CN105866054A - Apparatus and method for remote monitoring of gas in coal mine - Google Patents
Apparatus and method for remote monitoring of gas in coal mine Download PDFInfo
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- CN105866054A CN105866054A CN201610157941.5A CN201610157941A CN105866054A CN 105866054 A CN105866054 A CN 105866054A CN 201610157941 A CN201610157941 A CN 201610157941A CN 105866054 A CN105866054 A CN 105866054A
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- 238000000034 method Methods 0.000 title claims abstract description 34
- 239000003245 coal Substances 0.000 title claims abstract description 22
- 238000012544 monitoring process Methods 0.000 title claims abstract description 22
- DMLAVOWQYNRWNQ-UHFFFAOYSA-N azobenzene Chemical compound C1=CC=CC=C1N=NC1=CC=CC=C1 DMLAVOWQYNRWNQ-UHFFFAOYSA-N 0.000 claims abstract description 46
- 230000003287 optical effect Effects 0.000 claims abstract description 17
- 238000010183 spectrum analysis Methods 0.000 claims abstract description 8
- 239000013307 optical fiber Substances 0.000 claims abstract description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 82
- 239000010408 film Substances 0.000 claims description 42
- 238000001228 spectrum Methods 0.000 claims description 21
- 230000003595 spectral effect Effects 0.000 claims description 16
- 230000003750 conditioning effect Effects 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 14
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
- 230000008859 change Effects 0.000 claims description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
- 238000005070 sampling Methods 0.000 claims description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 2
- 238000004611 spectroscopical analysis Methods 0.000 claims description 2
- 239000010409 thin film Substances 0.000 claims description 2
- 238000012545 processing Methods 0.000 abstract description 7
- 239000007789 gas Substances 0.000 description 59
- 206010067171 Regurgitation Diseases 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- 238000002329 infrared spectrum Methods 0.000 description 3
- 238000004566 IR spectroscopy Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 238000005305 interferometry Methods 0.000 description 2
- DMLAVOWQYNRWNQ-YPKPFQOOSA-N (Z)-azobenzene Chemical compound C1=CC=CC=C1\N=N/C1=CC=CC=C1 DMLAVOWQYNRWNQ-YPKPFQOOSA-N 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000007084 catalytic combustion reaction Methods 0.000 description 1
- 230000008876 conformational transition Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000012806 monitoring device Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3504—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
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- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
The invention discloses an apparatus and method for remote monitoring of gas in a coal mine. The apparatus comprises a transparent gas pump, a flexible raster, a light source generation unit and a signal acquisition and processing unit, wherein the transparent gas pump and the flexible raster are arranged in the mine and can be driven by light; the light source generation unit and the signal acquisition and processing unit are arranged out of the mine; light generated by the light source generation unit irradiates onto the transparent gas pump and the flexible raster through an optical cable; the light source generation unit is connected with the signal acquisition and processing unit; the flexible raster is connected with the signal acquisition and processing unit through another optical cable; a non-return valve is arranged on the top of the transparent gas pump, and the bottom of the transparent gas pump is provided with an organic film I containing azobenzene luminophor; and the lower end of the flexible raster is provided with an organic film II containing azobenzene luminophor. According to the invention, the light source generation unit out of the mine is connected with the transparent gas pump and the flexible raster in the mine through the optical fiber, so the apparatus and method can carry out all-optical low-cost remote spectral analysis on gas and realizes real-time on-line monitoring of a plurality of components of gas; and since the mine is free of any electronic component, security in monitoring gas is improved.
Description
Technical field
The invention belongs to Mine Safety Appliances technical field, relate to device that a kind of coal mine gas remotely monitors and
Monitoring method, is specifically related to what a kind of coal mine gas based on optical drive flexibility grating and flexible pump was remotely monitored
Device and method.
Background technology
In progress of coal mining, gas safety has become the significant obstacle limiting coal mine output.Therefore, may be used
Lean on, accurately, quickly, low cost, in real time methane gas concentration is monitored and early warning, to the most pre-
Anti-mine gas accident is most important.
