CN105702763B - A kind of photovoltaic cell module and laser powered sensor equipment - Google Patents

A kind of photovoltaic cell module and laser powered sensor equipment Download PDF

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Publication number
CN105702763B
CN105702763B CN201610235060.0A CN201610235060A CN105702763B CN 105702763 B CN105702763 B CN 105702763B CN 201610235060 A CN201610235060 A CN 201610235060A CN 105702763 B CN105702763 B CN 105702763B
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cell module
photovoltaic cell
laser
gas
powered sensor
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CN105702763A (en
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王国芳
张俊峰
蒋晓菁
张永隽
李素贤
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Wuhan Jinlong Engineering Technology Co Ltd
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Wuhan Jinlong Engineering Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/0256Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
    • H01L31/0264Inorganic materials
    • H01L31/0328Inorganic materials including, apart from doping materials or other impurities, semiconductor materials provided for in two or more of groups H01L31/0272 - H01L31/032
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S10/00PV power plants; Combinations of PV energy systems with other systems for the generation of electric power
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
  • Lasers (AREA)

Abstract

This patent discloses a kind of photovoltaic cell module and laser powered sensor equipment, wherein, the material of photovoltaic cell module is phosphating metal composite, and its composition includes the element of following mass percent:5 15% phosphorus, 5 12.5% bronze medals, 25 35% selenium and 13 25% indiums.Laser powered sensor equipment includes electro-optic conversion system, photo-translating system and pressure regulation conversion equipment;Electro-optic conversion system includes gas-recycling plant;The gas of gas-recycling plant is excited by inputing power, is produced laser, is concurrently incident upon photo-translating system;Opto-electronic conversion dress system includes above-mentioned photovoltaic cell module, and photovoltaic cell module receives laser, is converted to output electric energy;Pressure regulation conversion equipment turns on photovoltaic cell module, is direct current by output electric energy rectification.The present invention can provide safely and steadly electric energy, have low high conversion efficiency, energy consumption, long-distance transmissions, low cost and other advantages.

