CN105778211A - Antiskid and anti-aging shoe material and production method thereof - Google Patents
Antiskid and anti-aging shoe material and production method thereof Download PDFInfo
- Publication number
- CN105778211A CN105778211A CN201610160058.1A CN201610160058A CN105778211A CN 105778211 A CN105778211 A CN 105778211A CN 201610160058 A CN201610160058 A CN 201610160058A CN 105778211 A CN105778211 A CN 105778211A
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- CN
- China
- Prior art keywords
- weight portion
- aging
- district
- temperature
- skidding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses antiskid and anti-aging shoe material and a production method thereof. The antiskid and anti-aging shoe material comprises, by weight, 70-80 parts of polyethylene, 15-20 parts of polyacrylonitrile fibers, 8-11 parts of sec-octyl phenol polyoxyethylene ether, 6-8 parts of magnesium carbonate, 2-4 parts of polymethyl methacrylate, 2-4 parts of polyglycerol fatty acid ester, 2-4 parts of polyoxyethylene rosin ester, 1-2 parts of glutaraldehyde, 0.5-1 part of magnesium zinc ferrite, 0.5-0.8 part of bis(2-chloroethyl)phosphoramidic dichloride, 0.04-0.1 part of nonylphenol ethoxylate and 0.02-0.04 part of pinene.
Description
Technical field
The invention belongs to footwear material field, particularly to a kind of footwear material anti-skidding, anti-aging and preparation method thereof.
Background technology
The quality of material for sole of shoe is in addition to non-skid property, and it is elastic and wearability is also the biggest of decision shoes comfort level
Influence factor, material for sole of shoe reaches certain skidproof effect by suppressing lines on sole at present, but this lines
Often it is smoothed because of the constantly friction after wearing a period of time between shoes and ground, does not still have anti-skidding effect, additionally
Wear sole and have obvious sense of discomfort, walk the most painstaking.
Polyethylene (being called for short PE) is the aggregated prepared a kind of thermoplastic resin of ethene, and polyethylene odorless, nontoxic, feel is seemingly
Wax, has excellent resistance to low temperature, and chemical stability is good, is resistant to the erosion of most of soda acid.
Summary of the invention
For above-mentioned demand, invention especially provides a kind of footwear material anti-skidding, anti-aging and preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of footwear material anti-skidding, anti-aging, is made up of the component comprising following weight portion:
Polyethylene 70-80 part,
Polyacrylonitrile fibre 15-20 part,
Secondary octyl phenol polyethenoxy ether 8-11 part,
Magnesium carbonate 6-8 part,
Polymethyl methacrylate 2-4 part,
Polyglyceryl fatty acid ester 2-4 part,
Polyoxylethylene abietate 2-4 part,
Glutaraldehyde 1-2 part,
MgZn ferrite 0.5-1 part,
Double (2-chloroethyl) dichlor-phosphoryl amine 0.5-0.8 part,
Poly-ethylene oxide nonyl phenol 0.04-0.1 part,
Firpene 0.02-0.04 part.
Described component also includes paraffin 0-1 weight portion.
Described component also includes polyoxyethylene oleic acid ester 0-0.5 weight portion.
A kind of preparation method of footwear material anti-skidding, anti-aging, the method comprises the following steps:
(1) polyethylene 70-80 weight portion, magnesium carbonate 6-8 weight portion, polymethyl methacrylate 2-4 weight portion, polyglycereol are weighed
Fatty acid ester 2-4 weight portion, polyoxylethylene abietate 2-4 weight portion, glutaraldehyde 1-2 weight portion, MgZn ferrite 0.5-1 weight
Amount part, double (2-chloroethyl) dichlor-phosphoryl amine 0.5-0.8 weight portion, poly-ethylene oxide nonyl phenol 0.04-0.1 weight portion, firpene
0.02-0.04 weight portion, paraffin 0-1 weight portion and polyoxyethylene oleic acid ester 0-0.5 weight portion, stir at 50-60 DEG C；
(2) said components is added pusher stirrer for mixing uniform, adds secondary octyl phenol polyethenoxy ether 8-11 weight portion,
Adding in double screw extruder, the side loading mouth at double screw extruder adds polyacrylonitrile fibre 15-20 weight portion, melt,
Extrusion, dry, pelletizing, obtain footwear material anti-skidding, anti-aging.