The main method being presently used for monitoring methane gas (about 83%~89% is methane gas) concentration has:
Production by Catalytic Combustion Process, Semiconductor gas sensors method, optical interferometry, gas chromatography and infrared spectrometry etc..Quasiconductor
In air-sensitive method, sensing element is easily subject to the interference such as noise, toxic gas, and accuracy is relatively low, and needs knot
Close other monitoring device to be monitored;Optical interferometry concentration index intuitively, is not stressed, temperature, humidity etc.
Substantially, the impact being especially vulnerable to the interference of other gas is serious in interference;The operating temperature of gas chromatography is high, steady
Qualitative poor with concordance, instrument is heavier, it is difficult to realize real-time, on-line checking, and actual application is hindered
Hinder;Thermocatalysis principle monitoring gas, because it is cheap, it is easy to colliery large area uses, and applies more,
But its monitoring composition is single, and early warning function is the most not enough, needs often to correct zeroing, service life
Short, and be not suitable for high concentration gas safety detection etc..Existing technology still can not fully meet present coalman
The industry demand to early warning and alarming highly sensitive, intelligent.
The feature of infrared spectrometry is to measure wide ranges, accuracy of detection height, capacity of resisting disturbance by force, can be remote
Remote measurement, compares additive method with the obvious advantage.But it is the most based on " single line spectrum " measuring principle, it is impossible to right
Gas multiple components is monitored simultaneously, and there is the potential safety hazard such as short circuit, electric discharge at gas surveying,
Device is expensive, and system is complex, it is difficult to realize at sensor side without electronic device, low cost watt
This multiple components spectrum analysis, hinders its popularization and application.
Summary of the invention
For the defect overcoming above-mentioned prior art to exist, it is an object of the invention to provide a kind of coal mine gas
The remotely device of monitoring and monitoring method, this apparatus structure is reasonable in design, simple to operate, by this device and
Method is capable of methane gas concentration carries out reliable, accurate, quick, the real-time monitoring of low cost.
The present invention is to be achieved through the following technical solutions:
The device that a kind of coal mine gas is remotely monitored, including being arranged in mine and can saturating by optical drive
Bright air pump and flexible grating;Also include light source generation and the signal acquisition process list being arranged on outside mine
Unit, the light that light source generation sends is irradiated to transparent air pump and flexible grating by optical cable, and light source occurs single
Unit is mutual with signal acquisition process unit, and flexible grating is connected with signal acquisition process unit by optical cable;
It is provided with check valve at the top of transparent air pump, is organic thin containing diphenyl diimide illuminophore bottom transparent air pump
Film I;Flexible grating lower end is provided with the organic film II containing diphenyl diimide illuminophore.
Described light source generation includes wide spectrum infrared light supply, the first ultraviolet source, the first visible ray light
Source, the second ultraviolet source and the second visible light source;Wherein, the light that wide spectrum infrared light supply sends passes through
The light that fiber-optic illuminated transparent air pump, the first ultraviolet source and the first visible light source send is by fiber-optic illuminated
The organic film I containing diphenyl diimide illuminophore bottom transparent air pump;Second ultraviolet source and the second visible ray
The light that light source sends is by the organic film II containing diphenyl diimide illuminophore of fiber-optic illuminated flexible grating lower end.
After the light that wide spectrum infrared light supply sends passes through fiber-optic illuminated to transparent air pump, then it is incident upon flexible grating
On.
When the first ultraviolet source or the first visible light source pass through containing occasionally bottom fiber-optic illuminated transparent air pump
During the organic film I of pyridine illuminophore, the organic film I of diphenyl diimide illuminophore deforms upon.
The light sent when the second ultraviolet source and the second visible light source passes through under fiber-optic illuminated flexible grating
During the organic film II containing diphenyl diimide illuminophore held, there is shape in the organic film II containing diphenyl diimide illuminophore
Become.
Described signal acquisition process unit includes that computer, detector and signal conditioning circuit, flexible grating lead to
Cross cable to be connected with the input of detector, the input phase of the outfan of detector and signal conditioning circuit
Even, the outfan of signal conditioning circuit is connected with computer.
Organic film II containing diphenyl diimide illuminophore is fixed on flexible grating lower end by fixture.
