A kind of acid soil improving agent being made up of iron ore mine and preparation method thereof
Technical field
The present invention relates to soil improvement field, be specifically related to a kind of acid soil improving agent being made up of iron ore mine and preparation method thereof.
Background technology
Acid ground is the general name of low ph value soil, including red soil, yellow earth, laterite, red earth and podzolic soil etc..Acid ground is the most widely distributed, is primarily present in rainy Temperate Region in China and tropical and subtropical region.Widely distributed large-area acid ground on the south China the Changjiang river, it is concentrated mainly on the provinces, south such as Zhejiang, Jiangxi, Fujian, Guangdong, Guangxi, Yunnan and Guizhou, also there is distribution in the areas such as Henan, Hebei, Liaoning and the Inner Mongol in northern area, the Yellow River, the gross area about 200,000,000 hectares.
Most acid ground pH value is less than 5.5, and wherein greatly less than 5.0, have is even lower.With China's economy, the development of society, ambient pressure is increasing, and various places report the generation of " acid rain " frequently, and these areas all demonstrating acid ground and acidizing degree have the trend of increase further.
In acid ground, under conditions of precipitation is more, there is strong eluviation in soil, causes K+、Ca2+、Mg2+Deng a large amount of leaching loss of mineral nutrient ion, on the one hand cause crop in default of calcium, magnesium and limiting growth;On the other hand can increase again the acidity of soil, improve the dissolubility of aluminum, discharge a large amount of aluminium ion, form the aluminium compound of plant available form.Plant excessive consumption aluminum, not only reduces the quality of plant product, and the root growth of plant particularly plant can be produced extreme influence, even result in dunsiekte dead.Simultaneously the most in acid condition, not only the micro organism quantity in soil reduces, and the growth of microorganism and activity are also suppressed, thus have impact on the circulation of C, N, P, S in the decomposition of the soil organism and soil.
Mineral resources are human development and one of particularly important material base of surviving, and develop rapidly along with China is industrialized, and barren rock and mine tailing that mineral resources produce during Development and Production also result in serious environmental pollution.According to statistics, being restricted by factors such as technique of preparing level, production equipment, the mine tailing of China's Mining Market has reached more than 10,000,000,000 tons, and has the trend increased year by year, and the utilization rate ratio of mine tailing is relatively low.
Iron ore mine is that Iron Works Plant is under the conditions of specific economic technology, iron ore is levigate, choose the garbage that " useful constituent " discharges afterwards, current China adds up to store up iron ore mine amount and is up to tens00000000 tons, and discharge nearly 300,000,000 tons of iron ore mine every year, comprehensive utilization ratio is less than 20%.A large amount of iron ore mines typically use landfill to dispose, and not only waste resource, tie up soil simultaneously, cause environmental pollution, and in view of above reason, the comprehensive utilization of iron ore mine is extremely necessary.
The present situation of iron ore mine research and utilization is mainly in the following aspects:
Spoil reclaming
Due to the restriction of technical conditions, some mines are the highest due to recovery rate in ore-dressing, and the utilization rate of mineral resources is not enough, use the technical matters improved, select iron ore mine again, extract valuable mineralogical composition therein.
Ceramic material
In iron ore mine, chemical composition mainly has silicon, aluminum, calcium, the oxide of magnesium and a small amount of potassium, sodium, sulfur oxide, wherein the content of silicon and aluminum is higher, it is similar to the main component of ceramic material, a small amount of iron ore mine is added in Production of Ceramics, the performance of pottery can be improved, be mainly used in little scope firing ceramics material, mine tailing ceramic glaze and mine tailing sanitary ware aspect.
Cement
Cement be mainly composed of sial based compound, also it is similar to the main component of iron ore mine, by adding iron ore mine in cement ingredient, not only can be by affecting formation and the mineral composition of clinker, make the material having other characteristics, moreover it is possible to reduce production cost.
Re-vegetation
China has carried out the work studies of reclaiming of vegetation in the later stage eighties to the nineties, Reclamation Technique condition and the airborne dust suppression etc. that are mainly iron ore mine are explored, carried out vegetation experiment simultaneously, have developed " Land Reclamation In Metallurgical Mine specialist system ", provide relevant Reclamation scheme for Different climate condition, different regions, different soils and ore characteristic.