The each zone temperatures of described double screw extruder is: district's temperature 170-180 DEG C, two district's temperature 190-210 DEG C, 3rd district
Temperature 220-230 DEG C, four district's temperature 200-210 DEG C, five district's temperature 170-180 DEG C.
Compared with prior art, it has the beneficial effect that the present invention
(1) the footwear material anti-skidding, anti-aging that the present invention prepares is with polyethylene as primary raw material, by adding polyacrylonitrile fibre, secondary
OPEO, magnesium carbonate, polymethyl methacrylate, polyglyceryl fatty acid ester, polyoxylethylene abietate, penta 2
Aldehyde, MgZn ferrite, double (2-chloroethyl) dichlor-phosphoryl amine, poly-ethylene oxide nonyl phenol and firpene, prepared is anti-skidding, anti-aging
Footwear material has good mechanical strength, remains to keep good mechanical property when temperature is relatively low.
(2) the footwear material anti-skidding, anti-aging of the present invention has good surface abrasion resistance, and has the longer use longevity
Life.
(3) the footwear material anti-skidding, anti-aging of the present invention, its preparation method is simple, it is easy to industrialized production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) polyethylene 70kg, magnesium carbonate 6kg, polymethyl methacrylate 2kg, polyglyceryl fatty acid ester 2kg, rosin acid are weighed
Polyoxyethylene ester 2kg, glutaraldehyde 1kg, MgZn ferrite 0.5kg, double (2-chloroethyl) dichlor-phosphoryl amine 0.5kg, poly-ethylene oxide
Nonyl phenol 0.04kg and firpene 0.02kg, stirs at 50 DEG C；
(2) said components is added pusher stirrer for mixing uniform, add secondary octyl phenol polyethenoxy ether 8kg, add double
In screw extruder, the side loading mouth at double screw extruder adds polyacrylonitrile fibre 15kg, melts, extrudes, is dried, cuts
Grain, obtains footwear material anti-skidding, anti-aging.
The each zone temperatures of described double screw extruder is: district's temperature 170 DEG C, two district's temperature 190 DEG C, three district's temperature 220
DEG C, four district's temperature 200 DEG C, five district's temperature 170 DEG C.
The performance test results preparing footwear material anti-skidding, anti-aging is as shown in table 1.
Embodiment 2
(1) polyethylene 70kg, magnesium carbonate 6kg, polymethyl methacrylate 2kg, polyglyceryl fatty acid ester 2kg, rosin acid are weighed
Polyoxyethylene ester 2kg, glutaraldehyde 1kg, MgZn ferrite 0.5kg, double (2-chloroethyl) dichlor-phosphoryl amine 0.5kg, poly-ethylene oxide
Nonyl phenol 0.04kg, firpene 0.02kg, paraffin 1kg and polyoxyethylene oleic acid ester 0.5kg, stir at 50 DEG C；
(2) said components is added pusher stirrer for mixing uniform, add secondary octyl phenol polyethenoxy ether 8kg, add double
In screw extruder, the side loading mouth at double screw extruder adds polyacrylonitrile fibre 15kg, melts, extrudes, is dried, cuts
Grain, obtains footwear material anti-skidding, anti-aging.
The each zone temperatures of described double screw extruder is: district's temperature 170 DEG C, two district's temperature 190 DEG C, three district's temperature 220
DEG C, four district's temperature 200 DEG C, five district's temperature 170 DEG C.
The performance test results preparing footwear material anti-skidding, anti-aging is as shown in table 1.
Embodiment 3
(1) polyethylene 80kg, magnesium carbonate 8kg, polymethyl methacrylate 4kg, polyglyceryl fatty acid ester 4kg, rosin acid are weighed
Polyoxyethylene ester 4kg, glutaraldehyde 2kg, MgZn ferrite 1kg, double (2-chloroethyl) dichlor-phosphoryl amine 0.8kg, poly-ethylene oxide nonyl
Base phenol 0.1kg, firpene 0.04kg, paraffin 1kg and polyoxyethylene oleic acid ester 0.5kg, stir at 60 DEG C；
(2) said components is added pusher stirrer for mixing uniform, add secondary octyl phenol polyethenoxy ether 11kg, add double
In screw extruder, the side loading mouth at double screw extruder adds polyacrylonitrile fibre 20kg, melts, extrudes, is dried, cuts
Grain, obtains footwear material anti-skidding, anti-aging.
