CN105837990A - Anti-microbial superfine fully-vulcanized powdered rubber and polyvinyl chloride composite water pipe and preparation method thereof - Google Patents
Anti-microbial superfine fully-vulcanized powdered rubber and polyvinyl chloride composite water pipe and preparation method thereof Download PDFInfo
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- CN105837990A CN105837990A CN201610325334.5A CN201610325334A CN105837990A CN 105837990 A CN105837990 A CN 105837990A CN 201610325334 A CN201610325334 A CN 201610325334A CN 105837990 A CN105837990 A CN 105837990A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses an anti-microbial superfine fully-vulcanized powdered rubber and polyvinyl chloride composite water pipe. The water pipe is prepared from, by weight, 29-30 parts of superfine fully-vulcanized powdered rubber, 68-70 parts of PVCSG-3, 2-2.3 parts of zinc oxide nano-wires, 3-3.2 parts of cerium nitrate, 70-80 parts of deionized water, 1.6-1.8 parts of butyl acrylate, 0.2-0.3 part of ammonium persulphate, 2.3-2.5 parts of graphene oxide, 0.8-1 part of nano-cuprous oxide, 0.8-1 part of asphalt, 2.6-2.8 parts of dodecafluoroheptyl-propyl-trimethoxysilane, 60-70 parts of ethyl alcohol and 15-16 parts of ammonium hydroxide. According to the water pipe, graphene oxide and nano-cuprous oxide are mixed and stirred for 20-30 min at 2-2.5 MPa, so that the surface of graphene oxide is loaded with nano-cuprous oxide, and a good anti-microbial effect is achieved; then, asphalt is added, so that the cohesiveness of graphene oxide, nano-cuprous oxide and PVC is improved.
Description
Technical field
The present invention relates to PVC water pipe technical field, particularly relate to a kind of antibiotic ultra-fine fully vulcanized powder rubber polrvinyl chloride
Composite water pipe and preparation method thereof.
Background technology
Pressure feed water plastic pipe should have high intensity and high tenacity simultaneously.RPVC (PVC-U) feed pipe
Material toughness is not enough, easy booster under the effect of external condition, and the mechanical property improving PVC-U material is to improve product to use the longevity
The effective way of life." the ultra-fine fully vulcanized powder rubber study on the modification to RPVC " literary composition actual is asked for this
Topic, from toughness reinforcing, the basic ideas of Reinforced PVC-U material property, uses high model resin extruded PVC-U feed pipe first
Material, uses full sulfuration ultra fine powder rubber blending and modifying PVC-U material first, has inquired into micro-cross-linking agent chemical modification PVC-U material
The effect of material.By test PVC-U system mechanical property, observe blending modification system microstructure, obtain following mainly
Conclusion: 1. by contrast experiment, draw SG-3 resin or SG-3 with SG-5 resin with certain proportion mix ratio individually with SG-5 tree
Fat material property is more preferable, is suitable for producing feedwater piping, has been used for actual production.2. at FWR-Z, SMS318, Ca-Zn with organic
In four kinds of stabilizers of stannum, FWR-Z stabilizer performance is worst.Water-feeding pipes should use organotin, Ca-Zn, SMS-318 stabilizer.Pipe
Part stabilizer cannot be used for producing tubing, jelly grade too much can be made because of in-lubricant excessive, affect the mechanical properties.3. at this
Under the experimental condition of literary composition, the effect that three kinds of full sulfuration micropowder art rubber improves the impact strength of PVC system is different, powder fourth
Nitrile rubber is better than acrylate rubber, and acrylate rubber is better than carboxy terminated nitrile rubber.When powdered rubber content is below 5 parts,
The impact strength of co-mixing system rises after falling before.When PNBR is 3 parts, the impact strength of co-mixing system rises relatively
Hurry up, exceed the impact strength of pure PVC, but be necessary to improve further the amplitude of increase, keep hot strength not reduce.4. exist
Under experimental condition herein, by observing the microstructure of PNBR/PVC co-mixing system section, find different microcell
Middle PNBR dispersion situation is different, and rubber has the bundles of phenomenon of gathering, also has finely dispersed phenomenon.Use banburying side
When formula is blended, it is possible to observe the microcell that PNBR dispersion size is less, its single particle is closely sized to 100nm, in
Existing fundamental particle dispersity.Ultra-fine fully vulcanized powder rubber to the study on the modification 5. of RPVC at this paper test bar
Under part, genuine milk rubber shares with powder butyronitrile rubber, can improve the interface of powder butyronitrile rubber and PVC, make co-mixing system rush
Hit intensity is improved, and in system microstructure, rubber particles dispersion size is less, shows coordination plasticizing effect.6.1 parts with
After upper powdered rubber mixes with PVC, the master stream property of compound is deteriorated, and affects the dispersion of powdered rubber granule, and then affects performance,
Powdered rubber surface appearance should be improved.The most under experimental conditions, the micro-cross-linking agent TAIC less than 0.1 part can be to a certain degree
Improve the mechanical property of PVC.In order to take into account processing characteristics and the requirement of product appearance quality in actual production, reduce cross-linking agent
After consumption, mechanical property is without significantly improving.
