CN105750032B - A kind of cement ball mill wear-resistant liner and its manufacturing method - Google Patents

A kind of cement ball mill wear-resistant liner and its manufacturing method Download PDF

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Publication number
CN105750032B
CN105750032B CN201610199238.0A CN201610199238A CN105750032B CN 105750032 B CN105750032 B CN 105750032B CN 201610199238 A CN201610199238 A CN 201610199238A CN 105750032 B CN105750032 B CN 105750032B
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China
Prior art keywords
wear
resistant coating
base material
resistant
tungsten carbide
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Expired - Fee Related
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CN201610199238.0A
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CN105750032A (en
Inventor
周俊华
尹方勇
王峰
王征
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Shandong Tohelm Grinding Wear-Resistant Technology Development Co Ltd
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Shandong Tohelm Grinding Wear-Resistant Technology Development Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C17/00Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls
    • B02C17/18Details
    • B02C17/22Lining for containers
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Crushing And Grinding (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention discloses a kind of cement ball mill wear-resistant liner, wherein, liner plate base material working face undulate or concave-convex latticed;Substrate surface is coated with wear-resistant coating, and the wear-resistant coating is the tungsten carbide system wear-resistant coating coated using supersonic flame spraying, and the tungsten-carbide powder particle grades which uses is WC10 WC100;The base material uses low-carbon steel making.For liner plate face surface hardness obtained in more than 2200HV, wearability is good;Strong shock resistance, and it is at low cost, it is corrosion-resistant;Working loss is low, and adaptability is good, and service life is long, good economy performance;Can assisted machining material, the antiknock ability of coating is strong, conducive to cutting;Coating binding force is good, not easily to fall off;The working efficiency of ball mill can be improved, while makes prepared material high purity.

