CN105884026A - Microbial carrier with core-shell structure and sinking and floating type polluted water body treatment method - Google Patents
Microbial carrier with core-shell structure and sinking and floating type polluted water body treatment method Download PDFInfo
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- CN105884026A CN105884026A CN201610270976.XA CN201610270976A CN105884026A CN 105884026 A CN105884026 A CN 105884026A CN 201610270976 A CN201610270976 A CN 201610270976A CN 105884026 A CN105884026 A CN 105884026A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/301—Aerobic and anaerobic treatment in the same reactor
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F2003/001—Biological treatment of water, waste water, or sewage using granular carriers or supports for the microorganisms
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/06—Nutrients for stimulating the growth of microorganisms
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- Biodiversity & Conservation Biology (AREA)
- Microbiology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biological Treatment Of Waste Water (AREA)
- Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
Abstract
The invention discloses a microbial carrier with a core-shell structure. The microbial carrier comprises an outer shell, a sphere core and a protective net cover, wherein both the outer shell and the sphere core are of porous micro-gap structure, the outer shell is subjected to aerobic microorganism culture implantation and curing treatment, the sphere core is subjected to anaerobic microorganism culture implantation and curing treatment, the sphere core is arranged in the outer shell, and the outside of the outer shell is wrapped with a layer of protective net cover. The microbial carrier automatically floats upwards through aerogenesis of anaerobic bacteria and sinks due to release of oxygen-rich nitrogen on the water surface so as to efficiently utilize biological reaction for polluted water treatment at low energy consumption, plays biological reaction advantages of aerobic/anaerobic bacteria respectively for different upper-layer oxygen-rich and bottom-layer anaerobic environments of a polluted water body, and achieves efficient and low-energy-consumption polluted water degradation treatment. In addition, the invention also discloses a manufacturing method of the microbial carrier with the core-shell structure and a sinking and floating type polluted water body treatment method.
Description
Technical field
The present invention is a kind of microbe carrier and the method for the formula pollution administration water body that drifts along of core shell structure, belongs to the technical field of bioengineering of sewage disposal.
Background technology
The biological treatment of sewage is the natural process of a microbial life process, compares physics and chemical treatment sideMethod is thrownThe few energy consumption of money is low.
Sewage Biological Treatment be generally divided into aerobic microbiological process and the raw speck of anaerobism process and, the oxygen environmental condition demand of this two quasi-microorganism existence is completely contradicted, simultaneously each with irreplaceable biochemical reaction advantage.In order to give full play to the biological different advantage of two classes, generally sewage in sequential and is spatially experienced " anaerobism " and " aerobic " this two procedures the most respectively, biodegradable the most thoroughly in the hope of sewage disposal.
Because the difference of aerobic/anaerobic microbe survival condition and incompatible, carrying out two kinds of bioprocesss reactions?When transition and conversion, need the most in time or spatially environment to be carried out the condition segmentation conversion of aerobic/anaerobic, then conversion flora carrying out aerobic/anaerobic flora is cultivated again, this all will take and consume plenty of time and place, cause the low rate bottleneck that the time-consuming long floor space of sewage disposal biological method popularization and application is big, seriously constrain the popularization and application of dirty water living creature processing technique.
Water body in nature, especially impounded body, the most natural or artificial water body, the water body that especially eutrophic pollution is serious, it the most naturally presents anoxia to oxygen-enriched water layer from bottom, yes due to the water surface contact high air of oxygen content in oxygen-enriched state, and bottom biological activity oxygen depleted and in anaerobic condition.
By the upper and lower water body of manual agitation, it is possible to achieve this aerobic/anaerobic micropopulation alternating action, but device is expensive and power consumption.
The most existing Sewage Biological Treatment must arrange on space or sequential the technical vulnerability of the incompatible macro environment of aerobic/Anaerobe reaction, the present invention proposes a kind of technical method arranging the compatible micro environment of aerobic/anaerobic, automatically floated by anaerobe aerogenesis, nitrogen oxygen-enriched with water surface release is sunk, and the biological respinse that utilizes carrying out high-efficiency low energy consumption processes new departure of sewage.
