CN105831798A - Fermentation type mouth-holding cigarette with slow release function and preparation method thereof - Google Patents
Fermentation type mouth-holding cigarette with slow release function and preparation method thereof Download PDFInfo
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- CN105831798A CN105831798A CN201610323524.3A CN201610323524A CN105831798A CN 105831798 A CN105831798 A CN 105831798A CN 201610323524 A CN201610323524 A CN 201610323524A CN 105831798 A CN105831798 A CN 105831798A
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- tobacco
- cigarette
- buccal cigarette
- granule
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B13/00—Tobacco for pipes, for cigars, e.g. cigar inserts, or for cigarettes; Chewing tobacco; Snuff
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/20—Biochemical treatment
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/283—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
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- General Chemical & Material Sciences (AREA)
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- Life Sciences & Earth Sciences (AREA)
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- Manufacture Of Tobacco Products (AREA)
Abstract
The invention discloses a fermentation type mouth-holding cigarette with a slow release function and a preparation method thereof. The mouth-holding cigarette is prepared from 50-80% of mixed cut tobacco granules, 10-30% of water, 1-5% of corrigent, 1-5% of sweetening agent and 1-10% of flavoring agent. The mixed cut tobacco granules is the mixture of cut tobacco granules and micro capsule granules, and the mixed mass ratio of the cut tobacco granules to the micro capsule granules is 2:1-4:1. Micro capsule packaging is scientifically adopted, the defects that according to an existing product, the nicotine release speed is too high, strength is too large in the early mouth-holding stage and is too small in the later mouth-holding stage, and cigarette flavor is rapidly weakened in the whole mouth-holding process are overcome, the nicotine dissolving-out resistance in the initial mouth-holding stage is increased, and the uniform-speed nicotine dissolving-out time is prolonged on the premise of not changing the total nicotine release amount, so that it is ensured that stable strength and cigarette flavor can be kept within a long time in the mouth-holding process; in addition, no alkali salt is added.
Description
Technical field
The present invention relates to tobacco leaf production technical field, packed more particularly, to a kind of fermented type with slow-release function
The preparation method of buccal cigarette and buccal cigarette.
Background technology
Smoke-free tobacco product refers to without combustion process, and is directly sucked the Nicotiana tabacum L. system of consumption by oral cavity or nasal cavity
Product.
World Health Organization's Framework Convention on Tobacco Control (WHO FCTC) proposes about forbidding that tobacco smoke is in public field
Restriction and the ban such as being spread, the development to conventional tobacco products Medicated cigarette causes powerful impact.Under this background, countries in the world
Tobacco business is using the research and development of smoke-free tobacco product with introduce to the market important as solve tobacco business future development
Means, in Europe, South and North America, India and Africa, smoke-less tobacco product various in style, consumption figure in various countries all in year by year
The trend increased.As a example by the U.S., in 2006 years, consumption figure is more than 4,000,000,000 dollars.
Buccal cigarette is a kind of smokeless tobacco containing nicotine, it is common that salt adding of Nicotiana tabacum L. being clayed into power again and water mixing and
Become, the most also can add spice, seem oleum bergamottae, Oleum Rosae Rugosae or Radix Glycyrrhizae.Buccal cigarette the earliest is in bulk, time to be sucked with
Finger is kneaded into a little group, then fills in upper lip rear.From the beginning of 1973, buccal cigarette is installed in the pouch as little tea bag.
At present, the new change of the research worker reply international Field of Tobacco development of domestic Field of Tobacco, exploitation is suitable for domestic
The smoke-free tobacco product of tobacco consumer.Such as disclosed patent: a kind of mouth insertion tobacco goods (200810050106.7), packed
Mouth insertion tobacco goods and preparation method thereof (200810049347.X), bagged buccal tobacco product (200810049346.5).
Bagging mouth-sucked drying tobacco products and preparation method thereof (200810049349.9), bagged buccal tobacco product
(200810049346.5) it is each provided with relevant smoke-free tobacco product.
The sense organ impact strength of smoke-free tobacco product is mainly affected by the organoleptic attribute of tobacco material, external product in order to
Ensure the fire-cured tobacco having significant proportion in the tobacco material formula that its distinctive organoleptic feature is conventional.Owing to fire-cured tobacco is state
Outer distinctive tobacco material, this raw material largely limiting domestic Foreign Experience exploitation smoke-free tobacco product is empty
Between.And its of the current smoke-free tobacco product of domestic-developed is mainly characterized by by all kinds of regulators, humectant, flavouring agent etc.
Carrying out formula modulation, domestic current smoke-free tobacco product technique is mostly and directly uses tobacco material grinding, seasoning, dress
Bag, exists that zest is excessive, bitter taste is dense, acid is strong, is not directed to the fermentation process technique of tobacco material.
The tobacco material of preparation buccal cigarette generally has two kinds of processing modes, and one is by tobacco natural is air-dried or high temperature goes out
Bacterium, production method be by natural air drying or high temperature sterilize after Nicotiana tabacum L. mixed with sodium carbonate and water, add spice the most again
Composition, seems oleum bergamottae, Oleum Rosae Rugosae, Radix Glycyrrhizae and spice etc..Such as number of patent application be 201410093051 China specially
Profit application provides a kind of wet type granular packed mouth insertion tobacco article formulations and preparation method thereof, and the raw tobacco material of employing is certainly
So air-dry to moisture be 12～16%.Another kind is to make (U.S.'s buccal cigarette) by fermented for Nicotiana tabacum L..Domestic preparation is sucked
Cigarette additionally uses the Chinese patent application of a kind of raw material, such as Application No. 201310663425 and uses cigarette industry by-product to make
For preparing the tobacco particle material of buccal cigarette, described cigarette industry by-product is the by-product produced between Primary processing shop or volume hired car
Product, from one or more mixing in flue-cured tobacco, burley tobaccos, dry in the sun cigarette, Turkish tobaccos, and are fragment, sesame-seed slice, offal, stalk
One or more mixing signed.But have in these cigarette industry by-products have passed through ferment making, and have does not has, and is made
For preparing the raw material of buccal cigarette, difficult quality controls, and is difficult to keep stable product special flavour.
