The flucculation process of particulate matter in a kind of removal waste water
Technical field
The present invention relates to a kind of wastewater processing technologies, and in particular to a kind of flucculation process for removing particulate matter in waste water belongs to
In environment protection field.
Background technique
The strand of polyacrylamide is very long, its amide groups can, absorption affine with many substances form hydrogen bond, this just makes
It can build bridge between the particle of absorption, and several or even dozens of particle is made to link together, generation floc sedimentation, under accelerated particle
It is heavy.This is similar with general flocculation mechanism, i.e., a molecule can adsorb several particles simultaneously, is pulled together them, settles rapidly.
Flocculation is extremely complex physics, chemical process, and present majority think that Flocculation Mechanism is two kinds of cohesion and flocculation
Mechanism.Coacervation process is that colloidal solid takes off process that is steady and forming tiny condensate;And flocculation process is to be formed carefully
Small condensate generates the process of the flocculate (i.e. floc sedimentation) of large volume under bridging (bridge formation) effect of flocculant.But
Existing compound material for water treatment is to pollutant substantially based on physical action, and which results in its capacity that flocculates is small, absorption is up to full
The slow disadvantage with the time, and it is unable to satisfy the requirement of industrial application.
And due to the development of nanotechnology, many nano materials are widely used, such as inorganic additive, polymer nano
Rice corpuscles etc.;A large amount of uses of these nano-sized particles objects are also produced and are much received while promoting material property progress
Rice grain waste, these nano particles have and can much be discharged into water, form nanoparticles pollution, these tiny nanoparticles
Son is much larger than micron particles object to the harm of human body;But existing water treatment technology is substantially invalid to small sized particles object.
Summary of the invention
The object of the present invention is to provide a kind of wastewater treatment method based on flocculant, in the method, flocculant flocculation effect
Fruit is strong, effectively can form flocculant with the particulate matter of the various sizes in waste water, substantially increase sewage treating efficiency.
To achieve the above object of the invention, the technical solution adopted by the present invention is that:The flocculation of particulate matter in a kind of removal waste water
Method includes the following steps:
(1)The preparation of flocculant, boiled silk is soluble in water, tetramethyl-ammonium iodide, manganese acetate and nitric acid is then added
Cobalt is uniformly mixed, back flow reaction 8 hours, is then dried to obtain fibroin membrane;Then fibroin membrane is small in 190~200 DEG C of processing 2
When after Freezing smashing obtain silk fibroin powder;Then in ethanol by silk fibroin powder dispersion, methyl orthosilicate and 2- ammonia are added
Base butyric acid and diethyl phosphite stir 3 hours at room temperature, add silane coupling agent, filter after stirring 1 hour and obtain solid
Compound;Sodium acrylate, 2- acrylamide-2-methylpro panesulfonic acid are added to the water, stirred 10 minutes, bis- (2,3- rings are added
Oxygroup cyclopenta) ether, is stirred 15 minutes;Then solid chemical compound and azodiisobutyronitrile are added, 90 DEG C are reacted 4 hours, finally
It is dried to obtain flocculant;
(2)By step(1)Flocculant dispersion in ethanol, obtain mixed liquor;Then by mixed liquor according to 50~80g/
The additive amount of ton is added in waste water;The removal that floccule body completes particulate matter in waste water is then demultiplex out.
In the present invention, in step (1), the boiled silk, tetramethyl-ammonium iodide, manganese acetate, cobalt nitrate mass ratio be 1
:(0.1~0.2):(0.3~0.5):(0.4~0.6).Manganese acetate during compatible with silk, can be reacted with cobalt nitrate
Corresponding manganese cobalt/cobalt oxide is generated, the flocculating effect of inorganic core in flocculant can be increased.
In the present invention, in step (1), the silk fibroin powder, methyl orthosilicate, 2-amino-butyric acid, diethyl phosphite, silicon
The mass ratio of alkane coupling agent is 1:(0.5~0.8):(0.03~0.05):(0.03~0.05):(0.05~0.06).Utilize phosphine
Hydrogenation can form stable, active organic matter layer in mineral surfaces, be conducive to flocculant outer layer copolymer and core
The promotion of the interface interaction power of inorganic matter, greatly improves the stability of flocculant.
