CN105802724A - Method for reutilizing cold pressed camellia oleifera seed meal - Google Patents
Method for reutilizing cold pressed camellia oleifera seed meal Download PDFInfo
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- CN105802724A CN105802724A CN201610227724.9A CN201610227724A CN105802724A CN 105802724 A CN105802724 A CN 105802724A CN 201610227724 A CN201610227724 A CN 201610227724A CN 105802724 A CN105802724 A CN 105802724A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/02—Pretreatment
- C11B1/04—Pretreatment of vegetable raw material
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/02—Pretreatment
- C11B1/025—Pretreatment by enzymes or microorganisms, living or dead
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/10—Production of fats or fatty oils from raw materials by extracting
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Abstract
The invention discloses a method for reutilizing cold pressed camellia oleifera seed meal.The method includes the steps that firstly, cold pressed camellia oleifera seed meal is mechanically crushed, pure water and complex enzyme are added, enzymolysis is conducted for 30-120 minutes at the temperature of 40-90 DEG C, upper-layer enzymolysis camellia oleifera oil is obtained through centrifugation and separation, filtering is conducted, and enzymatic hydrolysate is obtained; organic solvent is added to residues left over in the filtering process, the mixture is stirred and extracted, organic solvent is volatilized, and extracted camellia oleifera oil is obtained; the enzymatic hydrolysate is heated and subjected to enzyme deactivation ad concentration after being filtered till the enzymatic hydrolysate is in a paste state; the extracted residuals are subjected to fine grinding and made into camellia oleifera meal fine powder; the enzymolysis camellia oleifera oil can be used as edible oil, and the paste, the camellia oleifera oil and the camellia oleifera meal fine powder serve as raw materials to be prepared into skin care products.By means of the method, effective ingredients of the cold pressed camellia oleifera seed meal can be comprehensively utilized effectively, waste of natural resources is reduced, environmental pollution is reduced, and comprehensive utilization value of camellia oleifera planting and processing is improved.
Description
Technical field
The present invention relates to the Application way of a kind of camellia seed meal, particularly relate to a kind of by pressed oil leached tea oil slag recycling
Method.
Background technology
Cold-press liquefaction has feature few to nutrition of lipids component damage, but also has the shortcoming that Residual oil storage is many.
Containing compositions such as oil tea oil, tea polyphenols, tea saponin, tea polysaccharide in cake of camellia oleifera seeds, can be used.
The method that common edible oil and fat are produced has hot moulding method, cold-press, extraction, enzyme process, first three mode
Being industrialized production edible oil method, particularly the first is topmost liquefaction side of China with the third method
Method.Oils and fats first will be suppressed out after squeezing raw material heating parch by hot moulding method again by mechanical pressure, and cold-press is
Directly not suppressing out by oils and fats by mechanical pressure by heating, extraction uses petroleum benzin solvent by raw material
Middle oils and fats extracts, then by obtaining edible oil after degumming, decolouring, deacidification process recycling design.In three kinds of methods
Extraction oil yield is the highest, but is because using organic solvent to there is problem of solvent residual, and solvent extraction
In journey, some unedible oil composition is extracted, and adds the complexity that subsequent purification processes.Hot moulding method is by heating
Make protein denaturation, edible oil easily be squeezed out, but heating parch can bring toxicant benzopyrene etc. into,
The antioxidant content content such as vitamin E, polyphenol is suffered a loss, and color with oil color is deeper.Cold-press is the most extensive
Producing few, main cause is that cold-press oil yield is lower than hot moulding method, and cold-press makes finished product lack some vegetable oil
The fragrance baked, such as Oleum sesami.
Cold-press comparative maturity abroad, is such as applied in olive oil liquefaction, and hot moulding method can cause its local flavor to become
Difference and loss of effective components, cold pressing maintains distinctive local flavor and the nutritional labeling of olive oil.
No matter which kind of method, except in grouts such as minority such as Semen sojae atricolor, Semen arachidis hypogaeae etc., proteinaceous nutrient component content compares high energy
Beyond recycling, after major part oil expression, grouts go out of use and cause the pollution problem of environment to be difficult to solve.China at present
Main preparation oil tea oil uses hot moulding method, and Extracted From Oil-tea-cake not only causes environmental pollution after abandoning as processing refuse, its
In effective ingredient be also wasted.