Buccal cigarette is to absorb nicotine to internal by sucking, and makes people produce and rouse oneself sense after entering blood.It is in oral cavity
In the releasing effect of various compositions directly determine quality and the quality of buccal cigarette.Compared with Medicated cigarette, smoke-free tobacco product pair
Raw tobacco material quality requirements is higher, this is because: general 700～800 milligrams of Cigarette weight/, all only have after burning
The material of about 1% enters flue gas, and after filter tip filters, the amount finally experienced by smoker is very little.And smokeless cigarette
Straw-made articles directly acts on human body without burning, and therefore the quality of tobacco material is even more important.
Known in production of cigarettes technology, without the Nicotiana tabacum L. of fermentation process to some extent with multiple quality defect, have
Blue foreign smell and zest, aroma quality is dull, and perfume quantity is not enough, if being used directly to produce buccal cigarette, described defect will necessarily carry
Enter finished product, or need to add various additive to improve described defect.But existing research it has been generally acknowledged that the mouth fermented
More substantial oxious component nitrosamine is contained than the buccal cigarette of natural air drying or high temperature sterilize containing cigarette, the most domestic with buccal cigarette phase
Without reference to the relevant report using Nicotiana tabacum L. to prepare buccal cigarette after carrying out specifically fermentation in the research closed.
Nicotine is a kind of very important alkaloid in Nicotiana tabacum L., is also the important one-tenth of one of buccal type smokeless tobacco product with the plum flavor
Point.Nicotine rate of release and burst size are the important indicators of buccal type smokeless tobacco product with the plum flavor quality safety.Research shows: nicotine is released
Put speed relevant to factors such as the nicotine content of sample, pH value, moisture, granularities, but principal element is pH value.Existing buccal cigarette is produced
The additional alkali salt of product, meanwhile, its nicotine rate of release is too fast, sucks early stage strength excessive later stage strength less, whole sucks
During smoke the most thin out.In order to reach the effective control to the release of buccal type smokeless tobacco product with the plum flavor nicotine, research worker is
Having carried out the research work in terms of some nicotine releases, the Chinese patent application of Publication No. CN101254023 discloses one
Disclose nicotine sustained-release type mouth insertion tobacco tablet.Nicotine sustained-release type mouth insertion tobacco tablet is to be bonded by multilamellar smoked sheet superposition, each layer
Be provided with reconstituted tobacoo between smoked sheet, the compactness of each layer smoked sheet by intermediate layer to upper and lower both sides in distribution of successively decreasing successively.For regulation
The rate of release of nicotine, keeps relatively stable strength and smoke, and the density of compacted zone is 2 times of time compacted zone respectively, is thin
4 times of pine layer are to increase the course of nicotine at the uniform velocity dissolution；Publication No. CN 102940307 A discloses one microcapsule bag
The microcapsule made encapsulated alkali salt active component by film raw material, and slow-release alkaline capsule discharges alkalescence lentamente, can guarantee that the type of sucking
Tobacco product pH during edible is between neutral environment, it is ensured that nicotine discharges with molecular forms, makes to suck the cigarette of type cigarette
Alkali mouthfeel extends.The Chinese patent application of Publication No. CN 103494324 A discloses a kind of sodium bicarbonate or sodium carbonate for acid
Alkali regulator.
Control at present that the mode of nicotine rate of release all exists that nicotine rate of release is very fast, difference is very big before and after pH value,
Before and after causing the mouthfeel of buccal type smokeless tobacco product with the plum flavor, comparison in difference is big, and the most simply in conceptual phase, it is suitable the most not find
Way solve, make to suck type tobacco product and promote and be restricted.
So sum up tobacco fermentation technique to be effectively improved the quality of Nicotiana tabacum L., and the seasoning combining reasonable benefit/risk processes and obtains cigarette
Silk particulate material, and the nicotine release in described tobacco shred granule is controlled by the means of science, thus obtain high-quality sucking
Cigarette is the technical barrier that this area is urgently to be resolved hurrily.
Summary of the invention
The technical problem to be solved in the present invention is the technical deficiency overcoming existing buccal cigarette, it is provided that one has slow-release function
The preparation method of the packed buccal cigarette of fermented type, by the macromolecular substances in fermentable degrading tobacco, reduce bitter taste
And acid, the seasoning in conjunction with reasonable benefit/risk is processed acquisition comfortable taste and local flavor, and is controlled by the means of science described
Nicotine release in tobacco shred granule, can prepare high-quality buccal cigarette.
Another technical problem that the invention solves the problems that is to provide the buccal cigarette applying described tobacco shred.
The purpose of the present invention is achieved by the following technical programs:
A kind of fermented type buccal cigarette with slow-release function is provided, the component of following mass percentage content prepares
Arrive:
Pipe blend granule 50%～80%, water 10%～30%, correctives 1%～5%, sweeting agent 1%～5% is fragrant
Taste agent 1%～10%；
Described pipe blend granule is the mixture of tobacco shred granule and microcapsule granule, and the mixing quality ratio of the two is 2:
1～4:1.
The preparation method of described tobacco shred granule comprises the following steps:
S1. tobacco formulation group is prepared；
S2. Nicotiana tabacum L. processes: rinsed by tobacco leaf use water, removes surface dust, somewhat dries, and removes excessive moisture, cuts
Silk；
S3. tobacco shred fermentation: preparation inoculation liquid, is 1～15g inoculation liquid/100g tobacco shred inoculation after fermentation according to inoculum concentration, institute
That states inoculation liquid consists of high fructose syrup: protein peptide: strain: the mass ratio of water=(50～200) g:(0.1～10) g:(0.01
～1) g:(100～500) g；
S4., after fermentation ends, carry out sterilization treatment and get final product；
Described hydromining distilled water.
