CN105821561A - Manufacturing method of basalt composite fiber fabric for heat-insulating layer of heat-resistant conveyor belt - Google Patents
Manufacturing method of basalt composite fiber fabric for heat-insulating layer of heat-resistant conveyor belt Download PDFInfo
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- CN105821561A CN105821561A CN201610319925.1A CN201610319925A CN105821561A CN 105821561 A CN105821561 A CN 105821561A CN 201610319925 A CN201610319925 A CN 201610319925A CN 105821561 A CN105821561 A CN 105821561A
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- basalt
- basalt composite
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- fiber fabric
- conveyor belt
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
- D03D1/0094—Belts
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/242—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
- D03D15/247—Mineral
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Woven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a manufacturing method of basalt composite fiber fabric for a heat-insulating layer of a heat-resistant conveyor belt, and belongs to the field of manufacturing of canvas for heat-insulating layers of heat-resistant conveyor belts. The problem that in the prior art, basalt fabric is poor in break resistance is solved. According to the manufacturing method, after continuous basalt fibers and synthetic fibers are twisted in a blended mode, the basalt composite fibers with the advantages of being high in tensile strength, good in heat resistance, low in heat conduction, good in bending fatigue resistance and the like is manufactured; with basalt composite fibers as warp yarns and basalt composite fibers or continuous basalt composite fibers as weft yarns, canvas is woven, impregnation is carried out, and the basalt composite fiber fabric obtained after impregnation can be applied to the heat-insulating layer of the heat-resistant conveyor belt and have the advantages of good rubber bonding, good heat resistance, good heat-insulating performance, good wrinkle resistance and the like.
Description
Technical field
The invention belongs to heat resistance conveyor belt thermal insulation layer canvas and manufacture field, specifically, particularly relate to the manufacture method of a kind of heat resistance conveyor belt thermal insulation layer basalt composite fiber fabric.
Background technology
Conveyer belt, as the term suggests being exactly the product for the purpose of transmitting material.Under normal circumstances, conveyer belt is mainly by rubber, and framework material forms.Currently, conveyer belt has been applied to a lot of fields in production, life, the unique requirements to conveyer belt is had again, when such as transporting slag, coke, hot-cast part etc., it is necessary to conveyer belt has preferable resistance to elevated temperatures, heat-resistant anti-fatigue performance etc. except transmitting each field of material.This just requires rubber, skeleton, and the bonding of rubber and skeleton is required for good high temperature resistant, heat-resistant anti-fatigue performance.Currently in order to protect the adhesive layer of framework material and protection rubber and skeleton, the conveyer belt producer thermostability that majority selection is high when structure design and production, the material of low heat conductivity, it is used between framework material and topping rubber, is provided with thermal insulation layer.Currently, thermal insulation layer mainly has nylon dipped canvas, aramid fiber dipped canvas etc..
Basalt fibre, with the natural volcanic rock of inorganic material as raw material, is spun into fiber after have passed through high-temperature fusion.The excellent properties such as it has just possessed good resistance to elevated temperatures, thermal shock resistance, low thermal conductivity at the beginning of being born, and has higher hot strength and modulus, has higher sound-absorption coefficient, relatively low hydroscopicity.Due to unique performance of basalt fibre, have become as various countries pays close attention to object, either from the spinning of basalt fibre, or the application that basalt fibre is in the composite, in recent years, basalt fibre all has been achieved for the development advanced by leaps and bounds.In various fields, basalt fibre can substitute in performance, even more than the material such as aramid fiber, carbon fiber, steel wire.
At present, there are scholar and enterprise, basalt fibre has been carried out correlational study and exploration in the manufacturing application of conveyer belt.
On framework material with rubber adhesion, patent CN105175783A have studied can be by continuous basalt fiber technology together with elastomeric material bonding.
Designing in the structure of canvas, patent CN204777121U have studied the framework material canvas for conveyer belt, and this canvas structure is, through the canvas fabric that weft yarn is all made into by continuous basalt fiber.Patent CN104692027A have studied the framework material canvas for conveyer belt, and its warp thread is made up of continuous basalt fiber, the fabric that weft yarn is made into by continuous basalt fiber or other synthetic fibers.Also having patent CN105035629A to have studied the material fabric of thermal insulation layer of conveyer belt, its warp thread is nylon fiber, and weft yarn is continuous basalt fiber fabric.
Current basalt, at the correlational study of conveyer belt industry, is concentrated mainly in the design change of fabric construction.Or use impregnation basalt fabric woven nylon fiber is as sealing coat, or use single impregnation basalt Woven fabric as casing play.These means and method, the good characteristics such as basalt fibre intensity is high, heatproof height introduce in conveyer belt, improve the tear resistance of conveyer belt, improve the serviceability such as high temperature resistant of conveyer belt, but the anti-performance that fractures of continuous basalt is the most excellent, if only using single basalt fibre to carry out fabric manufacture as warp thread or weft yarn, and as the framework material of conveyer belt thermal insulation layer, then have impact on the overall performance of conveyer belt.