The invention also discloses the side that the device remotely monitored based on above-mentioned coal mine gas is remotely monitored
Method, comprises the following steps:
1) open wide spectrum infrared light supply, make the light sent irradiate flexible air pump;
2) open the first ultraviolet source or the first visible light source, irradiate bottom transparent air pump containing azo
The organic film I of benzene illuminophore, the organic film I containing diphenyl diimide illuminophore deform upon, and transparent air pump is inhaled
Enter the methane gas to be measured in mine, methane gas to be measured is carried out real-time sampling;
3), after methane gas to be measured absorbs the light that wide spectrum infrared light supply sends, the second ultraviolet source is opened
Or second visible light source, irradiate flexible grating lower end and be provided with the organic film II containing diphenyl diimide illuminophore, contain
The organic film II of diphenyl diimide illuminophore deforms upon, flexible grating pitch change, obtains methane gas to be measured
The spectral information of multiple components;
4) spectral information of methane gas multiple components to be measured is delivered to signal by optical fiber and adopts by flexible grating
Collection processing unit, it is achieved monitoring and the multiple components spectrum analysis in real time of methane gas to be measured.
The spectral information of flexible grating output is delivered to computer by detector and signal conditioning circuit, calculates
Obtain spectroscopic data.
Compared with prior art, the present invention has a following useful technique effect:
The device that coal mine gas disclosed by the invention is remotely monitored, including being arranged in mine and can be by light
The transparent air pump driven and flexible grating;Also include light source generation and the signals collecting being arranged on outside mine
Processing unit, is provided with check valve at the top of transparent air pump, is containing diphenyl diimide illuminophore bottom transparent air pump
Organic film I, flexible grating lower end is provided with the organic film II containing diphenyl diimide illuminophore, utilizes diphenyl diimide to send out
The photic suitable regurgitation structure of light blob, it is possible to make the organic film I containing diphenyl diimide illuminophore deform, thus
Make transparent air pump deform upon, suck methane gas to be measured, the illumination of light can be sent by regulation light source strong
Degree, time, control the deformation of transparent air pump.In like manner, the photic along regurgitation structure of diphenyl diimide illuminophore is utilized
Property, it is possible to make the organic film II containing diphenyl diimide illuminophore deform, make the pitch of flexible grating also occur
Change, it is possible to export the accurate spectral information of methane gas multiple components to be measured.The present invention passes through optical fiber by ore deposit
The outer light source generation air pump transparent with in mine of well and flexible grating are connected, it is possible to carry out methane gas
Full-optical, the long-range spectrum analysis of low cost, it is achieved real-time, the on-line monitoring to gas multiple components, ore deposit
Without the existence of electronic component in well, thus improve the safety of methane gas monitoring.
Disclosed by the invention carrying out the method that coal mine gas is remotely monitored based on said apparatus, broad spectrum light source is sent out
The light gone out irradiates transparent air pump, utilizes the photic method deformed along regurgitation structure of diphenyl diimide illuminophore,
The combination of two ultraviolet sources and visible light source drive respectively transparent air pump and the deformation of flexible grating and
Pitch changes, the wide spectral light after methane gas to be measured absorbs, and is changed by the pitch of flexible grating, obtains
Obtain the absorption spectrum of methane gas to be measured, the method using infrared spectrum analysis, determine methane gas concentration
And monitor the multiple components of methane gas.Owing to wide spectral light, ultraviolet light, visible ray all pass through fiber-optic transfer
In mine, by controlling the pitch of the flexible grating of the accurately regulation such as the intensity of illumination of ultraviolet light, time, and
Utilize infrared spectrum analysis methane gas to be measured, without the existence of electronic component in mine, thus improve gas
The safety of gas-monitoring, it is achieved that real-time, the Full-optical of the non-single composition of methane gas, remotely monitor.
Accompanying drawing explanation
Fig. 1 is the device that the coal mine gas based on optical drive flexibility grating and flexible pump of the present invention is remotely monitored
Schematic diagram;
Fig. 2 is the structural principle schematic diagram of transparent air pump;Wherein, (a) is the first ultraviolet light and first visible
When light is all not switched on, air pump is original state;B () is that the first ultraviolet light is opened, the first visible ray is not switched on,
Air pump sucks methane gas to be measured;C () is that the first ultraviolet light is closed, the first visible ray is opened, and air pump recovers
For original state;
Fig. 3 is the structural principle schematic diagram of flexible grating, and wherein, (a) is the second ultraviolet light and second visible
When light is all not switched on, flexible grating is initial pitch and seam width;B () is that the second ultraviolet light is opened, second can
Seeing that light is not switched on, pitch and the seam width of flexible grating become big;C () is that the second ultraviolet light is closed, second is visible
Light is opened, and flexible grating reverts to initial pitch and seam width.
