CN105885226A - Special insulation material for net cables - Google Patents

Special insulation material for net cables Download PDF

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Publication number
CN105885226A
CN105885226A CN201610294799.9A CN201610294799A CN105885226A CN 105885226 A CN105885226 A CN 105885226A CN 201610294799 A CN201610294799 A CN 201610294799A CN 105885226 A CN105885226 A CN 105885226A
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CN
China
Prior art keywords
parts
acid
insulation material
master batch
beta
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610294799.9A
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Chinese (zh)
Inventor
张军
何孔田
唐兰花
何孔高
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI JIUHUA KIMRUN COPPER INDUSTRY Co Ltd
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ANHUI JIUHUA KIMRUN COPPER INDUSTRY Co Ltd
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Priority to CN201610294799.9A priority Critical patent/CN105885226A/en
Publication of CN105885226A publication Critical patent/CN105885226A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a special insulation material for net cables. The special insulation material is prepared from the following raw materials in parts by weight: 55-70 parts of polypropylene resin, 25-40 parts of phenol propane epoxy resin, 25-40 parts of pentaerythritol triacrylate, 10-20 parts of phenyl-propanolamine (PPA), 8-15 parts of nano-zinc oxide, 8-12 parts of vanadium pentoxide, 8-12 parts of matting agent, 8-10 parts of ditridecyl phthalate, 5-8 parts of diatom powder, 2-5 parts of p-toluenesulfonic acid, 2-6 parts of beta-ketone acid and 25-30 parts of filling master batch. The special insulation material disclosed by the invention is resistant to bending, abrasion, chemical corrosion and mold degradation, still has excellent tenacity under the low temperature of -52 DEG C, is unlikely to be cracked by frost, has extremely excellent anti-electromagnetic interference capacity and insulation performance, sufficiently guarantees that signal transmission is distortionless, also can prevent baiting of mice, and has certain explosive-proof and flame-resistance performances.

