CN105885238A - Flame retardant polypropylene plastic film - Google Patents

Flame retardant polypropylene plastic film Download PDF

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Publication number
CN105885238A
CN105885238A CN201610491240.5A CN201610491240A CN105885238A CN 105885238 A CN105885238 A CN 105885238A CN 201610491240 A CN201610491240 A CN 201610491240A CN 105885238 A CN105885238 A CN 105885238A
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CN
China
Prior art keywords
parts
polypropylene
flame retardant
flame
plastic film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610491240.5A
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Chinese (zh)
Inventor
陈晖�
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Anhui Huilong Package Co Ltd
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Anhui Huilong Package Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Anhui Huilong Package Co Ltd filed Critical Anhui Huilong Package Co Ltd
Priority to CN201610491240.5A priority Critical patent/CN105885238A/en
Publication of CN105885238A publication Critical patent/CN105885238A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • C08J2323/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10Homopolymers or copolymers of propene
    • C08J2423/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The invention belongs to the field of plastic products and discloses a flame retardant polypropylene plastic film. The flame retardant polypropylene plastic film is composed of the following components in parts by weight: 55-65 parts of polypropylene resin, 10-25 parts of polypropylene, 5-8 parts of polypropylene glycol, 3-8 parts of methyl methacrylate, 4 parts of magnesium stearate, 5 parts of a propenyl thermoplastic elastomer, 3 parts of a dibutyl phthalate plasticizer, 3 parts of a corn fiber toughening agent and 4 parts of a zinc borate flame retardant. The flame retardant polypropylene plastic film is added with the inorganic zinc borate flame retardant, so that a thin film has good flame retardant property and also has the advantages of light plastic, stable chemical properties, high hardness and good impact resistance.

Description

A kind of flame-retardant polypropylene plastics film
Technical field
The present invention relates to a kind of plastic foil, particularly relate to a kind of flame-retardant polypropylene plastics film.
Background technology
At present, along with expanding economy, plastics are widely used in industry and life.Chinese Plastics film industry is in a flourish stage, it is reported, the demand of Chinese Plastics film every year by with more than 9% speed increment.And along with various new materials, new equipment and new technology are constantly emerged in large numbers, the plastic sheeting promoting China towards diversification of varieties, customizations and is possessed multi-functional composite membrane direction develops.Polypropylene as a big class of versatile material, the feature such as processing little with its proportion, easy, corrosion-resistant, nontoxic and high comprehensive performance and be used widely, all there is inflammable problem in present most polypropylene film.
Summary of the invention
It is an object of the invention to provide a kind of flame-retardant polypropylene plastics film, by inventing the formula of a kind of polypropylene plastic film and there is inflammable problem by adding fire retardant solution polypropylene plastic film.
For achieving the above object, the present invention adopts the following technical scheme that
A kind of flame-retardant polypropylene plastics film, this plastic foil is made up of following component in parts by weight: acrylic resin 55-65 part, polypropylene 10-25 part, POLYPROPYLENE GLYCOL 5-8 part, methyl methacrylate 3-8 part, magnesium stearate 4 parts, 5 parts of propylene-based thermoplastic's elastomer, 3 parts of plasticizer, toughener 3 parts, fire retardant 4 parts.
Further, described acrylic resin is low density polypropylene resin, weight average molecular weight 9000-12000 of acrylic resin.
Further, described plasticizer is dibutyl phthalate.
Further, described toughener is zein fiber.
Further, described fire retardant is Firebrake ZB.
Owing to using technique scheme, there is advantages that
The polypropylene plastic film of the present invention makes film have good fire resistance by the interpolation of inorganic combustion inhibitor Firebrake ZB, has plastics light weight, stable chemical performance simultaneously;Hardness high-impact can wait advantage well.
Detailed description of the invention
Embodiment one
A kind of flame-retardant polypropylene plastics film, this plastic foil is made up of following component in parts by weight: acrylic resin 55 parts, polypropylene 17 parts, POLYPROPYLENE GLYCOL 5 parts, methyl methacrylate 4 parts, magnesium stearate 4 parts, 5 parts of propylene-based thermoplastic's elastomer, 3 parts of plasticizer, toughener 3 parts, fire retardant 4 parts.
Further, described acrylic resin is low density polypropylene resin, weight average molecular weight 9000-12000 of acrylic resin.
Further, described plasticizer is dibutyl phthalate.
Further, described toughener is zein fiber.
Further, described fire retardant is Firebrake ZB.
Embodiment two
A kind of flame-retardant polypropylene plastics film, this plastic foil is made up of following component in parts by weight: acrylic resin 58 parts, polypropylene 12 parts, POLYPROPYLENE GLYCOL 6 parts, methyl methacrylate 5 parts, magnesium stearate 4 parts, 5 parts of propylene-based thermoplastic's elastomer, 3 parts of plasticizer, toughener 3 parts, fire retardant 4 parts.
Further, described acrylic resin is low density polypropylene resin, weight average molecular weight 9000-12000 of acrylic resin.
Further, described plasticizer is dibutyl phthalate.
Further, described toughener is zein fiber.
Further, described fire retardant is Firebrake ZB.
Embodiment three
A kind of flame-retardant polypropylene plastics film, this plastic foil is made up of following component in parts by weight: acrylic resin 60 parts, polypropylene 11 parts, POLYPROPYLENE GLYCOL 6 parts, methyl methacrylate 4 parts, magnesium stearate 4 parts, 5 parts of propylene-based thermoplastic's elastomer, 3 parts of plasticizer, toughener 3 parts, fire retardant 4 parts.
Further, described acrylic resin is low density polypropylene resin, weight average molecular weight 9000-12000 of acrylic resin.
Further, described plasticizer is dibutyl phthalate.
Further, described toughener is zein fiber.
Further, described fire retardant is Firebrake ZB.
The foregoing is only the better embodiment of the present invention; protection scope of the present invention is not limited with above-mentioned embodiment; in every case those of ordinary skill in the art modify or change according to the equivalence that disclosed content is made, and all should include in the protection domain described in claims.