In the present invention, in step (1), the sodium acrylate, 2- acrylamide-2-methylpro panesulfonic acid, bis- (2,3- epoxies
Cyclopentyl) ether, solid chemical compound, azodiisobutyronitrile mass ratio be 1:(0.7~0.8):(0.08~0.09):(0.3~
0.5):(0.005~0.006).By the addition of epoxy monomer, the flocculation ability of flocculant outer layer copolymer is increased;Simultaneously
Conducive to the promotion of the interface interaction power of polymer and inorganic core.
In the present invention, in step (2), the mass concentration of flocculant is 10%~15% in the mixed liquor.First by flocculant
Dispersion in ethanol, adds waste water, is conducive to the dispersed homogeneous degree for improving flocculant;Made simultaneously using the interface of ethyl alcohol and water
Firmly, increase the connection function between flocculating agent molecule, be conducive to the uniformity of particle removal;And increases particulate matter and form flocculation
The probability of body finally removes floccule body using conventional means, completes the removal of waste particles object.
The method of particulate matter is simple and effective in removal waste water disclosed by the invention, and the flocculant property utilized is stablized, dispersion
Floccule body can be formed with the particulate matter in waste water on a large scale in waste water, can especially remove the small particulate matter of partial size, go
Except rate is up to 95% or more.
Specific embodiment
Embodiment one
100g boiled silk is soluble in water, 10g tetramethyl-ammonium iodide, 30g manganese acetate and 40g cobalt nitrate is then added,
It is uniformly mixed, back flow reaction 8 hours, is then dried to obtain fibroin membrane;Then by fibroin membrane after 190~200 DEG C are handled 2 hours
Freezing smashing obtains silk fibroin powder;Then 10g silk fibroin powder is dispersed in 50g ethyl alcohol, add 5g methyl orthosilicate and
0.3g2- aminobutyric acid and 0.3g diethyl phosphite stir 3 hours at room temperature, add 0.5g Silane coupling agent KH550, stir
It is filtered after mixing 1 hour and obtains solid chemical compound;Water is added in 10g sodium acrylate, 7g2- acrylamide-2-methylpro panesulfonic acid
In, it stirs 10 minutes, bis- (2, the 3- epoxy cyclopentyl) ethers of 0.8g is added, stir 15 minutes;Then 3g solid chemical compound is added
With 0.05g azodiisobutyronitrile, 90 DEG C are reacted 4 hours, are finally dried to obtain flocculant.To contain mass concentration for 6% montmorillonite
(Micron order), 1% silica(Nanoscale)Aqueous solution be waste water, 10g flocculant is dispersed in 90g ethyl alcohol, is mixed
Liquid;Then mixed liquor is added in waste water according to 50g/ tons of additive amount;Floccule body is isolated after 30 minutes to complete in waste water
The removal of particulate matter.Removal efficiency, removal efficiency 94% are tested with photoelectric colorimeter, alumen ustum separation rate is 94%.
Embodiment two
100g boiled silk is soluble in water, 20g tetramethyl-ammonium iodide, 50g manganese acetate and 60g cobalt nitrate is then added,
It is uniformly mixed, back flow reaction 8 hours, is then dried to obtain fibroin membrane;Then by fibroin membrane after 190~200 DEG C are handled 2 hours
Freezing smashing obtains silk fibroin powder;Then 10g silk fibroin powder is dispersed in 50g ethyl alcohol, add 5g methyl orthosilicate and
0.3g2- aminobutyric acid and 0.3g diethyl phosphite stir 3 hours at room temperature, add 0.5g Silane coupling agent KH550, stir
It is filtered after mixing 1 hour and obtains solid chemical compound;Water is added in 10g sodium acrylate, 7g2- acrylamide-2-methylpro panesulfonic acid
In, it stirs 10 minutes, bis- (2, the 3- epoxy cyclopentyl) ethers of 0.8g is added, stir 15 minutes;Then 3g solid chemical compound is added
With 0.05g azodiisobutyronitrile, 90 DEG C are reacted 4 hours, are finally dried to obtain flocculant.To contain mass concentration for 6% montmorillonite
(Micron order), 1% silica(Nanoscale)Aqueous solution be waste water, 15g flocculant is dispersed in 85g ethyl alcohol, is mixed
Liquid;Then mixed liquor is added in waste water according to 80g/ tons of additive amount;Floccule body is isolated after 30 minutes to complete in waste water
The removal of particulate matter.Removal efficiency, removal efficiency 96% are tested with photoelectric colorimeter, alumen ustum separation rate is 95%.
