CN105713553A - Silicone sealant for aluminum alloy doors/windows - Google Patents
Silicone sealant for aluminum alloy doors/windows Download PDFInfo
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- CN105713553A CN105713553A CN201610300432.3A CN201610300432A CN105713553A CN 105713553 A CN105713553 A CN 105713553A CN 201610300432 A CN201610300432 A CN 201610300432A CN 105713553 A CN105713553 A CN 105713553A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5398—Phosphorus bound to sulfur
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Sealing Material Composition (AREA)
- Fireproofing Substances (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
The invention relates to a sealing material, particularly a silicone sealant for aluminum alloy doors/windows. The silicone sealant for aluminum alloy doors/windows is prepared from cyclotetrapolydimethylsiloxane, 5-ethoxycarbonyl-4,6-dimethyl-2-pyrone, sodium 4-methyl-2-oxo-valerate, methyltrimethoxy silane, ethyl 3-oxonortropane-8-carboxylate and the like. The silicone sealant for aluminum alloy doors/windows has the advantages of favorable sealing effect and high flame retardancy grade, and can perform favorable flame retardancy in case of a fire disaster. The silicone sealant for aluminum alloy doors/windows has the characteristics of favorable appearance property and long expiration date, and is suitable for popularization and application in the field of the silicone sealants for aluminum alloy doors/windows.
Description
Technical field
The present invention relates to a kind of encapsulant, be specifically related to a kind of aluminum alloy doors and windows silicone sealant.
Background technology
Aluminum alloy doors and windows, referring to use aluminum alloy extrusion section bar is that the door and window that frame, stile, fan material make is referred to as aluminum alloy doors and windows, is called for short aluminium door and window.Aluminum alloy doors and windows include the door and window being combined with timber, plastics making stressed member base material with aluminium alloy, are called for short aluminum wood composite door and window, aluminous plastic compound door & window.According to door and window material and function, substantially can be divided into following a few class: Wood-door window, steel casement door window, revolving door antitheft door, automatically-controlled door, plastic door-window, revolving door, ornamental work of iron door and window, plastic-steel door and window, Door or window made of stainless steel, aluminum alloy doors and windows, glass fiber reinforced plastic door and window etc..Living standards of the people improve constantly, and the kind of door and window and derived product thereof is on the increase, and class gradually rises, such as heat insulation aluminum alloy door window, wood aluminum composite door and window, aluminum wood composite door and window, solid wood door and window, sunlight energy room, glass curtain wall, wooden curtain wall etc..Can be divided into by opening ways: be opened flat, split, push-and-pull, folding, on hang, turn up etc..
Projecting top-hung window this be a kind of aluminium alloy plastic-steel window the most just occurred.It is the new model that developed on the basis of casement window.It has two kinds of opening ways, both can be opened flat, and can push open from top again.When casement window is closed, inwardly drawing the top of window, can open the gap of ten cm, say, that window can be opened from above a bit, the part opened is suspended in the air, is connected with window frame by hinge etc. and fixes, because of referred to herein as top suspension.Its advantage is: both can ventilate, and can ensure that again safety, because there being hinge, window can only open the seam of ten centimetres, and hands can not be stretched from the outside, is particularly suitable in family time nobody using.Function is not only limited to the window being opened flat, and sliding window can also top suspension be opened.
The greatest problem of aluminum alloy doors and windows is that its sealing is poor, and this causes due to distinctive structural system itself.Aluminum alloy doors and windows are widely applied in skyscraper now, the fire of skyscraper have spread fast, evacuating personnel difficulty, feature that difficulty of putting out a fire to save life and property is big, therefore lose the most serious, this just requires breaking out of fire when, silicone sealant to have good fire resistance, but silicone sealant on the market, flame retardant effect is bad, and sealing effectiveness is poor.
Summary of the invention
It is an object of the invention to provide the aluminum alloy doors and windows silicone sealant of a kind of good flame retardation effect and good sealing effect.
A kind of aluminum alloy doors and windows silicone sealant, it is characterized in that the raw material including following weight: ring four polydimethylsiloxane 60-66 part, 5-carbethoxyl group-4,6-dimethyl-2-pyranone 9-15 part, 4-methyl-2-oxo-pentanoic acid sodium salt 18-26 part, MTMS 36-42 part, 3-oxo nor-tropane-8-carboxylic acid, ethyl ester 7-13 part, o-methoxyacetophenone 6-12 part, three tert-butoxy vinyl silanes 20-28 parts, dimethylacetal 19-25 part, 2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate 3-9 part.