Fertilizer is commonly referred to as garbage and the animal residue of various animal, uses the treatment technology that physics, chemistry, biology or three have concurrently, through certain processing technique, eliminates harmful substance therein and reaches innoxious standard and the class fertilizer that formed.Fertilizer effect in agricultural production shows improvement soil and improves on utilization rate of fertilizer.
Improvement soil refers mainly to after fertilizer is manured into soil, can effectively improve physics and chemistry situation and the biological nature of soil, vegetable soil, strengthen the fertilizer supply and preservation ability of soil, and good edaphic condition is created in the growth for crop.It is many that fertilizer contains nutrient, but relative amount is low, and release is slow, and the nutrient content of chemical fertilizer is high, and composition is few, and release is fast.Both combine reasonable coordination and use, and are complementary to one another, and promote soil and the dissolving of chemical fertilizer mineral nutrient, and fertilizer and chemical fertilizer are mutually promoted, beneficially Crop, thus improve the utilization rate of fertilizer.
In the application for a patent for invention of Application No. CN201310028566.0, disclose the preparation method of a kind of acid soil improvement conditioner, the preparation method of this conditioner is grey as raw material with the leftover bits and pieces alkaline soil plant of bio-power plant, by this alkaline soil plant ash and calcium magnesium phosphate and furfural dregs mixing and stirring, it is finished product when the parts by weight of moisture are 15-18%.Wherein, the parts by weight of each raw material are: alkaline soil plant ash 60-80%, calcium magnesium phosphate 20-30%, furfural dregs 10-20%.The furfural dregs used in the acid soil improvement conditioner of this disclosure of the invention is acid, and salt content is high, the DeGrain when improveing acid ground, and use causes soil salt content high in a large number, is unfavorable for the growth of crops in soil.
In the application for a patent for invention of Application No. CN201210277844.1, disclosing a kind of soil conditioner and preparation method thereof, this modifying agent includes the component of following weight proportion: gangue 6-12 part, straw 8-16 part, ground phosphate rock 0.2-3 part.The soil conditioner of this disclosure of the invention is relatively suitable for the soil that phosphorus lacks, but this modifying agent is relatively low to the micronutrient levels ratio that crops are useful, it is difficult to improvement acid ground.
Summary of the invention
It is an object of the invention to provide a kind of acid soil improving agent being made up of iron ore mine, to improve acid ground, prevent it from constantly deteriorating the problems such as the grain drop in production, the soil degradation that cause.
Present invention also offers the preparation method of above-mentioned acid soil improving agent.
To achieve these goals, the invention provides a kind of acid soil improving agent being made up of iron ore mine, it comprises the component of following weight proportion: iron ore mine: 15-70 part, fertilizer: 1-30 part, coarse sand: 1-40 part, building stones: 1-20 part;Wherein said fertilizer includes straw and feces.
Preferably, described iron ore mine comprises following components in percentage by weight: SiO2: 30-70%, Al2O3: 5-30%, Fe2O3: 1-20%, CaO:1-10%, MgO:1-10%, K2O:0-5%, Na2O:0-5%, P:0-1%, MnO2: 0-0.5%, and possibly together with the various trace element needed for plant growing, such as B, Cu, Zn, Mo etc. in described iron ore mine.Iron ore mine described in Tong Shi is through detection, cadmium content≤0.06mg/kg therein, mercury content≤0.015mg/kg, arsenic content≤1.1mg/kg, copper content≤67mg/kg, lead content≤9mg/kg, chromium content≤41mg/kg, Zn content≤67mg/kg, nickel content≤37mg/kg, in addition to the national grade ii standard of a little higher than 50mg/kg of copper content, remaining content is all within country-level standard of soil environment quality, and environment and soil are safe from harm by i.e. described iron ore mine.
Preferably, described iron ore mine granularity and percentage by weight thereof be: 0.3-0.6mm:0-50%, 0.15-0.3mm:5-70%, 0.075-0.15mm:10-70%, 0-0.075mm:5-40%;The granularity of described coarse sand and percentage by weight thereof be: 1mm-4mm:0-5%, 0.6-1mm:1-40%, 0.1-0.6mm:5-80%, 0-0.1mm:0-10%;The granularity of described building stones and percentage by weight thereof: 1mm-4mm:0-10%, 0.6-1mm:1-50%, 0.1-0.6mm:5-70%, 0-0.1mm:0-10%.