Description

A kind of cement ball mill wear-resistant liner and its manufacturing method
Technical field
The present invention relates to cement manufacture field more particularly to a kind of cement ball mill wear-resistant liner and its manufacturing methods.
Background technology
Ball mill is the common milling equipment of the industries such as metallurgical ore grinding, cement, power generation.The main function of ball grinding machine lining board is Protection grinding machine and drive abrading-ball are ground and crush to material.The main failure forms of ball grinding machine lining board are that small energy repeatedly rushes Abrasive wear under hitting, according to statistics, the steel that China consumes on ball mill every year reach millions of tons.Therefore how ball milling is improved The wearability of machine liner plate is always the hot spot studied.
It is high strength steel, but its wearability is still poor now to commonly use lining material, and service life is short, since high strength steel is general Poor toughness, liner plate in use easily occur cracking, collapse it is broken so that repair demolition is extremely difficult;And use low-carbon alloy steel Manufacture ball grinding machine lining board, and there are intensity and hardness is low, the deficiency that wears no resistance;In order to improve the obdurability of steel alloy and wear-resisting Property, the alloying elements such as molybdenum, nickel, chromium, tungsten, vanadium will be usually added in, with increasingly in short supply, molybdenum, nickel, chromium, tungsten, the vanadium of alloy resource Alloys supply is waited to be becoming tight day, price rapidly goes up, and causes common steel wear-resistant material production cost constantly soaring;Meanwhile mesh Preceding mainstream liner plate is mostly martensite steel sections, is easily undergone phase transition at 250 DEG C or more, leads to liner plate hydraulic performance decline, therefore be not suitable for For a long time, it works under the operating mode of high intensity.In addition, existing more of liner plate considers intensity, toughness and the corrosion resistance of liner plate in itself etc., The ability of liner plate secondary process material is not accounted for, and material is easily adhered on liner plate;Meanwhile stainless steel it is of high cost and intolerant to Mill, high strength steel is wear-resisting but not corrosion-resistant, easily due to abrasion or corrosion impact working face, while reduces the pure of made material Degree.
In the related patents applied at home, patent《A kind of large-size ball mill liner plate and its casting method》(Application Number:201010294909.4 publication date:2011-01-26), it is excellent to disclose a kind of wear-resisting property, and hardness is high, good toughness, by force The preparation method of high liner plate is spent, a variety of alloying elements such as silicon, chromium, molybdenum, boron, niobium are added into conventional steel liner plate and promote liner plate Wearability and toughness, but the liner plate is not corrosion-resistant;In addition, be still martensite steel sections, non-refractory;Simultaneously as matrix limits System, impact resistance is still poor, and work long hours cracky.Patent《A kind of lining sheet for ball mill of high-wear resistance》(Shen Please number:201410364512.6 publication date:2014-10-29), disclose a kind of lining of essential high-strength stainless steel as base material Plate, and the average tempering technique used, high temperature resistant, but its it is a large amount of employ the alloying elements such as chromium, titanium, raw material smelt it is difficult and It is poor to simultaneously result in the liner plate Castability for costliness, it is impossible to be used in the large-scale liner plate of manufacture, application range is not wide, at the same time, greatly The addition of amount carbon also make the liner plate can not complete austenitizing, corrosion resistance is bad.In addition, above-mentioned two parts of patents only consider liner plate Itself intensity, toughness and corrosion resistance etc. do not account for the ability of liner plate secondary process material, and material is easily adhered to liner plate On.
Invention content
In view of the above defects of the prior art, it is the present invention is intended to provide a kind of wear-resisting, high temperature resistant, corrosion-resistant, resistance to Impact, good economy performance, service life are long, material is not easy to adhere to, can secondary process material and made material high purity cement Ball mill wear-resistant liner.
To achieve these goals, the present invention uses following technical scheme:A kind of cement ball mill wear-resistant liner, including Have the base material of mounting surface and working face, it is characterised in that:The base material working face undulate is concave-convex latticed;The base Material face surface is also coated with wear-resistant coating, and the wear-resistant coating is wear-resisting for the tungsten carbide system coated using supersonic flame spraying Coating.
Above-mentioned cement ball mill wear-resistant liner, wherein:Tungsten carbide system wear-resistant coating be preferably WC-CoCr or WC-Co, contained tungsten carbide powder particle grades are WC10-WC100.
Above-mentioned cement ball mill wear-resistant liner, wherein:The ingredient of tungsten carbide system wear-resistant coating further includes carbonization tantalum powder End, one kind or their compositions in titanium carbide powder;One kind in the tantalum carbide powder, titanium carbide powder or they Composition accounts for the 3-5% of tungsten carbide system wear-resistant coating gross mass altogether by mass percentage.
Above-mentioned cement ball mill wear-resistant liner, wherein:The base material uses low-carbon steel making, and the mild steel includes Carbon steel of the carbon content less than 0.25% and carbon content are less than 0.25% steel alloy.
The manufacturing method of the cement ball mill wear-resistant liner of above-mentioned water, includes the following steps:
(1) steel alloy of carbon steel of the carbon content less than 0.25% and carbon content less than 0.25% is selected as low-carbon base steel Material;
(2) low-carbon steel substrate is processed as to the size needed;
(3) base material working face is processed as to the shape needed, as waveform or bumps are latticed or stepped;
(4) raw material of configuration tungsten carbide system wear-resistant coating:Tungsten carbide powder WC-CoCr or WC-Co are selected, ensures its particle etc. Grade is WC10-WC100;
(5) using supersonic flame spraying technique, combustion flame speed >=2100m/s send the raw material powder that step (3) is configured Enter and fire flame, generate the particle of fusing or semi-molten, high-speed impact forms wear-resistant coating on base material face surface.
The manufacturing method of above-mentioned cement ball mill wear-resistant liner in step (3) in addition to tungsten carbide powder is selected, is also pressed The 3-5% incorporations tantalum carbide powder of tungsten carbide system wear-resistant coating gross mass, one kind or their compositions in titanium carbide powder, It is uniformly mixed.
