CN105886132A - Antibacterial biological sticky mud stripping agent and preparation method thereof - Google Patents

Antibacterial biological sticky mud stripping agent and preparation method thereof Download PDF

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Publication number
CN105886132A
CN105886132A CN201610296077.7A CN201610296077A CN105886132A CN 105886132 A CN105886132 A CN 105886132A CN 201610296077 A CN201610296077 A CN 201610296077A CN 105886132 A CN105886132 A CN 105886132A
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China
Prior art keywords
stirring
normal temperature
preparation
biological clay
percent
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Pending
Application number
CN201610296077.7A
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Chinese (zh)
Inventor
毛祝新
毛知新
崔新爱
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Individual
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Individual
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Priority to CN201610296077.7A priority Critical patent/CN105886132A/en
Publication of CN105886132A publication Critical patent/CN105886132A/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02—Acyclic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/26—Phosphorus; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3472—Organic compounds containing sulfur additionally containing -COOH groups or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses an antibacterial biological sticky mud stripping agent and a preparation method thereof. The antibacterial biological sticky mud stripping agent is prepared from the following ingredients in percentage by weight: 10 to 15 percent of sodium diethylhexyl sulfosuccinate, 1 to 5 percent of fatty alcohol-polyoxyethylene ether, 3 to 7 percent of sodium pyrophosphate, 27 to 35 percent of hydrogen peroxide and the balance water for supplementing the total weight into 100 percent. The antibacterial biological sticky mud stripping agent has good antibacterial performance; a good decomposition and stripping effect is achieved on biological sticky mud; the penetrability is high; the toxicity is low; no corrosion is caused on metal, rubber and plastics; the antibacterial biological sticky mud stripping agent can be used for removing biological sticky mud of a circulation cooling water system; meanwhile, the effects of cleaning old scales on the surface of metal and improving the equipment heat exchange rate are also achieved; a strong killing effect is realized on nitrifying bacteria and nitrite bacteria.