Summary of the invention
The present invention provides the manufacture method of a kind of heat resistance conveyor belt thermal insulation layer basalt composite fiber fabric, can be prepared the basalt composite fiber fabric with thermostability, resistance to fold, low cost by the manufacture method of the present invention, can be used as the thermal insulation layer of conveyer belt.
The present invention implements by the following technical programs:
Comprise the steps:
A, carry out mixing adding by continuous basalt fiber and synthetic fibers on plying twisting machine or straight twister and be twisted into basalt composite fibre;
B, the basalt composite fibre made is carried out warping by warping machine;
C, using basalt composite fibre complete for warping machine warping as warp thread, or will not pass through the warping machine directly basalt composite fibre on bobbin cradle as warp thread, use basalt composite fibre as weft yarn simultaneously, or use continuous basalt fiber as weft yarn, canvas loom is weaved;
D, by the fabric after weaving through a bath activation, enter two bath RFL system impregnations after drying, final drying obtains basalt composite fiber fabric.
Synthetic fibers in described step a are made up of one or more in terylene, nylon66 fiber, nylon 6, PEN fiber, aramid fiber, rayon fiber, in step a, basalt composite fibre is together added with sub-thread or multiply synthetic fibers by sub-thread or multiply continuous basalt and is twisted into, speed of twisting thread is 1000-5000rpm, after twisting thread, strength is 70-500N/ stock, and viscosity is 40-140 twist/m.
In described step c, the end count of Woven fabric is 60-120 root/10cm, and filling density is 30-120 root/10cm, and through being 1000-5000N/cm to ultimate strength after having weaved, broadwise ultimate strength is 300-1500N/cm.
In described step d, a bath activating component can use one or more in silane coupler, maleic anhydride, titanate coupling agent, diglycidyl ether type epoxy resin, total solid content is 0.1%-10%, one bath is dried temperature and is 50-200 DEG C, and drying time is 0.5-3min.
In described step d, two bath RFL systems include latex and a first resin, between first resin and latex solid content ratio be 10%-25%, the total solid content of system is 15%-25%, described latex can use one or more in styrene-butadiene latex, NBR latex, butadiene-vinylpyridine copylymer latex, Heveatex, binary or ethylene propylene diene rubber latex, chlorosulfonated polyethylene latex, two baths are dried temperature and are 100-250 DEG C, and drying time is 0.5-3min.
The rubber separation strength that described basalt composite fiber fabric obtains is 7.8N/mm, and it is 80%-100% that rubber peels off rubber coating rate.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention by after mixed to continuous basalt fiber and synthetic fibers sth. made by twisting, is made for having the basalt composite fibre of hot strength height, excellent heat resistance, the feature such as conduction of heat is low, bending fatigue resistance is excellent;This method is with basalt composite fibre as warp thread, basalt composite fibre or continuous basalt fiber are made into canvas fabric as weft yarn, carry out impregnation again, basalt composite fiber fabric after impregnation can be used for the thermal insulation layer of heat resistance conveyor belt, has the advantages such as good with rubber adhesion, thermostability is good, heat-proof quality is strong, anti-fold is good.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is the most further described in detail:
Example 1
With the twisting on plying twisting machine of sub-thread 1400dtex nylon 66 fiber, 2 strands of 660dtex continuous basalt fibers are prepared warp thread, and ingot speed 2500RPM, the twist is 60 twists/m;The twisting on plying twisting machine of 2 strands of 660dtex continuous basalt fibers is prepared weft yarn, and the twist is 60 twists/m.
Using bobbin cradle-loom process route, basalt-nylon66 fiber composite fibre and continuous basalt fiber are carried out canvas weaving, its fabric construction is plain weave, 100/10cm of end count, and filling density is 90/10cm.
Basalt composite fiber fabric weaving completed uses two bath impregnations to carry out impregnation production on Benniger cement dipping machine, gum dipping process is: a bath uses KH550 to carry out impregnation, baking temperature is 100 DEG C-200 DEG C, drying time is 1min, after one bath impregnation completes, two bath employing standards RFL carry out impregnation, baking temperature 120 DEG C-220 DEG C, drying time is 1min, and impregnation finally gives basalt composite fiber fabric after completing.
Example 2
With the twisting on plying twisting machine of sub-thread 1440dtex activated polyester fiber, 2 strands of 660dtex continuous basalt fibers are prepared warp thread, and ingot speed 2500RPM, the twist is 60 twists/m;The twisting on plying twisting machine of 4 strands of 660dtex continuous basalt fibers is prepared parallel, and the twist is 40 twists/m.
Using bobbin cradle-loom process route, basalt-polyester complex fiber and continuous basalt fiber are carried out canvas weaving, its fabric construction is plain weave, 100/10cm of end count, and filling density is 70/10cm.
Basalt composite fiber fabric weaving completed uses two bath impregnations to carry out impregnation production on Benniger cement dipping machine, gum dipping process is: a bath uses the mixture of KH550 Yu G1701 to carry out impregnation, be dried is 100 DEG C-200 DEG C, drying time is 1min, after one bath impregnation completes, two dry employing standards RFL of bath carry out impregnation, baking temperature is 120 DEG C-220 DEG C, and drying time is 1min, and impregnation finally gives basalt composite fiber fabric after completing.
