CN105696327B - 一种环保通用荧光增白剂及其制备方法 - Google Patents
一种环保通用荧光增白剂及其制备方法 Download PDFInfo
- Publication number
- CN105696327B CN105696327B CN201610101477.8A CN201610101477A CN105696327B CN 105696327 B CN105696327 B CN 105696327B CN 201610101477 A CN201610101477 A CN 201610101477A CN 105696327 B CN105696327 B CN 105696327B
- Authority
- CN
- China
- Prior art keywords
- parts
- sodium
- environmentally friendly
- fluorescent brightening
- biphenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000005282 brightening Methods 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 239000003054 catalyst Substances 0.000 claims abstract description 23
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 21
- 239000002270 dispersing agent Substances 0.000 claims abstract description 21
- 239000011521 glass Substances 0.000 claims abstract description 21
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 21
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims abstract description 19
- OKWWNWXAVYZDCP-UHFFFAOYSA-N [Na].C1(=CC=CC=C1)C1=CC=CC=C1.C1(=CC=CC=C1)C=CC1=CC=CC=C1 Chemical compound [Na].C1(=CC=CC=C1)C1=CC=CC=C1.C1(=CC=CC=C1)C=CC1=CC=CC=C1 OKWWNWXAVYZDCP-UHFFFAOYSA-N 0.000 claims abstract description 19
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical class OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims abstract description 19
- 235000010290 biphenyl Nutrition 0.000 claims abstract description 19
- 239000004305 biphenyl Substances 0.000 claims abstract description 19
- 239000008367 deionised water Substances 0.000 claims abstract description 19
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 19
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 19
- 239000011734 sodium Substances 0.000 claims abstract description 19
- 229940005574 sodium gluconate Drugs 0.000 claims abstract description 19
- 235000012207 sodium gluconate Nutrition 0.000 claims abstract description 19
- 239000000176 sodium gluconate Substances 0.000 claims abstract description 19
- 125000005504 styryl group Chemical group 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000006185 dispersion Substances 0.000 claims description 18
- DGSDBJMBHCQYGN-UHFFFAOYSA-M sodium;2-ethylhexyl sulfate Chemical compound [Na+].CCCCC(CC)COS([O-])(=O)=O DGSDBJMBHCQYGN-UHFFFAOYSA-M 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 9
- 238000010792 warming Methods 0.000 claims description 8
- 239000003643 water by type Substances 0.000 claims description 8
- -1 oleoyl N-methyltaurine sodium Chemical compound 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 3
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 2
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 2
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 2
- 229940113124 polysorbate 60 Drugs 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical group CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 claims 1
- 150000007942 carboxylates Chemical class 0.000 claims 1