Summary of the invention
It is an object of the invention to provide a kind of microbe carrier and the method for the formula pollution administration water body that drifts along of core shell structure, automatically floated by anaerobe aerogenesis, nitrogen oxygen-enriched with water surface release is sunk, the biological respinse that utilizes carrying out high-efficiency low energy consumption processes sewage, varying environment with bottom anaerobism oxygen-enriched for sewage water body upper strata, play the biologically advantage of aerobic/anaerobe respectively, it is achieved the sewage degradation treatment of high-efficiency low energy consumption.
The purpose of the present invention implements by the following technical programs:
A kind of microbe carrier of core shell structure, including shell body, core body and protection net, described shell body and described core body are porous microgap structure, described shell body cultivates implantation maturation process through aerobic microbiological, described core body cultivates implantation maturation process through anaerobe, described core body is placed among described shell body, and at one layer of described protection net of outside cladding of described shell body.
Further, several foamed plastic beads regulation proportion is put between described core body and described shell body, and ensure described core body and described shell body arranged concentric, also require that foamed plastic bead is evenly distributed between described core body and described shell body simultaneously.
Described shell body and described core body use clay,Activated carbonGranule, carbon fiber wire, organic fiber and inorfil silk are made.
Described inorfil silk includes any one in asbestos fibre silk, mineral fibres silk, glass fiber and carbon fiber wire;Preferably, described carbon fiber wire, organic fiber silk, inorfil silk diameter 10 microns-200 microns, length less than 10mm, the granularity of described activated carbon granule is between 30-200 mesh.
Wherein, described clay accounts for the 40% of volume parts, described activated carbon granule accounts for the 30% of volume parts, described organic fiber is preferably polyethylene fibre, accounts for the 15% of volume parts, and described inorfil silk accounts for the 15% of volume parts, carbon fiber wire in described inorfil silk accounts for the 10% of volume parts, and other inorfil silks account for the 5% of volume parts.
Described protection net uses any one of plastic wire, steel wire, aluminium alloy net or wire gauze.
A kind of manufacture method of the microbe carrier of described core shell structure, described shell body is divided into two half shells, the docking of two half shells form, two half shells of described shell body and described core body respectively by clay,Activated carbonGranule, carbon fiber wire raw material, organic fiber and inorfil silk mix through kneading; dry in the shade after being then punched into type, then carry out protective atmosphere sinter molding, control described organic fiber in sintering process, vaporize formation hole; and the carbonization when sintering of described carbon fiber wire raw material, is formedActivated carbonIntergranular carbon fiber wire passage;Two half shells of described shell body are cultivated implantation maturation process through aerobic microbiological, by described core body after anaerobe cultivates implantation maturation process, described core body is put in the shell body that two half shells fasten, and at one layer of protection net of outside cladding of described shell body.
Further, gap between described core body and described shell body is put into several foamed plastic beads regulation proportion, and ensure described core body and described shell body arranged concentric, also require that foamed plastic bead is evenly distributed between described core body and described shell body simultaneously.
Described organic fiber uses the organic fiber of low temperature volatilization, such as polyethylene kind fiber.
Described protection net uses any one of plastic wire, steel wire, aluminium alloy net or wire gauze.
Described clay accounts for the 40% of volume parts, and described activated carbon granule accounts for the 30% of volume parts, and described organic fiber is preferably polyethylene fibre, accounts for the 15% of volume parts, and described inorfil silk accounts for the 15% of volume parts.