Embodiment three
100g boiled silk is soluble in water, 10g tetramethyl-ammonium iodide, 30g manganese acetate and 40g cobalt nitrate is then added,
It is uniformly mixed, back flow reaction 8 hours, is then dried to obtain fibroin membrane;Then by fibroin membrane after 190~200 DEG C are handled 2 hours
Freezing smashing obtains silk fibroin powder;Then 10g silk fibroin powder is dispersed in 50g ethyl alcohol, add 8g methyl orthosilicate and
0.5g2- aminobutyric acid and 0.5g diethyl phosphite stir 3 hours at room temperature, add 0.6g silane coupling agent KH560, stir
It is filtered after mixing 1 hour and obtains solid chemical compound;Water is added in 10g sodium acrylate, 7g2- acrylamide-2-methylpro panesulfonic acid
In, it stirs 10 minutes, bis- (2, the 3- epoxy cyclopentyl) ethers of 0.8g is added, stir 15 minutes;Then 3g solid chemical compound is added
With 0.05g azodiisobutyronitrile, 90 DEG C are reacted 4 hours, are finally dried to obtain flocculant.To contain mass concentration for 6% montmorillonite
(Micron order), 1% silica(Nanoscale)Aqueous solution be waste water, 10g flocculant is dispersed in 90g ethyl alcohol, is mixed
Liquid;Then mixed liquor is added in waste water according to 70g/ tons of additive amount;Floccule body is isolated after forty minutes to complete in waste water
The removal of particulate matter.Removal efficiency, removal efficiency 95% are tested with photoelectric colorimeter, alumen ustum separation rate is 94%.
Example IV
100g boiled silk is soluble in water, 10g tetramethyl-ammonium iodide, 30g manganese acetate and 40g cobalt nitrate is then added,
It is uniformly mixed, back flow reaction 8 hours, is then dried to obtain fibroin membrane;Then by fibroin membrane after 190~200 DEG C are handled 2 hours
Freezing smashing obtains silk fibroin powder;Then 10g silk fibroin powder is dispersed in 50g ethyl alcohol, add 5g methyl orthosilicate and
0.3g2- aminobutyric acid and 0.3g diethyl phosphite stir 3 hours at room temperature, add 0.5g Silane coupling agent KH550, stir
It is filtered after mixing 1 hour and obtains solid chemical compound;Water is added in 10g sodium acrylate, 8g2- acrylamide-2-methylpro panesulfonic acid
In, it stirs 10 minutes, bis- (2, the 3- epoxy cyclopentyl) ethers of 0.9g is added, stir 15 minutes;Then 5g solid chemical compound is added
With 0.06g azodiisobutyronitrile, 90 DEG C are reacted 4 hours, are finally dried to obtain flocculant.To contain mass concentration for 6% montmorillonite
(Micron order), 1% silica(Nanoscale)Aqueous solution be waste water, 10g flocculant is dispersed in 90g ethyl alcohol, is mixed
Liquid;Then mixed liquor is added in waste water according to 60g/ tons of additive amount;Floccule body is isolated after 30 minutes to complete in waste water
The removal of particulate matter.Removal efficiency, removal efficiency 95% are tested with photoelectric colorimeter, alumen ustum separation rate is 93%.
Embodiment five
100g boiled silk is soluble in water, 15g tetramethyl-ammonium iodide, 40g manganese acetate and 50g cobalt nitrate is then added,
It is uniformly mixed, back flow reaction 8 hours, is then dried to obtain fibroin membrane;Then by fibroin membrane after 190~200 DEG C are handled 2 hours
Freezing smashing obtains silk fibroin powder;Then 10g silk fibroin powder is dispersed in 50g ethyl alcohol, add 5g methyl orthosilicate and
0.3g2- aminobutyric acid and 0.3g diethyl phosphite stir 3 hours at room temperature, add 0.5g Silane coupling agent KH550, stir
It is filtered after mixing 1 hour and obtains solid chemical compound;Water is added in 10g sodium acrylate, 7g2- acrylamide-2-methylpro panesulfonic acid
In, it stirs 10 minutes, bis- (2, the 3- epoxy cyclopentyl) ethers of 0.8g is added, stir 15 minutes;Then 3g solid chemical compound is added
With 0.05g azodiisobutyronitrile, 90 DEG C are reacted 4 hours, are finally dried to obtain flocculant.To contain mass concentration for 6% montmorillonite
(Micron order), 1% silica(Nanoscale)Aqueous solution be waste water, 12g flocculant is dispersed in 88g ethyl alcohol, is mixed
Liquid;Then mixed liquor is added in waste water according to 70g/ tons of additive amount;Floccule body is isolated after forty minutes to complete in waste water
The removal of particulate matter.Removal efficiency, removal efficiency 93% are tested with photoelectric colorimeter, alumen ustum separation rate is 93%.