Enzyme process liquefaction at home and abroad have research discuss, this method by the protease that adds water after raw material pulverizing, adds,
Cellulase, to reduce oils and fats and protein, cellulose attached for decomposing protein and cellulose under certain condition
Putting forth effort so that oils and fats easily is squeezed out, the enzymolysis time of this enzymolysis oil often reaches more than 4 hours and causes oil
Fat acid valency has additional nutrients component damages, and as edible oil, often safety requirements is the most up to standard, additionally deposits in enzymolysis solution
Not being utilized at mass efficient composition, directly discharge has pollution to environment.
Facial cleaning cream, emulsion, surfactant, facial film, clean skin soap etc. are daily cleaning, skin protection daily chemical products,
It is improved the demand of quality of life along with economic level improves people, needs to carry out the nursing of skin and reparation, protect
Hold the moist of skin and vigor.Owing to there is the problem of environmental pollutions such as haze, skin be will also result in certain damage
Wound makes it the oldest and the most feeble, and cleaning and the nursing of carrying out skin can reduce the environment damage to skin, prevent from polluting
Thing penetrates into.Containing organic silicone oil, sodium chloride, sodium hydroxide, potassium hydroxide, dodecane in common cleaning product
The chemical reagent such as base benzene sulfonic acid sodium salt, these products have certain stimulation and damage to skin, sebum can be caused to run off,
The phenomenons such as xerosis cutis, damage horny layer, these chemical reagent directly discharge and also can adversely affect environment
Destroy with certain.
Summary of the invention
Present invention aims to the deficiencies in the prior art, it is provided that a kind of by pressed oil leached tea oil slag recycle
Method, the method by the residue after Semen Camelliae cold pressing oil again refine acquisition extractum, enzymolysis oil tea oil,
Extraction oil Oleum Camelliae, Extracted From Oil-tea-cake fine powder composition, then prepare skin care item as raw material.
The method recycled by pressed oil leached tea oil slag of the present invention, first by pressed oil leached tea oil slag mechanical activation comminution Cheng Zhi
The little granule of footpath below 0.4cm, adds the pure water that quality is camellia seed meal quality 10-30 times, adds multiple
Synthase, enzymolysis 30-120 minute at 40-90 DEG C, centrifugation goes out upper strata enzymolysis oil tea oil, and sucking filtration goes out
Enzymolysis solution, obtained enzymolysis oil tea oil can be as edible oil；Adding quality in residual residue is camellia seed meal
The organic solvent of 5-20 times, filters after stirring 30-60 minute, and the filter vacuum evaporation of solvent of filtration is (molten
Agent reusable edible) it is extracted oil tea oil, after being filtered by above-mentioned enzymolysis solution, heating enzyme denaturing is concentrated into extractum shape
Obtain oil tea extractum；Above-mentioned stripped residue is finely ground to Extracted From Oil-tea-cake fine powder；By described oil tea extractum, oil
Oleum Camelliae and Extracted From Oil-tea-cake fine powder are used for preparing skin care item as raw material.
In such scheme, described compound enzyme is protease, cellulase, glucanase and pectase, by matter
Its ratio of gauge is protease: cellulase: glucanase: pectase=2:2:1:1.Adding of compound enzyme
Dosage is the 2%-20% of pressed oil leached tea oil slag quality.
Described organic solvent is gasoline, ethanol, petroleum ether or normal hexane.
Be used for preparing skin care item as raw material using above-mentioned extractum, extraction oil Oleum Camelliae and Extracted From Oil-tea-cake fine powder, mainly have with
Under several schemes:
1) residue after being filtered by described enzymolysis solution is crushed to more than 100 mesh, by oily, oily for described oil tea
Tea extract, citric acid, stearic acid, Cera Flava, glycerol, triethanolamine, Margarita powder and pure water as raw material,
First by oil-soluble ingredients therein and water soluble ingredient heating for dissolving respectively, oil-soluble ingredients refers to that oil tea is oily, stearic
Acid, Cera Flava and liquid paraffin, water soluble ingredient refers to oil tea extractum, citric acid, glycerol, triethanolamine and pure
Water, then joins in oil-soluble ingredients by water soluble ingredient, mixes saponification, adds above-mentioned oil tea residue powder
End and Margarita powder, use homogenizer homogenization, obtain facial cleaning cream.