The each zone temperatures of described double screw extruder is: district's temperature 180 DEG C, two district's temperature 210 DEG C, three district's temperature 230
DEG C, four district's temperature 210 DEG C, five district's temperature 180 DEG C.
The performance test results preparing footwear material anti-skidding, anti-aging is as shown in table 1.
Embodiment 4
(1) polyethylene 80kg, magnesium carbonate 8kg, polymethyl methacrylate 4kg, polyglyceryl fatty acid ester 4kg, rosin acid are weighed
Polyoxyethylene ester 2kg, glutaraldehyde 2kg, MgZn ferrite 0.5kg, double (2-chloroethyl) dichlor-phosphoryl amine 0.8kg, poly-ethylene oxide
Nonyl phenol 0.1kg, firpene 0.04kg, paraffin 1kg and polyoxyethylene oleic acid ester 0.5kg, stir at 60 DEG C；
(2) said components is added pusher stirrer for mixing uniform, add secondary octyl phenol polyethenoxy ether 11kg, add double
In screw extruder, the side loading mouth at double screw extruder adds polyacrylonitrile fibre 20kg, melts, extrudes, is dried, cuts
Grain, obtains footwear material anti-skidding, anti-aging.
The each zone temperatures of described double screw extruder is: district's temperature 180 DEG C, two district's temperature 210 DEG C, three district's temperature 230
DEG C, four district's temperature 210 DEG C, five district's temperature 180 DEG C.
The performance test results preparing footwear material anti-skidding, anti-aging is as shown in table 1.
Embodiment 5
(1) polyethylene 75kg, magnesium carbonate 7kg, polymethyl methacrylate 3kg, polyglyceryl fatty acid ester 3kg, rosin acid are weighed
Polyoxyethylene ester 3kg, glutaraldehyde 1.5kg, MgZn ferrite 1kg, double (2-chloroethyl) dichlor-phosphoryl amine 0.6kg, poly-ethylene oxide
Nonyl phenol 0.07kg, firpene 0.03kg, paraffin 0.5kg and polyoxyethylene oleic acid ester 0.2kg, stir at 55 DEG C；
(2) said components is added pusher stirrer for mixing uniform, add secondary octyl phenol polyethenoxy ether 9kg, add double
In screw extruder, the side loading mouth at double screw extruder adds polyacrylonitrile fibre 18kg, melts, extrudes, is dried, cuts
Grain, obtains footwear material anti-skidding, anti-aging.
The each zone temperatures of described double screw extruder is: district's temperature 175 DEG C, two district's temperature 200 DEG C, three district's temperature 225
DEG C, four district's temperature 205 DEG C, five district's temperature 175 DEG C.
The performance test results preparing footwear material anti-skidding, anti-aging is as shown in table 1.
Comparative example 1
(1) polyethylene 80kg, magnesium carbonate 8kg, polymethyl methacrylate 4kg, polyglyceryl fatty acid ester 4kg, rosin acid are weighed
Polyoxyethylene ester 4kg, glutaraldehyde 2kg, double (2-chloroethyl) dichlor-phosphoryl amine 0.8kg, poly-ethylene oxide nonyl phenol 0.1kg, pinane
Alkene 0.04kg, paraffin 1kg and polyoxyethylene oleic acid ester 0.5kg, stir at 60 DEG C；
(2) said components is added pusher stirrer for mixing uniform, add secondary octyl phenol polyethenoxy ether 11kg, add double
In screw extruder, the side loading mouth at double screw extruder adds polyacrylonitrile fibre 20kg, melts, extrudes, is dried, cuts
Grain, obtains footwear material anti-skidding, anti-aging.
The each zone temperatures of described double screw extruder is: district's temperature 180 DEG C, two district's temperature 210 DEG C, three district's temperature 230
DEG C, four district's temperature 210 DEG C, five district's temperature 180 DEG C.
