CN105746570A - Insecticidal composition containing spirocyclic tetronic acid compound and transfluthrin - Google Patents
Insecticidal composition containing spirocyclic tetronic acid compound and transfluthrin Download PDFInfo
- Publication number
- CN105746570A CN105746570A CN201610195518.4A CN201610195518A CN105746570A CN 105746570 A CN105746570 A CN 105746570A CN 201610195518 A CN201610195518 A CN 201610195518A CN 105746570 A CN105746570 A CN 105746570A
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- CN
- China
- Prior art keywords
- transfluthrin
- tetronic acid
- acid compounds
- spirocyclic tetronic
- pesticidal combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides an insecticidal composition containing a spirocyclic tetronic acid compound and transfluthrin.The insecticidal composition is characterized in that active ingredients in the insecticidal composition comprise the spirocyclic tetronic acid compound and transfluthrin, and the weight ratio of the spirocyclic tetronic acid compound to transfluthrin is 50:1 to 1:50.The two effective ingredients of the insecticidal composition are combined for use, an insecticidal spectrum is widened, a multi-pest treatment effect is achieved, generation of resistance of pests is delayed, an insecticidal effect is remarkable, and diseases and pests of crops can be effectively prevented and treated.In addition, compared with a spirocyclic tetronic acid compound single agent and a transfluthrin single agent, production and use cost is reduced, and pesticide use cost is reduced for farmers.
Description
Technical field
The present invention relates to agrochemical field, particularly to one containing spirocyclic tetronic acid compounds and four
The Pesticidal combination of fluorobenzene chrysanthemum ester.
Background technology
The resistance problem of agricultural pests is a global problem, and always agricultural science and technology worker is closed
The emphasis problem of note.Continuity year in year out, the increasing of Pesticide use amount along with Chemical Control of Harmful Insects
Adding and not scientifical use pesticide, pest resistance is day by day serious, and the pest species producing resistance constantly increases
Many.
Tetronic acid is present in multiple natural goods in a large number, has a lot of particularly biological medicine activity, its
In, tetronic acid derivatives also has antibacterial, antiviral, Insecticiding-miticiding, weeding and plant growth regulating
Isoreactivity.In recent years, spirocyclic tetronic acid compounds is due to its novel structure, high-efficiency low-toxicity, nothing friendship
The advantages such as fork drug dependence, it has also become one of hot fields of current pesticides discovery research.Spirocyclic tetronic acid
The Insecticiding-miticiding machine matter of compounds is totally different from existing various insecticidal/acaricidal agent, is by suppression
Insect or evil demodicid mite body in lipid synthesis, destroy acarid energy metabolism activity, finally kill off the insect pests or
Evil demodicid mite.
Transfluthrin, is a kind of important insecticide, belongs to broad spectrum pesticide, has efficient, low
Poison, the feature of low-residual, can effectively prevent and treat sanitary insect pest and store pest, have dipteral insect
Quickly knockdown effect.
Insecticide variety containing single component often existing defects in pesticide Pest control: use continuously
Easily developing immunity to drugs, insecticidal spectrum is narrow, it is impossible to for as providing comprehensively protection, peasant's drug cost
High.Above-mentioned lacking can be overcome to a certain extent by the combination of two or more various active component
Point.There is the combination mixture of two or more active component of potentiation, preventive effect can be improved,
Reduce effective ingredient ground consumption, save peasant's drug cost, slow down pest resistance and occur, and can expand
Preventing and treating spectrum, plays the double effect controlled of many worms.
Summary of the invention
For solving the problem of above-mentioned existence, it is an object of the invention to provide a kind of class Han spirocyclic tetronic acid
Compound and the Pesticidal combination of transfluthrin.Described Pesticidal combination, two kinds of combination of active principles
Use, expand insecticidal spectrum, play the double effect controlled of many worms, slow down pest resistance and occur, and parasite killing
Effect is notable, it is possible to effectively prevent and treat diseases and pests of agronomic crop;Additionally, with spirocyclic tetronic acid compounds and
Transfluthrin single dose is compared, and produces and use cost reduces, save peasant's drug cost.
For reaching above-mentioned purpose, the technical scheme is that
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, described parasite killing group
Active component in compound is spirocyclic tetronic acid compounds and transfluthrin, described spirocyclic tetronic acid
The weight ratio of compounds and transfluthrin is 50:1-1:50.
Further, the weight ratio of described spirocyclic tetronic acid compounds and transfluthrin is
30:1-1:30。
Further, the weight ratio of described spirocyclic tetronic acid compounds and transfluthrin is 18:1.
