CN105762618B - A kind of long-time iodine flow feedway - Google Patents

A kind of long-time iodine flow feedway Download PDF

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Publication number
CN105762618B
CN105762618B CN201410787297.0A CN201410787297A CN105762618B CN 105762618 B CN105762618 B CN 105762618B CN 201410787297 A CN201410787297 A CN 201410787297A CN 105762618 B CN105762618 B CN 105762618B
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iodine
gas
iodine vapor
temperature
long
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CN105762618A (en
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李国富
多丽萍
金玉奇
王元虎
于海军
汪健
曹靖
李留成
唐书凯
王增强
康元福
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Dalian Institute of Chemical Physics of CAS
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Dalian Institute of Chemical Physics of CAS
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Abstract

A kind of long-time iodine vapor feedway of the invention is related to CW chemical oxygen-iodine laser device gas supply technology.The main body of device is divided into two parts, and one is electrically heated iodine vapor storage tank, secondly for the combustion chamber of two kinds of gas burning.Solid-state iodine is heated to the liquid iodophor of certain temperature by electrically heated iodine vapor storage tank, and the iodine vapor with certain saturated vapor pressure is formed on liquid level.Carbon monoxide is in combustion chamber and oxygen provides the confined space of burning and the high temperature and high pressure gas generated enters in iodine vapor storage tank after diluent gas adjusts temperature.The carbon dioxide gas of high temperature forms bubble after entering in the liquid phase of iodine vapor storage tank, and transferring thermal energy to liquid iodophor makes iodine evaporation become iodine vapor, and the iodine vapor of certain density is just contained in bubble.During bubble constantly rises in the liquid phase, this mass-and heat-transfer phenomenon constantly occurs until reaching balance.It is entered from outflow in liquid phase and flows through supply air line after gas phase and enter laser bodies.

Description

A kind of long-time iodine flow feedway
Technical field
The present invention is related with oxygen iodine chemical laser material supply.
Technical background:
Iodine vapor is one of the material of CW chemical oxygen-iodine laser device indispensability, and the method generated determines iodine vapor stream Stability, volume and the duration of amount.The method of generation is mainly physical evaporation method, also there is chemical method.
Physical evaporation method is that solid-state iodine high-temperature heating is become liquid, controls liquid surface iodine by adjusting iodine solution temperature The saturated vapor pressure of steam, after the vent valve of closed container is opened, iodine vapor, which can flow out, to be entered in steam line.Tool Body is embodied as being placed on iodine crystal in the heatable stainless cylinder of steel body of vacuum tightness, have on tank body thermometric, survey pressure, pneumatic operated valve and The attachmentes such as temperature control.Heating device is generally stainless steel heating tube, is realized by temperature measuring equipment and temperature control equipment to tank The heating and temperature control of internal material.It is that pneumatic operated valve is opened when the intracorporal iodine vapor of tank reaches setting value, iodine vapor outflow enters Into steam line.
The shortcomings that iodine vapor feedway of such electric heating evaporation be iodine vapor be during supply gradually under Drop, it is gradually reduced so as to cause iodine vapor flow.Its reason is that stainless steel heating tube is placed in iodine solution body and conducts effect Rate is slower, is unable to satisfy the demand that iodine solution body persistently evaporates.
Summary of the invention
Present invention aims at provide a kind of iodine vapor flow confession of long-time stable for CW chemical oxygen-iodine laser device To device, the long-time steady operation of laser can satisfy.
In order to achieve the object of the present invention, specific technical solution is:
Long-time iodine vapor feedway mainly includes two parts, and one is that fluid reservoir, that is, iodine of electrically heated material iodine steams Gas storage tank, secondly the characteristics of being the combustion chamber of two kinds of gas burning, corresponding to CW chemical oxygen-iodine laser device, both gases It should be carbon monoxide and oxygen, wherein carbon monoxide is excessive.Iodine vapor storage tank uses the electricity with temperature control feedback device to add Hot systems, slow heating makes iodine solution body and iodine vapor in storage tank be in the state of constant temperature and pressure after heating reaches set temperature. The effect of combustion chamber is that oxidant gas and reducing agent gas is made to burn in its closed system, the high temperature that combustion reaction generates High pressure gas outflow enters in iodine vapor storage tank after diluent gas adjusts temperature.High-temperature gas passes through gas in air accumulator Distributor forms uniform bubble.Mass-and heat-transfer is completed with the iodine of liquid phase during bubble rises in liquid, in bubble It forms the iodine vapor of saturated vapor pressure and finally flows out.
Solid-state iodine is heated to the liquid iodophor of certain temperature, and the shape on liquid level by the electrically heated iodine vapor storage tank of the present invention At the iodine vapor with certain saturated vapor pressure.Combustion chamber for carbon monoxide and oxygen provides the confined space of burning and generates High temperature and high pressure gas enters in iodine vapor storage tank after diluent gas adjusts temperature.The carbon dioxide gas of high temperature enters iodine Bubble is formed after in the liquid phase of steam storage tank, transferring thermal energy to liquid iodophor makes iodine evaporation become iodine vapor, just contains in bubble The iodine vapor of certain density.During bubble constantly rises in the liquid phase, this mass-and heat-transfer phenomenon constantly occurs until reaching To balance.It is entered from outflow in liquid phase and flows through supply air line after gas phase and enter laser bodies.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of long-time iodine flow feedway of the invention.
Specific embodiment
As shown in Figure 1, cavity 2 and 10 tank body of fluid reservoir are respectively the fluid reservoir of combustion chamber and material iodine.Combustion chamber has not Rust steel is made and can not have gas leak phenomenon in hyperbar.The periphery of combustion chamber is the air inlet pipeline 2 of oxygen and carbon monoxide With 3.The spark plug 4 of igniting is used in outer wall of combustion chamber connection.Pipeline 5 is used to be added the diluent gas of regulating gas temperature such as Helium or nitrogen etc..Helium mix of the carbon dioxide gas of high temperature after the outflow of combustion chamber with low temperature, it is pneumatic to flow through first Valve 6 enters in gas distributor 9.Connecting line between first pneumatic operated valve 6 and gas distributor is used to be controlled with temperature Power supply 7 and heating tape 8 heat, keep its temperature identical or slightly higher as the intracorporal equilibrium temperature of tank.10 tank body of fluid reservoir is same Carrying out preheating to tank body using power supply 7 and heating tape 8 makes the internal material iodine solid installed become liquid iodophor.Component 11 and 12 Respectively thermocouple and pressure sensor are for monitoring the pressure of liquid iodophor temperature and iodine vapor in tank body.Second pneumatic operated valve 13 is beaten The iodine vapor outflow tank body of tank body enters pipeline 14 when opening, and enters eventually into laser bodies.