Preferably, the aluminum alloy doors and windows silicone sealant prepared including the raw material of following weight has a more preferable effect: ring four polydimethylsiloxane 63 parts, 5-carbethoxyl group-4,6-dimethyl-2-pyranone 9 parts, 4-methyl-2-oxo-pentanoic acid sodium salt 26 parts, MTMS 39 parts, 3-oxo nor-tropane-8-carboxylic acid, ethyl ester 7 parts, o-methoxyacetophenone 12 parts, three tert-butoxy vinyl silanes 24 parts, dimethylacetal 19 parts, 2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate 9 parts.
Further, in order to obtain effect more preferable aluminum alloy doors and windows silicone sealant, described aluminum alloy doors and windows silicone sealant also includes the raw material of following weight: 1,1-diethoxyethane 18-24 part, 6-(4,5-dihydro-3-methyl-5-oxo-1H-pyrazol-1-yl)-1,3-naphthalenedisulfonic acid 11-15 part, 3-methoxybutanol 8-16 part.
Preferably, aluminum alloy doors and windows silicone sealant, its parts by weight of raw materials proportioning is: 1,1-diethoxyethane 21 parts, 6-(4,5-dihydro-3-methyl-5-oxo-1H-pyrazol-1-yl)-1,3-naphthalenedisulfonic acid 11 parts, 3-methoxybutanol 16 parts.
The preparation method of the present invention: by ring four polydimethylsiloxane, 5-carbethoxyl group-4, 6-dimethyl-2-pyranone, 4-methyl-2-oxo-pentanoic acid sodium salt, MTMS adds in planetary mixer, evacuation, vacuum 0.09MPa, rotating speed 35r/min, after stirring 60 minutes, add 3-oxo nor-tropane-8-carboxylic acid, ethyl ester, o-methoxyacetophenone, three tert-butoxy vinyl silanes, it is heated to 100 DEG C of evacuation, vacuum 0.09MPa, stir 60 minutes, add dimethylacetal, 2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate, in vacuum 0.09MPa, chemical reaction is carried out after 90 minutes under rotating speed 35r/min, prepare required aluminum alloy doors and windows silicone sealant.
This aluminum alloy doors and windows silicone sealant, good sealing effect, flame retardant rating is high, breaking out of fire when, can well play fire resistance, and this aluminum alloy doors and windows silicone sealant, appearance property is excellent, shelf life of products is longer, is suitable to popularization and application in aluminum alloy doors and windows silicone sealant field.
Detailed description of the invention
The detailed description of the invention of the present invention given below, is used for being further described the present invention.In the present invention, if no special instructions, each raw material all by working substance content be in terms of 100%.
In following example, raw material introduction:
Ring four polydimethylsiloxane, CAS accession number is: 293-51-6；
5-carbethoxyl group-4,6-dimethyl-2-pyranone, CAS accession number is: 3385-34-0；
4-methyl-2-oxo-pentanoic acid sodium salt, CAS accession number is: 4502-00-5；
MTMS, CAS accession number is: 1185-55-3；
3-oxo nor-tropane-8-carboxylic acid, ethyl ester, CAS accession number is: 32499-64-2；
O-methoxyacetophenone, CAS accession number is: 579-74-8；
Three tert-butoxy vinyl silanes, CAS accession number is: 5356-88-7；
Dimethylacetal, CAS accession number is: 534-15-6；
2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate, CAS accession number is: 2597-03-7；
1,1-diethoxyethane, CAS accession number is: 105-57-7；
6-(4,5-dihydro-3-methyl-5-oxo-1H-pyrazol-1-yl)-1,3-naphthalenedisulfonic acid, CAS accession number is: 7277-87-4；
3-methoxybutanol, CAS accession number is: 2517-43-3.
Embodiment 1
Weigh the raw material of following weight: ring four polydimethylsiloxane 60kg, 5-carbethoxyl group-4,6-dimethyl-2-pyranone 15kg, 4-methyl-2-oxo-pentanoic acid sodium salt 22kg, MTMS 36kg, 3-oxo nor-tropane-8-carboxylic acid, ethyl ester 13kg, o-methoxyacetophenone 9kg, three tert-butoxy vinyl silanes 20kg, dimethylacetal 25kg, 2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate 6kg.
nullThe preparation method of the present embodiment aluminum alloy doors and windows silicone sealant: by ring four polydimethylsiloxane、5-carbethoxyl group-4,6-dimethyl-2-pyranone、4-methyl-2-oxo-pentanoic acid sodium salt、MTMS adds in planetary mixer，Evacuation，Vacuum 0.09MPa，Rotating speed 35r/min，After stirring 60 minutes，Add 3-oxo nor-tropane-8-carboxylic acid, ethyl ester、O-methoxyacetophenone、Three tert-butoxy vinyl silanes，It is heated to 100 DEG C of evacuation，Vacuum 0.09MPa，Stir 60 minutes，Add dimethylacetal、2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate，In vacuum 0.09MPa、Chemical reaction is carried out after 90 minutes under rotating speed 35r/min，Prepare required aluminum alloy doors and windows silicone sealant.