The performance test results preparing footwear material anti-skidding, anti-aging is as shown in table 1.
Comparative example 2
(1) polyethylene 80kg, magnesium carbonate 8kg, polymethyl methacrylate 4kg, polyglyceryl fatty acid ester 4kg, glutaraldehyde are weighed
2kg, MgZn ferrite 1kg, double (2-chloroethyl) dichlor-phosphoryl amine 0.8kg, poly-ethylene oxide nonyl phenol 0.1kg, firpene
0.04kg, paraffin 1kg and polyoxyethylene oleic acid ester 0.5kg, stir at 60 DEG C；
(2) said components is added pusher stirrer for mixing uniform, add secondary octyl phenol polyethenoxy ether 11kg, add double
In screw extruder, the side loading mouth at double screw extruder adds polyacrylonitrile fibre 20kg, melts, extrudes, is dried, cuts
Grain, obtains footwear material anti-skidding, anti-aging.
The each zone temperatures of described double screw extruder is: district's temperature 180 DEG C, two district's temperature 210 DEG C, three district's temperature 230
DEG C, four district's temperature 210 DEG C, five district's temperature 180 DEG C.
The performance test results preparing footwear material anti-skidding, anti-aging is as shown in table 1.
Comparative example 3
(1) polyethylene 80kg, magnesium carbonate 8kg, polymethyl methacrylate 4kg, polyglyceryl fatty acid ester 4kg, rosin acid are weighed
Polyoxyethylene ester 4kg, glutaraldehyde 2kg, MgZn ferrite 1kg, double (2-chloroethyl) dichlor-phosphoryl amine 0.8kg, poly-ethylene oxide nonyl
Base phenol 0.1kg, paraffin 1kg and polyoxyethylene oleic acid ester 0.5kg, stir at 60 DEG C；
(2) said components is added pusher stirrer for mixing uniform, add secondary octyl phenol polyethenoxy ether 11kg, add double
In screw extruder, the side loading mouth at double screw extruder adds polyacrylonitrile fibre 20kg, melts, extrudes, is dried, cuts
Grain, obtains footwear material anti-skidding, anti-aging.
The each zone temperatures of described double screw extruder is: district's temperature 180 DEG C, two district's temperature 210 DEG C, three district's temperature 230
DEG C, four district's temperature 210 DEG C, five district's temperature 180 DEG C.
Table 1
| Test event | Hardness (HW, degree) | Tearing toughness (KN/m) |
| Embodiment 1 | 77 | 33 |
| Embodiment 2 | 78 | 35 |
| Embodiment 3 | 84 | 39 |
| Embodiment 4 | 85 | 41 |
| Embodiment 5 | 87 | 45 |
| Comparative example 1 | 48 | 15 |
| Comparative example 2 | 45 | 17 |
| Comparative example 3 | 50 | 13 |
The invention is not restricted to embodiment here, those skilled in the art are according to the announcement of the present invention, without departing from scope
Improvement and the amendment made all should be within protection scope of the present invention.
Claims (5)
1. a footwear material anti-skidding, anti-aging, it is characterised in that be made up of the component comprising following weight portion:
Polyethylene 70-80 part,
Polyacrylonitrile fibre 15-20 part,
Secondary octyl phenol polyethenoxy ether 8-11 part,
Magnesium carbonate 6-8 part,
Polymethyl methacrylate 2-4 part,
Polyglyceryl fatty acid ester 2-4 part,
Polyoxylethylene abietate 2-4 part,
Glutaraldehyde 1-2 part,
MgZn ferrite 0.5-1 part,
Double (2-chloroethyl) dichlor-phosphoryl amine 0.5-0.8 part,
Poly-ethylene oxide nonyl phenol 0.04-0.1 part,
Firpene 0.02-0.04 part.
Footwear material the most anti-skidding, anti-aging, it is characterised in that described component also includes paraffin 0-1 weight
Part.
Footwear material the most anti-skidding, anti-aging, it is characterised in that described component also includes oleic acid polyoxyethylene
Ester 0-0.5 weight portion.