Claims (7)

1. a kind of long-time iodine vapor feedway, it is characterised in that: including closed combustion chamber (2) and closed material iodine The wall surface of fluid reservoir (10), combustion chamber is equipped with oxygen intake pipe road (1) and carbon monoxide air inlet pipeline (3), in combustion chamber side Wall is equipped with for the spark plug (4) to burning indoor gas igniting;The wall surface of combustion chamber is equipped with carbon dioxide gas stream Outlet;
Lower part in the fluid reservoir (10) of material iodine is equipped with gas distributor (9) and passes through pipeline (5) and tune through the first pneumatic operated valve (6) The diluent gas gas source of solar term temperature is connected, and the diluent gas is helium or nitrogen, in diluent gas gas source and first Connecting line between pneumatic operated valve (6) is equipped with the branch line being connected with the carbon dioxide gas outflux of combustion chamber;
Connecting line between first pneumatic operated valve (6) and gas distributor is wound with heat tape (8);Outside fluid reservoir (10) tank body Heat tape (8) are wound on wall surface;Fluid reservoir (10) tank body is equipped with for monitoring liquid iodophor temperature and iodine vapor in tank body The thermocouple (11) and pressure sensor (12) of pressure;Fluid reservoir (10) tank body top is equipped with iodine vapor outflux, iodine vapor stream Outlet is connected through the second pneumatic operated valve (13) with external pipe (14).
2. the long-time iodine vapor feedway as described in claim 1, it is characterised in that: external pipe (14) and laser The air inlet pipeline of main body is connected.
3. the long-time iodine vapor feedway as described in claim 1, it is characterised in that:
Heat tape (8) is electrically connected through temperature controller with power supply (7);Thermocouple (11) is connect with temperature controller signal.
4. the long-time iodine vapor feedway as described in claim 1, it is characterised in that:
Iodine vapor feedway includes fluid reservoir (10) the i.e. iodine vapor storage tank of electric heating material iodine and the combustion of two kinds of gas burning It burns room and infiltration is passed through the gas distributor of high temperature and high pressure gas in liquid iodophor, liquid iodophor is entered by gas distributor In high-temperature gas for liquid iodophor evaporation provide thermal energy;Burn generate high-temperature gas by diluent gas dilution cooling after with It is suitble to the temperature of requirement of engineering to enter in gas distributor;High-temperature gas forms gas after gas distributor in liquid iodophor Bubble, bubble are completed and the mass-and heat-transfer process of liquid iodophor in uphill process.
5. the long-time iodine vapor feedway as described in claim 1, it is characterised in that: during iodine vapor supply, liquid It is the chemical energy from carbon monoxide and oxygen combustion that the evaporation of state iodine, which becomes thermal energy required for gaseous iodine,.
6. the long-time iodine vapor feedway as described in claim 1, which is characterized in that high-temperature gas bubble uphill process In, the iodine of liquid phase is evaporated to the iodine vapor that vapour phase is formed in bubble.
7. the long-time iodine vapor feedway as described in claim 1, which is characterized in that the high-temperature gas for generation of burning is Iodine evaporation provides endlessly thermal energy, as long as the liquid iodophor in fluid reservoir (10) the i.e. iodine vapor storage tank of material iodine is enough, It can be with long-time steady operation.
CN201410787297.0A 2014-12-17 2014-12-17 A kind of long-time iodine flow feedway Active CN105762618B (en)

