CN105754257B - 一种注射成型闪彩鞋材及其制作方法 - Google Patents
一种注射成型闪彩鞋材及其制作方法 Download PDFInfo
- Publication number
- CN105754257B CN105754257B CN201610199430.XA CN201610199430A CN105754257B CN 105754257 B CN105754257 B CN 105754257B CN 201610199430 A CN201610199430 A CN 201610199430A CN 105754257 B CN105754257 B CN 105754257B
- Authority
- CN
- China
- Prior art keywords
- parts
- pvc
- golden shallot
- shallot plate
- footwear material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000463 material Substances 0.000 title claims abstract description 41
- 238000001746 injection moulding Methods 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title abstract description 6
- 244000291564 Allium cepa Species 0.000 claims abstract description 33
- 235000010167 Allium cepa var aggregatum Nutrition 0.000 claims abstract description 33
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 239000006260 foam Substances 0.000 claims abstract description 9
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 8
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 8
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 238000000465 moulding Methods 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000002347 injection Methods 0.000 claims description 3
- 239000007924 injection Substances 0.000 claims description 3
- 230000001404 mediated effect Effects 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 2
- -1 Formic acid dioctyl ester Chemical class 0.000 claims 1
- 235000019253 formic acid Nutrition 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 2
- 210000003205 muscle Anatomy 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 238000003483 aging Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
本发明涉及一种注射成型闪彩鞋材及其制作方法,组分及其重量份数为:PVC透明树脂100份,邻苯二甲酸二丁酯25~30份,邻苯二甲酸二辛酯25~30份,PVC热稳定剂4~8份,金葱片1~2份,PVC发泡剂0.5~0.8份;经混料包裹、塑化、成型冷却制成。具有有效提高鞋材使用寿命、美观大方的优点。
Description
技术领域
本发明涉及一种工艺改进的鞋材及其制作方法,具体地说,是涉及一种注射成型闪彩鞋材及其制作方法。
背景技术
现有鞋材一般是由塑料制成,在比较差的使用环境使用或者正常使用一段时间后,存在老化折断、断裂的隐患,而且,其色彩比较单调,外观比较呆板,不能满足消费者越来越高的审美需求。
发明内容
本发明的目的是针对上述存在问题,提供一种有效提高鞋材使用寿命、美观大方的注射成型闪彩鞋材及其制作方法。
本发明,一种注射成型闪彩鞋材,闪彩注射成型鞋材的组分及其重量份数为:PVC透明树脂100份,邻苯二甲酸二丁酯25~30份,邻苯二甲酸二辛酯25~30份,PVC热稳定剂4~8份,金葱片1~2份,PVC发泡剂0.5~0.8份。
本发明,每100份PVC透明树脂可加入色粉0.5~1份。
本发明,金葱片层的金葱片为正六边形,金葱片颗粒的大小为0.5~3mm。
本发明,一种注射成型闪彩鞋材的制作方法,包括以下步骤:
(1)备料:按比例称取100份PVC透明树脂、25~30份邻苯二甲酸二丁酯、25~30份邻苯二甲酸二辛酯、4~8份PVC热稳定剂、1~2份金葱片、0.5~0.8份PVC发泡剂备用;