The preparation of described microcapsule granule is to take described tobacco shred granule, then processes through following preparation process:
S5. extraction: tobacco shred granule employing water is extracted, filters to obtain solid content after extraction, solid content is dried through powder
Broken sieve after, take 40～60 mesh sieves and get extract composition；
S6. peplos: microcapsule, described micro-glue are made in the encapsulating of step S5 gained extract composition with microcapsular envelopes raw material
In capsule, mass percent shared by microcapsular envelopes raw material is 10～90%.It is further preferred that microcapsule bag in described microcapsule
Mass percent shared by film raw material is 15～25%, most preferably 20%.
Preferably, described sweeting agent is Mel, white sugar, brown sugar, glucose, fructose, sucrose, Aspartame, xylitol, wheat
Any one or a few mixture of bud sugar alcohol, saccharin sodium, tripotassium glycyrrhetate or Fructus Jujubae.
Preferably, described correctives is salt, cocoa powder, Radix Glycyrrhizae powder or coffee powder；Described flavouring agent is capsicum tincture, menthol
Or fruit extract.
Preferably, described flavouring agent is capsicum tincture, menthol or fruit extract.
Preferably, preparing tobacco formulation group described in step S1 is according in flue-cured tobacco, burley tobaccos, dry in the sun cigarette, Turkish tobaccos
Planting or formula mixing is pressed in several mixing, its mass ratio is flue-cured tobacco: burley tobaccos: dry in the sun cigarette: Turkish tobaccos=(0～2): (4～0):
(3～0): (0～3).
Preferably, shredding described in S2 step is that Nicotiana tabacum L. is cut to 0.5～6cm length, 0.1～1mm wide uniform filament.
Preferably, described in step S3, the condition of fermentation is: sweat remains that control temperature, at 35～45 DEG C, is fermented
Time is 7～35 days.The fermentation technology of the science that the present invention provides not only obtains good buccal cigarette local flavor, and does not produce
The raw nitrite exceeded standard.
Preferably, described inoculation liquid consist of high fructose syrup: protein peptide: strain: the mass ratio of distilled water=(50～
100) g:(1～10) g:(0.1～0.8) g:(200～500) g.
Preferably, strain described in step S3 is monascus (Monascus purpureus Went.), aspergillus oryzae
(Aspergillus oryzae), Zygosaccharomyces rouxii (Mucor roxianus) or rhizopus (Rhizopus), yeast
Or one or more of lactic acid bacteria (Lactobacillus) (Saccharomyces)；It is further preferred that described strain is rice
Aspergillosis (Aspergillus oryzae), yeast (Saccharomyces) or lactic acid bacteria (Lactobacillus).
Preferably, temperature described in step S3 is 35～45 DEG C, and fermentation time is 15～30 days.
Preferably, the protein peptide of inoculation liquid described in step S3 is soybean protein peptide, wheat protein peptide, rice protein peptide, cheese
Protein peptide, whey protein peptide one or more.
Preferably, sterilizing described in step S4 uses pasteurization, and sterilization treatment temperature is 70～121 DEG C, and sterilization time is 5
～30min.
Preferably, extraction described in step S5 is to extract 1 hour at 50 DEG C, and described tobacco shred is 1:5 with the mass ratio of water.
Described microcapsular envelopes raw material includes: arabic gum, sodium alginate, carrageenan, dextrin, oligosaccharide, starch derivatives
In biology, gelatin, casein, sodium carboxymethyl cellulose, ethyl cellulose or methylcellulose arbitrarily two or more
Combination.Preferably, the described mixture that microcapsular envelopes raw material is dextrin, oligosaccharide and methylcellulose.Further preferably
Ground, dextrin, oligosaccharide and methylcellulose combine according to the mass ratio of 1:2:1.
Preferably, described in step S6, encapsulating is in 60～70 DEG C of waters bath with thermostatic control, lower toward extract composition being stirred continuously
Middle addition peplos raw material, after peplos material dissolution is complete, carries out homogenizing, mixture is carried out high speed dispersion, obtains emulsion；
By emulsion spray drying, prepare microcapsule.The most described emulsion solid content is 40%.
Preferably, the process conditions of described spray drying are hot-air inlet temperature 180～250 DEG C, leaving air temp 80～
90℃。
There is the preparation method of the fermented type buccal cigarette of slow-release function, it is characterised in that be described in present invention simultaneously provides
According to pipe blend granule 50%～80%, water 10%～30%, correctives 1%～5%, sweeting agent 1%～5%, flavouring agent
After the ratio mixing of 1%～10%, poisture-penetrability sack is used to pack by the specification of 0.1～0.5g/ bag.
The present invention provides the buccal cigarette that described preparation method prepares.
Compared with prior art, the invention has the beneficial effects as follows:
Prior art rarely has takes necessary and rational fermentation process to Nicotiana tabacum L., and prepared buccal cigarette is generally not capable of removing
The blue foreign smell of Nicotiana tabacum L. and zest, need to carry out taste masking by the correctives of vast scale and cover blue foreign smell and zest, fragrance
Matter is the most dull, and perfume quantity is not enough.Although and using some raw material of by-product produced in production of cigarettes workshop section by fermentation
Processing, blue foreign smell and zest have reduced, but the starting point that these raw materials existing make is to participate in burning, and Nicotiana tabacum L. is sent out by it
The requirement that ferment processes differs greatly for the requirement of raw material with buccal cigarette, and local flavor is inharmonious.