Description

A kind of photovoltaic cell module and laser powered sensor equipment
Technical field
The invention belongs to power field, more particularly to a kind of photovoltaic cell module and laser powered sensor equipment.
Background technology
At present, electric energy mainly by the metal such as cable wire medium transmit, its transmit electric energy when, exist line impedance, Antijamming capability is weak, the shortcomings of ripple be present during AC-DC conversion, easily influences power supply effect, or even burns electrical equipment, nothing The equipment that method satisfaction needs are highly safe, stabilized power source ensures, such as industrial instrument, sensor and auto parts.In addition, cable Need to consume the materials such as a large amount of cables Deng metal wire medium transmission electric energy, cost is high.
The content of the invention
The present invention provides a kind of photovoltaic cell module and laser powered sensor equipment, the defects of to overcome prior art.
To achieve the above object, the present invention provides a kind of photovoltaic cell module, and the material of photovoltaic cell module is phosphating metal composite wood Material, its composition include the element of following mass percent:5-15% phosphorus, 5-12.5% copper, 25-35% selenium and 13-25% indiums, should Phosphating metal composite is the compound for including phosphorized copper, copper, phosphatization selenium, selenium, indium phosphide, indium and phosphorus composition.
Further, the present invention provides a kind of photovoltaic cell module, can also have the feature that:Phosphating metal composite, Its composition is made up of the element of following mass percent:7-11% phosphorus, 8-12% copper, 25.7-29.7% galliums, 28-32% selenium, 14.9-18.9% indiums and 4.4-8.4% germanium, the phosphating metal composite are to include phosphorized copper, copper, gallium phosphide, gallium, phosphatization The compound that selenium, selenium, indium phosphide, indium, phosphatization germanium, germanium and phosphorus form.
Preferably, the composition of phosphating metal composite is made up of the element of following mass percent:9% phosphorus, 10% bronze medal, 27.7% gallium, 30% selenium, 16.9% indium and 6.4% germanium.
Further, the present invention provides the preparation method of above-mentioned phosphating metal composite, metal composite and oxygen containing zirconium Change phosphorus and displacement reaction occurs, generate phosphating metal composite and zirconium oxide.
The present invention also provides a kind of laser powered sensor equipment, including electro-optic conversion system, photo-translating system and pressure regulation conversion Device;Wherein, electro-optic conversion system includes gas-recycling plant;The gas of gas-recycling plant is excited by inputing power, is produced Laser, concurrently it is incident upon photo-translating system;Opto-electronic conversion dress system includes above-mentioned photovoltaic cell module, and photovoltaic cell module receives laser, turns It is changed to output electric energy;Pressure regulation conversion equipment turns on photovoltaic cell module, is direct current by output electric energy rectification.
Further, the present invention provides a kind of laser powered sensor equipment, can also have the feature that:Wherein, gas circulation The specular material of device inwall is GaAs.
Further, the present invention provides a kind of laser powered sensor equipment, can also have the feature that:Wherein, gas circulation The gas of device is by CO2、N2, one or more of rare gas composition, its percent by volume is followed successively by 58-62%, 16-20%, 20- 24%.
Preferably, the gas of gas circulation device is by CO2、N2, He and Ar compositions, its percent by volume is followed successively by 60%, 18%th, 14% and 8%.
Further, the present invention provides a kind of laser powered sensor equipment, can also have the feature that:Wherein, electro-optic conversion System includes speculum, located at the non-laser transmitting terminal of gas circulation device;The specular material of speculum is electrum, by quality Percentage is:80-82% gold and 20-18% silver compositions.
Further, the present invention provides a kind of laser powered sensor equipment, can also have the feature that:Wherein, opto-electronic conversion System also includes receiving camera lens and spectroscope, is sequentially arranged in along Laser emission direction on the central shaft of laser;Camera lens is received to receive Laser, it is transferred to spectroscope;On spectroscope dispersion laser to photovoltaic cell module.
Further, the present invention provides a kind of laser powered sensor equipment, can also have the feature that:Wherein, photovoltaic cell module It is hemispherical.
Further, the present invention provides a kind of laser powered sensor equipment, can also have the feature that:Wherein, electro-optic conversion System also includes heat sink and temperature sensor;Heat sink is outside gas-recycling plant, for its cooling;Temperature sensor The temperature of detection gas EGR, when temperature is more than 130 DEG C, cut off inputing power.
The beneficial effect of this patent is:The present invention provides a kind of photovoltaic cell module, and material is phosphating metal composite, real Now efficiently opto-electronic conversion.The present invention also provides a kind of laser powered sensor equipment, including above-mentioned photovoltaic cell module, in addition to gas circulation Device, gas therein is by 60%CO2, 18%N2, 14%He and 8%Ar composition, efficiently inputing power can be converted to sharp Light, powerful Laser emission is realized, its inwall is coated with GaAs specular material, for reflection laser.Gas-recycling plant one End is provided with speculum, and its specular material is the alloy of 80% gold medal and 20% silver medal, can be with total-reflection laser.Outside gas-recycling plant Portion and the back side of photovoltaic cell module are respectively equipped with heat sink, it is maintained certain temperature, protection equipment operation, there is provided safe, steady Fixed electric energy.
Brief description of the drawings
Fig. 1 is a kind of structural representation of photovoltaic cell module and laser powered sensor equipment.
Embodiment
Illustrate the embodiment of the present invention below in conjunction with accompanying drawing.
As shown in figure 1, the present invention provides a kind of laser powered sensor equipment, including electro-optic conversion system 100, photo-translating system 200 and pressure regulation conversion equipment 300.
