CN105755819B - A kind of fire-type is electromagnetically shielded Antiradiation protection cloth - Google Patents
A kind of fire-type is electromagnetically shielded Antiradiation protection cloth Download PDFInfo
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- CN105755819B CN105755819B CN201610171052.4A CN201610171052A CN105755819B CN 105755819 B CN105755819 B CN 105755819B CN 201610171052 A CN201610171052 A CN 201610171052A CN 105755819 B CN105755819 B CN 105755819B
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
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- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06M13/144—Alcohols; Metal alcoholates
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- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
- D06M13/364—Cyanuric acid; Isocyanuric acid; Derivatives thereof
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
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- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
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Abstract
The invention discloses a kind of fire-type to be electromagnetically shielded Antiradiation protection cloth.It includes hypothallus, complex metal plating layer, high-temperature-resistant layer, anti oxidation layer and fireprotection layer, and the hypothallus is that hypothallus cloth is immersed in into dry after infiltration uniformly in the mixed solution of 30% Nano Silver and 70% binding agent composition form;The complex metal plating layer is located above hypothallus;Fireprotection layer is provided with above the complex metal plating layer;High-temperature-resistant layer is provided between the fireprotection layer and complex metal plating layer;Anti oxidation layer is additionally provided with above the fireprotection layer.The Antiradiation protection cloth possesses higher electromagnet shield effect in relative broad range, and with it is excellent prevent fires, anti-oxidant and resistance to elevated temperatures.
Description
Technical field
The present invention relates to one kind to be electromagnetically shielded Antiradiation protection cloth, specifically a kind of fire-type electromagnetic shielding Antiradiation protection cloth.
Background technology
With the fast development of hyundai electronicses electrical equipment industry, various wireless communication system and electronic device quantity are drastically
Increase, causes electromagnetic interference and electromagnetic compatibility phenomenon getting worse, electromagnetic radiation pollution problem is outstanding day by day, therefore electromagnetic radiation
Pollution has been to be concerned by more and more people.Electromagnetic interference caused by electromagnetic radiation not only has influence on the performance realization of electronic product,
And caused electromagnetic pollution can cause serious injury to the mankind and other organisms therefrom.Shielding is to utilize shield
(material with particular characteristic) prevents or the transmission channel of decay electromagnetic interference energy, so as to suppression electromagnetic interference.It is anti-
Only disturb and leak caused by electromagenetic wave radiation, it is the main side used at present using electromagnetic shielding material be electromagnetically shielded
Method.Existing shielding material includes electromagnetic shielding metallic plate, electromagnetic shield cloth etc., and wherein electromagnetic shield cloth is widely used in calculating
Professional's labour protection such as machine, microwave, antistatic, explosion-proof clothes, maternity dress, the shielding tent of military use, shielding curtain
Cloth, equipment drop cloth, the electrostatic protection of electronic instrument and information security shielding etc..At present, the existing electromagnetic shield cloth master of in the market
There are addition wire or conductive fiber when weaving cotton cloth to be made, this kind of method wire easy fracture, and flexible in process of production
Property is poor, and shield effectiveness is undesirable;Also some electromagnetic shield cloths are metal-coated fabrics, its generally there is also metal it is perishable,
The problems such as oxidizable, non-refractory, coating are easy to fall off, fire line is poor, far from suitable under some explosion-proof, military particular surroundings
Purposes.
The content of the invention
For problems of the prior art, the invention provides a kind of fire-type to be electromagnetically shielded Antiradiation protection cloth.This is anti-
Radiation cloth possesses higher electromagnet shield effect in relative broad range, and with it is excellent prevent fires, anti-oxidant and resistance to elevated temperatures.
The present invention uses following technical scheme:
A kind of fire-type is electromagnetically shielded Antiradiation protection cloth, it is characterised in that it includes hypothallus, complex metal plating layer, resistance to height
Warm layer, anti oxidation layer and fireprotection layer, the hypothallus are hypothallus cloth to be immersed in into 30% Nano Silver and 70% binding agent forms
Drying forms after being infiltrated uniformly in mixed solution;The complex metal plating layer is located above hypothallus;The complex metal plating layer
Top is provided with fireprotection layer;High-temperature-resistant layer is provided between the fireprotection layer and complex metal plating layer;It is additionally provided with above the fireprotection layer
Anti oxidation layer.
The Nano Silver is the particle that particle diameter is 20-30nm;The binding agent is 5% carboxymethylcellulose sodium solution.
The complex metal plating layer is nickel coating:Copper plate:The thickness of nickel coating is according to 1:2:1 ratio is made, described
Complex metal plating layer gross thickness is 0.2-0.3mm.
The anti oxidation layer is by graphite 55%, ceramic 15%, nano silicon 3%, binding agent 5%, silicate 5%
Coating coating with excess water composition is prepared.
The anti oxidation layer thickness is 0.5-1mm.
The high-temperature-resistant layer is silicone resin coating, and thickness is 0.3-0.5 mm.