The present invention uses the fermentation technology specific aim of science to process Nicotiana tabacum L., and the present invention uses the fermentation technology specific aim of science
Processing Nicotiana tabacum L., eliminate bitter taste and the acid of tobacco shred, its nitrogen substance is reduced conversion, improves buccal cigarette raw material
Comfortable taste, fragrance matter is enriched mellow, successfully eliminates blue foreign smell and the zest of raw material, is effectively improved the quality of Nicotiana tabacum L., and
Seasoning in conjunction with reasonable benefit/risk processes, and correctives and the sweeting agent etc. that use rational proportion are compatible with tobacco shred granule, it is thus achieved that more
Add abundant mouthfeel, flavor coordination, high-quality buccal cigarette.
Based on preferred fermentation raw material, the present invention summarizes microencapsulated further, overcomes existing product nicotine and releases
Put that speed is too fast, suck that early stage strength excessive later stage strength is less, whole and suck during the most thin out deficiency of smoke, increase
Suck initial stage nicotine dissolution resistance, on the premise of not changing overall nicotine burst size, delay the time of nicotine at the uniform velocity dissolution,
Thus stable strength and smoke can be kept during ensureing to suck within the longer time, and the most additional alkali salt of the present invention.
Detailed description of the invention
The present invention is further described below in conjunction with specific embodiment.Unless stated otherwise, the present invention use reagent,
Equipment is the art conventional reagent and equipment；Design philosophy of the present invention is summed up based on long-term great many of experiments and is obtained, following reality
Execute example and be merely to illustrate the present invention, but the most therefore limit the present invention.Following embodiment use high fructose syrup, protein peptide and
Monascus, aspergillus oryzae, Zygosaccharomyces rouxii or rhizopus, yeast or lactic acid bacteria are conventional commercial raw material.
Embodiment 1
The present embodiment prepares a kind of tobacco shred granule, and its preparation method comprises the following steps:
S1. tobacco formulation group is prepared: according to flue-cured tobacco: the mass ratio of burley tobaccos is that 2:4 prepares Nicotiana tabacum L. group；
S2. Nicotiana tabacum L. processes: rinsed by tobacco leaf use water, removes surface dust, somewhat dries, and removes excessive moisture, cuts
Silk；
S3. tobacco shred fermentation: preparation inoculation liquid, is 1g inoculation liquid/100g tobacco shred inoculation after fermentation according to inoculum concentration, and ferment bar
Part is: sweat remain control temperature at 45 DEG C, fermentation time is 15 days；The fermentation technology of science not only obtains good
Good buccal cigarette local flavor, and reduce content of nitrite.
Described inoculation liquid consist of high fructose syrup: protein peptide: strain: the mass ratio=50g:5g:0.1g of distilled water:
250g；Described strain is monascus and yeast, and after obtaining bacterium solution according to cellar culture respectively, the ratio according to 1:1 mixes；
The protein peptide of described inoculation liquid is soybean protein peptide；
S4. after fermentation ends, through 70 DEG C of pasteurization 30min.
Embodiment 2
The present embodiment prepares a kind of tobacco shred granule, and its preparation method comprises the following steps:
S1. tobacco formulation group is prepared: according to flue-cured tobacco: burley tobaccos: the mass ratio of dry in the sun cigarette is that 1:1:1 prepares Nicotiana tabacum L. group；
S2. Nicotiana tabacum L. processes: rinsed by tobacco leaf use water, removes surface dust, somewhat dries, and removes excessive moisture, cuts
Silk；
S3. tobacco shred fermentation: preparation inoculation liquid, is 1g inoculation liquid/100g tobacco shred inoculation after fermentation according to inoculum concentration, and ferment bar
Part is: sweat remain control temperature at 45 DEG C, fermentation time is 15 days；The fermentation technology of science not only obtains good
Good buccal cigarette local flavor, and reduce content of nitrite.
Described inoculation liquid consist of high fructose syrup: protein peptide: strain: the mass ratio=50g:5g:0.1g of distilled water:
250g；Described strain is monascus and yeast, and after obtaining bacterium solution according to cellar culture respectively, the ratio according to 2:1 mixes；
The protein peptide of described inoculation liquid is wheat protein peptide；
S4. after fermentation ends, through 85 DEG C of pasteurization 15min.
Embodiment 3
The present embodiment provides the preparation method of a kind of tobacco shred being applicable to buccal cigarette, comprises the following steps:
S1. tobacco formulation group is prepared: according to flue-cured tobacco: burley tobaccos: the mass ratio of dry in the sun cigarette is that 1:1:1 prepares Nicotiana tabacum L. group；
S2. Nicotiana tabacum L. processes: rinsed by tobacco leaf use water, removes surface dust, somewhat dries, and removes excessive moisture, cuts
Silk；
S3. tobacco shred fermentation: preparation inoculation liquid, is 10g inoculation liquid/100g tobacco shred inoculation after fermentation according to inoculum concentration, fermentation
Condition is: sweat remain control temperature at 35 DEG C, fermentation time is 20 days；The fermentation technology of science not only obtains
Good buccal cigarette local flavor, and do not have to produce the nitrite exceeded standard.
Described inoculation liquid consist of high fructose syrup: protein peptide: strain: the mass ratio=100g:1g:0.5g of distilled water:
200g；Described strain is aspergillus oryzae and lactic acid bacteria, and after obtaining bacterium solution according to cellar culture respectively, the ratio according to 1:1 mixes；
The protein peptide of described inoculation liquid is casein peptide；
S4. after fermentation ends, through 121 DEG C of pasteurization 5min.
Embodiment 4
The present embodiment provides the preparation method of a kind of tobacco shred being applicable to buccal cigarette, comprises the following steps:
S1. tobacco formulation group is prepared: according to burley tobaccos: dry in the sun cigarette: the mass ratio of Turkish tobaccos is that 3:2:1 prepares Nicotiana tabacum L.