The water pipe obtained by this research has good intensity and toughness, but the easy corrosion and ageing of rubber, thermostability
Poor, affect the service life of water pipe, need to improve, it addition, the progress also needing to the change according to environment and production improves water
The toughness of pipe, antibiotic property, corrosion resistance, quiet performance, elasticity, environmental protection, wear-resisting, antistatic behaviour, tensile strength, spoke antifouling, anti-
The performance such as penetrate, fire-retardant.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of antibiotic ultra-fine fully vulcanized powder rubber gathers
Vinyl chloride composite water pipe and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of antibiotic ultra-fine fully vulcanized powder rubber polrvinyl chloride composite water pipe, is prepared by the raw materials in: ultra-fine entirely
Sulfide powder rubber 29-30, PVCSG-3 68-70, zinc oxide nanowire 2-2.3, cerous nitrate 3-3.2, deionized water 70-80,
Butyl acrylate 1.6-1.8, Ammonium persulfate. 0.2-0.3, graphene oxide 2.3-2.5, nano cuprous oxide 0.8-1, Colophonium
0.8-1, ten difluoro heptyl propyl trimethoxy silicane 2.6-2.8, ethanol 60-70, ammonia 15-16.
The preparation method of described antibiotic ultra-fine fully vulcanized powder rubber polrvinyl chloride composite water pipe, comprises the following steps:
(1) by cerous nitrate, deionized water mixing, stirring obtains solution, adds ultra-fine fully vulcanized powder rubber, then limit stirring
While be slowly added dropwise by ammonia in people's said mixture, at 30-35 DEG C, stirring reaction 3-3.5h, filtration drying, obtain powder；
(2) by butyl acrylate, ten difluoro heptyl propyl trimethoxy silicane mixing, add ethanol and stir, add institute
State powder, zinc oxide nanowire, stir, add Ammonium persulfate., be heated to 60-70 DEG C, stir 30-40 minute, filter
It is dried, obtains modified superfine fully vulcanized powder rubber；
(3) by graphene oxide, nano cuprous oxide mixing, stir, stir 20-30 minute under 2-2.5MPa, recover
Normal pressure, adds asphalt mixing uniform, obtains mixed material；
(4) modified superfine fully vulcanized powder rubber, described mixed material are mixed with other residual componentss, carry out banburying, rotor
Speed is 40rpm, and temperature is 180-185 DEG C, mixes 10-12 minute, then carries out pelletize, injection, to obtain final product.
The invention have the advantage that and by the present invention in that and ultra-fine fully vulcanized powder rubber is modified, at powder with cerous nitrate
The nano-cerium oxide of end rubber surface deposition, improves thermostability and the resistance to ag(e)ing of powdered rubber, but is so that powdered rubber
Polarity strengthens, and reduces reinforcing property, re-uses zinc oxide nanowire, butyl acrylate, ten difluoro heptyl propyl trimethoxies
Silane is modified, active group and nano wire at powdered rubber surface grafting, and improves lubricity, improves powder
The dispersibility of rubber and resistance to water, improve powdered rubber and the contact area of PVC and adhesion strength, improve the breach of water pipe
Impact strength, toughness, improve resistance to ag(e)ing simultaneously；By using graphene oxide, nano cuprous oxide to mix, at 2-
Stir 20-30 minute under 2.5MPa so that surface of graphene oxide has loaded nano cuprous oxide, has good antibacterial effect
Really, add Colophonium, improve graphene oxide, nano cuprous oxide and the caking property of PVC, prevent nano cuprous oxide from oxygen
Functionalized graphene surface is peeled off, and affects anti-microbial property.
Detailed description of the invention
A kind of antibiotic ultra-fine fully vulcanized powder rubber polrvinyl chloride composite water pipe, by the raw material system of following weight portion (kilogram)
Become: ultra-fine fully vulcanized powder rubber 29, PVCSG-3 68, zinc oxide nanowire 2, cerous nitrate 3, deionized water 70, acrylic acid fourth
Ester 1.6, Ammonium persulfate. 0.2, graphene oxide 2.3, nano cuprous oxide 0.8, Colophonium 0.8, ten difluoro heptyl propyl group trimethoxy
Base silane 2.6, ethanol 60, ammonia 15.