Preferably, described fertilizer is straw and the feces of animal of plant, and the weight ratio of described straw and feces is preferably 0.2-1:1.Wherein, described straw includes but not limited to the straw of the plants such as Semen Maydis, millet, Semen Tritici aestivi, Sorghum vulgare Pers., Cotton Gossypii and Oryza sativa L.;Described feces includes but not limited to the feces of the animals such as pig, cattle, sheep, horse, chicken, duck and goose.
Further, described fertilizer also include cake fertilizer, compost, make compost, barnyard manure, natural pond be fertile and green manure.
Preferably, described building stones are one or both in limestone and dolomite.It is further preferred that described building stones are limestone and dolomite, its weight ratio can be 0.2-2:1.
It is further preferred that owing to, during ripening and using, described straw can gradually be decomposed by the microorganisms, and provides nutrient substance to plant, therefore can be by described crushed stalk to 2-150mm.
It is further preferred that the pH of described acid soil improving agent is 7-14.
On the other hand, present invention also offers the preparation method of above-mentioned acid soil improving agent, this preparation method comprises the following steps:
(1) by described crushed stalk to 2-150mm;
(2) according to iron ore mine, straw, feces, coarse sand and the building stones described in weight proportion mixing, in mixed process, point 3-8 interpolation water, then carries out material ripening;
(3) material after ripening passes through dry in the sun so that water content to 10-20%, obtains described acid soil improving agent.
Preferably, in step (2), during acid soil improving agent described in preparation, the condition of described material ripening is: temperature 15-50 DEG C, 10-40 days time, water content: 15-40%.
After preparing above-mentioned acid soil improving agent, the when of use, described acid soil improving agent and acid ground are mixed according to the weight ratio of 1-4:1, use pivot plow to plough deeply 5-30cm, then by rotary cultivator raker stirrer pressure.
Owing to the granularity of described iron ore mine is the thinnest, fly away the most everywhere in dry weather or when have wind, after coarse sand described in addition and building stones, the particle size distribution of final product (i.e. described acid soil improving agent) can be regulated so that it is granularity can be close to the particle size distribution of local soil;After being simultaneously introduced described fertilizer, described iron ore mine, coarse sand and building stones can be attached to described ripening after straw and feces on to reduce loss.
Described coarse sand can select river sand for building and sand ground to dig sand.Described building stones can select limestone, dolomite or both mixing, and the main component of described limestone is CaO, and the acid ingredient in energy sweetening of the soil steps up the pH value of soil and provides Ca2+So that it is it is suitable for the growth of crops;The main component of described dolomite is CaO and MgO, and it is except the acid ingredient in energy sweetening of the soil and Ca2+, moreover it is possible to the Mg needed for crop growth is provided2+.Described fertilizer includes but are not limited to straw and feces, and above-mentioned fertilizer can provide the nutritional labelings such as required N, P, K, improves the physics and chemistry situation of soil, strengthens the feeder capability of soil.
Owing to the pH value of the described acid soil improving agent being made up of iron ore mine is more than 7, this modifying agent can neutralize the H in acid ground+, improving the pH value of soil, add described building stones simultaneously, these building stones mainly contain MgO and CaO, under the effect of Soil Microorganism, it is possible to ionize out Mg2+、Ca2+And OH-, OH-The H in acid ground can be neutralized+, Mg2+And Ca2+Can be absorbed by crops, acid soil environment can be significantly improved, and nutrient substance is provided.Further, adjusted the granularity of described acid soil improving agent by the coarse sand described in interpolation, the voidage of soil can be increased, improve water conservation and the conveying capacity of nutritional labeling of soil;The use of described fertilizer can improve the physics and chemistry situation of soil, strengthens fertilizer supply and preservation ability and the buffer capacity of soil, simultaneously by and chemical fertilizer with the use of, be complementary to one another, mutually promote, beneficially the absorption of crops, and significantly improve the utilization rate of fertilizer.