And have, described Pesticidal combination is possibly together with dispersant, stabilizer, solvent, emulsifying agent, thickening
One or more in agent.
Separately, altogether to account for described Pesticidal combination total for described spirocyclic tetronic acid compounds and transfluthrin
The 20%-60% of weight.
Further, described spirocyclic tetronic acid compounds and transfluthrin account for described parasite killing group altogether
The 35%-50% of compound gross weight.
Meanwhile, described Pesticidal combination is applied to aphid in agricultural production, mythimna separata, black bean aphid, rice fly
The preventing and treating of louse, cotten aphid and bollworm.
The beneficial effects of the present invention is:
(1) a kind of parasite killing group containing spirocyclic tetronic acid compounds and transfluthrin that the present invention provides
Compound, two kinds of combination of active principles use, and expand insecticidal spectrum, play the double effect controlled of many worms, subtract
Slow pest resistance occurs, and insecticidal effect is notable, it is possible to effectively prevent and treat diseases and pests of agronomic crop;
(2) a kind of parasite killing group containing spirocyclic tetronic acid compounds and transfluthrin that the present invention provides
Compound, compared with spirocyclic tetronic acid compounds and transfluthrin single dose, produces and use cost drops
Low, save peasant's drug cost.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with enforcement
Example further describes.
Embodiment 1
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, described Insecticidal combinations
Active component in thing is spirocyclic tetronic acid compounds and transfluthrin, and its content is: volution season ketone
Acid compounds: 20%;Transfluthrin: 0.4%;Pesticidal combination possibly together with dispersant, stabilizer,
Solvent, emulsifying agent, thickening agent.
Embodiment 2
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, described Insecticidal combinations
Active component in thing is spirocyclic tetronic acid compounds and transfluthrin, and its content is: volution season ketone
Acid compounds: 30%;Transfluthrin: 1%;Pesticidal combination is possibly together with dispersant, solvent, breast
Agent, thickening agent.
Embodiment 3
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, described Insecticidal combinations
Active component in thing is spirocyclic tetronic acid compounds and transfluthrin, and its content is: volution season ketone
Acid compounds: 30%;Transfluthrin: 1.5%;Pesticidal combination possibly together with dispersant, stabilizer,
Solvent, thickening agent.
Embodiment 4
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, described Insecticidal combinations
Active component in thing is spirocyclic tetronic acid compounds and transfluthrin, and its content is: volution season ketone
Acid compounds: 40%;Transfluthrin: 2%;Pesticidal combination possibly together with dispersant, stabilizer,
Solvent, emulsifying agent, thickening agent.
Embodiment 5
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, described Insecticidal combinations
Active component in thing is spirocyclic tetronic acid compounds and transfluthrin, and its content is: volution season ketone
Acid compounds: 30%;Transfluthrin: 30%;Pesticidal combination possibly together with dispersant, stabilizer,
Solvent, emulsifying agent, thickening agent.
Embodiment 6
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, described Insecticidal combinations
Active component in thing is spirocyclic tetronic acid compounds and transfluthrin, and its content is: volution season ketone
Acid compounds: 2%;Transfluthrin: 40%;Pesticidal combination possibly together with dispersant, stabilizer,
Solvent, thickening agent.
Embodiment 7
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, described Insecticidal combinations
Active component in thing is spirocyclic tetronic acid compounds and transfluthrin, and its content is: volution season ketone
Acid compounds: 1.5%;Transfluthrin: 30%;Pesticidal combination possibly together with dispersant, solvent,
Emulsifying agent, thickening agent.
Embodiment 8
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, described Insecticidal combinations
Active component in thing is spirocyclic tetronic acid compounds and transfluthrin, and its content is: volution season ketone
Acid compounds: 1%;Transfluthrin: 30%;Pesticidal combination possibly together with dispersant, stabilizer,
Solvent, emulsifying agent, thickening agent.
Embodiment 9
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, described Insecticidal combinations
Active component in thing is spirocyclic tetronic acid compounds and transfluthrin, and its content is: volution season ketone
Acid compounds: 0.4%;Transfluthrin: 20%;Pesticidal combination possibly together with dispersant, stabilizer,
Solvent, emulsifying agent, thickening agent.
In order to the effect of Pesticidal combination in embodiment 1-5 is tested, it is used for killing bollworm, medicine
Effect result of the test is as shown in table 1.