Group；
S2. Nicotiana tabacum L. processes: rinsed by tobacco leaf use water, removes surface dust, somewhat dries, and removes excessive moisture, cuts
Silk；
S3. tobacco shred fermentation: preparation inoculation liquid, is 15g inoculation liquid/100g tobacco shred inoculation after fermentation according to inoculum concentration, fermentation
Condition is: sweat remain control temperature at 40 DEG C, fermentation time is 35 days；The fermentation technology of science not only obtains
Good buccal cigarette local flavor, and do not have to produce the nitrite exceeded standard.
Described inoculation liquid consist of high fructose syrup: protein peptide: strain: the mass ratio=80g:10g:0.8g of distilled water:
500g；Described strain is Zygosaccharomyces rouxii, rhizopus and yeast, obtains after bacterium solution the ratio according to 1:2 according to cellar culture respectively
Mixing；
The protein peptide of described inoculation liquid is soybean protein peptide and whey protein peptide mass ratio is 1:1；
S4. after fermentation ends, through 100 DEG C of pasteurization 10min.
Embodiment 5
The present embodiment provides the preparation method of a kind of tobacco shred being applicable to buccal cigarette, comprises the following steps:
S1. tobacco formulation group is prepared: according to flue-cured tobacco: burley tobaccos: dry in the sun cigarette: the mass ratio of Turkish tobaccos is 1:4:3:1；
S2. Nicotiana tabacum L. processes: rinsed by tobacco leaf use water, removes surface dust, somewhat dries, and removes excessive moisture, cuts
Silk；
S3. tobacco shred fermentation: preparation inoculation liquid, is 5g inoculation liquid/100g tobacco shred inoculation after fermentation according to inoculum concentration, and ferment bar
Part is: sweat remain control temperature at 45 DEG C, fermentation time is 30 days；The fermentation technology of science not only obtains good
Good buccal cigarette local flavor, and do not have to produce the nitrite exceeded standard.
Described inoculation liquid consist of high fructose syrup: protein peptide: strain: the mass ratio=80g:10g:0.8g of distilled water:
500g；Described strain is Zygosaccharomyces rouxii, rhizopus and yeast, obtains after bacterium solution the ratio according to 1:2:1 according to cellar culture respectively
Example mixes；
The protein peptide of described inoculation liquid is rice protein peptide；
S4. after fermentation ends, through 121 DEG C of pasteurization 5min.
Embodiment 6 prepares microcapsule granule
The preparation method of described microcapsule granule comprises the following steps:
The tobacco shred granule that Example 1 to 5 any embodiment prepares, then process through following preparation process:
S5. extraction: tobacco shred granule employing water is extracted, filters to obtain solid content after extraction, solid content is dried through powder
Broken sieve after, take 40～60 mesh sieves and get extract composition；Extracting 1 hour at 50 DEG C, described tobacco shred with the mass ratio of water is
1:5。
S6. peplos: microcapsule, described micro-glue are made in the encapsulating of step S5 gained extract composition with microcapsular envelopes raw material
In capsule, mass percent shared by microcapsular envelopes raw material is 10～90%.It is further preferred that microcapsule bag in described microcapsule
Mass percent shared by film raw material is 25%.
Described microcapsular envelopes raw material is the combination according to the mass ratio of 1:1 of arabic gum and maltodextrin.
Described in S6 step, encapsulating is in 60～70 DEG C of waters bath with thermostatic control, lower by extract composition addition peplos being stirred continuously
Raw material, after peplos material dissolution is complete, carries out homogenizing, mixture is carried out high speed dispersion, obtain emulsion, described emulsion
Solid content is 50%；By emulsion spray drying, prepare microcapsule.
The process conditions of described spray drying are hot-air inlet temperature 180 DEG C, leaving air temp 85～90 DEG C.
Embodiment 7
Example 1 to 5 any embodiment gained tobacco shred, then process through following preparation process:
S5. tobacco shred extraction: after tobacco shred fermentation, uses water to extract, filters to obtain solid content after extraction, dried by solid content
Size-reduced sieve after, take 40～60 mesh sieves and get extract composition；
Wherein, extraction described in S5 step is to extract 1 hour at 50 DEG C, and described tobacco shred is 1:5 with the mass ratio of water.
S6. peplos: microcapsule, microcapsule in described microcapsule are made in the encapsulating of extract composition with microcapsular envelopes raw material
Peplos raw materials quality percentage ratio is 20%.
Described microcapsular envelopes raw material includes: dextrin, oligosaccharide and methylcellulose combine according to the ratio of 1:2:1.
Described in S6 step, encapsulating is in 60～70 DEG C of waters bath with thermostatic control, lower by extract composition addition peplos being stirred continuously
Raw material, after peplos material dissolution is complete, carries out homogenizing, mixture is carried out high speed dispersion, obtain emulsion, described emulsion
Solid content is 40%；By emulsion spray drying, prepare microcapsule.
The process conditions of described spray drying are hot-air inlet temperature 250 DEG C, leaving air temp 90 DEG C.
Embodiment 8
Example 1 to 5 any embodiment gained tobacco shred, is processing through following preparation process:
S5. tobacco shred extraction: after tobacco shred fermentation, uses water to extract, filters to obtain solid content after extraction, dried by solid content
Size-reduced sieve after, take 40～60 mesh sieves and get extract composition；
Wherein, extraction described in S5 step is to extract 1 hour at 50 DEG C, and described tobacco shred is 1:5 with the mass ratio of water.
S6. peplos: microcapsule, microcapsule in described microcapsule are made in the encapsulating of extract composition with microcapsular envelopes raw material
Peplos raw materials quality percentage ratio is 30%.