Detailed description of the invention
Embodiment 1
The described acid soil improving agent being made up of iron ore mine comprises the component of following weight: iron ore mine: 15t, fertilizer: 30t, coarse sand: 40t, building stones: 15t.Wherein, above-mentioned fertilizer is straw and the feces of pig of Semen Maydis, and the weight ratio of its straw and feces is 0.2:1, and the weight of the most above-mentioned straw is 5t, and the weight of above-mentioned feces is 25t.Described building stones are limestone and dolomite, and the weight ratio of its limestone and dolomite is 0.2:1, and the weight of the most above-mentioned limestone is 2.5t, and the consumption of above-mentioned dolomite is 12.5t.
Described crushed stalk to 2mm, described iron ore mine granularity and percentage by weight thereof is: 0.3-0.6mm:1 %, 0.15-0.3mm:70%, 0.075-0.15mm:10%, 0-0.075mm:19%;The granularity of described coarse sand and percentage by weight thereof be: 1mm-4mm:1%, 0.6-1mm:40%, 0.1-0.6mm:49%, 0-0.1mm:10%;Described limestone and the granularity of dolomite and percentage by weight thereof is: 1mm-4mm:1%, 0.6-1mm:50%, 0.1-0.6mm:39%, 0-0.1mm:10%.
Described iron ore mine comprises following components in percentage by weight: SiO2: 70%, Al2O3: 20.2%, Fe2O3: 2%, CaO:1%, MgO:1%, K2O:0.3%, Na2O:0.2%, P:0.2%, MnO2: 0.1%.
The preparation method of described acid soil improving agent comprises the following steps:
(1) by described crushed stalk to 2mm;
(2) according to iron ore mine, straw, feces, coarse sand, limestone and the dolomite described in above-mentioned part by weight mixing, point 3 interpolation water in mixed process, then material ripening is carried out, i.e. under conditions of temperature 15 DEG C, water content 15%, ripening 40 days;
(3) material after ripening passes through dry in the sun so that water content to 10%, obtains described acid soil improving agent, and the pH of this acid soil improving agent is 8.7;
After preparing above-mentioned acid soil improving agent, the when of use, described acid soil improving agent and acid ground are mixed according to the weight ratio of 1:1, use pivot plow to plough deeply 5cm, then by rotary cultivator raker stirrer pressure.
Acid soil improving agent in table 1 embodiment 2-5 is made according to the raw material of following table Different Weight proportioning
Embodiment 2
Described crushed stalk to 4mm, described iron ore mine granularity and percentage by weight thereof is: 0.15-0.3mm:50.7%, 0.075-0.15mm:20.7%, 0-0.075mm:28.6%;The granularity of described coarse sand and percentage by weight thereof be: 0.6-1mm:30.5%, 0.1-0.6mm:52.6%, 0-0.1mm:16.9%;Described limestone and the granularity of dolomite and percentage by weight thereof is: 1mm-4mm:0.8%, 0.6-1mm:48.2%, 0.1-0.6mm:42.1%, 0-0.1mm:8.9%.
Described iron ore mine comprises following components in percentage by weight: SiO2: 65.3%, Al2O3: 15.5%, Fe2O3: 10.1%, CaO:2.1%, MgO:0.8%, K2O:0.5%, Na2O:0.5%, P:0.1%, MnO2: 0.1%.
The preparation method of described acid soil improving agent comprises the following steps:
(1) by described crushed stalk to 4mm;
(2) according to iron ore mine, straw, feces, coarse sand, limestone and the dolomite described in above-mentioned part by weight mixing, point 8 interpolation water in mixed process, then material ripening is carried out, i.e. under conditions of temperature 25 DEG C, water content 30%, ripening 30 days;
(3) material after ripening passes through dry in the sun so that water content to 15%, obtains described acid soil improving agent, and the pH of this acid soil improving agent is 12;
After preparing above-mentioned acid soil improving agent, the when of use, described acid soil improving agent and acid ground are mixed according to the weight ratio of 1:1, use pivot plow to plough deeply 20cm, then by rotary cultivator raker stirrer pressure.