(2)混料包裹:将上述PVC透明树脂、邻苯二甲酸二丁酯、邻苯二甲酸二辛酯、PVC热稳定剂、金葱片、PVC发泡剂混合搅拌均匀,在温度80~90℃下捏合90~110min,得到PVC透明树脂对金葱片均匀包裹的混匀物料;
(3)塑化:将螺杆机升温至168~180℃后,将步骤(2)得到的混匀物料投入螺杆机的料斗中进行塑化,得到具有均匀微小气泡及金葱片颗粒的塑化料;
(4)成型冷却:将步骤(3)得到的塑化料注入模具中成型冷却,得到闪彩鞋材。
本发明,金葱片层的金葱片为正六边形,金葱片颗粒的大小为0.5~3mm,气泡大小为1.5~2.5mm。
与现有技术相比,本发明具有以下有益效果:气泡能降低鞋材局部应力集中,减少鞋材断裂概率,延长鞋材使用寿命,同时,利用气泡的光折射,与金葱片颗粒光折射共同作用,起到鞋材闪彩效果。具有有效提高鞋材使用寿命、美观大方的优点。
具体实施方式
实施例1:一种注射成型闪彩鞋材,闪彩注射成型鞋材的组分及其重量份数为:PVC透明树脂100份,邻苯二甲酸二丁酯30份,邻苯二甲酸二辛酯30份,PVC热稳定剂6份,金葱片1份,PVC发泡剂0.5份;金葱片层的金葱片为正六边形,金葱片颗粒的大小为0.5~3mm。
实施例2:一种注射成型闪彩鞋材的制作方法,包括以下步骤:
(1)备料:按比例称取100份PVC透明树脂、30份邻苯二甲酸二丁酯、30份邻苯二甲酸二辛酯、6份PVC热稳定剂、1份金葱片、0.5份PVC发泡剂备用;
(2)混料包裹:将上述PVC透明树脂、邻苯二甲酸二丁酯、邻苯二甲酸二辛酯、PVC热稳定剂、金葱片、PVC发泡剂混合搅拌均匀,在温度80~90℃下捏合90~110min,得到PVC透明树脂对金葱片均匀包裹的混匀物料;
(3)塑化:将螺杆机升温至168~180℃后,将步骤(2)得到的混匀物料投入螺杆机的料斗中进行塑化,得到具有均匀微小气泡及金葱片颗粒的塑化料;
(4)成型冷却:将步骤(3)得到的塑化料注入模具中成型冷却,得到闪彩鞋材;
金葱片层的金葱片为正六边形,金葱片颗粒的大小为0.5~3mm,气泡大小为1.5~2.5mm。
本发明,稳定剂,可采用市售有机锡MS181稳定剂,稳定剂除在注塑过程起到PVC热稳定剂作用外,还有预防金葱片受热变黑功效,使金葱片在注塑后光亮。
本发明,金葱片,市售,由精亮度极高的不同厚度的电镀膜材料经精密切割而成,材质:PET、PVC、OPP、金属铝质、激光镭射材料;形状:四角形、六角形、长方形等,颜色:金色、银色、七彩色、彩色、幻彩色、珠光色、镭射等供于选择,应用领域:用于圣诞工艺品、蜡烛工艺、化妆品、丝网印刷行业、装饰材料、油漆装潢、家具喷漆,包装,圣诞礼品,玩具笔等领域,其特点在于增强产品的视觉效果,使装饰部分凹凸有层次,更具立体感。
本发明,发泡剂,一般可采用碳酸氢钠,白色粉末,比重2.16,分解温度约为100~140℃,并放出部分CO2,到270℃时失出全部CO2。
Claims (2)
1.一种注射成型闪彩鞋材的制作方法,其特征在于,包括以下步骤:
(1)备料:按比例称取100份PVC透明树脂、25~30份邻苯二甲酸二丁酯、25~30份邻苯二甲酸二辛酯、4~8份PVC热稳定剂、1~2份金葱片、0.5~0.8份PVC发泡剂备用;
(2)混料包裹:将上述PVC透明树脂、邻苯二甲酸二丁酯、邻苯二甲酸二辛酯、PVC热稳定剂、金葱片、PVC发泡剂混合搅拌均匀,在温度80~90℃下捏合90~110min,得到PVC透明树脂对金葱片均匀包裹的混匀物料;
(3)塑化:将螺杆机升温至168~180℃后,将步骤(2)得到的混匀物料投入螺杆机的料斗中进行塑化,得到具有均匀大小为1.5~2.5mm的气泡及金葱片颗粒的塑化料;
(4)成型冷却:将步骤(3)得到的塑化料注入模具中成型冷却,得到闪彩鞋材。
2.根据权利要求1所述的注射成型闪彩鞋材的制作方法,其特征在于:所述金葱片为正六边形,金葱片颗粒的大小为0.5~3mm。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610199430.XA CN105754257B (zh) | 2016-04-03 | 2016-04-03 | 一种注射成型闪彩鞋材及其制作方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610199430.XA CN105754257B (zh) | 2016-04-03 | 2016-04-03 | 一种注射成型闪彩鞋材及其制作方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105754257A CN105754257A (zh) | 2016-07-13 |
CN105754257B true CN105754257B (zh) | 2018-07-17 |
Family
ID=56346014
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610199430.XA Expired - Fee Related CN105754257B (zh) | 2016-04-03 | 2016-04-03 | 一种注射成型闪彩鞋材及其制作方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105754257B (zh) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1063116A (zh) * | 1992-01-10 | 1992-07-29 | 邵长青 | 聚氯乙烯(pvc)仿牛筋粉料 |
