CN105774286A - Environment-friendly ink-jet computer-to-plate material - Google Patents

Environment-friendly ink-jet computer-to-plate material Download PDF

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Publication number
CN105774286A
CN105774286A CN201610127101.4A CN201610127101A CN105774286A CN 105774286 A CN105774286 A CN 105774286A CN 201610127101 A CN201610127101 A CN 201610127101A CN 105774286 A CN105774286 A CN 105774286A
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China
Prior art keywords
ink
jet
aluminum substrate
version
plate
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Application number
CN201610127101.4A
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Chinese (zh)
Inventor
陈敦发
徐华昭
眭建民
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Huzhou Tai Dehui Printing Apparatus Co Ltd
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Huzhou Tai Dehui Printing Apparatus Co Ltd
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Priority to CN201610127101.4A priority Critical patent/CN105774286A/en
Publication of CN105774286A publication Critical patent/CN105774286A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41NPRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N1/00Printing plates or foils; Materials therefor
    • B41N1/04Printing plates or foils; Materials therefor metallic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet

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  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Ink Jet (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

The invention discloses an environment-friendly ink-jet computer-to-plate material. According to the environment-friendly ink-jet computer-to-plate material, a base plate, the manufacturing technology of pigment ink and raw materials are comprehensively optimized, manufacturing is easy and convenient, the pressrun of the manufactured computer-to-plate material is greater than 100 thousands, the light fastness is excellent, and the resolution ratio is high. The manufactured pigment ink does not block a printing head, is stable performance, can be fast attached to a plate base after being printed on the aluminum plate base, does not flow or cause image-text fuzziness, is resistant to water and is high in thermal sensitivity, the plate fixing temperature is low, and the plate fixing time is short.

Description

A kind of environmental protection ink-jet CTP version
Technical field
The invention belongs to CTP offset plate field, be specifically related to a kind of environmental protection ink-jet CTP version.
Background technology
CTP (CTP) technology is the state-of-the-art plate-making technology of offset printing plate-making in the present age, and its plate used is called CTP version.Along with the development of the key technology such as information, manufacture, before print, plate-making is positive with all strength towards CTP (ComputerToPlate, CTP) widespread development.CTP refers to after original copy information being input to and processing in computer, by computer control, directly information is exported the technology of forme, its essence is and control laser beam with computer instruction, the information on the digitalized electron space of a whole page to be printed sequenced by computer is delivered on printing plate, directly obtains the technology for printing forme.Offset printing CTP plate mainly has photosensitive plate, Thermal sensitive plate and ink-jet plate according to imaging mechanism, and wherein Thermal sensitive plate is in the market in the highest flight.
Recent years, ink-jet printer achieves very big development, and inkjet printing speed is fast, resolution is high, and the price of ink-jet apparatus and ink is relatively low, thus it is less costly to make a plate, simple to operate etc..This makes ink-jet CTP develop quickly, can be widely used in books and newpapers and periodicals printing.Ink-jet CTP printmaking is usually PS version type ink-jet CTP version.PS version type ink-jet CTP version is to repaste the ink-jet receiving layer of layer of transparent on common positive PS printing plate, then on ink-jet receiving layer, picture and text are printed with ink-jet printer, on-hook printing is got final product after processing then through printing down, development, washing, it eliminates the technique such as film, manual imposition and corresponding equipment compared with traditional PS version mask-making technology, shorten the plate-making time simultaneously, advantageously reduce cost.The patent of major part ink-jet CTP version is this PS version type ink-jet CTP offset master both at home and abroad, but this PS version type ink-jet CTP version still uses PS version, namely on aluminum substrate, to be coated with solvent type photoresists, lithography process is identical with traditional PS version simultaneously, also want the operations such as printing down, development, washing, as controlled the improper plate-making quality that also can affect, contaminated environment is also wanted in developer solution discharge simultaneously, is unfavorable for environmental protection.