Embodiment 3
Described crushed stalk to 50mm, described iron ore mine granularity and percentage by weight thereof is: 0.3-0.6mm:2.1%, 0.15-0.3mm:30.2%, 0.075-0.15mm:50.8%, 0-0.075mm:16.9%;The granularity of described coarse sand and percentage by weight thereof be: 0.6-1mm:20.1%, 0.1-0.6mm:65.1%, 0-0.1mm:14.8%;Described limestone and the granularity of dolomite and percentage by weight thereof is: 0.6-1mm:50.5%, 0.1-0.6mm:30.7%, 0-0.1mm:18.8%.
Described iron ore mine comprises following components in percentage by weight: SiO2: 67.8%, Al2O3: 10.6%, Fe2O3: 8.4%, CaO:4.4%, MgO:3.2%, K2O:0.8%, Na2O:0.8%, P:0.1%, MnO2: 0.1%.
The preparation method of described acid soil improving agent comprises the following steps:
(1) by described crushed stalk to 50mm;
(2) according to iron ore mine, straw, feces, coarse sand, limestone and the dolomite described in above-mentioned part by weight mixing, point 5 interpolation water in mixed process, then material ripening is carried out, i.e. under conditions of temperature 50 C, water content 40%, ripening 25 days;
(3) material after ripening passes through dry in the sun so that water content to 15%, obtains described acid soil improving agent, and the pH of this acid soil improving agent is 10;
After preparing above-mentioned acid soil improving agent, the when of use, described acid soil improving agent and acid ground are mixed according to the weight ratio of 3:1, use pivot plow to plough deeply 15cm, then by rotary cultivator raker stirrer pressure.
Embodiment 4
Described crushed stalk to 100mm, described iron ore mine granularity and percentage by weight thereof is: 0.3-0.6mm:50.5%, 0.15-0.3mm:28.2%, 0.075-0.15mm:15.8%, 0-0.075mm:5.5%;The granularity of described coarse sand and percentage by weight thereof be: 1mm-4mm:5%, 0.6-1mm:30.2%, 0.1-0.6mm:41.8%, 0-0.1mm:13%;Described limestone and the granularity of dolomite and percentage by weight thereof is: 1mm-4mm:10%, 0.6-1mm:29.1%, 0.1-0.6mm:40.5%, 0-0.1mm:20.4%.
Described iron ore mine comprises following components in percentage by weight: SiO2: 50.2%, Al2O3: 35.3%, Fe2O3: 3.1%, CaO:2.1%, MgO:1.2%, K2O:0.5%, Na2O:0.2%, P:0.2%, MnO2: 0.1%.
The preparation method of described acid soil improving agent comprises the following steps:
(1) by described crushed stalk to 100mm;
(2) according to iron ore mine, straw, feces, coarse sand, limestone and the dolomite described in above-mentioned part by weight mixing, point 4 interpolation water in mixed process, then material ripening is carried out, i.e. under conditions of temperature 40 DEG C, water content 25%, ripening 10 days;
(3) material after ripening passes through dry in the sun so that water content to 10%, obtains described acid soil improving agent, and the pH of this acid soil improving agent is 9.1.
After preparing above-mentioned acid soil improving agent, the when of use, described acid ground and acid soil improving agent are mixed according to the weight ratio of 2:1, described acid soil improving agent is spread on acid ground, uses pivot plow to plough deeply 10cm, then by rotary cultivator raker stirrer pressure.
Embodiment 5
By described crushed stalk to 150mm, described iron ore mine granularity and percentage by weight thereof be: 0.15-0.3mm:50.2%, 0.075-0.15mm:32.7%, 0-0.075mm:17.1%;The granularity of described coarse sand and percentage by weight thereof be: 0.6-1mm:20.1%, 0.1-0.6mm:55.1%, 0-0.1mm:24.8%;Described limestone and its percentage by weight of the granularity of dolomite be: 0.6-1mm:52.8%, 0.1-0.6mm:34.1%, 0-0.1mm:13.1%.
Described iron ore mine comprises following components in percentage by weight: SiO2: 40.1%, Al2O3: 38.2%, Fe2O3: 7.6%, CaO:3.2%, MgO:2.5%, K2O:0.5%, Na2O:0.3%, P:0.3%, MnO2: 0.1%.