Description

A kind of bactericidal properties biological clay remover and preparation method thereof
Technical field
The present invention relates to industrial circulating water cooling system mud and divest field, particularly relate to a kind of bactericidal properties biological clay stripping From agent and preparation method thereof.
Background technology
Cooling water treatment system is widely used in the field such as industry, chemical industry, in cooling water treatment system, often has big The biological clay deposition of amount, needs to add adhesive mud remover, after having processed, all discharges, these drains, mostly contain Antibacterial, environmental pollution is bigger.
Summary of the invention
The purpose of the present invention: providing a kind of bactericidal properties biological clay remover and preparation method thereof, environmental pollution is the least, And most importantly low cost, cost performance is high.
To achieve these goals, the technical scheme is that
A kind of bactericidal properties biological clay remover, the most composed of the following components:
Aerosol-OT salt 10-15%,
Fatty alcohol-polyoxyethylene ether 1-5%,
Sodium pyrophosphate 3-7%,
Hydrogen peroxide 27-35%,
Remaining is supplemented to 100% with deionized water.
The preparation method of a kind of bactericidal properties biological clay remover, the method at least comprises the steps:
Step 1: add hydrogen peroxide stirring at normal temperature in reaction vessel.
Step 2: add aerosol-OT salt stirring at normal temperature in the solution of step 1 gained.
Step 3: add fatty alcohol-polyoxyethylene ether stirring at normal temperature in the solution of step 2 gained.
Step 4: add sodium pyrophosphate stirring at normal temperature in the solution of step 3 gained.
Step 5: add deionized water in the solution of step 4 gained and stirring at normal temperature obtains biological clay remover.
The preparation method of above-mentioned bactericidal properties biological clay remover, wherein, in described step 1, stirring at normal temperature Time is 2 minutes.
The preparation method of above-mentioned bactericidal properties biological clay remover, wherein, in described step 2, stirring at normal temperature Time is 10 minutes.
The preparation method of above-mentioned bactericidal properties biological clay remover, wherein, in described step 3, stirring at normal temperature Time is 15 minutes.
The preparation method of above-mentioned bactericidal properties biological clay remover, wherein, in described step 4, stirring at normal temperature Time is 8 minutes.
The preparation method of above-mentioned bactericidal properties biological clay remover, wherein, in described step 5, stirring at normal temperature Time is 12 minutes.
The present invention has good bactericidal properties, has good decomposition peeling effect to biological clay, and its penetration is strong, malicious Property is low, corrosion-free to metal, rubber and plastics；Can be used for quickly removing the biological clay of recirculating cooling water system；Also have simultaneously Clean the old dirt of metal surface and improve the effect of equipment rate of heat exchange；Nitrobacteria and nitrite bacteria all there is the strongest killing The effect of going out.
Accompanying drawing explanation
Fig. 1 is the flow chart of the preparation method of the present invention a kind of bactericidal properties biological clay remover.
Detailed description of the invention
Embodiments of the invention are further illustrated below in conjunction with accompanying drawing.
A kind of bactericidal properties biological clay remover, the most composed of the following components:
Aerosol-OT salt 10-15%
Fatty alcohol-polyoxyethylene ether 1-5%
Sodium pyrophosphate 3-7%
Hydrogen peroxide 27-35%
Remaining is supplemented to 100% with deionized water.
Refer to shown in accompanying drawing 1, the preparation method of a kind of bactericidal properties biological clay remover, use sulfosuccinate dioctyl phthalate Sodium salt 15 kilograms, fatty alcohol-polyoxyethylene ether 5 kilograms, sodium pyrophosphate 7 kilograms and hydrogen peroxide 35 kilograms, balance deionized water system Becoming the adhesive mud remover of double centner, the method at least comprises the steps:
Step 1: add hydrogen peroxide stirring at normal temperature in reaction vessel.
Step 2: add aerosol-OT salt stirring at normal temperature in the solution of step 1 gained.
Step 3: add fatty alcohol-polyoxyethylene ether stirring at normal temperature in the solution of step 2 gained.
Step 4: add sodium pyrophosphate stirring at normal temperature in the solution of step 3 gained.
Step 5: add deionized water in the solution of step 4 gained and stirring at normal temperature obtains biological clay remover.
In described step 1, the time of stirring at normal temperature is 2 minutes.
In described step 2, the time of stirring at normal temperature is 10 minutes.
In described step 3, the time of stirring at normal temperature is 15 minutes.
In described step 4, the time of stirring at normal temperature is 8 minutes.
In described step 5, the time of stirring at normal temperature is 12 minutes.
Peeling effect evaluation test result see table:
Polyoses content (mg/L) Nucleic acid content (mg/L)
Diluent 30.85 3.21
Blank 8.37 1.22
In sum, the present invention has good bactericidal properties, has good decomposition peeling effect, its penetration to biological clay By force, toxicity low, corrosion-free to metal, rubber and plastics；Can be used for quickly removing the biological clay of recirculating cooling water system；Simultaneously Also have the old dirt cleaning metal surface and the effect improving equipment rate of heat exchange；Nitrobacteria and nitrite bacteria are all had the strongest Killing action.
The foregoing is only the preferred embodiments of the present invention, not thereby limit the scope of the claims of the present invention, every utilization The equivalent structure transformation that description of the invention content is made, or directly or indirectly use the technology neck being attached to other Related products Territory, is the most in like manner included in the scope of patent protection of the present invention.

Claims (7)

1. a bactericidal properties biological clay remover, it is characterised in that: the most composed of the following components:
Aerosol-OT salt 10-15%,
Fatty alcohol-polyoxyethylene ether 1-5%,
Sodium pyrophosphate 3-7%,
Hydrogen peroxide 27-35%,
Remaining is supplemented to 100% with deionized water.
2. the preparation method of the bactericidal properties biological clay remover that a kind is applied to described in claim 1, it is characterised in that: the party Method at least comprises the steps:
Step 1: add hydrogen peroxide stirring at normal temperature in reaction vessel；
Step 2: add aerosol-OT salt stirring at normal temperature in the solution of step 1 gained；
Step 3: add fatty alcohol-polyoxyethylene ether stirring at normal temperature in the solution of step 2 gained；
Step 4: add sodium pyrophosphate stirring at normal temperature in the solution of step 3 gained；
Step 5: add deionized water in the solution of step 4 gained and stirring at normal temperature obtains biological clay remover.
The preparation method of bactericidal properties biological clay remover the most according to claim 2, it is characterised in that: in described step In rapid 1, the time of stirring at normal temperature is 2 minutes.
The preparation method of bactericidal properties biological clay remover the most according to claim 2, it is characterised in that: in described step In rapid 2, the time of stirring at normal temperature is 10 minutes.
The preparation method of bactericidal properties biological clay remover the most according to claim 2, it is characterised in that: in described step In rapid 3, the time of stirring at normal temperature is 15 minutes.
The preparation method of bactericidal properties biological clay remover the most according to claim 2, it is characterised in that: in described step In rapid 4, the time of stirring at normal temperature is 8 minutes.
The preparation method of bactericidal properties biological clay remover the most according to claim 2, it is characterised in that: in described step In rapid 5, the time of stirring at normal temperature is 12 minutes.
CN201610296077.7A 2016-05-07 2016-05-07 Antibacterial biological sticky mud stripping agent and preparation method thereof Pending CN105886132A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610296077.7A CN105886132A (en) 2016-05-07 2016-05-07 Antibacterial biological sticky mud stripping agent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610296077.7A CN105886132A (en) 2016-05-07 2016-05-07 Antibacterial biological sticky mud stripping agent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN105886132A true CN105886132A (en) 2016-08-24