Description

A kind of netting twine special isolation material
Technical field
The present invention relates to netting twine Insulation Material technical field, be specifically related to a kind of netting twine special isolation material.
Background technology
LAN to be connected, netting twine is requisite.The most common netting twine mainly has multiple twin Line, coaxial cable, three kinds of optical cable.Twisted-pair feeder, data line line being made up of many.It Feature is exactly low price, so being widely used, and telephone wire etc. as common in us.It is used to and RJ45 connector is connected.It has again STP and UTP two kinds, and that we commonly use is UTP.
Along with developing rapidly of developing rapidly of economy, particularly the Internet, society's demand to netting twine Increasing, this just requires that netting twine must is fulfilled for diversified demand.
Summary of the invention
The technical problem to be solved is to provide a kind of netting twine special isolation material.
The technical problem to be solved realizes by the following technical solutions:
A kind of netting twine special isolation material, is made up of the raw material of following weight portion: acrylic resin 55-70 part, Phenolic group propane epoxy resin 25-40 part, pentaerythritol triacrylate 25-40 part, poly-terephthalate are to benzene Diamidogen 10-20 part, nano zine oxide 8-15 part, vanadic anhydride 8-12 part, flatting silica 8-12 part, adjacent benzene The double 13 ester 8-10 parts of dioctyl phthalate, diatom powder 5-8 part, p-methyl benzenesulfonic acid 2-5 part, beta-keto acid 2-6 part, Filling master batch 25-30 part;
Described filling master batch is made up of the raw material of following weight portion: 3,5-dimethoxy-4 's-hydroxy benzenes first Acid 18-26 part, hydrogenated styrene isoprene-styrene block copolymer 8-12 part, expanded graphite 4-13 Part, fume colloidal silica 4-13 part, 1-amyl group-4-furan hendecanoic acid 5-8 part, Nano titanium nitride 4-8 part, Ferulic acid 8-15 part, oryzanol 3-4 part, butadiene rubber 16-22 part, trifunctional third Olefin(e) acid grafted propylene acid rare earth 5.5-8.5 part, vinyl acetate-chloride copolymer 5.5-8.5 part, polychlorostyrene second Alkene grafted with maleic anhydride 25-35 part, acetyl vanillin 5-12 part, Ta Nb tailings 5-12 part;Preparation side Method is to be prepared by each raw materials melt mixing granulation.
A kind of netting twine special isolation material, preparation method is as follows: first by acrylic resin, phenolic group propane epoxy Mixing 1 hour of resin, pentaerythritol triacrylate, nano zine oxide, vanadic anhydride, flatting silica, Be subsequently adding poly-terephthalate p-phenylenediamine, double 13 esters of phthalic acid, diatom powder, p-methyl benzenesulfonic acid, Beta-keto acid continues mixing 2 hours, adds filling master batch mix homogeneously, finally by Single screw extrusion Machine extruding pelletization, body temperature during extrusion is 80~88 DEG C, and head temperature is 65~70 DEG C, and extrusion is adopted It is water-cooled.
The invention has the beneficial effects as follows: Insulation Material bend resistance of the present invention, wear-resistant, resistance to chemical attack, resistance to Mycete is degraded, and still has good toughness under-52 DEG C of low temperature, will not bursting by freezing, have the most superior anti- Electromagnetic interference capability and insulating properties, fully ensure that signal transmission is undistorted, and can also prevent mouse Bait, there is certain flame proof fire resistance.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of netting twine special isolation material, is made up of the raw material of following weight portion: acrylic resin 62 parts, phenol Base propane epoxy resin 34 parts, pentaerythritol triacrylate 34 parts, poly-terephthalate p-phenylenediamine 15 parts, Double 13 ester 9 parts of nano zine oxide 12 parts, vanadic anhydride 10 parts, flatting silica 10 parts, phthalic acid, Diatom powder 6 parts, p-methyl benzenesulfonic acid 3 parts, beta-keto acid 4 parts, filling master batch 28 parts;
Described filling master batch is made up of the raw material of following weight portion: 3,5-dimethoxy-4 's-hydroxy benzenes first Acid 22 parts, hydrogenated styrene isoprene-styrene block copolymer 10 parts, expanded graphite 9 parts, gas phase Method white carbon 9 parts, 1-amyl group-4-furan hendecanoic acid 6 parts, Nano titanium nitride 6 parts, 3-methoxyl group-4-hydroxyl Base cinnamic acid 12 parts, oryzanol 3 parts, butadiene rubber 19 parts, the acrylic acid-grafted acrylic rare earth of trifunctional 7 Part, vinyl acetate-chloride copolymer 7 parts, polyvinyl chloride graft maleic anhydride 30 parts, acetyl perfume Blue element 9 parts, Ta Nb tailings 9 parts;Preparation method is to be prepared by each raw materials melt mixing granulation.
