEO, stirs;
Step B, takes amylase, cellulase and APG and mixes to pasty state, add a mixing bowl, stir 10 minutes;
Step C, takes protease, lipase and cocoanut fatty acid diethanolamide and mixes to pasty state, add a mixing bowl, stir
Mix 5 minutes;
Step D, adds PEG400 stirring and clarifies to solution in a mixing bowl, with anhydrous citric acid regulation solution pH value to weak
Alkalescence (PH is 7-8), stirs 5 minutes, stands.
Compared with prior art, beneficial effects of the present invention: the one that the present invention provides is used as portable soil release pen
Detergent, select gentle non-stimulated nonionic surfactant to be equipped with biological enzyme formulation and obtain, surfactant is to commonly
The dirt-removing power of dirt is stronger, and biological enzyme formulation is more than surfactant, surface-active for single spot dirt-removing power
Agent and biological enzyme formulation are worked in coordination with and are played the respective decontamination to obstructed dirt, produce preferable clean effect.
In biological enzyme formulation, itself is containing enzymatic activity stabilizer, and biology enzyme is total to surfactant and enzymatic activity stabilizer
Under same-action, it is possible to permanent, stable, potent holding bioenzyme activity, in the dual decontamination of surfactant and biological enzyme formulation
Under effect, decontamination is more thorough, can remove the bloodstain on clothing, milk stain, sweat stain, ball pen oil stain and ink blok easily and effectively
Deng.
The detergent of the present invention all uses degradable, the proportioning component of environmental protection, it is possible to fast decoupled spot, and does not damages
Clothing, free from environmental pollution;Meanwhile, the transparent clarification of detergent, colorless and odorless, without any essence composition, will not produce and ring
The unbefitting smell in border.
The preparation method technological operation of the present invention is simple, it is not necessary to heat, and whole process is cold joins, and saves production cost.Use lemon
Free alkali too much present in lemon acid neutralization raw material, it is ensured that the high activity of biological enzyme formulation.In conjunction with biological enzyme formulation self
Characteristics, carry out with corresponding surfactant emulsification combine, be allowed to dispersed in the solution, effectively prevent biology
The sedimentation layering of enzyme preparation.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is described further.In preferred embodiment cited as
On " ", D score, "left", "right", the term such as " middle " and " ", only understanding for ease of narration, and be not used to limit the present invention
Enforceable scope, being altered or modified of its relativeness, changing under technology contents without essence, can be real when being also considered as the present invention
The category executed.
A kind of detergent as soil release pen of present invention design and preparation method thereof, specifically lists following
Embodiment.
Example one
A kind of detergent as soil release pen, it specifically includes that APG, ethoxylated fatty-acid methyl ester, coconut oil
Fatty diglycollic amide, Span APEO, PEG400, lipase, protease, amylase, fibre
Dimension element enzyme, anhydrous citric acid and deionized water, the mass fraction ratio of the most each component is:
APG 1%
Ethoxylated fatty-acid methyl ester 3%
Cocoanut fatty acid diethanolamide 2%
Sorbitan fatty acid APEO 2%
PEG400 15%
Lipase 0.5%
Proteinase-10 .2%
Amylase 0.2%
Cellulase 0.1%
Anhydrous citric acid 0.05%
Deionized water surplus.
A kind of detergent preparation method as soil release pen, comprises the steps: that each component is joined according to mass fraction
Ratio,
Step A, adds deionized water in a mixing bowl, opens stirring and adds 3% ethoxylated fatty-acid methyl ester and 2% sorb alcohol ester
Fat acid APEO, stirs.
Step B, takes 0.2% amylase, 0.1% cellulase and 1% APG and mixes to pasty state, add a mixing bowl,
Stir 10 minutes.
Step C, takes 0.2% protease, 0.5% lipase and 2% cocoanut fatty acid diethanolamide and mixes to stick with paste
Shape, adds a mixing bowl, stirs 5 minutes.
Step D, adds 15% PEG400 stirring and clarifies to solution in a mixing bowl, with 0.05% anhydrous citric acid regulation
Solution pH value, to alkalescent (PH is 7-8), stirs 5 minutes, stands.
Example two
A kind of detergent as soil release pen, it specifically includes that APG, ethoxylated fatty-acid methyl ester, coconut oil
Fatty diglycollic amide, Span APEO, PEG400, lipase, protease, amylase, fibre
Dimension element enzyme, anhydrous citric acid and deionized water, the mass fraction ratio of the most each component is:
APG 2%
Ethoxylated fatty-acid methyl ester 6%
Cocoanut fatty acid diethanolamide 3%
Sorbitan fatty acid APEO 3.6%
PEG400 25%
Lipase 0.6%
Proteinase-10 .4%
Amylase 0.3%
Cellulase 0.2%
Anhydrous citric acid 0.1%
Deionized water surplus.
A kind of detergent preparation method as soil release pen, comprises the steps: that each component is joined according to mass fraction
Ratio,
Step A, adds deionized water in a mixing bowl, opens stirring and adds 6% ethoxylated fatty-acid methyl ester and 3.6% sorbierite
Aliphatic acid polyethenoxy ether, stirs.