The fireprotection layer is by APP 30%, melamine 30%, epoxy resin 20%, sodium metasilicate 5%, nanometer titanium dioxide
The coating coating that silicon 5%, pentaerythrite 10% form is prepared.
The fireprotection layer thickness is 0.1-0.3mm.
The hypothallus cloth is the tatting, knitting, woven nitride layer of cotton, fiber crops, silk, terylene, polyamide fibre, acrylic or its blending
Or nonwoven layer.
Complex metal plating layer is using conventional metallization film plating process, such as magnetron sputtering method or galvanoplastic in the present invention.
The beneficial effects of the invention are as follows:
1)Shield effectiveness is high.The present invention realizes product and existed by adjusting metal species and content and functional layer position
Possess higher shield effectiveness in scope wider 10MHZ ~ 40GHz, its shield effectiveness can reach more than 80dB.
2)Functional.Compared with common metal coating cloth, cloth of the invention has by the optimum choice of coating
Good pliability, electric conductivity, inoxidizability, heat-resisting quantity, antibiotic property and fire line, feature is extremely strong, be suitable for it is civilian,
The multiple fields such as military, telecommunications and the particular surroundings such as explosion-proof.Its toughness is still preferable after multiple functions coating and use,
This is due to that anti oxidation layer and fire prevention interlayer with the addition of appropriate Nano particles of silicon dioxide, and it is to due to complex metal plating layer
Use and with obvious toughening effect the problem of the big hardness brought, maintain the pliability of matrix layer material, can
Plasticity is extremely strong.In high temperature environments, sodium metasilicate and nano silicon in component coordinate fireprotection layer of the present invention with other components
Use, the toughness of product can also be strengthened by having not only acted as the fire-retardant effect of synergistic, and fire protecting performance is good.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention.
In figure, 1 is hypothallus, and 2 be complex metal plating layer, and 3 be high-temperature-resistant layer, and 4 be fireprotection layer, and 5 be anti oxidation layer.
Embodiment
The present invention is described in further detail with specific embodiment below in conjunction with the accompanying drawings.
Embodiment 1
A kind of fire-type is electromagnetically shielded Antiradiation protection cloth, and it includes hypothallus, complex metal plating layer, resistance to height successively from top to bottom
Warm layer, fireprotection layer and anti oxidation layer.
Its specific preparation method is as follows:
1)Choose tatting, knitting, woven nitride layer or the nonwoven layer of cotton, fiber crops, silk, terylene, polyamide fibre, acrylic or its blending
As hypothallus cloth;
2)By particle diameter be 20-30nm Nano Silvers 30g be dispersed in 70g5% carboxymethylcellulose sodium solution be made it is mixed
Solution is closed, then hypothallus cloth is immersed wherein, drying is taken out after infiltration completely;
3)According to the metallization film plating process of routine successively by metallic nickel, metallic copper, metal on hypothallus after the drying
Nickel is according to thickness ratio 1:2:1 ratio uniform plating forms complex metal plating layer on the surface, and complex metal plating layer gross thickness is
0.2-0.3mm;
4)Silicone resin coating is coated uniformly on complex metal plating layer and forms high-temperature-resistant layer, freeze-day with constant temperature, is applied
Thickness degree is 0.3-0.5 mm;
5)By APP 30%, melamine 30%, epoxy resin 20%, sodium metasilicate 5%, nano silicon 5%, season penta
The coating that tetrol 10% forms, which is coated uniformly on high-temperature-resistant layer, forms fireprotection layer, freeze-day with constant temperature, coating layer thickness 0.1-
0.3mm;
6)Will be by graphite 55%, ceramic 15%, nano silicon 3%, binding agent 5%, silicate 5% and excess water group
Into coating be coated uniformly on freeze-day with constant temperature on fireprotection layer and obtain final products, fire resisting covering 0.5-1mm.
Fire-type electromagnetic shielding Antiradiation protection cloth prepared by above-described embodiment carries out shielding properties test.Using SJ20524-
1995 method carries out electricity in 10MHZ ~ 40GHz frequency range to electromagnetic shielding Antiradiation protection cloth sample prepared by embodiment 1
Magnetic shield performance is tested, and its shield effectiveness is 80-86dB, thus the present invention has higher shielding in wider frequency range
Efficiency, it is a kind of excellent electromagnetic shielded product, available for effectively preventing all kinds of electromagnetic radiation pollutions and telecommunications purposes.