2) by described oil tea extractum, described oil tea oil, stearic acid, hexadecanol, polyoxyethylene, single oil
Acid esters, Polyethylene Glycol, triethanolamine, pure water, spice (Flos Camelliae Japonicae quintessence oil, rose ethereal oil) are as former
Material, wherein oil tea extractum, hexadecanol, Polyethylene Glycol, triethanolamine and pure water heating for dissolving will obtain aqueous phase,
Other oil-soluble ingredients Hybrid Heating are obtained oil phase, keeps 70 DEG C, under stirring, aqueous phase is added in oil phase, so
Rear addition Flos Camelliae Japonicae and rose ethereal oil, carry out emulsifying, stirring cooling with homogenizer after mixing saponification, obtain
To milky lotion.
3) by described oil tea extractum, pure water, hexadecanol, ethanol, glycerol, rose ethereal oil, Flos Camelliae Japonicae
Flower essential oil mixes, and carries out uniform emulsifying with homogenizer, cools down, obtain lotion after sterilizing.
4) add water the oil tea extractum described in heating for dissolving, addition, pure water, polyethylene by carboxymethyl cellulose
Alcohol, glycerol, ethanol, vitamin C, Flos Camelliae Japonicae quintessence oil, rose ethereal oil mix, and carry out homogenizing with homogenizer
Emulsifying, cools down after sterilizing, obtains facial treatment mask.
5) by described oil tea oil, Cera Flava, olive oil, Oleum Cocois, Petiolus Trachycarpi oil, stearic acid mixing, water-bath
Heating for dissolving obtains oil phase, by described oil tea extractum, hexadecanol, glycerol, Borax, triethanolamine and pure water
Stirring Hybrid Heating obtains aqueous phase, above-mentioned aqueous phase and oil-phase component is mixed at 40 DEG C-50 DEG C, and stirring 20-30 divides
Clock, adds Flos Camelliae Japonicae quintessence oil and Herba Lysimachiae foenum-graeci quintessence oil mixing, pours cooling in mould into fixing, it is thus achieved that Manual perfumed soap.
The invention has the beneficial effects as follows:
1) present invention uses enzymolysis-solvent extraction two-step method to process pressed oil tea-cake dregs, the most greatly
Extract the Oleum Camelliae composition in camellia seed meal, and by segmentation liquefaction, by equal to different oil products and other compositions
Be obtained by, it is thus achieved that enzymolysis oil tea oil can be used for eating, it is thus achieved that extraction oil Oleum Camelliae for daily chemical products develop,
The oil tea oil that the scheme extracted again after this enzymolysis can extract reaches the 8-15% of camellia seed meal quality, it is achieved that to oil
The depth extraction of leached tea oil slag.
2) product using this method prepares skin care item as primary raw material, because of the protein wherein contained, polypeptide,
The materials such as aminoacid, monosaccharide, oligosaccharide, tea polysaccharide, and the effective ingredient such as tea polyphenols, tea saponin plays guarantor
The effects such as wet, emulsifying, cleaning, antibacterial, nutrition, it is not necessary to add the chemistry examination being irritating to the skin and injuring again
Agent, can be truly realized all-natural product, skin protection safety, environmental friendliness.
3) this method achieves the very utilization of camellia seed meal, without waste, environmentally safe；Greatly
Improve the economic worth of oil tea plantation.