Prior art was also disclosed a kind of paint ink and the environment-friendly type on-press-coating ink-jet CTP offset master being made thereof.Using the naked version ink-jet CTP version of environment-friendly type that the paint ink of the present invention is fabricated to, its processing technology is simple, eliminates the techniques such as printing down, development, washing, is absent from environment polluting, also reduces printing cost simultaneously.But this technology yet suffers from press resistance rate not high enough (2-3 ten thousand), the shortcomings such as light fastness is good not, and resolution is high not.
Summary of the invention
The purpose of the present invention can be achieved through the following technical solutions:
It is an object of the invention to provide a kind of novel environmental protection ink-jet CTP version, it is from processing technology, and raw material comprehensively optimizes, and simple for production, and the CTP version press resistance rate prepared prints more than 100,000, and light fastness is splendid, and resolution can reach significantly high.
A kind of novel environmental protection ink-jet CTP version, it is prepared from by the following method:
(1) preparation of aluminum substrate:
Under 30 DEG C of conditions, fine aluminium sulphuric acid by model is 1050: hydrogen peroxide=3:2(volume ratio) mixed solution in and carry out supersound process 2-5s, use deionized water wash clean, then again with 5% sodium hydroxide solution by 1050 fine aluminium clean 50 seconds, being neutralized to PH with hydrochloric acid is 7, then washes with deionized water;Then under alternating current effect, electrolysis loop is formed with graphite electrode, it is thus achieved that surface roughness Ra is the porous surface of 0.60;The space of a whole page after alligatoring is carried out then through being placed in the hydrogenperoxide steam generator of 2.7M concentration, ash disposal, then carries out oxidation processes with deionized water after washing, and generates the hydrophilic layer of aluminium sesquioxide;At 20 DEG C, carry out sealing pores 5 seconds with concentration 3%K2SrF6 aqueous solution as hole sealing agent after washing, wash, be then brought rapidly up 100 DEG C of maintenance 5s, be then cooled to 50 DEG C of drying, obtain the aluminum substrate of CTP plate;
(2) special paint ink is prepared:
nullAccording to weight portion,By 6 part of 50% acrylic acid-acrylic butyl acrylate copolymer emulsion (M=25000 ± 200),Mol ratio acrylic acid: butyl acrylate=1:1.5,It is sequentially added into 2 parts of pigment wherein,0.2-0.3 part trehalose,0.05 part of malic acid,0.02 part of tea saponin,0.08 part of polyethylene glycol oxide alkyl phenol,5-6 part Polyethylene Glycol,0.5-0.8 part glycerol,0.5 part of isopropanol,0.8 part of hexamethylol melamine resin,0.1 part of molecular weight is the phenolic resin of 9000,0.15 part of molecular weight is the phenolic resin of 120000,16 parts of deionized waters,30min is stirred with the blender that rotating speed is 300 revs/min at 30 DEG C,It is cooled to 5 DEG C,Again by the mulser high-speed stirred 35 minutes of 1500 revs/min,50min is pulverized again with sand mill,Regulate pH value to 8,Insoluble impurity is fallen or pigment that particle diameter exceeds standard with the filtering with microporous membrane of 1 μm,Namely paint ink is obtained;
(3) adopt above-mentioned paint ink, directly pattern is printed upon aluminum substrate with ink-jet printer, after conventional solid version processes, namely obtain the environmental protection ink-jet CTP version of the present invention.
The invention have benefit that:
(1) present invention is from base version, and to the processing technology of paint ink, raw material comprehensively optimizes, and simple for production, and the CTP version press resistance rate prepared prints more than 100,000, and light fastness is splendid, and resolution can reach significantly high.
(2) paint ink that the present invention prepares does not block printing head, stable performance, can quickly be attached on edition base after being printed upon on aluminum substrate, will not trickle and cause picture and text to obscure, and water-fast, thermal sensitivity is high, Gu version temperature is low, the time is short.