The fire-type prepared in above-described embodiment electromagnetic shielding Antiradiation protection cloth is subjected to fire protecting performance test.Marked according to country
Experimental method as defined in quasi- GB5455-85, to products measure flame-retardant textile char length of the present invention, after flame time and it is fire-retardant when
Between.Test result is as follows:Flame-retardant textile char length≤120mm;After flame time≤5s;Smoldering time≤20s.It follows that
The fire protecting performance of the electromagnetic shielding Antiradiation protection cloth of the present invention is preferable, excellent by being carried out to the various components and content for interlayer of preventing fires
Change, each component is microcosmic it is upper to have reached good flame retardant effect there occurs mutual chemical action, while with other functional components association
The advantages that same-action is the functional of the present invention, and usage time is permanent, high temperature resistant, and shield effectiveness is high.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (6)
1. a kind of fire-type is electromagnetically shielded Antiradiation protection cloth, it is characterised in that it includes hypothallus, complex metal plating layer, high temperature resistant
Layer, anti oxidation layer and fireprotection layer, the hypothallus are that hypothallus cloth is immersed in into the mixed of 30% Nano Silver and 70% binding agent composition
Drying after infiltrating uniformly in solution is closed to form;The complex metal plating layer is located above hypothallus;On the complex metal plating layer
Side is provided with fireprotection layer;High-temperature-resistant layer is provided between the fireprotection layer and complex metal plating layer;It is additionally provided with above the fireprotection layer anti-
Oxide layer;The high-temperature-resistant layer is the silicone resin coating that thickness is 0.3-0.5mm;The fireprotection layer is that thickness is 0.1-
0.3mm by APP 30%, melamine 30%, epoxy resin 20%, sodium metasilicate 5%, nano silicon 5%, pentaerythrite
The coating coating of 10% composition is prepared.
2. fire-type according to claim 1 is electromagnetically shielded Antiradiation protection cloth, it is characterised in that the Nano Silver is that particle diameter is
20-30nm particle;The binding agent is 5% carboxymethylcellulose sodium solution.
3. fire-type according to claim 1 is electromagnetically shielded Antiradiation protection cloth, it is characterised in that the complex metal plating layer is
Nickel coating:Copper plate:The thickness of nickel coating is according to 1:2:1 ratio is made, and the complex metal plating layer gross thickness is 0.2-
0.3mm。
4. fire-type according to claim 1 is electromagnetically shielded Antiradiation protection cloth, it is characterised in that the anti oxidation layer is by stone
It is prepared by the coating coating of ink 55%, ceramic 15%, nano silicon 3%, binding agent 5%, silicate 5% and excess water composition
Form.
5. the fire-type electromagnetic shielding Antiradiation protection cloth according to claim 1 or 3, it is characterised in that the anti-oxidant thickness
Spend for 0.5-1mm.
6. fire-type according to claim 1 is electromagnetically shielded Antiradiation protection cloth, it is characterised in that the hypothallus cloth is
Cotton, fiber crops, silk, terylene, polyamide fibre, tatting, knitting, woven nitride layer or the nonwoven layer of acrylic fibers or its blending.
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CN109392239B (en) * | 2018-09-29 | 2021-01-08 | 江苏芯力特电子科技有限公司 | Heat-resistant flame-retardant ceramic printed circuit board |
CN112981976A (en) * | 2021-02-06 | 2021-06-18 | 李金赛 | Fireproof tent fabric and preparation method thereof |
CN113400731A (en) * | 2021-05-17 | 2021-09-17 | 昆山翌铭汽车配件有限公司 | Electromagnetic shielding composite coating, breathable electromagnetic shielding heat insulation cloth and preparation process thereof |
CN115534443A (en) * | 2022-10-08 | 2022-12-30 | 苏州盛达飞智能科技股份有限公司 | Electromagnetic shielding material for hard package |
CN116289190B (en) * | 2023-05-12 | 2023-07-18 | 深圳启赋科创技术有限公司 | Electromagnetic shielding material |
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CN1467337A (en) * | 2002-07-10 | 2004-01-14 | 郑成通 | Conductive fiber cloth |
CN1268803C (en) * | 2004-01-13 | 2006-08-09 | 长沙力元新材料股份有限公司 | Nickel-copper composite metal textile and preparation method thereof |
KR100684132B1 (en) * | 2005-05-26 | 2007-02-20 | 배종호 | A carbon coating fabric and manufacture method of it |
CN101451306A (en) * | 2008-12-26 | 2009-06-10 | 盛虹集团有限公司 | Antibacterial, moisture-absorbing and sweat-releasing finishing combination method for nylon printed knitted fabric |
CN201826193U (en) * | 2009-12-11 | 2011-05-11 | 渤扬复合面料科技(昆山)有限公司 | Wet-process antiflaming, thermal-insulation and breathable coated fabric |
CN102168366A (en) * | 2010-02-26 | 2011-08-31 | 上海亿金纳米科技有限公司 | Novel nanometer silver antibacterial fabric and preparation method thereof |
CN102851949B (en) * | 2012-09-28 | 2014-12-31 | 嘉兴市安瑞材料科技有限公司 | Flame retardant flexible ceiling film and method for preparing same |
CN204589718U (en) * | 2015-01-04 | 2015-08-26 | 成都建丰装饰纸有限公司 | Floor flame retardant type impregnated paper |
CN205046403U (en) * | 2015-09-30 | 2016-02-24 | 吴江市雪尔美纺织有限公司 | Ultra -thin electrically conductive cloth shielding surface fabric |
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