Detailed description of the invention
The method recycled by pressed oil leached tea oil slag of the present invention, first by pressed oil leached tea oil slag mechanical activation comminution Cheng Zhi
The little granule of footpath below 0.4cm, adds the pure water that quality is camellia seed meal quality 10-30 times, adds multiple
Synthase, enzymolysis 30-120 minute at 40-90 DEG C, centrifugation goes out upper strata enzymolysis oil tea oil, and sucking filtration goes out
Enzymolysis solution；Adding organic solvent extraction in remaining residue and obtain extraction oil Oleum Camelliae, organic solvent can be with recycling profit
With, use enzymolysis and these two parts of extraction can extract the oil tea oil of pressed oil leached tea oil slag quality 8-15% altogether.Will
After above-mentioned enzymolysis solution filters, heating enzyme denaturing is condensed into oil tea extractum；Above-mentioned oil tea extractum and extraction oil Oleum Camelliae are made
It is used for preparing skin care item for raw material, extracts remaining residue after drying through being finely ground into Extracted From Oil-tea-cake fine powder, it is also possible to
It is applied in skin care item preparation.
Embodiment 1: facial cleaning cream
Facial cleaning cream is a kind of skin-cleaning cosmetics, has skin care effect concurrently.Facial cleaning cream is possible not only in clean skin one
As dirt, and the oils and fats of pore inner accumulated, scurf and the vestiges of heavy make-up cosmetics can be removed.
Facial cleaning cream formula 1
Suggestion facial cleaning cream formula (in terms of 100g finished product, each component uses ratio): oil tea oil 20%, glycerol
15%, Cera Flava 7%, triethanolamine 6.8%, hexadecanol 2.5%, stearic acid 5.5%, oil tea extractum 12%, oil
Tea seed cake fine powder 3%, Margarita powder 0.5%, citric acid 0.7%, pure water 27%.
Operating procedure
1,1kg pressed oil leached tea oil slag pulverizer is ground into diameter 0.4cm following camellia seed meal coarse powder.
2, in rustless steel or glass container, add camellia seed meal coarse powder, add 10kg to 30kg pure water,
Open stirring, with 20-30 rev/min of rotating speed agitating solution, open heating, make liquid be warming up to 40-90 DEG C.
3, add compound enzyme (composition and the ratio of compound enzyme is protease in the present embodiment: cellulase:
Glucanase: pectase=2:2:1:1, in mass) compound enzyme adds total amount is pressed oil leached tea oil slag matter
The 2%-20% of amount, maintains the temperature at 40-90 DEG C after adding compound enzyme, continues stirring 40 minutes.
4, after enzymolysis terminates, supernatant liquid is extracted, with centrifugal separator with the speed of 2500 revs/min
Separate, obtain enzymolysis oil tea oil about 60g.
5, remaining enzymolysis solution flannelette is filtered, separates enzymolysis solution and Extracted From Oil-tea-cake residue,
6, the enzymolysis solution that will collect, is heated to 100 DEG C and keeps 15 minutes enzyme denaturing, be then concentrated in vacuo oily
Tea extract 5kg.
7, it is filtrated to get Extracted From Oil-tea-cake residue to be put in rustless steel or glass container, adds 10kg petroleum benzin, with
20-30 rev/min of rotating speed stirring is extracted 20 minutes, after stirring terminates, is filtered by flannelette, separates solvent and oil
Leached tea oil slag residue, volatilizees and recycling design with vacuum rotating at 60 DEG C, and solvent is recycling, and residue obtains about
The oil tea oil of 80g solvent extraction.
8, previous step gained camellia seed meal residue is put into baking oven or drying room, adjust the temperature to 60-90 DEG C, will
Residue is dried.Residue ball mill grinding after drying, to more than fineness 100 mesh, obtains Extracted From Oil-tea-cake fine powder.
9, in a rustless steel or glass container add water-phase component i.e. glycerol, triethanolamine, hexadecanol,
Oil tea extractum, citric acid and pure water, be heated to 90 DEG C and make mentioned component dissolve and sterilize, and continues stirring cold
But to 70 DEG C-80 DEG C.
10, in another one rustless steel or glass container, oil-phase component i.e. oil tea oil, Cera Flava, stearic acid are added,
Oil phase is also heated to 90 DEG C by stirring, makes solid state component dissolve and sterilizes.
11, it is kept stirring for oil phase, then aqueous phase is added rapidly in oil phase, during aqueous phase adds,
It is possible that of short duration a small amount of soap blank clustering phenomena produced in system, wait aqueous phase to add completely and terminate rear soap group
Nature can disappear.