Compared with the prior art, the present invention is as a result of said program, and liner plate working face wearability obtained is high, table Surface hardness is in more than 2200HV, far above the hardness of conventional High Intensity steel 700HV or so;Mild steel strong shock resistance, and into This is low, although itself is not wear-resisting anti-corrosion, since working face is coated with wear-resisting, anti-corrosion tungsten carbide coating, solves its work Make face wear-and corrosion-resistant problem, mounting surface is bonded with shell, not perishable, even if having slight erosion nor affect on its working performance and The degree of purity of made material;Tungsten carbide material high abrasion resistance, have concurrently shock resistance, good toughness mild steel as base material, work It is lost low, adaptability is good, and service life is long, good economy performance;Base material working face is wavy or textured, coated in its surface Also similary form thus is presented in coating, can assisted machining material, preferred coating composition further increases the antiknock ability of coating, profit In cutting cement granules;Meanwhile tungsten carbide coating is coated in the good surface of low-carbon steel of affinity, knot using supersonic flame spraying Good with joint efforts, not easily to fall off, furthermore tungsten carbide cutting power is strong, wearability is good, can greatly improve the working efficiency of ball mill, together When make prepared material high purity.
Description of the drawings
Fig. 1 is the partial schematic diagram of the waveform working face of base material of the present invention;
Fig. 2 is the partial schematic diagram of the stepped working face of base material of the present invention;
Fig. 3 is the partial schematic diagram of the latticed working face of bumps of base material of the present invention.
Specific embodiment
Embodiment 1:
A kind of cement ball mill wear-resistant liner, including having the base material of mounting surface and working face and coated in substrate surface Wear-resistant coating, wherein:The base material working face undulate;The wear-resistant coating is what is coated using supersonic flame spraying The WC-Co coatings of 3% tantalum carbide powder are added to, the powder particle grade which uses is WC10;The base material uses 10# Steel making.Its manufacturing method includes the following steps:
(1) 10 are selected#Steel is as low-carbon steel substrate;
(2) low-carbon steel substrate is processed as to the size needed;
(3) base material working face is processed as waveform;
(4) raw material of configuration tungsten carbide system wear-resistant coating:Tungsten carbide powder WC-Co is selected, it is WC10 to ensure its particle grades; And it by 3% incorporation tantalum carbide powder of tungsten carbide system wear-resistant coating gross mass, is uniformly mixed;
(5) using supersonic flame spraying technique, combustion flame speed >=2100m/s send the raw material powder that step (3) is configured Enter and fire flame, generate the particle of fusing or semi-molten, high-speed impact forms wear-resistant coating on base material face surface.
Wherein, the method for supersonic flame spraying, the method for liner plate installation are the prior art, are repeated no more, similarly hereinafter.
Embodiment 2:
A kind of cement ball mill wear-resistant liner, including having the base material of mounting surface and working face and coated in substrate surface Wear-resistant coating, wherein:The base material working face is in concave-convex latticed;The wear-resistant coating is applies using supersonic flame spraying What is covered is added to the WC-CoCr coatings of 5% titanium carbide powder, and the powder particle grade which uses is WC100;The base material Using 20Cr steel makings.Its manufacturing method includes the following steps:
(1) 20Cr steel is selected as low-carbon steel substrate;
(2) low-carbon steel substrate is processed as to the size needed;
(3) base material working face is processed as concave-convex latticed;
(4) raw material of configuration tungsten carbide system wear-resistant coating:Tungsten carbide powder WC-CoCr is selected, ensures that its particle grades is WC100;
(5) using supersonic flame spraying technique, combustion flame speed >=2100m/s send the raw material powder that step (3) is configured Enter and fire flame, generate the particle of fusing or semi-molten, high-speed impact forms wear-resistant coating on base material face surface.
Embodiment 3:
A kind of cement ball mill wear-resistant liner, including having the base material of mounting surface and working face and coated in substrate surface Wear-resistant coating, wherein:The base material working face undulate;The wear-resistant coating is what is coated using supersonic flame spraying The WC-CoCr coatings of 2% titanium carbide powder and 2% tantalum carbide powder are added to, the powder particle grade which uses is WC20; The base material uses 20Cr steel makings.
Its manufacturing method includes the following steps:
(1) 20Cr steel is selected as low-carbon steel substrate;
(2) low-carbon steel substrate is processed as to the size needed;
(3) base material working face is processed as waveform;
(4) raw material of configuration tungsten carbide system wear-resistant coating:Tungsten carbide powder WC-CoCr is selected, ensures that its particle grades is WC20;And it is uniformly mixed respectively by the 2% addition titanium carbide powder and tantalum carbide powder of tungsten carbide system wear-resistant coating gross mass;
(5) using supersonic flame spraying technique, combustion flame speed >=2100m/s send the raw material powder that step (3) is configured Enter and fire flame, generate the particle of fusing or semi-molten, high-speed impact forms wear-resistant coating on base material face surface.
Embodiment 4:
A kind of cement ball mill wear-resistant liner, including having the base material of mounting surface and working face and coated in substrate surface Wear-resistant coating, wherein:The base material working face is in concave-convex latticed or stepped;The wear-resistant coating is using supersonic speed fire The WC-CoCr coatings of flame spray coating, the powder particle grade which uses is WC100;The base material uses 20Cr steels It makes.Its manufacturing method includes the following steps:
(1) 20Cr steel is selected as low-carbon steel substrate;
(2) low-carbon steel substrate is processed as to the size needed;
(3) base material working face is processed as concave-convex latticed or stepped;
(4) raw material of configuration tungsten carbide system wear-resistant coating:Tungsten carbide powder WC-CoCr is selected, ensures that its particle grades is WC100;
(5) using supersonic flame spraying technique, combustion flame speed >=2100m/s send the raw material powder that step (3) is configured Enter and fire flame, generate the particle of fusing or semi-molten, high-speed impact forms wear-resistant coating on base material face surface.
Embodiment 5:
A kind of cement ball mill wear-resistant liner, including having the base material of mounting surface and working face and coated in substrate surface Wear-resistant coating, wherein:The base material working face undulate or stepped;The wear-resistant coating is sprays using supersonic flame The WC-Co coatings of coating, the powder particle grade which uses is WC10;The base material uses 25#Steel making.It is manufactured Method includes the following steps:
(1) 25 are selected#Steel is as low-carbon steel substrate;
(2) low-carbon steel substrate is processed as to the size needed;
(3) base material working face is processed as waveform or stepped;
(4) raw material of configuration tungsten carbide system wear-resistant coating:Tungsten carbide powder WC-Co is selected, it is WC10 to ensure its particle grades;
(5) using supersonic flame spraying technique, combustion flame speed >=2100m/s send the raw material powder that step (3) is configured Enter and fire flame, generate the particle of fusing or semi-molten, high-speed impact forms wear-resistant coating on base material face surface.
The foregoing description of the disclosed embodiments, only for professional and technical personnel in the field is enable to realize or use this Invention.A variety of modifications of these embodiments will be apparent for those skilled in the art, institute herein The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, The present invention is not intended to be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty The consistent most wide range of point.