A kind of method of the formula pollution administration water body that drifts along, in using at least, the carrier of outer two-layer porous microgap structure, the most externally-located porous microgap structure cultivates implantation maturation process through aerobic microbiological, internally positioned porous microgap structure cultivates implantation maturation process through anaerobe, make carrier when sinking to water bottom, during anaerobe digestion ammonia nitrogen produces nitrogen and remains in the porous microgap structure of carrier, the proportion of carrier reduces and upwards floats to the water surface, when carrier emerges, the aerobic bacteria of carrier outer layer starts the organic contamination composition clearing up in water body, the anaerobe simultaneously remaining in inside is in anaerobic environment;When carrier is kept afloat, the nitrogen in porous microgap structure outside carrier is discharged into the atmosphere, so that the porous microgap structure gradually water-filling of carrier, increases along with proportion and again sinks to water bottom, circulate with this.
Preferably, described carrier uses spherical structure, and the inside and outside two-layer porous microgap structure of carrier is also respectively adopted spherical structure.
Further, between inside and outside two-layer porous microgap structure, add several foamed plastic balls to regulate proportion, and ensure two-layer porous microgap structure arranged concentric, also require that foamed plastic bead is evenly distributed between two-layer porous microgap structure simultaneously.
Further, the outside in outer layer porous microgap structure is coated with one layer of protection net.
Described protection net uses any one of plastic wire, steel wire, aluminium alloy net or wire gauze.
Being thrown among pending sewage water body by the carrier made, sink to the anaerobe in the carrier of sewage water bottom and obtain optimum anaerobic environment, digestion ammonia nitrogen produces nitrogen, and carrier progressively floats up to the water surface along with the increase proportion of anaerobe production nitrogen alleviates.In the shell of carrier, the aerobic bacteria of implantation obtains suitable oxygen enriched environment condition, starts to clear up the work of water body organic contamination composition, and the anaerobic condition maintaining carrier inside protects anaerobic bacteria flora.When haydite spheroid is kept afloat, after the microgap of carrier outer surface touches air, the vapour lock that former water body tension force causes rapidly disappears, rapidly the nitrogen in carrier is discharged into the atmosphere, carrier is gradually filled with water by microgap, proportion increases and sinks under water, and thus starts next floating/heavy aerobic/anaerobic and clears up the circulation processing sewage.
The present invention discloses the microbe carrier of the core shell structure of a kind of inside and outside layering being made up of clay composite; make interior spheroid and shell body form suitable aerobic/anaerobic flora respectively and adhere to the microenvironment of existence the most respectively; and the mutual UNICOM of ectonexine is easy to mass transfer and aerofluxus, outer layer is coated with by protecting net.When the top and the bottom of sewage water body form aerobic/anaerobic environment respectively, put into the microbe carrier of core shell structure therein under the activity of internal anaerobic-aerobic flora, can be automatically at the upper and lower porpoising of water body, the organic matter of sewage composition that digestion is the most required respectively, realize the purpose that organic matter of sewage is cleared up, solve in traditional wastewater biological treatment process, owing to although facility cost, the operation energy consumption that the environmental condition of aerobic/anaerobic space-time is changed, the displacement of aerobic/anaerobic microbiologic population is caused is low, but the technical bottleneck restricted by low operational efficiency.
Accompanying drawing explanation
Below according toAccompanying drawingWith embodiment, the present invention is described in further detail.
Figure 1It it is the structural representation of the microbe carrier of core shell structure described in the embodiment of the present inventionFigure。
Figure 2It it is the structural representation of shell bodyFigure。
Detailed description of the invention
Embodiment one
Such as figure 1-2Shown in, the microbe carrier of a kind of core shell structure described in the embodiment of the present invention, including shell body 1, core body 2 and protection net 4, described shell body 1 and described core body 2 are porous microgap structure, described shell body 1 cultivates implantation maturation process through aerobic microbiological, described core body 2 cultivates implantation maturation process through anaerobe, described core body is placed among described shell body, and at one layer of described protection net 4 of outside cladding of described shell body 1, prevent from mutually touching between carrier and create and bad with the wiping clashing and breaking of limit wall.