The preparation method of described acid soil improving agent comprises the following steps:
(1) by described crushed stalk to 150mm;
(2) according to iron ore mine, straw, feces, coarse sand, limestone and the dolomite described in above-mentioned part by weight mixing, point 4 interpolation water in mixed process, then material ripening is carried out, i.e. under conditions of temperature 20 DEG C, water content 20%, ripening 20 days;
(3) material after ripening passes through dry in the sun so that water content to 10%, obtains described acid soil improving agent, and the pH of this acid soil improving agent is 8.1.
After preparing above-mentioned acid soil improving agent, the when of use, described acid soil improving agent and acid ground are mixed according to the weight ratio of 1:1, use pivot plow to plough deeply 15cm, then by rotary cultivator raker stirrer pressure.
Test example 1
1, select in above-described embodiment 1-5 proportioning and mix acid ground and each 10kg of acid soil improving agent mixed soil that rake presses, blank select described in acid ground 10kg to carry out pot experiment as follows:
(1) 6 same flowerpots, respectively numbering 1,2,3,4,5,6 (blank) are prepared.
(2) acid ground of the mixed soil in the above embodiments 1-5 and blank is respectively charged in above-mentioned flowerpot in order.
(3) adjusting the soil moisture content in above-mentioned 1-6 flowerpot is all 25%, is planted in above-mentioned 6 flowerpots by millet (the Liao Dynasty paddy four) each 10 of seed substantially similar to same kind, size and turgor the most simultaneously, and planting depth is 1.5cm.
(4) identical external environment is provided, the time and intensity of such as illumination, temperature etc., water the most identical with the time applied fertilizer and consumption simultaneously, process of the test records the parameters such as millet seedling-growing time and height.
Result of the test is as follows:
Table 2 results from pot experiment test record (seedling-growing time)
Table 3 results from pot experiment test record (highly: cm)
From upper table 2, the seed sprouting time in the described flowerpot of numbered 3 and 4, relatively early a little later, and seed (blank assay) seedling-growing time in the flowerpot of numbered 6 was the latest, reaches 9 days for the seed in the described flowerpot of numbered 2 and 5.
From upper table 3, general 35 days when, the paddy height of seedling degree in the flowerpot of above-mentioned numbered 1-5 is the most all at about 9cm, and the height of the paddy Seedling in blank assay i.e. acid ground is at about 6cm, hence it is evident that the comparison of growth is short.Finally, in the watery stage, the paddy height of seedling degree in the flowerpot of above-mentioned numbered 1-5 is all at about 70cm, and the paddy height of seedling degree in blank assay i.e. acid ground is at 50cm.And in growth course, the paddy Seedling color in the flowerpot of above-mentioned numbered 1-5 is all emerald green, grows fine, and the paddy Seedling in blank assay i.e. acid ground shows as yellow green, and growing way is poor.
2, field demonstration test
(1) smooth go out 12 mu of acid ground fields, be divided into 6 parts, be designated as No. 1 field, No. 2 fields, No. 3 fields, No. 4 fields, No. 5 fields and No. 6 fields.
(2) adding acid soil improving agent according to proportioning in aforesaid embodiment 1-5 to aforesaid 1-5 Tanaka the most successively, No. 6 fields are blank assay field.
(3) plantation is with kind through the millet (the Liao Dynasty paddy four) of screening, and carries out field management in the same fashion, such as, apply fertilizer, the work such as weeding of watering.
(4) gather in the crops and record of weighing is such as following table.
Table 4 is weighed log (kg)
From upper table 4, the yield in blank assay field only has 385kg, and by the acid soil improving agent described in use, above-described embodiment 1-5 proportioning is used to test, the yield in result above-mentioned 1-5 field has had significant raising, especially No. 3 real estate amounts to reach 620kg, increased production fairly obvious;Relative to blank assay, yield adds 235kg, and amount of increase in production reaches 37.9%, is the most significant.
Above-described embodiment is only for technology design and the feature of the explanation present invention; its object is to allow person skilled in the art will appreciate that present disclosure and to be carried out; can not limit the scope of the invention with this; all equivalence changes made according to spirit of the invention or modification, all should contain within the scope of the present invention.