Wherein, 1 is computer;2 is wide spectrum infrared light supply;3 is transparent air pump;4 is gas to be measured
Gas;5 is the first ultraviolet source;6 is the first visible light source;7 is the second ultraviolet source;8 are
Second visible light source;9 is flexible grating;10 is detector;11 is signal conditioning circuit, and 12 are
Check valve, 13 is the organic film I containing diphenyl diimide illuminophore, and 14 is fixture, and 15 for send out containing diphenyl diimide
The organic film II of light blob.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail, described in the present invention
Explain rather than limit.
As it is shown in figure 1, in including being arranged on mine and can be by the transparent air pump 3 of optical drive and flexible light
Grid 9;Also including light source generation and the signal acquisition process unit being arranged on outside mine, light source occurs single
The light that unit sends is irradiated to transparent air pump 3 and flexible grating 9 by optical cable, and light source generation is adopted with signal
Collection processing unit is mutual, and flexible grating 9 is connected with signal acquisition process unit by optical cable;
It is provided with check valve 12 at the top of transparent air pump 3, is containing diphenyl diimide illuminophore bottom transparent air pump 3
Organic film I13;Flexible grating 9 lower end is provided with the organic film II15 containing diphenyl diimide illuminophore.
Described light source generation includes that wide spectrum infrared light supply the 2, first ultraviolet source 5, first is visible
Radiant the 6, second ultraviolet source 7 and the second visible light source 8;Wherein, wide spectrum infrared light supply 2
The light sent passes through fiber-optic illuminated transparent air pump 3, the first ultraviolet source 5 and the first visible light source 6
The light gone out is by the organic film I13 containing diphenyl diimide illuminophore bottom fiber-optic illuminated transparent air pump 3;Second
The light that ultraviolet source 7 and the second visible light source 8 send is contained by fiber-optic illuminated flexible grating 9 lower end
The organic film II15 of diphenyl diimide illuminophore.
Described signal acquisition process unit includes computer 1, detector 10 and signal conditioning circuit 11, soft
Property grating 9 be connected with the input of detector 10 by cable, the outfan of detector 10 and signal condition
The input of circuit 11 is connected, and the outfan of signal conditioning circuit 11 is connected with computer 1.
Computer 1 is connected with wide spectrum infrared light supply 2, the light that the wide spectrum infrared light supply 2 outside mine sends
By the transparent air pump 3 in fiber-optic illuminated mine, computer 1 with mine outside the first ultraviolet source 5,
First visible light source 6 is connected, and check valve 12 is connected with transparent air pump 3, opens the first ultraviolet source 5,
The light that first ultraviolet source 5 sends passes through fiber-optic illuminated transparent air pump 3 in mine, sends out containing diphenyl diimide
The organic film I 13 of light blob deforms, and methane gas 4 to be measured enters transparent air pump by check valve 12
3, to close the first ultraviolet source 5, open the first visible light source 6, transparent air pump 3 recovers original shape
Shape, methane gas 4 to be measured of sampling.
Computer 1 with mine outside second ultraviolet source the 7, second visible light source 8 be connected, open
Two ultraviolet sources 7, the light that the second ultraviolet source 8 sends passes through fiber-optic illuminated flexible light in mine
Grid 9, organic film II 15 two ends containing diphenyl diimide illuminophore use fixture 14 to fix, send out containing diphenyl diimide
The conformation transition of diphenyl diimide one's share of expenses for a joint undertaking in the organic film II 15 of light blob, orderly Azobenzene mesogen becomes
Unordered, thus deform, the pitch of flexible grating 9 changes, and closes the second ultraviolet source 7,
Opening the second visible light source 8, the cis-azobenzene in the organic film II 15 containing diphenyl diimide illuminophore recovers
To transoid conformation, flexible grating 9 recovers original screen periods, flexible grating 9 outfan in mine with
Detector 10 input outside mine is connected, and is connected with computer 1 through signal conditioning circuit 11.