Further, between described core body 2 and described shell body 1, put into several foamed plastic beads 3 regulate proportion, and ensure described core body and described shell body arranged concentric, also require that foamed plastic bead is evenly distributed between described core body and described shell body simultaneously.So design be advantageous in that, when carrier emerges, first the gas of upper carrier discharge, and the ratio causing upper carrier is great, so that the top that carrier releases gas deflects down, promote the gas of other parts to discharge.
Described shell body 1 and described core body 2 use clay,Activated carbonGranule, carbon fiber wire, organic fiber and inorfil silk are made.
Wherein, described clay accounts for the 40% of volume parts, as microorganism implantation base material and sphere structure and binding agent;
Described activated carbon granule accounts for the 30% of volume parts, adheres to bed for microorganism;
Described inorfil silk includes any one in asbestos fibre silk, mineral fibres silk, glass fiber and carbon fiber wire;Preferably, described carbon fiber wire, organic fiber silk, inorfil silk diameter 10 microns-200 microns, length less than 10mm, the granularity of described activated carbon granule is between 30-200 mesh.
Described organic fiber accounts for the 15% of volume parts, uses the organic fiber of low temperature volatilization, elects polyethylene kind fiber as so that it is when sintering, volatilization forms discharge duct, it is also possible to as sewage because of concentration difference mass transfer channel;
Described inorfil silk accounts for the 15% of volume parts, plays high temperature resistant, strengthens spherical shell effect, selects glass fibre, quartz glass fibre, boron fibre, ceramic fibre etc..
Carbon fiber wire in wherein said inorfil silk accounts for the 10% of volume parts, and carbon fiber wire raw material such as bamboo fibre is under sintering temperature, and it strengthens sphere structure effect, the carbonization when roasting, forms the carbon fiber wire passage between carbon granule, strengthens the restoring force of flora of the same race;Other inorfil silks account for the 5% of volume parts.
Described protection net uses any one of plastic wire, steel wire, aluminium alloy net or wire gauze.
Embodiment two
The manufacture method of the microbe carrier of core shell structure described in the present embodiment, described shell body is divided into two half shells, two half shell docking form, and when making two half shells, the edge of docking needs to make double buckle form so that fastening and cohering.
Two half shells of described shell body and described core body respectively by clay,Activated carbonGranule, carbon fiber wire raw material, organic fiber and inorfil silk mix through kneading, dry in the shade, then carry out protective atmosphere sinter molding after being then punched into type.
Two half shells of shell body and core body, because function difference, formula proportion is different.For shell body and core body, provide preferred formula proportion the most respectively.
Control described organic fiber in sintering process, vaporize formation hole, and the carbonization when sintering of described carbon fiber wire raw material, formedActivated carbonIntergranular carbon fiber wire passage;Two half shells of described shell body are cultivated implantation maturation process through aerobic microbiological, by described core body after anaerobe cultivates implantation maturation process, described core body is put in the shell body that two half shells fasten, and at one layer of protection net of outside cladding of described shell body, prevent from mutually touching between carrier and create and bad with the wiping clashing and breaking of limit wall.
Further, gap between described core body and described shell body is put into several foamed plastic beads regulation proportion, and ensure described core body and described shell body arranged concentric, also require that foamed plastic bead is evenly distributed between described core body and described shell body simultaneously.So design be advantageous in that, when carrier emerges, first the gas of upper carrier discharge, and the ratio causing upper carrier is great, so that the top that carrier releases gas deflects down, promote the gas of other parts to discharge.
Described organic fiber uses the organic fiber of low temperature volatilization, such as polyethylene kind fiber.
Described protection net uses any one of plastic wire, steel wire, aluminium alloy net or wire gauze.
Described clay accounts for the 40% of volume parts, described activated carbon granule accounts for the 30% of volume parts, described organic fiber is preferably polyethylene fibre, account for the 15% of volume parts, described inorfil silk accounts for the 15% of volume parts, in described inorfil silk, carbon fiber wire accounts for the 10% of volume parts, and other inorfil silks account for the 5% of volume fraction.