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106854009A (en) * 2017-02-27 2017-06-16 苏州顶裕节能设备有限公司 Efficient heavy waste water flocculant based on plant extracts and preparation method thereof
CN109399795A (en) * 2017-08-15 2019-03-01 中国石油化工股份有限公司 Circulating water cooling treatment system and its method of application and circulating water cooling treatment
CN110980897A (en) * 2019-12-24 2020-04-10 广州市粤新工程技术有限公司 Environment-friendly sterilizing algicide for cooling system

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6013896A (en) * 1983-07-01 1985-01-24 ライオン株式会社 Foamable hard surface detergent composition
JP2002114810A (en) * 2000-08-03 2002-04-16 Hymo Corp Method for producing water-in-oil type polymer emulsion and method for using the same
CN101985125A (en) * 2010-11-05 2011-03-16 邵永富 Silt stripping method for circulating cooling water system
CN102399633A (en) * 2010-09-13 2012-04-04 张红涛 Cleaning agent for cooling water processing device
CN102994264A (en) * 2012-11-12 2013-03-27 新疆德安环保科技有限公司 Preparation method for high-efficiency slim stripping bactericide
CN103771593A (en) * 2012-10-23 2014-05-07 中国石油化工股份有限公司 Remover for removing biological slime in recirculated cooling water and method for removing biological slime in recirculated cooling water system
CN103975948A (en) * 2014-06-10 2014-08-13 山东瑞爱特环保科技有限公司 Biocide-algaecide for circulating water and preparation method thereof
CN104372363A (en) * 2014-10-13 2015-02-25 淄博彬盛翔化工有限公司 Slime stripping agent and preparation method thereof
CN104651090A (en) * 2013-11-20 2015-05-27 青岛水世界环保科技有限公司 Chelating cleaning agent

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6013896A (en) * 1983-07-01 1985-01-24 ライオン株式会社 Foamable hard surface detergent composition
JP2002114810A (en) * 2000-08-03 2002-04-16 Hymo Corp Method for producing water-in-oil type polymer emulsion and method for using the same
CN102399633A (en) * 2010-09-13 2012-04-04 张红涛 Cleaning agent for cooling water processing device
CN101985125A (en) * 2010-11-05 2011-03-16 邵永富 Silt stripping method for circulating cooling water system
CN103771593A (en) * 2012-10-23 2014-05-07 中国石油化工股份有限公司 Remover for removing biological slime in recirculated cooling water and method for removing biological slime in recirculated cooling water system
CN102994264A (en) * 2012-11-12 2013-03-27 新疆德安环保科技有限公司 Preparation method for high-efficiency slim stripping bactericide
CN104651090A (en) * 2013-11-20 2015-05-27 青岛水世界环保科技有限公司 Chelating cleaning agent
CN103975948A (en) * 2014-06-10 2014-08-13 山东瑞爱特环保科技有限公司 Biocide-algaecide for circulating water and preparation method thereof
CN104372363A (en) * 2014-10-13 2015-02-25 淄博彬盛翔化工有限公司 Slime stripping agent and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106854009A (en) * 2017-02-27 2017-06-16 苏州顶裕节能设备有限公司 Efficient heavy waste water flocculant based on plant extracts and preparation method thereof
CN109399795A (en) * 2017-08-15 2019-03-01 中国石油化工股份有限公司 Circulating water cooling treatment system and its method of application and circulating water cooling treatment
CN109399795B (en) * 2017-08-15 2020-07-21 中国石油化工股份有限公司 System for treating circulating cooling water, application thereof and method for treating circulating cooling water
CN110980897A (en) * 2019-12-24 2020-04-10 广州市粤新工程技术有限公司 Environment-friendly sterilizing algicide for cooling system

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Application publication date: 20160824

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