Electro-optic conversion system 100 includes voltage generation circuit 101, gas-recycling plant 102, emitter 103, speculum 104th, heat sink and temperature sensor 105, wherein, heat sink includes chilled water unit 106 and blower fan 107.
Voltage generation circuit 101 produces 20000V DC high-voltages, and gas-recycling plant 102 is installed in as inputing power Both positive and negative polarity interface on, the discharge current on the interface is 5000mA.
The gas of gas-recycling plant 102 is by CO2、N2, one or more of rare gas composition, its percent by volume is successively For 58-62%, 16-20%, 18-26%.In the present embodiment, the gas of gas-recycling plant 102 is by CO2、N2, He and Ar composition, Its content is followed successively by 60%, 18%, 14% and 8%.
Optionally, the gas of gas-recycling plant 102 is by CO2、N2Formed with He, its percent by volume is followed successively by 58%, 16% and 26%.
Optionally, the gas of gas-recycling plant 102 is included by CO2、N2, He and Ne compositions, its percent by volume is followed successively by 62%th, 20%, 12% and 6%.
Optionally, the gas of gas-recycling plant 102 is by CO2、N2, Kr and Xe compositions, its percent by volume is followed successively by 60%th, 18%, 14% and 8%.
N2, He and Ar molecules excited by inputing power, with CO2Collide, self-energy is passed into CO2Molecule, CO2 Violent random motion occurs for intramolecule, produces energy and forms laser.The specular material of the inwall of gas-recycling plant 102 is arsenic Change gallium, for reflection laser.
Emitter 103 is located at the end of gas-recycling plant 102, the Laser emission formed to photo-translating system 200, optical maser wavelength is 10.6 μm, power 100kW, transmitting range 100km.
Speculum 104 is located at the non-laser transmitting terminal of gas-recycling plant 102, and its specular material is electrum, by matter Measuring percentage is:80-82% gold and 20-18% silver compositions.In the present embodiment, the mass percent of electrum specular material For:80% gold medal and 20% silver medal.Speculum 104 can with total-reflection laser, meanwhile, the inwall of gas-recycling plant 102 also reflection laser, The laser for forming gas-recycling plant 102 is concentrated through emitter 103 and launched to photo-translating system 200.
Chilled water unit 106 and blower fan 107 are outside gas-recycling plant 102, for reducing gas-recycling plant 102 Temperature, protection equipment.Chilled water unit 106 is by the outer wall circulating cooling water-cooled of gas-recycling plant 102, making its temperature Kept for less than 85 DEG C.
Temperature sensor 105 is located at the edge of speculum 104, the temperature of detection gas EGR 102, works as gas circulation When the temperature of device 102 is more than 130 DEG C, the power supply of voltage generation circuit 101 is cut off.
Photo-translating system 200 includes reception camera lens 201, spectroscope 202 and the light set gradually along Laser emission direction Cell panel 203, in addition to photovoltaic cell module chilled water unit 204.
Receive camera lens 201 and spectroscope 202 is sequentially arranged on the central shaft of laser along Laser emission direction, receive camera lens 201 receive laser, and are transferred to spectroscope 202, on the dispersion laser of spectroscope 202 to photovoltaic cell module 203.Wherein, camera lens is received 201 and emitter 103 distance can according to transmission demand and Laser emission distance and adjust.202 trapezoidal circle of spectroscope Hemisphere is bored, both ends radius is respectively 0.5cm and 5cm, high 6.3cm, focal length 20cm.
Photovoltaic cell module 203 is hemispherical, and its material is phosphating metal composite, and in the present embodiment, phosphating metal is compound The composition of material is made up of the element of following mass percent:7-11% phosphorus, 8-12% copper, 25.7-29.7% galliums, 28-32% Selenium, 14.9-18.9% indiums and 4.4-8.4% germanium, output electric energy can be efficiently converted laser light into, the phosphating metal composite wood Material is the compound for including phosphorized copper, copper, gallium phosphide, gallium, phosphatization selenium, selenium, indium phosphide, indium, phosphatization germanium, germanium and phosphorus.
Preferably, the composition of phosphating metal composite is made up of the element of following mass percent:9% phosphorus, 10% bronze medal, 27.7% gallium, 30% selenium, 16.9% indium and 6.4% germanium.
Optionally, the composition of phosphating metal composite is made up of the element of following mass percent:7% phosphorus, 8% bronze medal, 25.7% gallium, 32% selenium, 18.9% indium and 8.4% germanium.
Optionally, the composition of phosphating metal composite is made up of the element of following mass percent:11% phosphorus, 12% Copper, 29.7% gallium, 28% selenium, 14.9% indium and 4.4% germanium.
Photovoltaic cell module chilled water unit 204 is located at the back side of photovoltaic cell module 203, recirculated cooling water, is dropped for photovoltaic cell module 203 Temperature, its temperature is set to be kept for less than 200 DEG C.
Pressure regulation conversion equipment 300 turns on photovoltaic cell module 203, is 3000mA, 200V direct current by output electric energy rectification, is The device stable power-supplying such as instrument, sensor, auto parts.
Embodiment 2
The present embodiment is same as Example 1, differs only in the material of photovoltaic cell module.
The material of photovoltaic cell module is phosphating metal composite, in the present embodiment, the composition of phosphating metal composite by The element composition of following mass percent:5-15% phosphorus, 5-12.5% copper, 25-35% selenium, 13-25% indium 23-40% galliums should Phosphating metal composite is the compound for including phosphorized copper, copper, phosphatization selenium, selenium, indium phosphide, indium, gallium phosphide, gallium and phosphorus.
Preferably, the composition of phosphating metal composite is made up of the element of following mass percent:15% phosphorus, 12.5% Copper, 35% selenium, 13% indium and 24.5% gallium.
Optionally, the composition of phosphating metal composite is made up of the element of following mass percent:5% phosphorus, 5% bronze medal, 25% selenium, 25% indium and 40% gallium.
Optionally, the composition of phosphating metal composite is made up of the element of following mass percent:11% phosphorus, 11% Copper, 32% selenium, 23% indium and 23% gallium.
Embodiment 2 is identical with the application process of embodiment 1.