Embodiment three
The method of formula of drifting along described in the present embodiment pollution administration water body, in using at least, the carrier of outer two-layer porous microgap structure, the most externally-located porous microgap structure cultivates implantation maturation process through aerobic microbiological, internally positioned porous microgap structure cultivates implantation maturation process through anaerobe, make carrier when sinking to water bottom, during anaerobe digestion ammonia nitrogen produces nitrogen and remains in the porous microgap structure of carrier, the proportion of carrier reduces and upwards floats to the water surface, when carrier emerges, the aerobic bacteria of carrier outer layer starts the organic contamination composition clearing up in water body, the anaerobe simultaneously remaining in inside is in anaerobic environment;When carrier is kept afloat, the nitrogen in porous microgap structure outside carrier is discharged into the atmosphere, so that the porous microgap structure gradually water-filling of carrier, increases along with proportion and again sinks to water bottom, circulate with this.
Preferably, described carrier uses spherical structure, and the inside and outside two-layer porous microgap structure of carrier is also respectively adopted spherical structure.
Further, between inside and outside two-layer porous microgap structure, add several foamed plastic balls to regulate proportion, and ensure two-layer porous microgap structure arranged concentric, also require that foamed plastic bead is evenly distributed between two-layer porous microgap structure simultaneously.
Further, the outside in outer layer porous microgap structure is coated with one layer of protection net.
Described protection net uses any one of plastic wire, steel wire, aluminium alloy net or wire gauze.
Being thrown among pending sewage water body by the carrier made, sink to the anaerobe in the carrier of sewage water bottom and obtain optimum anaerobic environment, digestion ammonia nitrogen produces nitrogen, and carrier progressively floats up to the water surface along with the increase proportion of anaerobe production nitrogen alleviates.In the shell of carrier, the aerobic bacteria of implantation obtains suitable oxygen enriched environment condition, starts to clear up the work of water body organic contamination composition, and the anaerobic condition maintaining carrier inside protects anaerobic bacteria flora.When haydite spheroid is kept afloat, after the microgap of carrier outer surface touches air, the vapour lock that former water body tension force causes rapidly disappears, rapidly the nitrogen in carrier is discharged into the atmosphere, carrier is gradually filled with water by microgap, proportion increases and sinks under water, and thus starts next floating/heavy aerobic/anaerobic and clears up the circulation processing sewage.
The present invention discloses the microbe carrier of the core shell structure of a kind of inside and outside layering being made up of clay composite; make interior spheroid and shell body form suitable aerobic/anaerobic flora respectively and adhere to the microenvironment of existence the most respectively; and the mutual UNICOM of ectonexine is easy to mass transfer and aerofluxus, outer layer is coated with by protecting net.When the top and the bottom of sewage water body form aerobic/anaerobic environment respectively, put into the microbe carrier of core shell structure therein under the activity of internal anaerobic-aerobic flora, can be automatically at the upper and lower porpoising of water body, the organic matter of sewage composition that digestion is the most required respectively, realize the purpose that organic matter of sewage is cleared up, solve in traditional wastewater biological treatment process, owing to although facility cost, the operation energy consumption that the environmental condition of aerobic/anaerobic space-time is changed, the displacement of aerobic/anaerobic microbiologic population is caused is low, but the technical bottleneck restricted by low operational efficiency.
Claims (12)
1. the microbe carrier of a core shell structure, it is characterized in that, including shell body, core body and protection net, described shell body and described core body are porous microgap structure, described shell body cultivates implantation maturation process through aerobic microbiological, described core body cultivates implantation maturation process through anaerobe, and described core body is placed among described shell body, and at one layer of described protection net of outside cladding of described shell body.
The most such asClaimThe microbe carrier of a kind of core shell structure described in 1, it is characterized in that, several foamed plastic beads regulation proportion is put between described core body and described shell body, and ensure described core body and described shell body arranged concentric, also require that foamed plastic bead is evenly distributed between described core body and described shell body simultaneously.