Detailed description of the invention
Embodiment 1:
A kind of novel environmental protection ink-jet CTP version, it is prepared from by the following method:
(1) preparation of aluminum substrate:
Under 30 DEG C of conditions, fine aluminium sulphuric acid by model is 1050: hydrogen peroxide=3:2(volume ratio) mixed solution in and carry out supersound process 2s, use deionized water wash clean, then again with 5% sodium hydroxide solution by 1050 fine aluminium clean 50 seconds, being neutralized to PH with hydrochloric acid is 7, then washes with deionized water;Then under alternating current effect, electrolysis loop is formed with graphite electrode, it is thus achieved that surface roughness Ra is the porous surface of 0.60;The space of a whole page after alligatoring is carried out then through being placed in the hydrogenperoxide steam generator of 2.7M concentration, ash disposal, then carries out oxidation processes with deionized water after washing, and generates the hydrophilic layer of aluminium sesquioxide;At 20 DEG C, carry out sealing pores 5 seconds with concentration 3%K2SrF6 aqueous solution as hole sealing agent after washing, wash, be then brought rapidly up 100 DEG C of maintenance 5s, be then cooled to 50 DEG C of drying, obtain the aluminum substrate of CTP plate;
(2) special paint ink is prepared:
nullAccording to weight portion,By 6 part of 50% acrylic acid-acrylic butyl acrylate copolymer emulsion (M=25000 ± 200),Mol ratio acrylic acid: butyl acrylate=1:1.5,It is sequentially added into 2 parts of particle diameters pigment black at 100 300nm wherein,0.2 portion of trehalose,0.05 part of malic acid,0.02 part of tea saponin,0.08 part of polyethylene glycol oxide alkyl phenol,5 parts of Polyethylene Glycol,0.5 part of glycerol,0.5 part of isopropanol,0.8 part of hexamethylol melamine resin,0.1 part of molecular weight is the phenolic resin of 9000,0.15 part of molecular weight is the phenolic resin of 120000,16 parts of deionized waters,30min is stirred with the blender that rotating speed is 300 revs/min at 30 DEG C,It is cooled to 5 DEG C,Again by the mulser high-speed stirred 35 minutes of 1500 revs/min,50min is pulverized again with sand mill,Regulate pH value to 8,With the filtering with microporous membrane of 1 μm,Namely paint ink is obtained;
(3) adopting above-mentioned paint ink, pattern is directly printed upon with ink-jet printer aluminum substrate, printed aluminum substrate heats 50s at high temperature 180 DEG C, namely obtains the environmental protection ink-jet CTP version of the present invention.
For printing test, result: the number of resistance to impression: 13w, resolution reaches as high as 390dpi, and the light fastness of ink is splendid, and dot reproduction rate is 99.0%.
Embodiment 2:
A kind of novel environmental protection ink-jet CTP version, it is prepared from by the following method:
(1) preparation of aluminum substrate:
Under 30 DEG C of conditions, fine aluminium sulphuric acid by model is 1050: hydrogen peroxide=3:2(volume ratio) mixed solution in and carry out supersound process 5s, use deionized water wash clean, then again with 5% sodium hydroxide solution by 1050 fine aluminium clean 50 seconds, being neutralized to PH with hydrochloric acid is 7, then washes with deionized water;Then under alternating current effect, electrolysis loop is formed with graphite electrode, it is thus achieved that surface roughness Ra is the porous surface of 0.60;The space of a whole page after alligatoring is carried out then through being placed in the hydrogenperoxide steam generator of 2.7M concentration, ash disposal, then carries out oxidation processes with deionized water after washing, and generates the hydrophilic layer of aluminium sesquioxide;At 20 DEG C, carry out sealing pores 5 seconds with concentration 3%K2SrF6 aqueous solution as hole sealing agent after washing, wash, be then brought rapidly up 100 DEG C of maintenance 5s, be then cooled to 50 DEG C of drying, obtain the aluminum substrate of CTP plate;