The preparation method of described antibiotic ultra-fine fully vulcanized powder rubber polrvinyl chloride composite water pipe, comprises the following steps:
(1) by cerous nitrate, deionized water mixing, stirring obtains solution, adds ultra-fine fully vulcanized powder rubber, then limit stirring
While be slowly added dropwise by ammonia in people's said mixture, at 30 DEG C, stirring reaction 3h, filtration drying, obtain powder；
(2) by butyl acrylate, ten difluoro heptyl propyl trimethoxy silicane mixing, add ethanol and stir, add institute
State powder, zinc oxide nanowire, stir, add Ammonium persulfate., be heated to 60 DEG C, stir 30 minutes, filtration drying,
To modified superfine fully vulcanized powder rubber；
(3) by graphene oxide, nano cuprous oxide mixing, stir, stir 20 minutes under 2MPa, recover normal pressure, then
Add asphalt mixing uniform, obtain mixed material；
(4) modified superfine fully vulcanized powder rubber, described mixed material are mixed with other residual componentss, carry out banburying, rotor
Speed is 40rpm, and temperature is 180 DEG C, mixes 10 minutes, then carries out pelletize, injection, to obtain final product.
The notch impact strength of the present embodiment supplying pipe is 11.5KJ/m2, hot strength is 61.4MPa, extension at break
Rate is 83.6%.
Claims (2)
1. an antibiotic ultra-fine fully vulcanized powder rubber polrvinyl chloride composite water pipe, it is characterised in that by the raw material of following weight portion
Make: ultra-fine fully vulcanized powder rubber 29-30, PVCSG-3 68-70, zinc oxide nanowire 2-2.3, cerous nitrate 3-3.2, go from
Sub-water 70-80, butyl acrylate 1.6-1.8, Ammonium persulfate. 0.2-0.3, graphene oxide 2.3-2.5, nano cuprous oxide
0.8-1, Colophonium 0.8-1, ten difluoro heptyl propyl trimethoxy silicane 2.6-2.8, ethanol 60-70, ammonia 15-16.
The preparation method of antibiotic ultra-fine fully vulcanized powder rubber polrvinyl chloride composite water pipe the most according to claim 1, its
It is characterised by comprising the following steps:
(1) by cerous nitrate, deionized water mixing, stirring obtains solution, adds ultra-fine fully vulcanized powder rubber, then limit stirring
While be slowly added dropwise by ammonia in people's said mixture, at 30-35 DEG C, stirring reaction 3-3.5h, filtration drying, obtain powder；
(2) by butyl acrylate, ten difluoro heptyl propyl trimethoxy silicane mixing, add ethanol and stir, add institute
State powder, zinc oxide nanowire, stir, add Ammonium persulfate., be heated to 60-70 DEG C, stir 30-40 minute, filter
It is dried, obtains modified superfine fully vulcanized powder rubber；
(3) by graphene oxide, nano cuprous oxide mixing, stir, stir 20-30 minute under 2-2.5MPa, recover
Normal pressure, adds asphalt mixing uniform, obtains mixed material；
(4) modified superfine fully vulcanized powder rubber, described mixed material are mixed with other residual componentss, carry out banburying, rotor
Speed is 40rpm, and temperature is 180-185 DEG C, mixes 10-12 minute, then carries out pelletize, injection, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610325334.5A CN105837990A (en) | 2016-05-17 | 2016-05-17 | Anti-microbial superfine fully-vulcanized powdered rubber and polyvinyl chloride composite water pipe and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610325334.5A CN105837990A (en) | 2016-05-17 | 2016-05-17 | Anti-microbial superfine fully-vulcanized powdered rubber and polyvinyl chloride composite water pipe and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105837990A true CN105837990A (en) | 2016-08-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610325334.5A Pending CN105837990A (en) | 2016-05-17 | 2016-05-17 | Anti-microbial superfine fully-vulcanized powdered rubber and polyvinyl chloride composite water pipe and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108440922A (en) * | 2018-03-21 | 2018-08-24 | 安徽江淮汽车集团股份有限公司 | A kind of PET composite material and preparation method thereof |
| CN114015299A (en) * | 2021-09-19 | 2022-02-08 | 宿迁空天新材料有限公司 | Preparation and application of composite nano antibacterial and antiviral coating |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103483716A (en) * | 2012-06-08 | 2014-01-01 | 中国石油化工股份有限公司 | Hard impact-resistant polyvinyl chloride composition and preparation method thereof |
-
2016
- 2016-05-17 CN CN201610325334.5A patent/CN105837990A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103483716A (en) * | 2012-06-08 | 2014-01-01 | 中国石油化工股份有限公司 | Hard impact-resistant polyvinyl chloride composition and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108440922A (en) * | 2018-03-21 | 2018-08-24 | 安徽江淮汽车集团股份有限公司 | A kind of PET composite material and preparation method thereof |
| CN114015299A (en) * | 2021-09-19 | 2022-02-08 | 宿迁空天新材料有限公司 | Preparation and application of composite nano antibacterial and antiviral coating |
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Application publication date: 20160810 |
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