Described microcapsular envelopes raw material includes: arabic gum, casein, ethyl cellulose are according to the ratio of 2:1:1
Combination.
Described in S6 step, encapsulating is in 60～70 DEG C of waters bath with thermostatic control, lower by extract composition addition peplos being stirred continuously
Raw material, after peplos material dissolution is complete, carries out homogenizing, mixture is carried out high speed dispersion, obtain emulsion, described emulsion
Solid content is 50%；By emulsion spray drying, prepare microcapsule.
The process conditions of described spray drying be inlet temperature be 220 DEG C, leaving air temp is 80 DEG C.
Embodiment 9
Example 1 to 5 any embodiment gained tobacco shred, is processing through following preparation process:
S5. tobacco shred extraction: after tobacco shred fermentation, uses water to extract, filters to obtain solid content after extraction, dried by solid content
Size-reduced sieve after, take 40～60 mesh sieves and get tobacco shred granule；
Wherein, extraction described in S5 step is to extract 1 hour at 50 DEG C, and described tobacco shred is 1:5 with the mass ratio of water.
S6. peplos: microcapsule, microcapsule in described microcapsule are made in the encapsulating of extract composition with microcapsular envelopes raw material
Peplos raw materials quality percentage ratio is 30%.
Described microcapsular envelopes raw material includes: gelatin and ethyl cellulose are according to the combination of the ratio of 1:1.
Described in S6 step, encapsulating is in 60～70 DEG C of waters bath with thermostatic control, lower by extract composition addition peplos being stirred continuously
Raw material, after peplos material dissolution is complete, carries out homogenizing 15min, mixture is carried out high speed dispersion, obtain emulsion, described
Emulsion solid content is 60%；By emulsion spray drying, prepare microcapsule.
The process conditions of described spray drying be inlet temperature be 185 DEG C, leaving air temp is 80 DEG C.
Embodiment 10
The tobacco shred granule that Example 1 to 5 any embodiment prepares, Example 6 to 9 any embodiment gained is micro-
Capsule particle, the two obtains pipe blend granule after mixing with the mass ratio of 2:1, is equipped with auxiliaries and forms buccal cigarette
Grain, described in be equipped with the formula of auxiliaries and be: according to mass percent, pipe blend granule 80%, water 14%, correctives
3%, sweeting agent 2%, flavouring agent 1%.Correctives is salt, and sweeting agent is Mel, and flavouring agent is menthol.
Embodiment 11
The tobacco shred granule that Example 1 to 5 any embodiment prepares, Example 6 to 9 any embodiment gained is micro-
Capsule particle, the two obtains pipe blend granule after mixing with the mass ratio of 3:1, is equipped with auxiliaries and forms buccal cigarette
Grain, described in be equipped with the formula of auxiliaries and be: according to mass percent, pipe blend granule 90%, water 4%, correctives
4%, sweeting agent 1%, flavouring agent 1%.Correctives is salt with cocoa powder according to the mass ratio of 1:1, and sweeting agent is Mel, fragrance
Agent is capsicum tincture.
Embodiment 12
The tobacco shred granule that Example 1 to 5 any embodiment prepares, Example 6 to 9 any embodiment gained is micro-
Capsule particle, the two obtains pipe blend granule after mixing with the mass ratio of 4:1, is equipped with auxiliaries and forms buccal cigarette
Grain, described in be equipped with the formula of auxiliaries and be: according to mass percent, pipe blend granule 90%, water 4%, correctives
5%, flavouring agent 2%.Correctives is salt with Radix Glycyrrhizae powder according to the mass ratio of 1:1, flavouring agent be capsicum tincture with menthol according to
The mass ratio of 1:5.
Embodiment 13
The tobacco shred granule that Example 1 to 5 any embodiment prepares, Example 6 to 9 any embodiment gained is micro-
Capsule particle, the two obtains pipe blend granule after mixing with the mass ratio of 3:1, is equipped with auxiliaries and forms buccal cigarette
Grain, described in be equipped with the formula of auxiliaries and be: according to mass percent, pipe blend granule 85%, water 9%, correctives
3%, sweeting agent 2%, flavouring agent 1%.Correctives is, sweeting agent is Mel, and flavouring agent is menthol.
Embodiment 14
The buccal cigarette granule with slow-release function that Example 10 to embodiment 13 any embodiment prepares, by 0.3g/
Bag specification by buccal cigarette granule packaging in poisture-penetrability pouch.
Embodiment 15 detection and experiment of smokeing panel test
The mensuration of content of nitrite: the chromatography of ions (NY/T 1375-2007 plant product nitrite and nitric acid
The mensuration of salt)；The mensuration of protein content: Ke Daerfa be (YCT 166-2003 Nicotiana tabacum L. and tobacco product total protein content
Measure)；The mensuration of content of cellulose: enzymolysis-flow analysis (list of references: Guo Song. China examines cigarette Nicotiana tabacum L. pectin, cellulose
Content distribution feature and impact [D] Henan on reviewing prnciple: Agricultural University Of He'nan, 2011,18～19)；The survey of pectin content
Fixed: the chromatography of ions (YC/T 346-2010 Nicotiana tabacum L. and the mensuration chromatography of ions of tobacco product pectin)；The survey of content of cellulose
Fixed: enzyme hydrolysis-chromatography of ions (YC/T 283-2009 Nicotiana tabacum L. and tobacco product. the mensuration of starch. enzyme hydrolysis-chromatography of ions
Method)；The mensuration of content of lignin: sulfuric acid process (list of references: Tao Yongzhen, Guan Yingting. the chemical constitution of lignin and application thereof
[J]. Cellulose Science and technology, 2003,11 (1): 43-55).