(2) special paint ink is prepared:
nullAccording to weight portion,By 6 part of 50% acrylic acid-acrylic butyl acrylate copolymer emulsion (M=25000 ± 200),Mol ratio acrylic acid: butyl acrylate=1:1.5,It is sequentially added into 2 parts of particle diameters pigment black at 100 300nm wherein,0.3 portion of trehalose,0.05 part of malic acid,0.02 part of tea saponin,0.08 part of polyethylene glycol oxide alkyl phenol,6 parts of Polyethylene Glycol,0.8 part of glycerol,0.5 part of isopropanol,0.8 part of hexamethylol melamine resin,0.1 part of molecular weight is the phenolic resin of 9000,0.15 part of molecular weight is the phenolic resin of 120000,16 parts of deionized waters,30min is stirred with the blender that rotating speed is 300 revs/min at 30 DEG C,It is cooled to 5 DEG C,Again by the mulser high-speed stirred 35 minutes of 1500 revs/min,50min is pulverized again with sand mill,Regulate pH value to 8,With the filtering with microporous membrane of 1 μm,Namely paint ink is obtained;
(3) adopting above-mentioned paint ink, pattern is directly printed upon with ink-jet printer aluminum substrate, printed aluminum substrate heats 50s at high temperature 180 DEG C, namely obtains the environmental protection ink-jet CTP version of the present invention.
For printing test, result: the number of resistance to impression: 12w, resolution reaches as high as 380dpi, and the light fastness of ink is splendid, and dot reproduction rate is 99.1%.
Embodiment 3:
A kind of novel environmental protection ink-jet CTP version, it is prepared from by the following method:
(1) preparation of aluminum substrate:
Under 30 DEG C of conditions, fine aluminium sulphuric acid by model is 1050: hydrogen peroxide=3:2(volume ratio) mixed solution in and carry out supersound process 2-5s, use deionized water wash clean, then again with 5% sodium hydroxide solution by 1050 fine aluminium clean 50 seconds, being neutralized to PH with hydrochloric acid is 7, then washes with deionized water;Then under alternating current effect, electrolysis loop is formed with graphite electrode, it is thus achieved that surface roughness Ra is the porous surface of 0.60;The space of a whole page after alligatoring is carried out then through being placed in the hydrogenperoxide steam generator of 2.7M concentration, ash disposal, then carries out oxidation processes with deionized water after washing, and generates the hydrophilic layer of aluminium sesquioxide;At 20 DEG C, carry out sealing pores 5 seconds with concentration 3%K2SrF6 aqueous solution as hole sealing agent after washing, wash, be then brought rapidly up 100 DEG C of maintenance 5s, be then cooled to 50 DEG C of drying, obtain the aluminum substrate of CTP plate;
(2) special paint ink is prepared:
nullAccording to weight portion,By 6 part of 50% acrylic acid-acrylic butyl acrylate copolymer emulsion (M=25000 ± 200),Mol ratio acrylic acid: butyl acrylate=1:1.5,It is sequentially added into 2 parts of particle diameters pigment black at 100 300nm wherein,0.2 portion of trehalose,0.05 part of malic acid,0.02 part of tea saponin,0.08 part of polyethylene glycol oxide alkyl phenol,6 parts of Polyethylene Glycol,0.5 part of glycerol,0.5 part of isopropanol,0.8 part of hexamethylol melamine resin,0.1 part of molecular weight is the phenolic resin of 9000,0.15 part of molecular weight is the phenolic resin of 120000,16 parts of deionized waters,30min is stirred with the blender that rotating speed is 300 revs/min at 30 DEG C,It is cooled to 5 DEG C,Again by the mulser high-speed stirred 35 minutes of 1500 revs/min,50min is pulverized again with sand mill,Regulate pH value to 8,With the filtering with microporous membrane of 1 μm,Namely paint ink is obtained;
(3) adopting above-mentioned paint ink, pattern is directly printed upon with ink-jet printer aluminum substrate, printed aluminum substrate heats 50s at high temperature 180 DEG C, namely obtains the environmental protection ink-jet CTP version of the present invention.