12, after aqueous phase has added, in the case of keeping system temperature to be not less than 70 DEG C, it is incubated saponification 30-60
Minute.
13, adding Extracted From Oil-tea-cake fine powder and the Margarita powder being crushed to more than 100 mesh at the end of saponification is fast, stirring makes it
Be evenly distributed in mastic, it is to avoid excessive whipping produce bubble.
14, mixture is used homogenizer homogeneous micronization, mastic is loaded in container containing, seal.
Containing protein, polypeptide, tea polyphenols, tea polysaccharide, tea saponin, oligosaccharide, monosaccharide, fibre in this product
The Natural surfactant compositions such as dimension element, have antibacterial, moisturizing, antiviral, reparation skin components, and Extracted From Oil-tea-cake is thin
Powder is as natural polymers, by the CONTACT WITH FRICTION with skin during cleaning, by skin dirt and metabolite
Adsorption, is that cleaning effect is good, moistens, stimulates little facial cleaning cream.
Embodiment 2: milky lotion
Milky lotion can make skin keep the skin wet, and protects the skin from the external environment stimulation to skin, through skin table
Face supplements suitable moisture and lipid, keeps the moist, soft of skin and high resilience.
Suggestion milky lotion formula (in terms of 100g finished product, each component uses ratio): oil tea oil 5%, oil tea is soaked
Cream 2%, triethanolamine 1.5%, Polyethylene Glycol 1.5%, hexadecanol 1%, stearic acid 0.8%, polyoxyethylene 0.1%,
Monoleate 0.5%, Flos Camelliae Japonicae quintessence oil 1.0%, rose ethereal oil 0.5%, pure water 86.1%.
This product contains the composition such as natural anti-oxidation, antibacterial, water holding, has protection, Glycerin function
Liquid.Mainly supplement moisture content, nutrition, belong to basis skin protection etc.And have the effect of whitening, moisturizing, wrinkle removal
Really.
Operating procedure
1, in first rustless steel or glass container, add water-phase component i.e. oil tea extractum, triethanolamine, gather
Ethylene glycol, hexadecanol, pure water, be heated to 90 DEG C and dissolve and sterilizing.
2, in second rustless steel or glass container, oil-phase component i.e. oil tea oil, stearic acid, polyoxy second are added
Alkene, monoleate, oil phase is also heated to 90 DEG C by limit stirring, makes solid state component dissolve and sterilizing, then by
Gradually stir and be cooled to 70 DEG C.
3, aqueous phase is added rapidly in oil phase, during aqueous phase adds, it is possible that short in system
Temporary a small amount of soap blank clustering phenomena produced, waits aqueous phase to add completely and terminates rear soap group and can disappear.
4, after aqueous phase has added, in the case of keeping system temperature to be not less than 70 DEG C, it is incubated saponification 30-60
Minute, add Flos Camelliae Japonicae quintessence oil and rose ethereal oil, mix homogeneously.
5, milky lotion homogenizer homogenizing after mixing, is filled to mastic in container, seals.
Embodiment 3: surfactant
Surfactant is with water as substrate, and adds other additive with not same-action and make, major function be moisturizing,
Soft, clean, restrain, the effect such as antibacterial.
Suggested formula (in terms of 100g finished product, each component uses ratio): oil tea extractum 3%, hexadecanol 3%, second
Alcohol 10%, glycerol 5%, rose ethereal oil 0.5%, Flos Camelliae Japonicae quintessence oil 1%, pure water 77.5%
Operating procedure
1, in rustless steel or glass container, oil tea extractum and hexadecanol are added, ethanol, glycerol and pure water,
Stirring mixed dissolution.
2, it is heated to 90 DEG C and keeps sterilization in 15 minutes, be cooled to less than 40 DEG C and add Flos Camelliae Japonicae and Flos Rosae Rugosae
Flower essential oil.
3, by mixture by homogenizer emulsifying, it is filled in container, seals.
This product adds on skin after facial cleansing at once, plays moisturizing, moisturizing, skin care, promotees
Enter skin physiology functional recovery.