Claims (12)

  1. A kind of 1. photovoltaic cell module, it is characterised in that:
    The material of the photovoltaic cell module is phosphating metal composite, and the phosphating metal composite includes phosphorized copper, copper, phosphorus Change the compound of selenium, selenium, indium phosphide, indium and phosphorus composition, its composition includes the element of following mass percent:5-15% phosphorus, 5- 12.5% bronze medal, 25-35% selenium and 13-25% indiums.
  2. 2. photovoltaic cell module according to claim 1, it is characterised in that:
    The phosphating metal composite, its composition are made up of the element of following mass percent:7-11% phosphorus, 8-12% copper, 25.7-29.7% galliums, 28-32% selenium, 14.9-18.9% indiums and 4.4-8.4% germanium.
  3. 3. photovoltaic cell module according to claim 1, it is characterised in that:
    The composition of the phosphating metal composite is made up of the element of following mass percent:9% phosphorus, 10% bronze medal, 27.7% Gallium, 30% selenium, 16.9% indium and 6.4% germanium.
  4. 4. photovoltaic cell module according to claim 1, it is characterised in that:
    With phosphorous oxide displacement reaction occurs for the metal composite containing zirconium, generates the phosphating metal composite and zirconium oxide.
  5. A kind of 5. laser powered sensor equipment, it is characterised in that:
    Including electro-optic conversion system, photo-translating system and pressure regulation conversion equipment;
    Wherein, the electro-optic conversion system includes gas-recycling plant;
    The gas of the gas-recycling plant is excited by inputing power, is produced laser, is concurrently incident upon the photo-translating system;
    The opto-electronic conversion dress system includes the photovoltaic cell module as described in any one in claim 1-4, the photovoltaic cell module The laser is received, is converted to output electric energy;
    The pressure regulation conversion equipment turns on the photovoltaic cell module, is direct current by the output electric energy rectification.
  6. 6. laser powered sensor equipment according to claim 5, it is characterised in that:
    Wherein, the specular material of the gas-recycling plant inwall is GaAs.
  7. 7. laser powered sensor equipment according to claim 5, it is characterised in that:
    Wherein, the gas of the gas circulation device is by CO2、N2, one or more of rare gas composition, its percent by volume is successively For 58-62%, 16-20%, 20-24%.
  8. 8. laser powered sensor equipment according to claim 7, it is characterised in that:
    Wherein, the gas of the gas circulation device is by CO2、N2, He and Ar compositions, its percent by volume is followed successively by 60%, 18%, 14% and 8%.
  9. 9. laser powered sensor equipment according to claim 5, it is characterised in that:
    Wherein, the electro-optic conversion system also includes speculum, located at the non-laser transmitting terminal of the gas circulation device;
    The specular material of the speculum is electrum, is by mass percent:80-82% gold and 20-18% silver compositions.
  10. 10. laser powered sensor equipment according to claim 5, it is characterised in that:
    Wherein, the photo-translating system also includes receiving camera lens and spectroscope, and institute is sequentially arranged in along the Laser emission direction State on the central shaft of laser;
    The reception camera lens receives the laser, is transferred to the spectroscope;
    The spectroscope disperses the laser to the photovoltaic cell module.
  11. 11. laser powered sensor equipment according to claim 5, it is characterised in that:
    Wherein, the photovoltaic cell module is hemispherical.
  12. 12. laser powered sensor equipment according to claim 5, it is characterised in that:
    Wherein, the electro-optic conversion system also includes heat sink and temperature sensor;
    The heat sink is outside the gas-recycling plant, for its cooling;
    The temperature sensor detects the temperature of the gas-recycling plant, and when the temperature is more than 130 DEG C, cut-out is described defeated Enter electric energy.
CN201610235060.0A 2016-04-15 2016-04-15 A kind of photovoltaic cell module and laser powered sensor equipment Active CN105702763B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106712700B (en) * 2016-12-29 2019-05-28 武汉凹伟能源科技有限公司 High-power monochrome photovoltaic devices and monochromatic photo-cell assembly
CN107769723A (en) * 2017-11-06 2018-03-06 浙江工业大学 Integrating sphere type photovoltaic receiver device for laser radio charging
CN109366017A (en) * 2018-11-12 2019-02-22 江苏大学 A kind of apparatus and method of the cooling auxiliary laser punching of energy-saving liquid nitrogen

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101183688A (en) * 2006-11-15 2008-05-21 通用电气公司 Amorph-kristalline solarzellen mit tandem-nanostruktur
CN103534804A (en) * 2010-12-13 2014-01-22 阿森特太阳能技术公司 Apparatus and method for hybrid photovoltaic device having multiple, stacked, heterogeneous, semiconductor junctions

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101183688A (en) * 2006-11-15 2008-05-21 通用电气公司 Amorph-kristalline solarzellen mit tandem-nanostruktur
CN103534804A (en) * 2010-12-13 2014-01-22 阿森特太阳能技术公司 Apparatus and method for hybrid photovoltaic device having multiple, stacked, heterogeneous, semiconductor junctions

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