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CN106647526A (en) * 2017-01-16 2017-05-10 中国人民解放军国防科学技术大学 Distributed embedded-type intelligent measurement and control system for chemical laser
CN108144428A (en) 2017-03-15 2018-06-12 江苏新世纪江南环保股份有限公司 A kind of method and device of ammonia process efficient removal gas sulphur oxide and dirt
CN107235474B (en) * 2017-07-28 2023-07-21 贵州开磷碘业有限责任公司 Method and device for purifying crude iodine
CN108457826B (en) * 2018-03-09 2020-03-03 中国科学院微电子研究所 Working medium supply device of electric propeller and electric propeller
CN110374830A (en) * 2019-07-15 2019-10-25 上海交通大学 Storage tank is heated in heat radiation suitable for iodine working medium electric propulsion device

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US5693267A (en) * 1996-09-27 1997-12-02 Boeing North American, Inc. Fast response iodine vaporization with an integrated atomizer and mixer
CN2327440Y (en) * 1998-06-18 1999-07-07 中国科学院大连化学物理研究所 Small-size high-performance energy-saving iodine vapor generator
CN2333439Y (en) * 1998-05-14 1999-08-18 中国科学院大连化学物理研究所 Composite iodine steam generator
CN2517476Y (en) * 2002-01-11 2002-10-23 中国科学院大连化学物理研究所 Internally-externally heated dynamic balance iodine steam generator
CN101436754A (en) * 2007-11-14 2009-05-20 中国科学院大连化学物理研究所 Rapid continuous iodine-feeding device
CN201644054U (en) * 2010-03-16 2010-11-24 中国船舶重工集团公司第七一八研究所 Iodine vapor allocating device
CN103111211A (en) * 2012-11-05 2013-05-22 哈尔滨工程大学 Iodine vapor distributing device with on-line iodine function

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JP3006760B2 (en) * 1997-09-26 2000-02-07 川崎重工業株式会社 Iodine laser generator

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5693267A (en) * 1996-09-27 1997-12-02 Boeing North American, Inc. Fast response iodine vaporization with an integrated atomizer and mixer
CN2333439Y (en) * 1998-05-14 1999-08-18 中国科学院大连化学物理研究所 Composite iodine steam generator
CN2327440Y (en) * 1998-06-18 1999-07-07 中国科学院大连化学物理研究所 Small-size high-performance energy-saving iodine vapor generator
CN2517476Y (en) * 2002-01-11 2002-10-23 中国科学院大连化学物理研究所 Internally-externally heated dynamic balance iodine steam generator
CN101436754A (en) * 2007-11-14 2009-05-20 中国科学院大连化学物理研究所 Rapid continuous iodine-feeding device
CN201644054U (en) * 2010-03-16 2010-11-24 中国船舶重工集团公司第七一八研究所 Iodine vapor allocating device
CN103111211A (en) * 2012-11-05 2013-05-22 哈尔滨工程大学 Iodine vapor distributing device with on-line iodine function

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