For printing test, result: the number of resistance to impression: 10w, resolution reaches as high as 350dpi, and the light fastness of ink is splendid, and dot reproduction rate is 99.0%.
Embodiment 4:
A kind of novel environmental protection ink-jet CTP version, it is prepared from by the following method:
(1) preparation of aluminum substrate:
Under 30 DEG C of conditions, fine aluminium sulphuric acid by model is 1050: hydrogen peroxide=3:2(volume ratio) mixed solution in and carry out supersound process 3s, use deionized water wash clean, then again with 5% sodium hydroxide solution by 1050 fine aluminium clean 50 seconds, being neutralized to PH with hydrochloric acid is 7, then washes with deionized water;Then under alternating current effect, electrolysis loop is formed with graphite electrode, it is thus achieved that surface roughness Ra is the porous surface of 0.60;The space of a whole page after alligatoring is carried out then through being placed in the hydrogenperoxide steam generator of 2.7M concentration, ash disposal, then carries out oxidation processes with deionized water after washing, and generates the hydrophilic layer of aluminium sesquioxide;At 20 DEG C, carry out sealing pores 5 seconds with concentration 3%K2SrF6 aqueous solution as hole sealing agent after washing, wash, be then brought rapidly up 100 DEG C of maintenance 5s, be then cooled to 50 DEG C of drying, obtain the aluminum substrate of CTP plate;
(2) special paint ink is prepared:
nullAccording to weight portion,By 6 part of 50% acrylic acid-acrylic butyl acrylate copolymer emulsion (M=25000 ± 200),Mol ratio acrylic acid: butyl acrylate=1:1.5,It is sequentially added into 2 parts of particle diameters pigment black at 100 300nm wherein,0.3 portion of trehalose,0.05 part of malic acid,0.02 part of tea saponin,0.08 part of polyethylene glycol oxide alkyl phenol,5.3 parts of Polyethylene Glycol,0.5-0.8 part glycerol,0.5 part of isopropanol,0.8 part of hexamethylol melamine resin,0.1 part of molecular weight is the phenolic resin of 9000,0.15 part of molecular weight is the phenolic resin of 120000,16 parts of deionized waters,30min is stirred with the blender that rotating speed is 300 revs/min at 30 DEG C,It is cooled to 5 DEG C,Again by the mulser high-speed stirred 35 minutes of 1500 revs/min,50min is pulverized again with sand mill,Regulate pH value to 8,With the filtering with microporous membrane of 1 μm,Namely paint ink is obtained;
(3) adopting above-mentioned paint ink, pattern is directly printed upon with ink-jet printer aluminum substrate, printed aluminum substrate heats 50s at high temperature 180 DEG C, namely obtains the environmental protection ink-jet CTP version of the present invention.
For printing test, result: the number of resistance to impression: 15w, resolution reaches as high as 350dpi, and the light fastness of ink is splendid, and dot reproduction rate is 99.5%.