Claims (5)

1. a flame-retardant polypropylene plastics film, this plastic foil is made up of following component in parts by weight: acrylic resin 55-65 part, polypropylene 10-25 part, POLYPROPYLENE GLYCOL 5-8 part, methyl methacrylate 3-8 part, magnesium stearate 4 parts, 5 parts of propylene-based thermoplastic's elastomer, 3 parts of plasticizer, toughener 3 parts, fire retardant 4 parts.
A kind of flame-retardant polypropylene plastics film the most according to claim 1, it is characterised in that: described acrylic resin is low density polypropylene resin, weight average molecular weight 9000-12000 of acrylic resin.
A kind of flame-retardant polypropylene plastics film the most according to claim 1, it is characterised in that: described plasticizer is dibutyl phthalate.
A kind of flame-retardant polypropylene plastics film the most according to claim 1, it is characterised in that: described toughener is zein fiber.
A kind of flame-retardant polypropylene plastics film the most according to claim 1, it is characterised in that: described fire retardant is Firebrake ZB.
CN201610491240.5A 2016-06-29 2016-06-29 Flame retardant polypropylene plastic film Pending CN105885238A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610491240.5A CN105885238A (en) 2016-06-29 2016-06-29 Flame retardant polypropylene plastic film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610491240.5A CN105885238A (en) 2016-06-29 2016-06-29 Flame retardant polypropylene plastic film

Publications (1)

Publication Number Publication Date
CN105885238A true CN105885238A (en) 2016-08-24

Family

ID=56718494

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610491240.5A Pending CN105885238A (en) 2016-06-29 2016-06-29 Flame retardant polypropylene plastic film

Country Status (1)

Country Link
CN (1) CN105885238A (en)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101412830A (en) * 2008-12-02 2009-04-22 上海金发科技发展有限公司 Non-halogen flame-retardant polypropylene composite material and preparation thereof
CN101418099A (en) * 2008-12-02 2009-04-29 上海金发科技发展有限公司 Natural fiber reinforcement halogen-free flame retardant polypropylene composite material and preparation method thereof
CN101619152A (en) * 2009-07-30 2010-01-06 聊城大学 High tenacity low smoke zero halogen flame retardant polypropylene and preparation method thereof
CN101831112A (en) * 2010-05-14 2010-09-15 金发科技股份有限公司 Halogen-free flame-retardant type injection molding-class polyolefin wood plastic composite material and preparation method thereof
CN101851362A (en) * 2010-05-28 2010-10-06 金发科技股份有限公司 Halogen-free flame-retardant polyolefin injection-grade wood-plastic composite and preparation method thereof
CN102775675A (en) * 2011-05-10 2012-11-14 苏州汉扬精密电子有限公司 Flame retardant polypropylene composition and preparation method thereof
CN102964681A (en) * 2012-11-13 2013-03-13 沈阳化工大学 Halogen-free flame-retardant polypropylene material and preparation method thereof
CN103374180A (en) * 2012-04-26 2013-10-30 滁州格美特科技有限公司 Polypropylene composite material and preparation method and application thereof
CN105086153A (en) * 2015-09-07 2015-11-25 太仓金昊达新材料有限公司 Polypropylene plastic particles
CN106147013A (en) * 2016-06-28 2016-11-23 安徽徽隆包装有限公司 A kind of preparation method of polypropylene plastic film

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101412830A (en) * 2008-12-02 2009-04-22 上海金发科技发展有限公司 Non-halogen flame-retardant polypropylene composite material and preparation thereof
CN101418099A (en) * 2008-12-02 2009-04-29 上海金发科技发展有限公司 Natural fiber reinforcement halogen-free flame retardant polypropylene composite material and preparation method thereof
CN101619152A (en) * 2009-07-30 2010-01-06 聊城大学 High tenacity low smoke zero halogen flame retardant polypropylene and preparation method thereof
CN101831112A (en) * 2010-05-14 2010-09-15 金发科技股份有限公司 Halogen-free flame-retardant type injection molding-class polyolefin wood plastic composite material and preparation method thereof
CN101851362A (en) * 2010-05-28 2010-10-06 金发科技股份有限公司 Halogen-free flame-retardant polyolefin injection-grade wood-plastic composite and preparation method thereof
CN102775675A (en) * 2011-05-10 2012-11-14 苏州汉扬精密电子有限公司 Flame retardant polypropylene composition and preparation method thereof
CN103374180A (en) * 2012-04-26 2013-10-30 滁州格美特科技有限公司 Polypropylene composite material and preparation method and application thereof
CN102964681A (en) * 2012-11-13 2013-03-13 沈阳化工大学 Halogen-free flame-retardant polypropylene material and preparation method thereof
CN105086153A (en) * 2015-09-07 2015-11-25 太仓金昊达新材料有限公司 Polypropylene plastic particles
CN106147013A (en) * 2016-06-28 2016-11-23 安徽徽隆包装有限公司 A kind of preparation method of polypropylene plastic film

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Application publication date: 20160824

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