Step B, takes 0.3% amylase, 0.2% cellulase and 2% APG and mixes to pasty state, add a mixing bowl,
Stir 10 minutes.
Step C, takes 0.4% protease, 0.6% lipase and 3% cocoanut fatty acid diethanolamide and mixes to stick with paste
Shape, adds a mixing bowl, stirs 5 minutes.
Step D, adds 25% PEG400 stirring and clarifies to solution in a mixing bowl, molten with 0.1% anhydrous citric acid regulation
Liquid pH value, to alkalescent (PH is 7-8), stirs 5 minutes, stands.
Example three
A kind of detergent as soil release pen, it specifically includes that APG, ethoxylated fatty-acid methyl ester, coconut oil
Fatty diglycollic amide, Span APEO, PEG400, lipase, protease, amylase, fibre
Dimension element enzyme, anhydrous citric acid and deionized water, the mass fraction ratio of the most each component is:
APG 2.5%
Ethoxylated fatty-acid methyl ester 8%
Cocoanut fatty acid diethanolamide 4%
Sorbitan fatty acid APEO 5%
PEG400 30%
Lipase 1%
Proteinase-10 .5%
Amylase 0.4%
Cellulase 0.3%
Anhydrous citric acid 0.2%
Deionized water surplus.
A kind of detergent preparation method as soil release pen, comprises the steps: that each component is joined according to mass fraction
Ratio,
Step A, adds deionized water in a mixing bowl, opens stirring and adds 8% ethoxylated fatty-acid methyl ester and 5% sorb alcohol ester
Fat acid APEO, stirs.
Step B, takes 0.4% amylase, 0.3% cellulase and 2.5 APGs and mixes to pasty state, add stirring
Cylinder, stirs 10 minutes.
Step C, takes 0.5% protease, 1% lipase and 4% cocoanut fatty acid diethanolamide and mixes to pasty state,
Add a mixing bowl, stir 5 minutes.
Step D, adds 30% PEG400 stirring and clarifies to solution in a mixing bowl, molten with 0.2% anhydrous citric acid regulation
Liquid pH value, to alkalescent (PH is 7-8), adds the water of surplus, stirs 5 minutes, stand.
APG, ethoxylated fatty-acid methyl ester, cocoanut fatty acid diethanolamide, Span polyoxy
Vinethene is nonionic surfactant, and lipase, protease, amylase, cellulase are biology enzyme.The present invention uses surface
Activating agent and the method for biology enzyme compound emulsion, protection biological enzyme formulation will not be because of solution alkaline during configuration greatly
Too high and affect enzymatic activity.Use the markings such as low foaming surfactant, cleaning spot noresidue foam, one wipe gently with paper handkerchief
?.
Three of the above example is according to standard GB/T/T13173-2008 " dress material washing agent detergency and circulation washing performance
Can mensuration " the standard washing powder of ining contrast to carries out detergency test, three kinds of examples act on the decontamination value contrast on different soiled cotton
In the decontamination value of standard washing powder, its ratio result is as follows:
Soiled cotton kind | Example one in contrast to standard soiled cloth | Example two in contrast to standard soiled cloth | Example three in contrast to standard soiled cloth |
Albumen soiled cotton | 1.2 | 1.7 | 1.9 |
Edible oil soiled cotton | 1.1 | 1.5 | 1.6 |
Carbon black soiled cotton | 1.1 | 1.2 | 1.2 |
Can be drawn following two conclusion by above table data: first, the dirt-removing power of detergent is compared to standard washing powder
Dirt-removing power is remarkably reinforced;Second, along with the content of the deionized water component of detergent reduces, i.e. enrichment increases, its decontamination
Ability strengthens therewith.
The above, be only presently preferred embodiments of the present invention, and the present invention not makees any pro forma restriction, appoints
What those skilled in the art, in the range of without departing from technical solution of the present invention, implements above according to the technical spirit of the present invention
Any brief introduction amendment, equivalent variations and the modification that example is made, all still falls within the range of technical solution of the present invention.
Claims (5)
1. the detergent being used as soil release pen, it is characterised in that include following by each component of mass fraction proportioning:
APG 1-2.5%
Ethoxylated fatty-acid methyl ester 3-8%
Cocoanut fatty acid diethanolamide 2-4%
Sorbitan fatty acid APEO 2-5%
PEG400 15-30%
Lipase 0.5-1%
Proteinase-10 .2-0.5%
Amylase 0.2-0.4%
Cellulase 0.1-0.3%
Anhydrous citric acid 0.05-0.2%
Deionized water surplus.
Detergent as soil release pen the most according to claim 1, it is characterised in that include following by mass fraction
Each component of proportioning:
APG 1%
Ethoxylated fatty-acid methyl ester 3%
Cocoanut fatty acid diethanolamide 2%
Sorbitan fatty acid APEO 2%
PEG400 15%
Lipase 0.5%
Proteinase-10 .2%
Amylase 0.2%
Cellulase 0.1%
Anhydrous citric acid 0.05%
Deionized water surplus.