Embodiment 5:
A kind of novel environmental protection ink-jet CTP version, it is prepared from by the following method:
(1) preparation of aluminum substrate:
Under 30 DEG C of conditions, fine aluminium sulphuric acid by model is 1050: hydrogen peroxide=3:2(volume ratio) mixed solution in and carry out supersound process 4s, use deionized water wash clean, then again with 5% sodium hydroxide solution by 1050 fine aluminium clean 50 seconds, being neutralized to PH with hydrochloric acid is 7, then washes with deionized water;Then under alternating current effect, electrolysis loop is formed with graphite electrode, it is thus achieved that surface roughness Ra is the porous surface of 0.60;The space of a whole page after alligatoring is carried out then through being placed in the hydrogenperoxide steam generator of 2.7M concentration, ash disposal, then carries out oxidation processes with deionized water after washing, and generates the hydrophilic layer of aluminium sesquioxide;At 20 DEG C, carry out sealing pores 5 seconds with concentration 3%K2SrF6 aqueous solution as hole sealing agent after washing, wash, be then brought rapidly up 100 DEG C of maintenance 5s, be then cooled to 50 DEG C of drying, obtain the aluminum substrate of CTP plate;
(2) special paint ink is prepared:
nullAccording to weight portion,By 6 part of 50% acrylic acid-acrylic butyl acrylate copolymer emulsion (M=25000 ± 200),Mol ratio acrylic acid: butyl acrylate=1:1.5,It is sequentially added into 2 parts of particle diameters pigment black at 100 300nm wherein,0.5 portion of trehalose,0.05 part of malic acid,0.02 part of tea saponin,0.08 part of polyethylene glycol oxide alkyl phenol,5.8 parts of Polyethylene Glycol,0.7 part of glycerol,0.5 part of isopropanol,0.8 part of hexamethylol melamine resin,0.1 part of molecular weight is the phenolic resin of 9000,0.15 part of molecular weight is the phenolic resin of 120000,16 parts of deionized waters,30min is stirred with the blender that rotating speed is 300 revs/min at 30 DEG C,It is cooled to 5 DEG C,Again by the mulser high-speed stirred 35 minutes of 1500 revs/min,50min is pulverized again with sand mill,Regulate pH value to 8,With the filtering with microporous membrane of 1 μm,Namely paint ink is obtained;
(3) adopting above-mentioned paint ink, pattern is directly printed upon with ink-jet printer aluminum substrate, printed aluminum substrate heats 50s at high temperature 180 DEG C, namely obtains the environmental protection ink-jet CTP version of the present invention.
For printing test, result: the number of resistance to impression: 25w, resolution reaches as high as 500dpi, and the light fastness of ink is splendid, and dot reproduction rate is 99.8%.
In sum, the present invention is from base version, and to the processing technology of paint ink, raw material comprehensively optimizes, and simple for production, and the CTP version press resistance rate prepared prints more than 100,000, and light fastness is splendid, and resolution can reach significantly high.The paint ink that the present invention prepares does not block printing head, stable performance, can quickly be attached on edition base after being printed upon on aluminum substrate, will not trickle and cause picture and text to obscure, and water-fast, thermal sensitivity is high, Gu version temperature is low, the time is short.
The above; it is only the present invention preferably detailed description of the invention; but protection scope of the present invention is not limited thereto; any those familiar with the art is in the technical scope that the invention discloses; it is equal to replacement according to technical scheme and inventive concept thereof or is changed, all should be encompassed within protection scope of the present invention.

Claims (3)

1. the preparation method of an environmental protection ink-jet CTP version, it is characterised in that step is as follows:
(1) aluminum substrate is prepared;
(2) special paint ink is prepared;
(3) adopt above-mentioned paint ink, directly pattern is printed upon aluminum substrate with ink-jet printer, after conventional solid version processes, namely obtain the environmental protection ink-jet CTP version of the present invention.