The method that the device remotely monitored based on coal mine gas disclosed above is remotely monitored, with wide spectrum
Infrared light supply irradiates in transparent air pump as the light source of spectrum analysis, the light using wide spectrum infrared light supply to send
Methane gas to be measured.Then, the first ultraviolet source and the first visible light source, as driving light source, drive
Dynamic transparent air pump, sends the intensity of illumination of light, time by regulation light source, controls optical drive flexible pump
Deformation.Second ultraviolet source and the second visible light source, as driving light source, drive flexible grating, pass through
Regulation " driving light intensity ", it is achieved the continuous of flexible grating pitch changes and accurately control.Finally, flexible light
The spectral information of grid output sends into computer by detector and signal conditioning circuit, thus calculates spectrum number
According to, it is achieved the spectrum analysis of methane gas multiple components to be measured and in real time monitoring.
Specifically include following steps:
1) open wide spectrum infrared light supply 2, make the light sent irradiate flexible air pump 3;
2) open the first ultraviolet source 5 or the first visible light source 6, irradiate containing bottom transparent air pump 3
The organic film I 13 of diphenyl diimide illuminophore, the organic film I 13 containing diphenyl diimide illuminophore deform upon, thoroughly
Bright air pump 3 sucks the methane gas to be measured 4 in mine, and methane gas to be measured is carried out real-time sampling;
3), after methane gas 4 to be measured absorbs the light that wide spectrum infrared light supply 2 sends, the second ultraviolet light is opened
Light source 7 or the second visible light source 8, irradiate that flexible grating 9 lower end is provided with containing diphenyl diimide illuminophore is organic
Thin film II15, the organic film II15 containing diphenyl diimide illuminophore deform upon, flexible grating 9 pitch change,
Obtain the spectral information of methane gas multiple components to be measured;
4) spectral information of methane gas multiple components to be measured is delivered to signal by optical fiber by flexible grating 9
Acquisition process unit, it is achieved monitoring and the multiple components spectrum analysis in real time of methane gas to be measured.
Seeing Fig. 2, wherein, (a) is the first ultraviolet light and time the first visible ray is all not switched on, and air pump is just
Beginning state;B () is that the first ultraviolet light is opened, the first visible ray is not switched on, and air pump sucks methane gas to be measured;
C () is that the first ultraviolet light is closed, the first visible ray is opened, and air pump reverts to original state.Wide spectral light
The methane gas to be measured 4 in transparent air pump 3 is irradiated in source 2, and wide spectral light absorbs through methane gas 4 to be measured,
First ultraviolet source 5 and the first visible light source 6 drive optical drive flexible pump 3.See Fig. 3, wherein,
A () is the second ultraviolet light and time the second visible ray is all not switched on, flexible grating is initial pitch and seam width;(b)
Being that the second ultraviolet light is opened, the second visible ray is not switched on, and pitch and the seam width of flexible grating become big;(c) be
Second ultraviolet light is closed, and the second visible ray is opened, and flexible grating reverts to initial pitch and seam width.Second is purple
The flexible grating 9 that outer radiant 7 and the second visible light source 8 send, flexible grating 9 transmits gas to be measured
Gas 4 absorb after the spectral information of wide spectral light to detector 10,10 corresponding signals of detector,
Being transferred to computer 1 through signal conditioning circuit 11, by computer 1 infrared spectrum analysis, monitoring in real time is treated
Survey the multiple components of methane gas 4.
With the above-mentioned desirable embodiment according to the present invention for enlightenment, by above-mentioned description, related work
Personnel can be carried out various change and repair completely in the range of without departing from this invention technological thought
Change.The content that the technical scope of this invention is not limited in description, it is necessary to according to claim
Scope determines its technical scope.
Claims (9)
1. the device that a coal mine gas is remotely monitored, it is characterised in that in including being arranged on mine and
Can be by the transparent air pump (3) of optical drive and flexible grating (9);Also include the light source being arranged on outside mine
Generating unit and signal acquisition process unit, the light that light source generation sends is irradiated to transparent gas by optical cable
Pump (3) and flexible grating (9), light source generation is connected with signal acquisition process unit, flexible grating
(9) it is connected with signal acquisition process unit by optical cable;
Be provided with check valve (12) at the top of transparent air pump (3), transparent air pump (3) bottom is containing azo
The organic film I (13) of benzene illuminophore;It is organic that flexible grating (9) lower end is provided with containing diphenyl diimide illuminophore
Thin film II (15).
