CN105753080A - 一种金属基水处理材料及其制备方法 - Google Patents
一种金属基水处理材料及其制备方法 Download PDFInfo
- Publication number
- CN105753080A CN105753080A CN201610295255.4A CN201610295255A CN105753080A CN 105753080 A CN105753080 A CN 105753080A CN 201610295255 A CN201610295255 A CN 201610295255A CN 105753080 A CN105753080 A CN 105753080A
- Authority
- CN
- China
- Prior art keywords
- water treatment
- water
- metal substrate
- substrate material
- graphite oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 239000000463 material Substances 0.000 title claims abstract description 42
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 35
- 239000002184 metal Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 126
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 60
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 41
- 239000010439 graphite Substances 0.000 claims abstract description 41
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 25
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims abstract description 21
- QAQJMLQRFWZOBN-LAUBAEHRSA-N L-ascorbyl-6-palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](O)[C@H]1OC(=O)C(O)=C1O QAQJMLQRFWZOBN-LAUBAEHRSA-N 0.000 claims abstract description 21
- 239000011786 L-ascorbyl-6-palmitate Substances 0.000 claims abstract description 21
- 238000002156 mixing Methods 0.000 claims abstract description 21
- 235000010241 potassium sorbate Nutrition 0.000 claims abstract description 21
- 239000004302 potassium sorbate Substances 0.000 claims abstract description 21
- 229940069338 potassium sorbate Drugs 0.000 claims abstract description 21
- 238000003756 stirring Methods 0.000 claims abstract description 20
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims abstract description 12
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims abstract description 12
- 230000010355 oscillation Effects 0.000 claims abstract description 12
- 239000012153 distilled water Substances 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 10
- 238000001291 vacuum drying Methods 0.000 claims abstract description 10
- 235000015165 citric acid Nutrition 0.000 claims abstract description 9
- 239000000758 substrate Substances 0.000 claims description 30
- 239000002253 acid Substances 0.000 claims description 24
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 20
- 235000010385 ascorbyl palmitate Nutrition 0.000 claims description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 19
- 229910052708 sodium Inorganic materials 0.000 claims description 19
- 239000011734 sodium Substances 0.000 claims description 19
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 19
- QGXJTDHPWUQRFT-UHFFFAOYSA-N 2-methyl-3H-furan-2-carboxylic acid Chemical compound CC1(OC=CC1)C(=O)O QGXJTDHPWUQRFT-UHFFFAOYSA-N 0.000 claims description 11
- 235000011187 glycerol Nutrition 0.000 claims description 11
- 239000004615 ingredient Substances 0.000 claims description 9
- 238000002604 ultrasonography Methods 0.000 claims description 9
- 235000015424 sodium Nutrition 0.000 claims description 8
- 230000015556 catabolic process Effects 0.000 abstract description 4
- 238000006731 degradation reaction Methods 0.000 abstract description 4
- 238000001179 sorption measurement Methods 0.000 abstract description 4
- 230000000593 degrading effect Effects 0.000 abstract description 2
- HFZWRUODUSTPEG-UHFFFAOYSA-N 2,4-dichlorophenol Chemical compound OC1=CC=C(Cl)C=C1Cl HFZWRUODUSTPEG-UHFFFAOYSA-N 0.000 abstract 1
- 235000000072 L-ascorbyl-6-palmitate Nutrition 0.000 abstract 1
- HDJLSECJEQSPKW-UHFFFAOYSA-N Methyl 2-Furancarboxylate Chemical compound COC(=O)C1=CC=CO1 HDJLSECJEQSPKW-UHFFFAOYSA-N 0.000 abstract 1
- 239000004288 Sodium dehydroacetate Substances 0.000 abstract 1
- 229960004106 citric acid Drugs 0.000 abstract 1
- 229960002089 ferrous chloride Drugs 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 229910021389 graphene Inorganic materials 0.000 abstract 1
- 238000009775 high-speed stirring Methods 0.000 abstract 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 abstract 1
- 150000001455 metallic ions Chemical class 0.000 abstract 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract 1
- 229940079839 sodium dehydroacetate Drugs 0.000 abstract 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 abstract 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000000598 endocrine disruptor Substances 0.000 description 2
- 231100000049 endocrine disruptor Toxicity 0.000 description 2
- 230000001473 noxious effect Effects 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 206010058314 Dysplasia Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