4. the preparation method of a footwear material anti-skidding, anti-aging, it is characterised in that the method comprises the following steps:
(1) polyethylene 70-80 weight portion, magnesium carbonate 6-8 weight portion, polymethyl methacrylate 2-4 weight portion, polyglycereol are weighed
Fatty acid ester 2-4 weight portion, polyoxylethylene abietate 2-4 weight portion, glutaraldehyde 1-2 weight portion, MgZn ferrite 0.5-1 weight
Amount part, double (2-chloroethyl) dichlor-phosphoryl amine 0.5-0.8 weight portion, poly-ethylene oxide nonyl phenol 0.04-0.1 weight portion, firpene
0.02-0.04 weight portion, paraffin 0-1 weight portion and polyoxyethylene oleic acid ester 0-0.5 weight portion, stir at 50-60 DEG C；
(2) said components is added pusher stirrer for mixing uniform, adds secondary octyl phenol polyethenoxy ether 8-11 weight portion,
Adding in double screw extruder, the side loading mouth at double screw extruder adds polyacrylonitrile fibre 15-20 weight portion, melt,
Extrusion, dry, pelletizing, obtain footwear material anti-skidding, anti-aging.
The preparation method of footwear material anti-skidding, anti-aging the most according to claim 4, it is characterised in that described twin-screw extrusion
The each zone temperatures of machine is: district's temperature 170-180 DEG C, two district's temperature 190-210 DEG C, three district's temperature 220-230 DEG C, four district's temperature
200-210 DEG C, five district's temperature 170-180 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610160058.1A CN105778211A (en) | 2016-03-21 | 2016-03-21 | Antiskid and anti-aging shoe material and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610160058.1A CN105778211A (en) | 2016-03-21 | 2016-03-21 | Antiskid and anti-aging shoe material and production method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105778211A true CN105778211A (en) | 2016-07-20 |
Family
ID=56394191
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610160058.1A Pending CN105778211A (en) | 2016-03-21 | 2016-03-21 | Antiskid and anti-aging shoe material and production method thereof |
Country Status (1)
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011121352A (en) * | 2009-12-09 | 2011-06-23 | Sonsei Go | Prescription and manufacturing method of lightweight plastic shoe-shape |
| CN102850633A (en) * | 2012-09-24 | 2013-01-02 | 吴江市信许塑料鞋用配套有限公司 | Preparation method of protective sole material |
| CN103756078A (en) * | 2014-01-20 | 2014-04-30 | 张子亮 | Natural product and TR (Thermoplastic Rubber) synthetic shoe sole as well as formula and preparation process thereof |
| CN104194122A (en) * | 2014-09-03 | 2014-12-10 | 晋江市金城盛鞋材工业有限公司 | TPE (thermoplastic elastomer) gross-porosity foaming material and manufacturing method thereof |
| CN105330945A (en) * | 2015-12-01 | 2016-02-17 | 吴江市风尚鞋厂 | Wear-resisting light sole material and preparation method thereof |
-
2016
- 2016-03-21 CN CN201610160058.1A patent/CN105778211A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011121352A (en) * | 2009-12-09 | 2011-06-23 | Sonsei Go | Prescription and manufacturing method of lightweight plastic shoe-shape |
| CN102850633A (en) * | 2012-09-24 | 2013-01-02 | 吴江市信许塑料鞋用配套有限公司 | Preparation method of protective sole material |
| CN103756078A (en) * | 2014-01-20 | 2014-04-30 | 张子亮 | Natural product and TR (Thermoplastic Rubber) synthetic shoe sole as well as formula and preparation process thereof |
| CN104194122A (en) * | 2014-09-03 | 2014-12-10 | 晋江市金城盛鞋材工业有限公司 | TPE (thermoplastic elastomer) gross-porosity foaming material and manufacturing method thereof |
| CN105330945A (en) * | 2015-12-01 | 2016-02-17 | 吴江市风尚鞋厂 | Wear-resisting light sole material and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 吴世敏等: "《简明精细化工大辞典》", 30 June 1999 * |
| 张万鲲: "《电子信息材料手册》", 31 July 2001 * |
| 王国建: "《功能高分子材料》", 30 June 2014 * |
| 甘孟瑜等: "《大学化学 第4版》", 31 October 2014 * |
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Application publication date: 20160720 |