The device that coal mine gas the most according to claim 1 is remotely monitored, it is characterised in that described
Light source generation includes wide spectrum infrared light supply (2), the first ultraviolet source (5), the first visible ray light
Source (6), the second ultraviolet source (7) and the second visible light source (8);Wherein, wide spectrum infrared light
The light that source (2) sends passes through fiber-optic illuminated transparent air pump (3), and the first ultraviolet source (5) and first can
See light that radiant (6) sends by fiber-optic illuminated transparent air pump (3) bottom containing diphenyl diimide illuminophore
Organic film I (13);The light that second ultraviolet source (7) and the second visible light source (8) send passes through
The organic film II (15) containing diphenyl diimide illuminophore of fiber-optic illuminated flexible grating (9) lower end.
The device that coal mine gas the most according to claim 2 is remotely monitored, it is characterised in that wide light
After the light that spectrum infrared light supply (2) sends passes through fiber-optic illuminated to transparent air pump (3), then it is incident upon flexible grating
(9) on.
The device that coal mine gas the most according to claim 2 is remotely monitored, it is characterised in that when
One ultraviolet source (5) or the first visible light source (6) are by fiber-optic illuminated transparent air pump (3) bottom
Organic film I (13) containing diphenyl diimide illuminophore time, the organic film I (13) of diphenyl diimide illuminophore send out
Raw deformation.
The device that coal mine gas the most according to claim 2 is remotely monitored, it is characterised in that when
The light that two ultraviolet sources (7) and the second visible light source (8) send is by fiber-optic illuminated flexible grating (9)
During organic film II (15) containing diphenyl diimide illuminophore of lower end, the organic film II containing diphenyl diimide illuminophore
(15) deform upon.
The device that coal mine gas the most according to claim 1 is remotely monitored, it is characterised in that described
Signal acquisition process unit includes computer (1), detector (10) and signal conditioning circuit (11), soft
Property grating (9) be connected with the input of detector (10) by cable, the outfan of detector (10)
It is connected with the input of signal conditioning circuit (11), the outfan of signal conditioning circuit (11) and computer
(1) it is connected.
The device that coal mine gas the most according to claim 1 is remotely monitored, it is characterised in that containing even
The organic film II (15) of pyridine illuminophore is fixed on flexible grating (9) lower end by fixture (14).
8. the device remotely monitored based on the coal mine gas described in any one in claim 2~7 is carried out far
The method of journey monitoring, it is characterised in that comprise the following steps:
1) open wide spectrum infrared light supply (2), make the light sent irradiate flexible air pump (3);
2) open the first ultraviolet source (5) or the first visible light source (6), irradiate transparent air pump (3)
The organic film I (13) containing diphenyl diimide illuminophore, the organic film I (13) containing diphenyl diimide illuminophore of bottom
Deforming upon, transparent air pump (3) sucks the methane gas to be measured (4) in mine, to methane gas to be measured
Carry out real-time sampling;
3), after methane gas to be measured (4) absorbs the light that wide spectrum infrared light supply (2) sends, second is opened
Ultraviolet source (7) or the second visible light source (8), irradiate flexible grating (9) lower end and be provided with containing azo
The organic film II (15) of benzene illuminophore, the organic film II (15) containing diphenyl diimide illuminophore deform upon,
Flexible grating (9) pitch change, obtains the spectral information of methane gas multiple components to be measured;
4) spectral information of methane gas multiple components to be measured is delivered to letter by optical fiber by flexible grating (9)
Number acquisition process unit, it is achieved monitoring and the multiple components spectrum analysis in real time of methane gas to be measured.
The method of long-range monitoring the most according to claim 8, it is characterised in that flexible grating (9)
The spectral information of output is delivered to computer (1) by detector (10) and signal conditioning circuit (11),
It is calculated spectroscopic data.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106989965A (en) * | 2017-06-09 | 2017-07-28 | 辽宁工程技术大学 | A kind of coal mine underground gas sampling apparatus and method |
CN112304891A (en) * | 2020-10-14 | 2021-02-02 | 西安工程大学 | System for detecting gas by adopting flexible grating and detection method thereof |
Citations (6)
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