Claims (2)

1. a kind of cement ball mill wear-resistant liner, including base material, the base material includes mounting surface and working face, and feature exists In:The base material working face undulate is concave-convex latticed;Substrate surface is coated with wear-resistant coating, and the wear-resistant coating is adopts The tungsten carbide system wear-resistant coating coated with supersonic flame spraying;The ingredient of tungsten carbide system wear-resistant coating further includes carbonization tantalum powder End;The tantalum carbide powder accounts for the 3-5% of tungsten carbide system wear-resistant coating gross mass altogether by mass percentage;The base material uses Low-carbon steel making, the mild steel include the steel alloy of carbon steel of the carbon content less than 0.25% and carbon content less than 0.25%.
2. cement ball mill wear-resistant liner according to claim 1, it is characterised in that:Tungsten carbide system wear-resistant coating For WC-CoCr or WC-Co, contained tungsten carbide powder particle grades are WC10-WC100.
CN201610199238.0A 2016-04-02 2016-04-02 A kind of cement ball mill wear-resistant liner and its manufacturing method Expired - Fee Related CN105750032B (en)

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CN109127101A (en) * 2018-08-09 2019-01-04 北京天山新材料技术有限公司 The means of defence and coal pulverizer of coal pulverizer
CN109808214A (en) * 2019-02-18 2019-05-28 北京固本科技有限公司 A kind of wear-resisting squeezing item
CN110404638B (en) * 2019-08-29 2021-04-20 盐城工学院 Ball mill lining plate structure suitable for superfine ball milling
CN110512164A (en) * 2019-09-06 2019-11-29 武汉苏伯曼科技有限公司 Improve the method and mineral fine powder steam dryer of the anti-wear abrasive capacity of thermally conductive coil pipe in mineral fine powder steam dryer
CN115740462A (en) * 2022-09-28 2023-03-07 铜陵有色金属集团股份有限公司 Ball mill lining plate with high wear resistance and preparation process thereof

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JPH04158866A (en) * 1990-10-23 1992-06-01 Masaru Ogiwara Heat treating machine for sterilization of industrial waste
CN2517488Y (en) * 2001-06-25 2002-10-23 姚雷雨 Hard surface durable element made of Ti carbide
CN201603585U (en) * 2010-01-08 2010-10-13 三河市科大博德粉末有限公司 Ball mill lining plate with wear resistance coating layer
CN105063539B (en) * 2015-07-20 2018-04-13 安徽工程大学 A kind of preparation method of ball grinding machine lining board wear-resistant coating
CN105289805A (en) * 2015-10-30 2016-02-03 姜殿付 Ball grinding mill

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