Through inspection, the quality data of embodiment 1 to 5 gained tobacco shred are shown in Table 1；Simultaneously by the embodiment of the present invention 1
～5 prepare tobacco shred ask 10 experts that smoke panel test to carry out experiment of smokeing panel test.Method of smokeing panel test for directly inserting upper lip and upper row's tooth by tobacco shred
Between tooth, the tobacco shred granular mass every time putting into lip is 0.2g, and standard edible time is set to 10min.
The quality of table 1 tobacco shred
Through inspection, the quality data of embodiment 10 to 13 gained buccal cigarette are shown in Table 2.Smoke panel test method for sucking
Cigarette is directly inserted between upper lip and upper row's tooth, and the buccal cigarette quality every time putting into lip is 0.2g, and standard edible time is set to
10min.Scoring criterion is, the alkali rate of release of buccal cigarette, sucks early stage and later stage strength, compliance (buccal cigarette edible time
Below standard quasi-edible time is considered as poor compliance by discharge), local flavor, fragrance, pleasant impression respectively account for 10 points, total score 70 points.
The quality of table 2 buccal cigarette
| Sample | Alkali rate of release | Suck early stage strength | Suck later stage strength | Compliance | Local flavor | Fragrance | Pleasant impression | Total score |
| Embodiment 10 | 8 | 7 | 9 | 9 | 9 | 9 | 9 | 60 |
| Embodiment 11 | 9 | 9 | 8.5 | 9 | 9 | 9 | 8.5 | 62 |
| Embodiment 12 | 9 | 8 | 9 | 9 | 9 | 9 | 9.5 | 62.5 |
| Embodiment 13 | 8.5 | 8 | 8 | 9 | 9 | 9 | 8.5 | 60 |
The present invention uses the fermentation technology specific aim of science to process Nicotiana tabacum L., and the present invention uses the fermentation technology specific aim of science
Processing Nicotiana tabacum L., eliminate bitter taste and the acid of tobacco shred, its nitrogen substance is reduced conversion, improves buccal cigarette raw material
Comfortable taste, fragrance matter is enriched mellow, successfully eliminates blue foreign smell and the zest of raw material, is effectively improved the quality of Nicotiana tabacum L., and
Seasoning in conjunction with reasonable benefit/risk processes, and correctives and the sweeting agent etc. that use rational proportion are compatible with tobacco shred granule, it is thus achieved that more
Add abundant mouthfeel, flavor coordination, high-quality buccal cigarette.Based on preferred fermentation raw material, the present invention summarizes micro-glue further
Capsule is encapsulated, and overcomes that existing product nicotine rate of release is too fast, sucks that early stage strength excessive later stage strength is less, whole to be sucked
The deficiency that in journey, smoke is the most thin out, adds and sucks initial stage nicotine dissolution resistance, before not changing overall nicotine burst size
Putting, the time delaying nicotine at the uniform velocity dissolution, (time without the nicotine dissolution of the tobacco shred granule of microcapsule granule interpolation was usual
It is 10～12min, and with the addition of the nicotine dissolution time average out to 15～18min of the pipe blend granule of microcapsule granule, prolong
Grow 50%), thus stable strength and smoke can be kept within the longer time during ensureing to suck, and also the present invention is not
Need additional alkali salt.
Claims (10)
1. a fermented type buccal cigarette with slow-release function, it is characterised in that by the component of following mass percentage content
Preparation obtains:
Pipe blend granule 50%～80%, water 10%～30%, correctives 1%～5%, sweeting agent 1%～5%, flavouring agent 1%～10%；
Described pipe blend granule is the mixture of tobacco shred granule and microcapsule granule, the mixing quality ratio of the two be 2:1～
4:1；
The preparation method of described tobacco shred granule comprises the following steps:
S1. tobacco formulation group is prepared；
S2. Nicotiana tabacum L. processes: rinsed by tobacco leaf use water, removes surface dust, somewhat dries, and removes excessive moisture, shredding；
S3. tobacco shred fermentation: preparation inoculation liquid, is the inoculation after fermentation of 1～15g inoculation liquid/100g tobacco shred according to inoculum concentration, described in connect
That plants liquid consists of high fructose syrup: protein peptide: strain: the mass ratio of water=(50～200) g:(0.1～10) g:(0.01～1) g:
(100～500) g；
S4., after fermentation ends, carry out sterilization treatment and get final product；
The preparation method of described microcapsule granule comprises the following steps:
S5. extraction: tobacco shred granule employing water is extracted, filters to obtain solid content after extraction, solid content is dried size-reduced mistake
After sieve, take 40～60 mesh sieves and get extract composition；
S6. peplos: the encapsulating of step S5 gained extract composition is made microcapsule, in described microcapsule with microcapsular envelopes raw material
Mass percent shared by microcapsular envelopes raw material is 20～25%.
The most according to claim 1, there is the fermented type buccal cigarette of slow-release function, it is characterised in that described sweeting agent is honeybee
Honey, white sugar, brown sugar, glucose, fructose, sucrose, Aspartame, xylitol, maltose alcohol, saccharin sodium, tripotassium glycyrrhetate or big
Any one or a few mixture of Fructus Jujubae.
The most according to claim 1, there is the fermented type buccal cigarette of slow-release function, it is characterised in that described correctives be salt,
Cocoa powder, Radix Glycyrrhizae powder or coffee powder；Described flavouring agent is capsicum tincture, menthol or fruit extract.
The most according to claim 1, there is the fermented type buccal cigarette of slow-release function, it is characterised in that described flavouring agent is Fructus Capsici
Tincture, menthol or fruit extract.
The most according to claim 1, there is the fermented type buccal cigarette of slow-release function, it is characterised in that strain described in step S3 is
Monascus (Monascus purpureus Went.), aspergillus oryzae (Aspergillus oryzae), Zygosaccharomyces rouxii (Mucor
Or rhizopus (Rhizopus), yeast (Saccharomyces) or the one of lactic acid bacteria (Lactobacillus) roxianus)
Or it is several.