- C02F2101/345—Phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Water Treatment By Sorption (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610295255.4A CN105753080B (zh) | 2016-05-06 | 2016-05-06 | 一种金属基水处理材料及其制备方法 |
Applications Claiming Priority (1)
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CN201610295255.4A CN105753080B (zh) | 2016-05-06 | 2016-05-06 | 一种金属基水处理材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105753080A true CN105753080A (zh) | 2016-07-13 |
CN105753080B CN105753080B (zh) | 2018-12-04 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201610295255.4A Active CN105753080B (zh) | 2016-05-06 | 2016-05-06 | 一种金属基水处理材料及其制备方法 |
Country Status (1)
Country | Link |
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CN (1) | CN105753080B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107902857A (zh) * | 2017-12-14 | 2018-04-13 | 张亚欣 | 一种处理重金属的污泥稳定剂及其制备方法和应用 |
CN109940169A (zh) * | 2019-04-19 | 2019-06-28 | 陕西科技大学 | 一种纳米铜及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20110119164A (ko) * | 2010-04-26 | 2011-11-02 | 포항공과대학교 산학협력단 | 그라펜 및 산화철을 포함하는 혼성체, 이를 제조하는 방법 및 이를 이용한 폐수처리장치 |
US20130099153A1 (en) * | 2011-10-23 | 2013-04-25 | Postech Academy-Industry Foundation | Hybrid material comprising graphene and iron oxide, method for manufacturing the same, and apparatus for treating waste water using the same |
CN103241829A (zh) * | 2013-05-20 | 2013-08-14 | 南通市争妍颜料化工有限公司 | 石墨烯量子点/四氧化三铁复合物催化降解酚类废水的方法 |
CN104667869A (zh) * | 2015-02-11 | 2015-06-03 | 四川大学 | 一种利用单过硫酸盐及负载钴铁双相复合氧化石墨烯去除水中内分泌干扰物的方法 |
CN105457597A (zh) * | 2015-12-08 | 2016-04-06 | 华南理工大学 | 一种石墨烯/二氧化硅/纳米零价铁复合材料及其制备方法与应用 |
-
2016
- 2016-05-06 CN CN201610295255.4A patent/CN105753080B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20110119164A (ko) * | 2010-04-26 | 2011-11-02 | 포항공과대학교 산학협력단 | 그라펜 및 산화철을 포함하는 혼성체, 이를 제조하는 방법 및 이를 이용한 폐수처리장치 |
US20130099153A1 (en) * | 2011-10-23 | 2013-04-25 | Postech Academy-Industry Foundation | Hybrid material comprising graphene and iron oxide, method for manufacturing the same, and apparatus for treating waste water using the same |
CN103241829A (zh) * | 2013-05-20 | 2013-08-14 | 南通市争妍颜料化工有限公司 | 石墨烯量子点/四氧化三铁复合物催化降解酚类废水的方法 |
CN104667869A (zh) * | 2015-02-11 | 2015-06-03 | 四川大学 | 一种利用单过硫酸盐及负载钴铁双相复合氧化石墨烯去除水中内分泌干扰物的方法 |
CN105457597A (zh) * | 2015-12-08 | 2016-04-06 | 华南理工大学 | 一种石墨烯/二氧化硅/纳米零价铁复合材料及其制备方法与应用 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107902857A (zh) * | 2017-12-14 | 2018-04-13 | 张亚欣 | 一种处理重金属的污泥稳定剂及其制备方法和应用 |
CN109940169A (zh) * | 2019-04-19 | 2019-06-28 | 陕西科技大学 | 一种纳米铜及其制备方法 |
Also Published As
Publication number | Publication date |
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CN105753080B (zh) | 2018-12-04 |
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Effective date of registration: 20181025 Address after: 312513 Zhejiang province Shaoxing city Xinchang County South Township Shi Xi Village Applicant after: XINCHANG COUNTY YILIN ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Address before: 215000 Xiaoshi Lane 22, Canglang District, Suzhou, Jiangsu 3, 503 room. Applicant before: Chen Chang |
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Effective date of registration: 20191129 Address after: 314200 No.168 Hongxia Road, Danghu street, Pinghu City, Jiaxing City, Zhejiang Province Patentee after: Pinghu JINDA waste renewable fuel industry Co.,Ltd. Address before: 312513 Shixi Village, Nanxiang, Xinchang County, Shaoxing City, Zhejiang Province Patentee before: XINCHANG COUNTY YILIN ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. |
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Denomination of invention: A metal-based water treatment material and its preparation method Effective date of registration: 20230109 Granted publication date: 20181204 Pledgee: Danghu Branch of Zhejiang Pinghu Rural Commercial Bank Co.,Ltd. Pledgor: Pinghu JINDA waste renewable fuel industry Co.,Ltd. Registration number: Y2023330000075 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20181204 Pledgee: Danghu Branch of Zhejiang Pinghu Rural Commercial Bank Co.,Ltd. Pledgor: Pinghu JINDA waste renewable fuel industry Co.,Ltd. Registration number: Y2023330000075 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A metal based water treatment material and its preparation method Granted publication date: 20181204 Pledgee: Danghu Branch of Zhejiang Pinghu Rural Commercial Bank Co.,Ltd. Pledgor: Pinghu JINDA waste renewable fuel industry Co.,Ltd. Registration number: Y2024980014805 |