Embodiment 4: facial treatment mask
It is that one has cleaning and caring skin and beautification function cosmetics that film is executed in face, is spread upon on skin of face,
Gradually form one layer of membranoid substance through certain time at skin surface, this one-tenth thin film is taken off or eccysis, on skin
Dirt, scurf is also attached on thin film and is eliminated therewith.
Suggested formula (in terms of 100g finished product, each component uses ratio): polyvinyl alcohol 20%, carboxymethyl cellulose
5%, glycerol 4%, ethanol 10%, oil tea extractum 5%, vitamin C 1.0%, Flos Camelliae Japonicae quintessence oil 1.0%, rose
Rare flower essential oil 0.5%, pure water 53.5%
Operating procedure:
1, in rustless steel or glass container, add carboxymethyl cellulose, add the pure water of total amount half, while stir
Mix limit to be heated to 50 DEG C and make it dissolve.
2, continuously add polyvinyl alcohol, glycerol, ethanol, oil tea extractum, vitamin C in a reservoir, and remain
Remaining pure water, is stirred and heated to 90 DEG C of sterilizings, carries out emulsifying with homogenizer.
3, to be cooled it is filled in container to 50 DEG C, seals.
Embodiment 5: oil tea Manual perfumed soap
Crude vegetal is substrate by oil tea salted cake fried in sesame oil soap, and adds other additive with not same-action and make, right
Skin injury is little, have horny layer softening layer, clean, restrain, the effect such as antibacterial.
Suggested formula (in terms of 100g finished product, each component uses ratio): oil tea oil 20%, Cera Flava 10%, Fructus Canarii albi
Oil 5%, Oleum Cocois 5%, Petiolus Trachycarpi oil 3%, stearic acid 2%, oil tea extractum 2%, hexadecanol 3%, glycerol 5%,
Borax 22.0%, triethanolamine 6.5%, Flos Camelliae Japonicae quintessence oil 0.5%, Herba Lysimachiae foenum-graeci quintessence oil 0.5%, pure water 15.5%
Operating procedure:
1, in first rustless steel or glass container add oil-phase component i.e. oil tea oil, Cera Flava, olive oil,
Oleum Cocois, Petiolus Trachycarpi oil, stearic acid, be heated to 90 DEG C of dissolved solids sterilizing, then allows it be cooled to 40
DEG C about-50 DEG C.
2, in second rustless steel or glass container, water-phase component i.e. oil tea extractum is added, hexadecanol, glycerol,
Borax, triethanolamine, pure water, it is heated to 90 DEG C of dissolved solids sterilizing, then allows it be cooled to 40 DEG C
About-50 DEG C.
3, aqueous phase is added rapidly in oil phase, during aqueous phase adds, it is possible that short in system
Temporary a small amount of soap blank clustering phenomena produced, is kept stirring for, until aqueous phase add completely terminate after soap group nature can disappear
Lose.It is kept stirring for saponification 20-30 minute, adds Flos Camelliae Japonicae quintessence oil and Garden lavender quintessence oil mix homogeneously.
4, mastic is poured cooling in the mould of definite shape into fixing.
This product has the natural components such as antibacterial, moisturizing, not injured skin, has horny layer softening layer, cleans, receives
Hold back, antibacterial etc. acts on, and life-time service can make skin moist, is effectively improved skin quality.
Claims (9)
1. the method that pressed oil leached tea oil slag is recycled, it is characterised in that first by pressed oil leached tea oil slag
Mechanical activation comminution becomes the little granule of below diameter 0.4cm, and adding quality is the pure of camellia seed meal quality 10-30 times
Water, adds compound enzyme, enzymolysis 30-120 minute at 40-90 DEG C, and centrifugation goes out upper strata enzymolysis oil tea
Oil, and sucking filtration goes out enzymolysis solution, adds the organic solvent that quality is camellia seed meal 5-20 times in residual residue,
Filter after stirring 30-60 minute, filter vacuum evaporation of solvent acquisition extraction oil Oleum Camelliae, recycled solvent,
After being filtered by above-mentioned enzymolysis solution, heating enzyme denaturing is concentrated into extractum shape and obtains oil tea extractum；By above-mentioned stripped residual
Sizing is fine into Extracted From Oil-tea-cake fine powder；Using described oil tea extractum, extraction oil Oleum Camelliae and Extracted From Oil-tea-cake fine powder as the most former
Material is used for preparing skin care item.
