CN105801607B - 一种pvc热稳定剂及其制备方法 - Google Patents
一种pvc热稳定剂及其制备方法 Download PDFInfo
- Publication number
- CN105801607B CN105801607B CN201610243133.0A CN201610243133A CN105801607B CN 105801607 B CN105801607 B CN 105801607B CN 201610243133 A CN201610243133 A CN 201610243133A CN 105801607 B CN105801607 B CN 105801607B
- Authority
- CN
- China
- Prior art keywords
- heat stabilizer
- pvc
- pyridin
- methyl
- present
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Links
- 239000012760 heat stabilizer Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title abstract description 7
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 13
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
- 239000011701 zinc Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- YUWAUUTYKFAJBH-UHFFFAOYSA-N pyridin-4-ylmethanethiol Chemical class SCC1=CC=NC=C1 YUWAUUTYKFAJBH-UHFFFAOYSA-N 0.000 claims description 10
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 235000019441 ethanol Nutrition 0.000 claims description 7
- 239000012046 mixed solvent Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 238000010992 reflux Methods 0.000 claims description 2
- 238000010583 slow cooling Methods 0.000 claims description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 1
- NAYVGHQGPTTZPA-UHFFFAOYSA-N diimino(diphenyl)-$l^{6}-sulfane Chemical compound C=1C=CC=CC=1S(=N)(=N)C1=CC=CC=C1 NAYVGHQGPTTZPA-UHFFFAOYSA-N 0.000 abstract description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 238000010189 synthetic method Methods 0.000 abstract description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 description 27
- 229920000915 polyvinyl chloride Polymers 0.000 description 26
- 239000000463 material Substances 0.000 description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- ATHHXGZTWNVVOU-UHFFFAOYSA-N N-methylformamide Chemical compound CNC=O ATHHXGZTWNVVOU-UHFFFAOYSA-N 0.000 description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- KLUYWDYLSMHCMR-UHFFFAOYSA-N 4-(pyridin-4-ylmethylsulfanylmethyl)pyridine Chemical compound C=1C=NC=CC=1CSCC1=CC=NC=C1 KLUYWDYLSMHCMR-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 150000002311 glutaric acids Chemical class 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- IQFVPQOLBLOTPF-HKXUKFGYSA-L congo red Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(/N=N/C3=CC=C(C=C3)C3=CC=C(C=C3)/N=N/C3=C(C4=CC=CC=C4C(=C3)S([O-])(=O)=O)N)=CC(S([O-])(=O)=O)=C21 IQFVPQOLBLOTPF-HKXUKFGYSA-L 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 208000034874 Product colour issue Diseases 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 150000004291 polyenes Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/06—Zinc compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/378—Thiols containing heterocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/13—Crystalline forms, e.g. polymorphs
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
温度时间ts(min) | |
本发明热稳定剂 | 108.2 |
对比例 | 78.9 |
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610243133.0A CN105801607B (zh) | 2016-04-19 | 2016-04-19 | 一种pvc热稳定剂及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610243133.0A CN105801607B (zh) | 2016-04-19 | 2016-04-19 | 一种pvc热稳定剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105801607A CN105801607A (zh) | 2016-07-27 |
CN105801607B true CN105801607B (zh) | 2018-05-22 |
Family
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CN201610243133.0A Active CN105801607B (zh) | 2016-04-19 | 2016-04-19 | 一种pvc热稳定剂及其制备方法 |
Country Status (1)
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CN (1) | CN105801607B (zh) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1253144A (zh) * | 1998-09-16 | 2000-05-17 | 莫顿国际股份有限公司 | 有机硫化合物和巯基酯的锌盐组合作为pvc加工热稳定剂 |
US20020044968A1 (en) * | 1996-10-28 | 2002-04-18 | General Mills, Inc. | Embedding and encapsulation of sensitive components into a matrix to obtain discrete controlled release particles |
CN102993220A (zh) * | 2012-12-06 | 2013-03-27 | 洛阳师范学院 | 5-溴间苯二甲酸锌配合物及其制备方法 |
CN103183690A (zh) * | 2011-12-31 | 2013-07-03 | 深圳市志海实业有限公司 | 一种pvc用的钙锌热稳定剂、含锌化合物及应用 |
CN104262368A (zh) * | 2014-10-04 | 2015-01-07 | 刘国政 | 脂肪类多羧酸配体侧基调控的配位聚合物及其制备方法 |
-
2016
- 2016-04-19 CN CN201610243133.0A patent/CN105801607B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020044968A1 (en) * | 1996-10-28 | 2002-04-18 | General Mills, Inc. | Embedding and encapsulation of sensitive components into a matrix to obtain discrete controlled release particles |
CN1253144A (zh) * | 1998-09-16 | 2000-05-17 | 莫顿国际股份有限公司 | 有机硫化合物和巯基酯的锌盐组合作为pvc加工热稳定剂 |
CN103183690A (zh) * | 2011-12-31 | 2013-07-03 | 深圳市志海实业有限公司 | 一种pvc用的钙锌热稳定剂、含锌化合物及应用 |
CN102993220A (zh) * | 2012-12-06 | 2013-03-27 | 洛阳师范学院 | 5-溴间苯二甲酸锌配合物及其制备方法 |
CN104262368A (zh) * | 2014-10-04 | 2015-01-07 | 刘国政 | 脂肪类多羧酸配体侧基调控的配位聚合物及其制备方法 |
Non-Patent Citations (1)
Title |
---|
Complex Compounds Based on 1-Isopropenylimidazoles and -pyrazole;Zyryanova, I. A. et al;《Russian Journal of General Chemistry》;20051231;第75卷;第1283-1289页 * |
Also Published As
Publication number | Publication date |
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CN105801607A (zh) | 2016-07-27 |
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SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information |
Inventor after: Cai Jintian Inventor before: Lai Shuxing |
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CB03 | Change of inventor or designer information | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20180425 Address after: 528100 9 North factory building of hardware workshop, 9-2-1, C, 9-2-1, Sanshui Park, Sanshui center, Guangdong. Applicant after: Guangdong common force building materials Co., Ltd. Address before: 528100 1509, room 8, Royal Longwan garden, 28 Xiqing Avenue, Southwest District, Sanshui District, Foshan, Guangdong Applicant before: Lai Shuxing |
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TA01 | Transfer of patent application right | ||
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A PVC heat stabilizer and its preparation method Effective date of registration: 20200826 Granted publication date: 20180522 Pledgee: Guangdong Nanhai Rural Commercial Bank branch branch of Limited by Share Ltd. Pledgor: GUANGDONG GONGLI BUILDING MATERIALS Co.,Ltd. Registration number: Y2020440000238 |
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