Embodiment six
100g boiled silk is soluble in water, 10g tetramethyl-ammonium iodide, 30g manganese acetate and 40g cobalt nitrate is then added,
It is uniformly mixed, back flow reaction 8 hours, is then dried to obtain fibroin membrane;Then by fibroin membrane after 190~200 DEG C are handled 2 hours
Freezing smashing obtains silk fibroin powder;Then 10g silk fibroin powder is dispersed in 60g ethyl alcohol, add 6g methyl orthosilicate and
0.4g2- aminobutyric acid and 0.4g diethyl phosphite stir 3 hours at room temperature, add 0.5g Silane coupling agent KH550, stir
It is filtered after mixing 1 hour and obtains solid chemical compound;Water is added in 10g sodium acrylate, 7g2- acrylamide-2-methylpro panesulfonic acid
In, it stirs 10 minutes, bis- (2, the 3- epoxy cyclopentyl) ethers of 0.8g is added, stir 15 minutes;Then 3g solid chemical compound is added
With 0.05g azodiisobutyronitrile, 90 DEG C are reacted 4 hours, are finally dried to obtain flocculant.To contain mass concentration for 6% montmorillonite
(Micron order), 1% silica(Nanoscale)Aqueous solution be waste water, 13g flocculant is dispersed in 87g ethyl alcohol, is mixed
Liquid;Then mixed liquor is added in waste water according to 50g/ tons of additive amount;Floccule body is isolated after 35 minutes to complete in waste water
The removal of particulate matter.Removal efficiency, removal efficiency 95% are tested with photoelectric colorimeter, alumen ustum separation rate is 94%.
Embodiment seven
100g boiled silk is soluble in water, 10g tetramethyl-ammonium iodide, 30g manganese acetate and 40g cobalt nitrate is then added,
It is uniformly mixed, back flow reaction 8 hours, is then dried to obtain fibroin membrane;Then by fibroin membrane after 190~200 DEG C are handled 2 hours
Freezing smashing obtains silk fibroin powder;Then 10g silk fibroin powder is dispersed in 50g ethyl alcohol, add 5g methyl orthosilicate and
0.3g2- aminobutyric acid and 0.3g diethyl phosphite stir 3 hours at room temperature, add 0.5g Silane coupling agent KH550, stir
It is filtered after mixing 1 hour and obtains solid chemical compound;Water is added in 10g sodium acrylate, 7.5g2- acrylamide-2-methylpro panesulfonic acid
In, it stirs 10 minutes, bis- (2, the 3- epoxy cyclopentyl) ethers of 0.85g is added, stir 15 minutes;Then 4g solid chemical compound is added
With 0.05g azodiisobutyronitrile, 90 DEG C are reacted 4 hours, are finally dried to obtain flocculant.To contain mass concentration for 6% montmorillonite
(Micron order), 1% silica(Nanoscale)Aqueous solution be waste water, 14g flocculant is dispersed in 86g ethyl alcohol, is mixed
Liquid;Then mixed liquor is added in waste water according to 75g/ tons of additive amount;Floccule body is isolated after 35 minutes to complete in waste water
The removal of particulate matter.Removal efficiency, removal efficiency 95% are tested with photoelectric colorimeter, alumen ustum separation rate is 93%.