A kind of netting twine special isolation material, preparation method is as follows: first by acrylic resin, phenolic group propane epoxy Mixing 1 hour of resin, pentaerythritol triacrylate, nano zine oxide, vanadic anhydride, flatting silica, Be subsequently adding poly-terephthalate p-phenylenediamine, double 13 esters of phthalic acid, diatom powder, p-methyl benzenesulfonic acid, Beta-keto acid continues mixing 2 hours, adds filling master batch mix homogeneously, finally by Single screw extrusion Machine extruding pelletization, body temperature during extrusion is 80~88 DEG C, and head temperature is 65~70 DEG C, and extrusion is adopted It is water-cooled.
Embodiment 2
A kind of netting twine special isolation material, is made up of the raw material of following weight portion: acrylic resin 55 parts, phenol Base propane epoxy resin 25 parts, pentaerythritol triacrylate 25 parts, poly-terephthalate p-phenylenediamine 10 parts, Nano zine oxide 8 parts, vanadic anhydride 8 parts, flatting silica 8 parts, phthalic acid double 13 ester 8 parts, silicon 5 parts of algae powder, p-methyl benzenesulfonic acid 2 parts, beta-keto acid 2 parts, filling master batch 25 parts;
Described filling master batch is made up of the raw material of following weight portion: 3,5-dimethoxy-4 's-hydroxy benzenes first Acid 18 parts, hydrogenated styrene isoprene-styrene block copolymer 8 parts, expanded graphite 4 parts, gas phase Method white carbon 4 parts, 1-amyl group-4-furan hendecanoic acid 5 parts, Nano titanium nitride 4 parts, 3-methoxyl group-4-hydroxyl Base cinnamic acid 8 parts, oryzanol 3 parts, butadiene rubber 16 parts, the acrylic acid-grafted acrylic rare earth of trifunctional 5.5 Part, vinyl acetate-chloride copolymer 5.5 parts, polyvinyl chloride graft maleic anhydride 25 parts, acetyl Vanillin 5 parts, Ta Nb tailings 5 parts;Preparation method is to be prepared by each raw materials melt mixing granulation.
A kind of netting twine special isolation material, preparation method is as follows: first by acrylic resin, phenolic group propane epoxy Mixing 1 hour of resin, pentaerythritol triacrylate, nano zine oxide, vanadic anhydride, flatting silica, Be subsequently adding poly-terephthalate p-phenylenediamine, double 13 esters of phthalic acid, diatom powder, p-methyl benzenesulfonic acid, Beta-keto acid continues mixing 2 hours, adds filling master batch mix homogeneously, finally by Single screw extrusion Machine extruding pelletization, body temperature during extrusion is 80~88 DEG C, and head temperature is 65~70 DEG C, and extrusion is adopted It is water-cooled.
Embodiment 3
A kind of netting twine special isolation material, is made up of the raw material of following weight portion: acrylic resin 70 parts, phenol Base propane epoxy resin 40 parts, pentaerythritol triacrylate 40 parts, poly-terephthalate p-phenylenediamine 20 parts, Double 13 ester 10 parts of nano zine oxide 15 parts, vanadic anhydride 12 parts, flatting silica 12 parts, phthalic acid, Diatom powder 8 parts, p-methyl benzenesulfonic acid 5 parts, beta-keto acid 6 parts, filling master batch 30 parts;
Described filling master batch is made up of the raw material of following weight portion: 3,5-dimethoxy-4 's-hydroxy benzenes first Acid 26 parts, hydrogenated styrene isoprene-styrene block copolymer 12 parts, expanded graphite 13 parts, gas Phase method white carbon 13 parts, 1-amyl group-4-furan hendecanoic acid 8 parts, Nano titanium nitride 8 parts, 3-methoxyl group-4- Hydroxycinnamic acid 15 parts, oryzanol 4 parts, butadiene rubber 22 parts, the acrylic acid-grafted acrylic rare earth of trifunctional 8.5 parts, vinyl acetate-chloride copolymer 8.5 parts, polyvinyl chloride graft maleic anhydride 35 parts, second Acyl vanillin 12 parts, Ta Nb tailings 12 parts;Preparation method is to be prepared by each raw materials melt mixing granulation.
A kind of netting twine special isolation material, preparation method is as follows: first by acrylic resin, phenolic group propane epoxy Mixing 1 hour of resin, pentaerythritol triacrylate, nano zine oxide, vanadic anhydride, flatting silica, Be subsequently adding poly-terephthalate p-phenylenediamine, double 13 esters of phthalic acid, diatom powder, p-methyl benzenesulfonic acid, Beta-keto acid continues mixing 2 hours, adds filling master batch mix homogeneously, finally by Single screw extrusion Machine extruding pelletization, body temperature during extrusion is 80~88 DEG C, and head temperature is 65~70 DEG C, and extrusion is adopted It is water-cooled.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention, The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model In enclosing.Claimed scope is defined by appending claims and equivalent thereof.