Embodiment 2
Weigh the raw material of following weight: ring four polydimethylsiloxane 63kg, 5-carbethoxyl group-4,6-dimethyl-2-pyranone 9kg, 4-methyl-2-oxo-pentanoic acid sodium salt 26kg, MTMS 39kg, 3-oxo nor-tropane-8-carboxylic acid, ethyl ester 7kg, o-methoxyacetophenone 12kg, three tert-butoxy vinyl silanes 24kg, dimethylacetal 19kg, 2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate 9kg.
The preparation method of the present embodiment aluminum alloy doors and windows silicone sealant is with embodiment 1.
Embodiment 3
Weigh the raw material of following weight: ring four polydimethylsiloxane 66kg, 5-carbethoxyl group-4,6-dimethyl-2-pyranone 12kg, 4-methyl-2-oxo-pentanoic acid sodium salt 18kg, MTMS 42kg, 3-oxo nor-tropane-8-carboxylic acid, ethyl ester 10kg, o-methoxyacetophenone 6kg, three tert-butoxy vinyl silanes 28kg, dimethylacetal 22kg, 2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate 3kg.
The preparation method of the present embodiment aluminum alloy doors and windows silicone sealant is with embodiment 1.
Embodiment 4
Weigh the raw material of following weight: ring four polydimethylsiloxane 63kg, 5-carbethoxyl group-4, 6-dimethyl-2-pyranone 9kg, 4-methyl-2-oxo-pentanoic acid sodium salt 26kg, MTMS 39kg, 3-oxo nor-tropane-8-carboxylic acid, ethyl ester 7kg, o-methoxyacetophenone 12kg, three tert-butoxy vinyl silanes 24kg, dimethylacetal 19kg, 2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate 9kg, 1, 1-diethoxyethane 18kg, 6-(4, 5-dihydro-3-methyl-5-oxo-1H-pyrazol-1-yl)-1, 3-naphthalenedisulfonic acid 15kg, 3-methoxybutanol 12kg.
nullThe preparation method of the present embodiment aluminum alloy doors and windows silicone sealant: by ring four polydimethylsiloxane、5-carbethoxyl group-4,6-dimethyl-2-pyranone、4-methyl-2-oxo-pentanoic acid sodium salt、MTMS adds in planetary mixer，Evacuation，Vacuum 0.09MPa，Rotating speed 35r/min，After stirring 60 minutes，Add 3-oxo nor-tropane-8-carboxylic acid, ethyl ester、O-methoxyacetophenone、Three tert-butoxy vinyl silanes，It is heated to 100 DEG C of evacuation，Vacuum 0.09MPa，Stir 60 minutes，Add dimethylacetal、2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate、1,1-diethoxyethane、6-(4,5-dihydro-3-methyl-5-oxo-1H-pyrazol-1-yl)-1,3-naphthalenedisulfonic acid、3-methoxybutanol，In vacuum 0.09MPa、Chemical reaction is carried out after 90 minutes under rotating speed 35r/min，Prepare required aluminum alloy doors and windows silicone sealant.
Embodiment 5
Weigh the raw material of following weight: ring four polydimethylsiloxane 63kg, 5-carbethoxyl group-4, 6-dimethyl-2-pyranone 9kg, 4-methyl-2-oxo-pentanoic acid sodium salt 26kg, MTMS 39kg, 3-oxo nor-tropane-8-carboxylic acid, ethyl ester 7kg, o-methoxyacetophenone 12kg, three tert-butoxy vinyl silanes 24kg, dimethylacetal 19kg, 2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate 9kg, 1, 1-diethoxyethane 21kg, 6-(4, 5-dihydro-3-methyl-5-oxo-1H-pyrazol-1-yl)-1, 3-naphthalenedisulfonic acid 11kg, 3-methoxybutanol 16kg.
The preparation method of the present embodiment aluminum alloy doors and windows silicone sealant is with embodiment 4.