The method that pressed oil leached tea oil slag is recycled the most according to claim 1, it is characterised in that institute
The compound enzyme stated is protease, cellulase, glucanase and pectase, and compound enzyme its ratio by mass is
Protease: cellulase: glucanase: pectase=2:2:1:1.
The method that pressed oil leached tea oil slag is recycled the most according to claim 1, it is characterised in that institute
The addition of the compound enzyme stated is the 2%-20% of pressed oil leached tea oil slag quality.
The method that pressed oil leached tea oil slag is recycled the most according to claim 1, it is characterised in that institute
The organic solvent stated is petroleum benzin, ethanol, petroleum ether or normal hexane.
The method that pressed oil leached tea oil slag is recycled the most according to claim 1, it is characterised in that will
Residue after described enzymolysis solution filters is crushed to more than 100 mesh, by described oil tea oil, oil tea extractum, on
State residue powder, Margarita powder, citric acid, stearic acid, Cera Flava, liquid paraffin, glycerol, triethanolamine and pure
Water purification is as raw material, by oil-soluble ingredients heating for dissolving therein, oil-soluble ingredients refer to oil tea oil, stearic acid,
Cera Flava and liquid paraffin；By water soluble ingredient heating for dissolving therein, water soluble ingredient refers to oil tea extractum, Fructus Citri Limoniae
Acid, glycerol, triethanolamine and pure water, then the water soluble ingredient after dissolving joins the oil-soluble after dissolving
In composition, mixing, add described residue powder, Margarita powder, use homogenizer homogenization, obtain facial cleaning cream.
The method that pressed oil leached tea oil slag is recycled the most according to claim 1, it is characterised in that will
Described oil tea extractum, described oil tea oil, stearic acid, hexadecanol, polyoxyethylene, monoleate, poly-second
Water soluble ingredient therein, as raw material, is dissolved in pure water and obtains water by glycol, triethanolamine, pure water, spice
Phase, water soluble ingredient refers to oil tea extractum, hexadecanol, Polyethylene Glycol, triethanolamine and pure water, other is become
Point Hybrid Heating obtains oil phase, keeps 70 DEG C, adds in oil phase by aqueous phase under stirring, with all after mixing pre-emulsification
Matter device carries out uniform emulsifying, stirring cooling, obtains milky lotion.
The method that pressed oil leached tea oil slag is recycled the most according to claim 1, it is characterised in that will
The mixing of described extractum, pure water, hexadecanol, ethanol, glycerol, rose ethereal oil, Flos Camelliae Japonicae quintessence oil, uses
Homogenizer carries out uniform emulsifying, cools down, obtain lotion after sterilizing.
The method that pressed oil leached tea oil slag is recycled the most according to claim 1, it is characterised in that will
Carboxymethyl cellulose adds water heating for dissolving, oil tea extractum described in addition, pure water, polyvinyl alcohol, glycerol,
Ethanol, vitamin C, Flos Camelliae Japonicae quintessence oil, rose ethereal oil mix, and carry out emulsifying, sterilizing with homogenizer
Rear cooling, obtains facial treatment mask.
The method that pressed oil leached tea oil slag is recycled the most according to claim 1, it is characterised in that will
The mixing of described oil tea oil, Cera Flava, olive oil, Oleum Cocois, Petiolus Trachycarpi oil, stearic acid, heating for dissolving obtains oil phase,
Described oil tea extractum, hexadecanol, glycerol, Borax, triethanolamine and pure water stirring Hybrid Heating is obtained water
Phase, mixes above-mentioned aqueous phase and oil phase at 40-50 DEG C, stirs 20-30 minute, add Flos Camelliae Japonicae quintessence oil and smoke
Clothing grass quintessence oil mixes, and pours cooling in mould into fixing, it is thus achieved that Manual perfumed soap.
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