Claims (2)

1. a netting twine special isolation material, it is characterised in that be made up of the raw material of following weight portion: poly-third Olefine resin 55-70 part, phenolic group propane epoxy resin 25-40 part, pentaerythritol triacrylate 25-40 part, Poly-terephthalate p-phenylenediamine 10-20 part, nano zine oxide 8-15 part, vanadic anhydride 8-12 part, delustring Powder 8-12 part, the double 13 ester 8-10 parts of phthalic acid, diatom powder 5-8 part, p-methyl benzenesulfonic acid 2-5 part, Beta-keto acid 2-6 part, filling master batch 25-30 part;
Described filling master batch is made up of the raw material of following weight portion: 3,5-dimethoxy-4 's-hydroxy benzenes first Acid 18-26 part, hydrogenated styrene isoprene-styrene block copolymer 8-12 part, expanded graphite 4-13 Part, fume colloidal silica 4-13 part, 1-amyl group-4-furan hendecanoic acid 5-8 part, Nano titanium nitride 4-8 part, Ferulic acid 8-15 part, oryzanol 3-4 part, butadiene rubber 16-22 part, trifunctional third Olefin(e) acid grafted propylene acid rare earth 5.5-8.5 part, vinyl acetate-chloride copolymer 5.5-8.5 part, polychlorostyrene second Alkene grafted with maleic anhydride 25-35 part, acetyl vanillin 5-12 part, Ta Nb tailings 5-12 part;Preparation side Method is to be prepared by each raw materials melt mixing granulation.
2. a kind of netting twine special isolation material as claimed in claim 1, it is characterised in that preparation method is such as Under: first by acrylic resin, phenolic group propane epoxy resin, pentaerythritol triacrylate, nano oxidized Mixing 1 hour of zinc, vanadic anhydride, flatting silica, be subsequently adding poly-terephthalate p-phenylenediamine, adjacent benzene two Double 13 esters of formic acid, diatom powder, p-methyl benzenesulfonic acid, beta-keto acid continue mixing 2 hours, add and fill out Fill masterbatch mix homogeneously, finally by single screw extrusion machine extruding pelletization, body temperature during extrusion be 80~ 88 DEG C, head temperature is 65~70 DEG C, and extrusion uses water cooling.
CN201610294799.9A 2016-05-03 2016-05-03 Special insulation material for net cables Withdrawn CN105885226A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023078773A1 (en) 2021-11-05 2023-05-11 Imertech Sas Composition comprising carbon black and expanded graphite and shaped articles and substrate coatings comprising same, uses thereof and methods for reducing volume resistivity and for providing electromagnetic interference shielding as well as thermal conductivity

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104017330A (en) * 2014-05-16 2014-09-03 赵莎莎 Twisted-pair insulating material for connection of computer networks
CN104231520A (en) * 2014-10-21 2014-12-24 广东中德电缆有限公司 Flame retardant material for flame retardant network cable
CN104292646A (en) * 2014-10-30 2015-01-21 安徽电信器材贸易工业有限责任公司 High temperature resisting material for communication optical cable sheath and preparation method of high temperature resisting material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104017330A (en) * 2014-05-16 2014-09-03 赵莎莎 Twisted-pair insulating material for connection of computer networks
CN104231520A (en) * 2014-10-21 2014-12-24 广东中德电缆有限公司 Flame retardant material for flame retardant network cable
CN104292646A (en) * 2014-10-30 2015-01-21 安徽电信器材贸易工业有限责任公司 High temperature resisting material for communication optical cable sheath and preparation method of high temperature resisting material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023078773A1 (en) 2021-11-05 2023-05-11 Imertech Sas Composition comprising carbon black and expanded graphite and shaped articles and substrate coatings comprising same, uses thereof and methods for reducing volume resistivity and for providing electromagnetic interference shielding as well as thermal conductivity

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Application publication date: 20160824

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