Impregnation basalt composite fiber fabric embodiment 1 prepared with embodiment 2 and EP, EE, NN canvas use GB method of testing to test, and every data target contrast of test is as follows:
Table 1
From table 1 it follows that the basalt composite fiber fabric that the present invention produces has, heat resistance is high, heat conductivity is compared with the end, the advantage such as hot strength is higher, the anti-fold of resist bending is good.
In sum, it is only presently preferred embodiments of the present invention, not being used for limiting the scope that the present invention implements, all equalizations done according to the shape described in scope of the invention as claimed, structure, feature and spirit change and modify, all should be included in scope of the presently claimed invention.
Claims (6)
1. the heat resistance conveyor belt thermal insulation layer manufacture method of basalt composite fiber fabric, it is characterised in that: comprise the steps:
A, carry out mixing adding by continuous basalt fiber and synthetic fibers on plying twisting machine or straight twister and be twisted into basalt composite fibre;
B, the basalt composite fibre made is carried out warping by warping machine;
C, using basalt composite fibre complete for warping machine warping as warp thread, or will not pass through the warping machine directly basalt composite fibre on bobbin cradle as warp thread, use basalt composite fibre as weft yarn simultaneously, or use continuous basalt fiber as weft yarn, canvas loom is weaved;
D, by the fabric after weaving through a bath activation, enter two bath RFL system impregnations after drying, final drying obtains basalt composite fiber fabric.
The manufacture method of heat resistance conveyor belt thermal insulation layer basalt composite fiber fabric the most according to claim 1, it is characterized in that: the synthetic fibers in described step a are made up of one or more in terylene, nylon66 fiber, nylon 6, PEN fiber, aramid fiber, rayon fiber, in step a, basalt composite fibre is together added with sub-thread or multiply synthetic fibers by sub-thread or multiply continuous basalt and is twisted into, speed of twisting thread is 1000-5000rpm, after twisting thread, strength is 70-500N/ stock, and viscosity is 40-140 twist/m.
The manufacture method of heat resistance conveyor belt thermal insulation layer basalt composite fiber fabric the most according to claim 1, it is characterized in that: in described step c, the end count of Woven fabric is 60-120 root/10cm, filling density is 30-120 root/10cm, through being 1000-5000N/cm to ultimate strength after having weaved, broadwise ultimate strength is 300-1500N/cm.
The manufacture method of heat resistance conveyor belt thermal insulation layer basalt composite fiber fabric the most according to claim 1, it is characterized in that: in described step d, a bath activating component can use one or more in silane coupler, maleic anhydride, titanate coupling agent, diglycidyl ether type epoxy resin, total solid content is 0.1%-10%, one bath is dried temperature and is 50-200 DEG C, and drying time is 0.5-3min.
The manufacture method of heat resistance conveyor belt thermal insulation layer basalt composite fiber fabric the most according to claim 1, it is characterized in that: in described step d, two bath RFL systems include latex and a first resin, between first resin and latex solid content ratio be 10%-25%, the total solid content of system is 15%-25%, described latex can use one or more in styrene-butadiene latex, NBR latex, butadiene-vinylpyridine copylymer latex, Heveatex, binary or ethylene propylene diene rubber latex, chlorosulfonated polyethylene latex, two baths are dried temperature and are 100-250 DEG C, and drying time is 0.5-3min.
The manufacture method of heat resistance conveyor belt thermal insulation layer basalt composite fiber fabric the most according to claim 1, it is characterised in that: the rubber separation strength that described basalt composite fiber fabric obtains is 7.8N/mm, and it is 80%-100% that rubber peels off rubber coating rate.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105926301A (en) * | 2016-06-08 | 2016-09-07 | 江苏太极实业新材料有限公司 | Manufacturing method of basalt composite fiber fabric for layered conveyor belt |
CN107804979A (en) * | 2017-11-08 | 2018-03-16 | 四川省玻纤集团有限公司 | One kind enhancing rubber basalt fibre size and preparation method of being chopped |
CN108035092A (en) * | 2017-11-23 | 2018-05-15 | 柳州市橡六中青橡胶有限公司 | The equipment that impregnation is carried out for the sizing material of fabric core conveyor belt impregnation and with the sizing material |
CN109411164A (en) * | 2018-09-12 | 2019-03-01 | 全球能源互联网研究院有限公司 | A kind of composite post insulator plug and preparation method thereof |
CN110863351A (en) * | 2019-10-10 | 2020-03-06 | 安徽华烨特种材料有限公司 | Impregnation method of ultrahigh molecular weight polyethylene framework material |
US11247871B2 (en) | 2017-11-10 | 2022-02-15 | Otis Elevator Company | Elevator system belt |
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CN105926301A (en) * | 2016-06-08 | 2016-09-07 | 江苏太极实业新材料有限公司 | Manufacturing method of basalt composite fiber fabric for layered conveyor belt |
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CN109411164A (en) * | 2018-09-12 | 2019-03-01 | 全球能源互联网研究院有限公司 | A kind of composite post insulator plug and preparation method thereof |
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