Detergent as soil release pen the most according to claim 1, it is characterised in that include following by mass fraction
Each component of proportioning:
APG 2%
Ethoxylated fatty-acid methyl ester 6%
Cocoanut fatty acid diethanolamide 3%
Sorbitan fatty acid APEO 3.6%
PEG400 25%
Lipase 0.6%
Proteinase-10 .4%
Amylase 0.3%
Cellulase 0.2%
Anhydrous citric acid 0.1%
Deionized water surplus.
Detergent as soil release pen the most according to claim 1, it is characterised in that include following by mass fraction
Each component of proportioning:
APG 2.5%
Ethoxylated fatty-acid methyl ester 8%
Cocoanut fatty acid diethanolamide 4%
Sorbitan fatty acid APEO 5%
PEG400 30%
Lipase 1%
Proteinase-10 .5%
Amylase 0.4%
Cellulase 0.3%
Anhydrous citric acid 0.2%
Deionized water surplus.
5. the detergent preparation method as soil release pen as described in any one of Claims 1-4, its feature exists
In, comprise the steps:
Step A, adds deionized water in a mixing bowl, opens stirring and adds ethoxylated fatty-acid methyl ester and sorbitan fatty acid
APEO, stirs;
Step B, takes amylase, cellulase and APG and mixes to pasty state, add a mixing bowl, stir 10 minutes;
Step C, takes protease, lipase and cocoanut fatty acid diethanolamide and mixes to pasty state, add a mixing bowl, stir
Mix 5 minutes;
Step D, adds PEG400 stirring and clarifies to solution in a mixing bowl, with anhydrous citric acid regulation solution pH value to weak
Alkalescence (PH is 7-8), stirs 5 minutes, stands.
Priority Applications (1)
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CN201610352318.5A CN105907484A (en) | 2016-05-25 | 2016-05-25 | Detergent as stain removal pen and preparation method of detergent |
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Application Number | Priority Date | Filing Date | Title |
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CN201610352318.5A CN105907484A (en) | 2016-05-25 | 2016-05-25 | Detergent as stain removal pen and preparation method of detergent |
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Family
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CN201610352318.5A Pending CN105907484A (en) | 2016-05-25 | 2016-05-25 | Detergent as stain removal pen and preparation method of detergent |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108315103A (en) * | 2018-01-29 | 2018-07-24 | 深圳市芭格美生物科技有限公司 | A kind of jewellery cleaner and preparation method thereof |
CN113413809A (en) * | 2021-07-16 | 2021-09-21 | 上海洁澜日化有限公司 | Preparation method of portable powerful stain remover |
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JP2004211080A (en) * | 2002-12-19 | 2004-07-29 | Kao Corp | Bleaching detergent composition |
CN102559421A (en) * | 2011-12-23 | 2012-07-11 | 广州立白企业集团有限公司 | Enzyme-containing fabric detergent with synergistic anticorrosion effect |
CN102703240A (en) * | 2012-06-19 | 2012-10-03 | 海安县国力化工有限公司 | Heavy-duty liquid scouring agent |
CN103242973A (en) * | 2013-05-16 | 2013-08-14 | 纳爱斯集团有限公司 | Three-effect liquid laundry detergent composition and preparation method thereof |
CN103666883A (en) * | 2013-12-24 | 2014-03-26 | 北京绿伞化学股份有限公司 | Compound enzyme powerful photoflo for portable stain removal pen and preparation method thereof |
CN103865663A (en) * | 2012-12-12 | 2014-06-18 | 深圳市绿微康生物工程有限公司 | Medical multi-enzyme cleaning agent and preparation method thereof |
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2016
- 2016-05-25 CN CN201610352318.5A patent/CN105907484A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2004211080A (en) * | 2002-12-19 | 2004-07-29 | Kao Corp | Bleaching detergent composition |
CN102559421A (en) * | 2011-12-23 | 2012-07-11 | 广州立白企业集团有限公司 | Enzyme-containing fabric detergent with synergistic anticorrosion effect |
CN102703240A (en) * | 2012-06-19 | 2012-10-03 | 海安县国力化工有限公司 | Heavy-duty liquid scouring agent |
CN103865663A (en) * | 2012-12-12 | 2014-06-18 | 深圳市绿微康生物工程有限公司 | Medical multi-enzyme cleaning agent and preparation method thereof |
CN103242973A (en) * | 2013-05-16 | 2013-08-14 | 纳爱斯集团有限公司 | Three-effect liquid laundry detergent composition and preparation method thereof |
CN103666883A (en) * | 2013-12-24 | 2014-03-26 | 北京绿伞化学股份有限公司 | Compound enzyme powerful photoflo for portable stain removal pen and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108315103A (en) * | 2018-01-29 | 2018-07-24 | 深圳市芭格美生物科技有限公司 | A kind of jewellery cleaner and preparation method thereof |
CN113413809A (en) * | 2021-07-16 | 2021-09-21 | 上海洁澜日化有限公司 | Preparation method of portable powerful stain remover |
CN113413809B (en) * | 2021-07-16 | 2023-01-17 | 上海洁澜日化有限公司 | Preparation method of portable powerful stain remover |
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