Embodiment 6
Weigh the raw material of following weight: ring four polydimethylsiloxane 63kg, 5-carbethoxyl group-4, 6-dimethyl-2-pyranone 9kg, 4-methyl-2-oxo-pentanoic acid sodium salt 26kg, MTMS 39kg, 3-oxo nor-tropane-8-carboxylic acid, ethyl ester 7kg, o-methoxyacetophenone 12kg, three tert-butoxy vinyl silanes 24kg, dimethylacetal 19kg, 2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate 9kg, 1, 1-diethoxyethane 24kg, 6-(4, 5-dihydro-3-methyl-5-oxo-1H-pyrazol-1-yl)-1, 3-naphthalenedisulfonic acid 13kg, 3-methoxybutanol 8kg.
The preparation method of the present embodiment aluminum alloy doors and windows silicone sealant is with embodiment 4.
Properties of product test result
Doing properties of product test with regard to this aluminum alloy doors and windows silicone sealant below, details is shown in Table 1.
Table 1: properties of product test result
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Extrudability | Good | Good | Good | Good | Good | Good |
| Outward appearance | Uniform and smooth | Uniform and smooth | Uniform and smooth | Uniform and smooth | Uniform and smooth | Uniform and smooth |
| Elongation at break (%) | 480 | 490 | 485 | 500 | 520 | 510 |
| Hot strength (MPa) | 0.88 | 0.96 | 0.92 | 1.04 | 1.12 | 1.08 |
| The storage phase (moon) | 14 | 14 | 14 | 14 | 14 | 14 |
| Flame retardant rating | V0 | V0 | V0 | V0 | V0 | V0 |
As can be seen from the above table, this aluminum alloy doors and windows silicone sealant is extrudability good, and appearance uniform is fine and smooth, has higher elongation at break, and hot strength is relatively strong, and it is long to store the time, and flame retardant rating has reached highest standard.Wherein, the aluminum alloy doors and windows silicone sealant best performance of embodiment 5 is different, extrudability good, and appearance uniform is fine and smooth, and elongation at break is 520, and hot strength is 1.12MPa, and the storage phase is 14 months, and flame retardant rating is V0.
Claims (4)
1. an aluminum alloy doors and windows silicone sealant, it is characterized in that including the raw material of following weight: ring four polydimethylsiloxane 60-66 part, 5-carbethoxyl group-4,6-dimethyl-2-pyranone 9-15 part, 4-methyl-2-oxo-pentanoic acid sodium salt 18-26 part, MTMS 36-42 part, 3-oxo nor-tropane-8-carboxylic acid, ethyl ester 7-13 part, o-methoxyacetophenone 6-12 part, three tert-butoxy vinyl silanes 20-28 parts, dimethylacetal 19-25 part, 2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate 3-9 part.
2. aluminum alloy doors and windows silicone sealant as claimed in claim 1, it is characterized in that including the raw material of following weight: ring four polydimethylsiloxane 63 parts, 5-carbethoxyl group-4,6-dimethyl-2-pyranone 9 parts, 4-methyl-2-oxo-pentanoic acid sodium salt 26 parts, MTMS 39 parts, 3-oxo nor-tropane-8-carboxylic acid, ethyl ester 7 parts, o-methoxyacetophenone 12 parts, three tert-butoxy vinyl silanes 24 parts, dimethylacetal 19 parts, 2-[(dimethoxy sulfur is for phosphono) sulfenyl] ethyl phenylacetate 9 parts.
3. aluminum alloy doors and windows silicone sealant as claimed in claim 1 or 2, characterized by further comprising the raw material of following weight: 1,1-diethoxyethane 18-24 part, 6-(4,5-dihydro-3-methyl-5-oxo-1H-pyrazol-1-yl)-1,3-naphthalenedisulfonic acid 11-15 part, 3-methoxybutanol 8-16 part.
4. as claimed in claim 3 aluminum alloy doors and windows silicone sealant, it is characterised in that include the raw material of following weight: 1,1-diethoxyethane 21 parts, 6-(4,5-dihydro-3-methyl-5-oxo-1H-pyrazol-1-yl)-1,3-naphthalenedisulfonic acid 11 parts, 3-methoxybutanol 16 parts.
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| CN201610300432.3A CN105713553A (en) | 2016-05-06 | 2016-05-06 | Silicone sealant for aluminum alloy doors/windows |
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| CN201610300432.3A CN105713553A (en) | 2016-05-06 | 2016-05-06 | Silicone sealant for aluminum alloy doors/windows |
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Application publication date: 20160629 |