Embodiment eight
100g boiled silk is soluble in water, 18g tetramethyl-ammonium iodide, 45g manganese acetate and 45g cobalt nitrate is then added,
It is uniformly mixed, back flow reaction 8 hours, is then dried to obtain fibroin membrane;Then by fibroin membrane after 190~200 DEG C are handled 2 hours
Freezing smashing obtains silk fibroin powder;Then 10g silk fibroin powder is dispersed in 50g ethyl alcohol, add 5g methyl orthosilicate and
0.4g2- aminobutyric acid and 0.4g diethyl phosphite stir 3 hours at room temperature, add 0.6g Silane coupling agent KH550, stir
It is filtered after mixing 1 hour and obtains solid chemical compound;Water is added in 10g sodium acrylate, 7.8g2- acrylamide-2-methylpro panesulfonic acid
In, it stirs 10 minutes, bis- (2, the 3- epoxy cyclopentyl) ethers of 0.82g is added, stir 15 minutes;Then 3g solid chemical compound is added
With 0.05g azodiisobutyronitrile, 90 DEG C are reacted 4 hours, are finally dried to obtain flocculant.To contain mass concentration for 6% montmorillonite
(Micron order), 1% silica(Nanoscale)Aqueous solution be waste water, 11g flocculant is dispersed in 89g ethyl alcohol, is mixed
Liquid;Then mixed liquor is added in waste water according to 70g/ tons of additive amount;Floccule body is isolated after 30 minutes to complete in waste water
The removal of particulate matter.Removal efficiency, removal efficiency 96% are tested with photoelectric colorimeter, alumen ustum separation rate is 93%.
Embodiment nine
100g boiled silk is soluble in water, 20g tetramethyl-ammonium iodide, 50g manganese acetate and 60g cobalt nitrate is then added,
It is uniformly mixed, back flow reaction 8 hours, is then dried to obtain fibroin membrane;Then by fibroin membrane after 190~200 DEG C are handled 2 hours
Freezing smashing obtains silk fibroin powder;Then 10g silk fibroin powder is dispersed in 50g ethyl alcohol, add 8g methyl orthosilicate and
0.3g2- aminobutyric acid and 0.5g diethyl phosphite stir 3 hours at room temperature, add 0.5g Silane coupling agent KH550, stir
It is filtered after mixing 1 hour and obtains solid chemical compound;Water is added in 10g sodium acrylate, 7g2- acrylamide-2-methylpro panesulfonic acid
In, it stirs 10 minutes, bis- (2, the 3- epoxy cyclopentyl) ethers of 0.8g is added, stir 15 minutes;Then 5g solid chemical compound is added
With 0.05g azodiisobutyronitrile, 90 DEG C are reacted 4 hours, are finally dried to obtain flocculant.To contain mass concentration for 6% montmorillonite
(Micron order), 1% silica(Nanoscale)Aqueous solution be waste water, 10g flocculant is dispersed in 90g ethyl alcohol, is mixed
Liquid;Then mixed liquor is added in waste water according to 55g/ tons of additive amount;Floccule body is isolated after 30 minutes to complete in waste water
The removal of particulate matter.Removal efficiency, removal efficiency 94% are tested with photoelectric colorimeter, alumen ustum separation rate is 94%.
Embodiment ten
100g boiled silk is soluble in water, 10g tetramethyl-ammonium iodide, 37g manganese acetate and 40g cobalt nitrate is then added,
It is uniformly mixed, back flow reaction 8 hours, is then dried to obtain fibroin membrane;Then by fibroin membrane after 190~200 DEG C are handled 2 hours
Freezing smashing obtains silk fibroin powder;Then 10g silk fibroin powder is dispersed in 50g ethyl alcohol, add 6.5g methyl orthosilicate with
And 0.3g2- aminobutyric acid and 0.35g diethyl phosphite, it stirs 3 hours at room temperature, adds 0.5g silane coupling agent
KH550 is filtered after stirring 1 hour and is obtained solid chemical compound;By 10g sodium acrylate, 7.2g2- acrylamido -2- methyl-prop sulphur
Acid is added to the water, and stirs 10 minutes, and bis- (2, the 3- epoxy cyclopentyl) ethers of 0.88g are added, and stirs 15 minutes;Then 4.2g is added
Solid chemical compound and 0.05g azodiisobutyronitrile, 90 DEG C are reacted 4 hours, are finally dried to obtain flocculant.To be containing mass concentration
6% montmorillonite(Micron order), 1% silica(Nanoscale)Aqueous solution be waste water, 15g flocculant is dispersed in 85g ethyl alcohol,
Obtain mixed liquor;Then mixed liquor is added in waste water according to 65g/ tons of additive amount;It is i.e. complete that floccule body is isolated after 35 minutes
At the removal of particulate matter in waste water.Removal efficiency, removal efficiency 96%, alumen ustum separation are tested with photoelectric colorimeter
Rate is 93%.