2. the preparation method described in claim 1, it is characterised in that its step is as follows:
(1) preparation of aluminum substrate:
Under 30 DEG C of conditions, fine aluminium sulphuric acid by model is 1050: hydrogen peroxide=3:2(volume ratio) mixed solution in and carry out supersound process 2-5s, use deionized water wash clean, then again with 5% sodium hydroxide solution by 1050 fine aluminium clean 50 seconds, being neutralized to PH with hydrochloric acid is 7, then washes with deionized water;Then under alternating current effect, electrolysis loop is formed with graphite electrode, it is thus achieved that surface roughness Ra is the porous surface of 0.60;The space of a whole page after alligatoring is carried out then through being placed in the hydrogenperoxide steam generator of 2.7M concentration, ash disposal, then carries out oxidation processes with deionized water after washing, and generates the hydrophilic layer of aluminium sesquioxide;At 20 DEG C, carry out sealing pores 5 seconds with concentration 3%K2SrF6 aqueous solution as hole sealing agent after washing, wash, be then brought rapidly up 100 DEG C of maintenance 5s, be then cooled to 50 DEG C of drying, obtain the aluminum substrate of CTP plate;
(2) special paint ink is prepared:
nullAccording to weight portion,By 6 part of 50% acrylic acid-acrylic butyl acrylate copolymer emulsion (M=25000 ± 200),Mol ratio acrylic acid: butyl acrylate=1:1.5,It is sequentially added into 2 parts of pigment wherein,0.2-0.3 part trehalose,0.05 part of malic acid,0.02 part of tea saponin,0.08 part of polyethylene glycol oxide alkyl phenol,5-6 part Polyethylene Glycol,0.5-0.8 part glycerol,0.5 part of isopropanol,0.8 part of hexamethylol melamine resin,0.1 part of molecular weight is the phenolic resin of 9000,0.15 part of molecular weight is the phenolic resin of 120000,16 parts of deionized waters,30min is stirred with the blender that rotating speed is 300 revs/min at 30 DEG C,It is cooled to 5 DEG C,Again by the mulser high-speed stirred 35 minutes of 1500 revs/min,50min is pulverized again with sand mill,Regulate pH value to 8,Insoluble impurity is fallen or pigment that particle diameter exceeds standard with the filtering with microporous membrane of 1 μm,Namely paint ink is obtained;
(3) adopt above-mentioned paint ink, directly pattern is printed upon aluminum substrate with ink-jet printer, after conventional solid version processes, namely obtain the environmental protection ink-jet CTP version of the present invention.
3. the environmental protection ink-jet CTP version that the method described in claim 1-2 prepares.
CN201610127101.4A 2016-03-07 2016-03-07 Environment-friendly ink-jet computer-to-plate material Pending CN105774286A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050199149A1 (en) * 2004-03-10 2005-09-15 Creo Il. Ltd. Method and materials for improving resolution for ctp-inkjet
CN1800982A (en) * 2005-12-27 2006-07-12 中国科学院化学研究所 CTP plate making method and apparatus by using ink jet imaging principle
CN101081952A (en) * 2007-07-12 2007-12-05 石深泉 Environment-friendly type on-press-coating ink-jet CTP offset master, pigment ink and preparation method thereof
CN101293441A (en) * 2008-06-23 2008-10-29 石深泉 Environment-friendly ink-jet CTP offset master and production method thereof
CN101373333A (en) * 2008-08-22 2009-02-25 北京银月精铝科技有限公司 Planographic plate for laser digital scanning and manufacture method thereof
CN101747683A (en) * 2008-12-11 2010-06-23 中国科学院化学研究所 Nanometer pigment ink for computer to plate inkjet print and preparing method thereof
CN102464915A (en) * 2010-11-05 2012-05-23 中国科学院化学研究所 Oily ink for inkjet computer to plate, preparation method and application thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050199149A1 (en) * 2004-03-10 2005-09-15 Creo Il. Ltd. Method and materials for improving resolution for ctp-inkjet
CN1800982A (en) * 2005-12-27 2006-07-12 中国科学院化学研究所 CTP plate making method and apparatus by using ink jet imaging principle
CN101081952A (en) * 2007-07-12 2007-12-05 石深泉 Environment-friendly type on-press-coating ink-jet CTP offset master, pigment ink and preparation method thereof
CN101293441A (en) * 2008-06-23 2008-10-29 石深泉 Environment-friendly ink-jet CTP offset master and production method thereof
CN101373333A (en) * 2008-08-22 2009-02-25 北京银月精铝科技有限公司 Planographic plate for laser digital scanning and manufacture method thereof
CN101747683A (en) * 2008-12-11 2010-06-23 中国科学院化学研究所 Nanometer pigment ink for computer to plate inkjet print and preparing method thereof
CN102464915A (en) * 2010-11-05 2012-05-23 中国科学院化学研究所 Oily ink for inkjet computer to plate, preparation method and application thereof

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Application publication date: 20160720