The most according to claim 1, there is the fermented type buccal cigarette of slow-release function, it is characterised in that extraction described in step S5 is
Extract 1 hour at 50 DEG C after adding water.
The most according to claim 1, there is the fermented type buccal cigarette of slow-release function, it is characterised in that described microcapsular envelopes
Raw material is arabic gum, sodium alginate, carrageenan, dextrin, oligosaccharide, starch derivatives, gelatin, casein, carboxymethyl cellulose
Arbitrarily two or more combination in element sodium, ethyl cellulose or methylcellulose.
The most according to claim 1, there is the fermented type buccal cigarette of slow-release function, it is characterised in that encapsulating described in step S6 is
In 60～70 ° of C waters bath with thermostatic control, lower toward addition peplos raw material in extract composition being stirred continuously, when peplos material dissolution is complete
Quan Hou, carries out homogenizing, mixture is carried out high speed dispersion, obtains emulsion, by emulsion spray drying, prepares microcapsule；Excellent
Selecting the process conditions of described spray drying is hot-air inlet temperature 180～250 DEG C, leaving air temp 80～90 DEG C.
9. there is described in claim 1 to 8 preparation method of the fermented type buccal cigarette of slow-release function, it is characterised in that be according to
Pipe blend granule 50%～80%, water 10%～30%, correctives 1%～5%, sweeting agent 1%～5%, the ratio of flavouring agent 1%～10%
After mixing, poisture-penetrability sack is used to pack by the specification of 0.1～0.5g/ bag.
10. the buccal cigarette that preparation method described in claim 9 prepares.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3620068A1 (en) * | 2018-09-04 | 2020-03-11 | Reemtsma Cigarettenfabriken GmbH | A pouched smokeless oral product comprising at least one flavour capsule |
| CN112444466A (en) * | 2019-09-05 | 2021-03-05 | 上海新型烟草制品研究院有限公司 | Method for evaluating in-vitro absorption of nicotine buccal nicotine |
| CN117625420A (en) * | 2024-01-25 | 2024-03-01 | 天津科技大学 | Method for preparing essence and spice by composite microorganism liquid state fermentation of tobacco leaves and saccharomyces cerevisiae |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101262786A (en) * | 2005-05-25 | 2008-09-10 | 美国无烟烟草制品公司 | Tobacco compositions |
| CN101548797A (en) * | 2008-03-31 | 2009-10-07 | 湖北中烟工业有限责任公司 | Cigarette and preparation method thereof |
| CN102715647A (en) * | 2012-07-02 | 2012-10-10 | 湖北中烟工业有限责任公司 | Novel buccal cigarette |
| CN102933102A (en) * | 2010-04-08 | 2013-02-13 | R.J.雷诺兹烟草公司 | Smokeless tobacco composition comprising tobacco-derived material and non-tobacco plant material |
| CN102920013A (en) * | 2012-11-19 | 2013-02-13 | 湖南中烟工业有限责任公司 | Tobacco extractive microcapsule and preparation method thereof |
| CN105286080A (en) * | 2015-11-12 | 2016-02-03 | 贵州中烟工业有限责任公司 | Smokeless tobacco product held in mouth and preparation method thereof |
| WO2016025116A1 (en) * | 2014-08-13 | 2016-02-18 | R.J. Reynolds Tobacco Company | Smokeless tobacco products |
-
2016
- 2016-05-13 CN CN201610323524.3A patent/CN105831798B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101262786A (en) * | 2005-05-25 | 2008-09-10 | 美国无烟烟草制品公司 | Tobacco compositions |
| CN101548797A (en) * | 2008-03-31 | 2009-10-07 | 湖北中烟工业有限责任公司 | Cigarette and preparation method thereof |
| CN102933102A (en) * | 2010-04-08 | 2013-02-13 | R.J.雷诺兹烟草公司 | Smokeless tobacco composition comprising tobacco-derived material and non-tobacco plant material |
| CN102715647A (en) * | 2012-07-02 | 2012-10-10 | 湖北中烟工业有限责任公司 | Novel buccal cigarette |
| CN102920013A (en) * | 2012-11-19 | 2013-02-13 | 湖南中烟工业有限责任公司 | Tobacco extractive microcapsule and preparation method thereof |
| WO2016025116A1 (en) * | 2014-08-13 | 2016-02-18 | R.J. Reynolds Tobacco Company | Smokeless tobacco products |
| CN105286080A (en) * | 2015-11-12 | 2016-02-03 | 贵州中烟工业有限责任公司 | Smokeless tobacco product held in mouth and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3620068A1 (en) * | 2018-09-04 | 2020-03-11 | Reemtsma Cigarettenfabriken GmbH | A pouched smokeless oral product comprising at least one flavour capsule |
| WO2020048891A1 (en) * | 2018-09-04 | 2020-03-12 | Reemtsma Cigarettenfabriken Gmbh | A pouched smokeless oral product comprising at least one flavour capsule |
| CN112444466A (en) * | 2019-09-05 | 2021-03-05 | 上海新型烟草制品研究院有限公司 | Method for evaluating in-vitro absorption of nicotine buccal nicotine |
| CN112444466B (en) * | 2019-09-05 | 2023-02-28 | 上海新型烟草制品研究院有限公司 | Method for evaluating in-vitro absorption of nicotine buccal cigarette |
| CN117625420A (en) * | 2024-01-25 | 2024-03-01 | 天津科技大学 | Method for preparing essence and spice by composite microorganism liquid state fermentation of tobacco leaves and saccharomyces cerevisiae |
| CN117625420B (en) * | 2024-01-25 | 2024-05-03 | 天津科技大学 | Method for preparing essence and spice by composite microorganism liquid state fermentation of tobacco leaves and saccharomyces cerevisiae |
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|---|---|
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