Drug effect calculates as follows:
Table 1: embodiment 1-5 prevents and treats the field control effectiveness test result of bollworm with comparative example 1-2
Wherein: comparative example 1: spirocyclic tetronic acid compounds mu effective ingredient: 15 × 10%=1.5
Gram;Comparative example 2: transfluthrin mu effective ingredient: 60 × 10%=6 gram.
Being found out by table 1 result of the test, described Pesticidal combination, two kinds of combination of active principles use,
Insecticidal effect is notable, compared with spirocyclic tetronic acid compounds and transfluthrin single dose, plays potentiation and makees
With, and produce and use cost reduction, save peasant's drug cost.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted.
Although being described in detail the present invention with reference to preferred embodiment, those of ordinary skill in the art should
Work as understanding, the technical scheme of invention can be modified or equivalent, without deviating from the present invention
The scope of technical scheme, it all should be contained in scope of the presently claimed invention.
Claims (7)
1. one kind contains spirocyclic tetronic acid compounds and the Pesticidal combination of transfluthrin, it is characterized in that, active component in described Pesticidal combination is spirocyclic tetronic acid compounds and transfluthrin, and the weight ratio of described spirocyclic tetronic acid compounds and transfluthrin is 50:1-1:50.
The most according to claim 1 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, it is characterised in that the weight ratio of described spirocyclic tetronic acid compounds and transfluthrin is 30:1-1:30.
The most according to claim 1 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, it is characterised in that the weight ratio of described spirocyclic tetronic acid compounds and transfluthrin is 18:1.
4. according to a kind of according to any one of claim 1-3 containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, it is characterized in that, described Pesticidal combination is possibly together with one or more in dispersant, stabilizer, solvent, surfactant, thickening agent.
The most according to claim 1 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, it is characterised in that described spirocyclic tetronic acid compounds and transfluthrin account for the 20%-60% of described Pesticidal combination gross weight altogether.
The most according to claim 5 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, it is characterised in that described spirocyclic tetronic acid compounds and transfluthrin account for the 35%-50% of described Pesticidal combination gross weight altogether.
The most according to claim 1 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of transfluthrin, it is characterised in that described Pesticidal combination is applied to the preventing and treating of aphid in agricultural production, mythimna separata, black bean aphid, planthopper, cotten aphid and bollworm.
Priority Applications (1)
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CN201610195518.4A CN105746570A (en) | 2016-03-31 | 2016-03-31 | Insecticidal composition containing spirocyclic tetronic acid compound and transfluthrin |
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CN201610195518.4A CN105746570A (en) | 2016-03-31 | 2016-03-31 | Insecticidal composition containing spirocyclic tetronic acid compound and transfluthrin |
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CN201610195518.4A Pending CN105746570A (en) | 2016-03-31 | 2016-03-31 | Insecticidal composition containing spirocyclic tetronic acid compound and transfluthrin |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1400864A (en) * | 2000-02-18 | 2003-03-05 | 拜尔公司 | Active substance combinations comprising insecticidal and acaricidal properties |
CN1635834A (en) * | 2000-03-21 | 2005-07-06 | 拜尔公司 | Combinations of active ingredients with insecticidal and acaricidal properties |
CN101437402A (en) * | 2006-02-24 | 2009-05-20 | 拜尔农作物科学股份公司 | Combination of active ingredients with insecticidal and acaricidal properties |
EP2446742A1 (en) * | 2010-10-28 | 2012-05-02 | Bayer CropScience AG | Insecticide or acaricide compositions containing mono- or disaccharides as activity enhancers |
CN103621548A (en) * | 2012-08-28 | 2014-03-12 | 陕西美邦农药有限公司 | Insect disinfestation composition containing spiromesifen and pyrethroid |
-
2016
- 2016-03-31 CN CN201610195518.4A patent/CN105746570A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1400864A (en) * | 2000-02-18 | 2003-03-05 | 拜尔公司 | Active substance combinations comprising insecticidal and acaricidal properties |
CN1635834A (en) * | 2000-03-21 | 2005-07-06 | 拜尔公司 | Combinations of active ingredients with insecticidal and acaricidal properties |
CN101437402A (en) * | 2006-02-24 | 2009-05-20 | 拜尔农作物科学股份公司 | Combination of active ingredients with insecticidal and acaricidal properties |
EP2446742A1 (en) * | 2010-10-28 | 2012-05-02 | Bayer CropScience AG | Insecticide or acaricide compositions containing mono- or disaccharides as activity enhancers |
CN103621548A (en) * | 2012-08-28 | 2014-03-12 | 陕西美邦农药有限公司 | Insect disinfestation composition containing spiromesifen and pyrethroid |
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Application publication date: 20160713 |