CN1600803A (zh) * | 2003-09-24 | 2005-03-30 | 贾连萍 | 一种旅游保健鞋的配方及制备方法 |
CN103483736A (zh) * | 2013-09-24 | 2014-01-01 | 吴江市董鑫塑料包装厂 | 一种软质pvc发泡鞋底塑料 |
CN103819846A (zh) * | 2014-02-26 | 2014-05-28 | 东阳市通达塑胶有限公司 | 一种汽车pvc地板配方及采用该配方的地板加工工艺 |
CN104044240A (zh) * | 2014-06-20 | 2014-09-17 | 广东溢达纺织有限公司 | 注塑绳头及其制备方法 |
CN104817829A (zh) * | 2015-04-30 | 2015-08-05 | 广东金榜塑料包装有限公司 | 一种用于包装的pet透明闪光片材及其制备方法 |
-
2016
- 2016-04-03 CN CN201610199430.XA patent/CN105754257B/zh not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1063116A (zh) * | 1992-01-10 | 1992-07-29 | 邵长青 | 聚氯乙烯(pvc)仿牛筋粉料 |
CN1600803A (zh) * | 2003-09-24 | 2005-03-30 | 贾连萍 | 一种旅游保健鞋的配方及制备方法 |
CN103483736A (zh) * | 2013-09-24 | 2014-01-01 | 吴江市董鑫塑料包装厂 | 一种软质pvc发泡鞋底塑料 |
CN103819846A (zh) * | 2014-02-26 | 2014-05-28 | 东阳市通达塑胶有限公司 | 一种汽车pvc地板配方及采用该配方的地板加工工艺 |
CN104044240A (zh) * | 2014-06-20 | 2014-09-17 | 广东溢达纺织有限公司 | 注塑绳头及其制备方法 |
CN104817829A (zh) * | 2015-04-30 | 2015-08-05 | 广东金榜塑料包装有限公司 | 一种用于包装的pet透明闪光片材及其制备方法 |
Non-Patent Citations (1)
Title |
---|
聚氯乙烯发泡双色拖鞋注射工艺;孙秀云;《塑料科技》;19881231(第2期);第12-14页,第51页 * |
Also Published As
Publication number | Publication date |
---|---|
CN105754257A (zh) | 2016-07-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6752941B2 (en) | Additives for special effect appearances in plastic parts | |
CN104031344A (zh) | 一种仿木纹pvc木塑装饰型材及其制备方法 | |
CN101497726B (zh) | 非木质复合环保装饰材料及其制备方法 | |
CN105907321B (zh) | 一种凹凸模内吸塑pvc贴标及其制备方法 | |
CN109135061B (zh) | 一种仿大理石纹牙刷柄及其制备方法 | |
CN107629317B (zh) | 一种仿木纹色母、聚乙烯复合材料及其制备方法 | |
CN106905494B (zh) | 树脂促塑化剂及其制备和应用其制造木塑装饰材料的方法 | |
CN102604254A (zh) | 双层pvc复合材料及其制备方法 | |
CN105754257B (zh) | 一种注射成型闪彩鞋材及其制作方法 | |
CN101177531A (zh) | 一种彩色油泥及制备方法 | |
CN106046616A (zh) | 一种仿木楼梯扶手材料及其制备方法 | |
CN107011639A (zh) | 一种铜掺杂塑料抗菌母粒 | |
CN108329576A (zh) | 一种用于注塑水口料的防潮母粒及其制备方法 | |
US20130227881A1 (en) | Recycled plastic composite composition | |
CN102514143B (zh) | 木塑制品的制造方法 | |
CN105235108A (zh) | 一种新型迷彩橡胶大底的硫化成型工艺 | |
CN110206265A (zh) | 一种户外防虫,耐老化木塑地板及加工方法 | |
CN104002415A (zh) | 一种温变玩具的生产工艺及其生产玩具用的材料的生产方法 | |
CN103030338A (zh) | 一种盐雕原料及采用该原料生产盐雕的方法 | |
CN104842494A (zh) | 注塑工艺中随机形成仿木纹疤节装饰的方法 | |
JP2002309096A (ja) | コルク砕粒組成物及びコルク砕粒成型物 | |
KR20100039798A (ko) | 고광택 컬러 플라스틱 사출물 제조방법 및 그 사출물 | |
CN105907320B (zh) | 一种凹凸模内吸塑pet贴标及其制备方法 | |
CN107880443A (zh) | 一种塑胶模型及制备方法 | |
CN105907319A (zh) | 一种凹凸模内吸塑贴标及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180717 |