The most such asClaimThe microbe carrier of a kind of core shell structure described in 1 or 2, it is characterised in that described shell body and described core body all use clay,Activated carbonGranule, organic fiber silk and inorfil silk are made.
The most such asClaimThe microbe carrier of a kind of core shell structure described in 3, it is characterised in that described inorfil silk includes any one in asbestos fibre silk, mineral fibres silk, glass fiber and carbon fiber wire;Preferably, described carbon fiber wire, organic fiber silk, inorfil silk diameter 10 microns-200 microns, length less than 10mm, the granularity of described activated carbon granule is between 30-200 mesh.
The most such asClaimThe microbe carrier of a kind of core shell structure described in 4, it is characterized in that, wherein, described clay accounts for the 40% of volume parts, and described activated carbon granule accounts for the 30% of volume parts, described organic fiber silk uses the organic fiber of low temperature volatilization, being preferably polyethylene fibre, account for the 15% of volume parts, described inorfil silk accounts for the 15% of volume parts, carbon fiber wire in described inorfil silk accounts for the 10% of volume parts, and other inorfil silks account for the 5% of volume parts.
The most such asClaimThe microbe carrier of a kind of core shell structure described in 1, it is characterised in that described protection net uses any one of plastic wire, steel wire, aluminium alloy net or wire gauze.
7. one kindClaimThe manufacture method of the microbe carrier of the described core shell structure of one of 1-6, it is characterised in that described shell body is divided into two half shells, is formed by the docking of two half shells, two half shells of described shell body and described core body respectively by clay,Activated carbonGranule, organic fiber silk and inorfil silk mix through kneading, and wherein, described inorfil silk includes any one in asbestos fibre silk, mineral fibres silk, glass fiber and carbon fiber wire;Dry in the shade after being then punched into type, then in protective atmosphere, be sintered molding, control described organic fiber silk in sintering process, vaporize formation hole, and the carbonization when sintering of described carbon fiber wire raw material, formedActivated carbonIntergranular carbon fiber wire passage;Two half shells of described shell body are cultivated implantation maturation process through aerobic microbiological, by described core body after anaerobe cultivates implantation maturation process, described core body is put in the shell body that two half shells fasten, and at one layer of protection net of outside cladding of described shell body.
8. the method for the formula pollution administration water body that drifts along, it is characterized in that, in using at least, the carrier of outer two-layer porous microgap structure, the most externally-located porous microgap structure cultivates implantation maturation process through aerobic microbiological, internally positioned porous microgap structure cultivates implantation maturation process through anaerobe, make carrier when sinking to water bottom, during anaerobe digestion ammonia nitrogen produces nitrogen and remains in the porous microgap structure of carrier, the proportion of carrier reduces and upwards floats to the water surface, when carrier emerges, the aerobic bacteria of carrier outer layer starts the organic contamination composition clearing up in water body, the anaerobe simultaneously remaining in inside is in anaerobic environment;When carrier is kept afloat, the nitrogen in porous microgap structure outside carrier is discharged into the atmosphere, so that the porous microgap structure gradually water-filling of carrier, increases along with proportion and again sinks to water bottom, circulate with this.
The most such asClaimMethod described in 6, it is characterised in that described carrier uses spherical structure, and the inside and outside two-layer porous microgap structure of carrier is also respectively adopted spherical structure.
The most such asClaimMethod described in 6, it is characterized in that, between inside and outside two-layer porous microgap structure, add several foamed plastic balls to regulate proportion, and ensure two-layer porous microgap structure arranged concentric, also require that foamed plastic bead is evenly distributed between two-layer porous microgap structure simultaneously.
11. such asClaimMethod described in 6, it is characterised in that be coated with one layer of protection net in the outside of outer layer porous microgap structure.
12. such asClaimMethod described in 6, it is characterised in that described protection net uses any one of plastic wire, steel wire, aluminium alloy net or wire gauze.
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