- RPNNPZHFJPXFQS-UHFFFAOYSA-N methane;rhodium Chemical compound C.[Rh] RPNNPZHFJPXFQS-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000006081 fluorescent whitening agent Substances 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000003860 storage Methods 0.000 abstract description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- LFLCNBLTOXIVOQ-UHFFFAOYSA-N hydron;octan-3-yl sulfate Chemical class CCCCCC(CC)OS(O)(=O)=O LFLCNBLTOXIVOQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 5
- 230000008033 biological extinction Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000006862 quantum yield reaction Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical group CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- XHCADAYNFIFUHF-TVKJYDDYSA-N esculin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC(C(=C1)O)=CC2=C1OC(=O)C=C2 XHCADAYNFIFUHF-TVKJYDDYSA-N 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0034—Mixtures of two or more pigments or dyes of the same type
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/262—Sulfated compounds thiosulfates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/10—Non-macromolecular compounds
- C09K2211/1003—Carbocyclic compounds
- C09K2211/1007—Non-condensed systems
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
- Materials For Photolithography (AREA)
Abstract
本发明公开了一种环保通用荧光增白剂，以重量份计，包括以下组分：4,4’‑双(2,4‑二磺酸钠苯乙烯基)联苯10‑20份，二苯乙烯联苯二磺酸钠15‑20份，β‑环糊精衍生物5‑8份，2‑乙基己基硫酸钠3‑7份，葡萄糖酸钠5‑10份，纳米氧化钛2‑3份，玻璃微珠0.5‑1份，分散剂0.5‑1份，交联剂1‑2份，催化剂1.5‑3份，去离子水25‑30份。本发明还公开了该环保通用荧光增白剂的制备方法。本发明提供的荧光增白剂，增白和增艳效果好，分散性和储存稳定性优异，且具有一定的可生物降解性能，有利于环境保护。
Description
技术领域：
本发明涉及纺织助剂领域，具体的涉及一种环保通用荧光增白剂。
背景技术：
荧光增白剂是一种能产生荧光的有机化合物，其增白原理不同于化学氧化增白，而是一种物理过程。它自身不能使物质染色，也不会损伤织物，但却能提高物质的白度和光泽，使产品夺目亮丽，广泛应用于洗涤剂、纺织、造纸、塑料、涂料等工业产品中。
荧光增白剂的功能和作用取决于：①荧光增白剂的固有特性；②荧光增白剂的光谱吸收和发射特性；③光的紫外线含量。最佳荧光增白剂应该满足3个条件：①吸收尽可能多的紫外光和具有尽可能浅的本身颜色，在基质上应是光学无色的，这意味着增白剂的最大吸收波长应该在350～375nm、有高的摩尔消光系数、在接近400nm时的吸收带应急剧减弱、不应该吸收光谱的可见部分；②荧光应该尽可能强和能产生最大的白度，这意味着荧光量子产率应接近1.0、最大荧光波长应在415～445nm、荧光带在长波长一边应尽可能快地减弱；③荧光增白剂在基质中的分布应该是单分子的，即使在高浓度时，荧光增白剂分子的聚集体也会显著地降低其荧光量子产率且常会产生不同的光谱。
由于荧光增白剂的重要功能和作用，自1929年发现一种名为七叶灵的化合物(即6,7-二羟基香豆素的β-D-葡萄糖甙)开创了荧光增白剂的历史以来，已经历了85年，发展很快；特别是20世纪60年代到21世纪初，荧光增白剂的结构类型随着新纺织纤维、新型洗涤剂、高级纸张和新型化妆品等的快速开发而不断创新。近年来又开发了一些新的结构类型如杂环基苯乙烯类荧光增白剂、带有2个乙烯基的杂环基乙烯类荧光增白剂、杂环基呋喃类荧光增白剂和二芳烃基苯并二呋喃类荧光增白剂等，但技术进展的重点在现有发色共轭体系的扩展、取代基的改变和现有重要品种的工艺改革等创新上。据不完全统计，各种不同结构的荧光增白剂已超过500种，不同形态的商品超过了3000种。但是目前的荧光增白剂专一性很强，不同种类的荧光增白剂只能用于特定的织物。
发明内容：
本发明的目的是提供一种环保通用荧光增白剂，其通用性强，可以用于不同种类织物的增白，且效果好，其分散性好，储存稳定性优异，且具有一定的可生物降解性能，有利于环境保护。
本发明的另一个目是提供该环保通用荧光增白剂的制备方法。
为实现上述目的，本发明采用以下技术方案：
一种环保通用荧光增白剂，以重量份计，包括以下组分：
4,4’-双(2,4-二磺酸钠苯乙烯基)联苯10-20份，
二苯乙烯联苯二磺酸钠15-20份，
β-环糊精衍生物5-8份，
2-乙基己基硫酸钠3-7份，
葡萄糖酸钠5-10份，
纳米氧化钛2-3份，
玻璃微珠0.5-1份，
分散剂0.5-1份，
交联剂1-2份，
催化剂1.5-3份，
去离子水25-30份。
作为上述技术方案的优选，一种环保通用荧光增白剂，以重量份计，包括以下组分：
4,4’-双(2,4-二磺酸钠苯乙烯基)联苯15份，
二苯乙烯联苯二磺酸钠18份，
β-环糊精衍生物6.5份，
2-乙基己基硫酸钠5份，
葡萄糖酸钠10份，
纳米氧化钛2份，
玻璃微珠0.5份，
分散剂1份，
交联剂1.5份，
催化剂2份，
去离子水30份。
作为上述技术方案的优选，所述纳米氧化钛的粒径大小为20-25nm。
作为上述技术方案的优选，所述玻璃微珠的粒径大小为40-70nm。
作为上述技术方案的优选，所述分散剂为油酰甲基牛磺酸钠、C10-15脂肪酸聚氧乙烯酯、span80、吐温60中的一种或多种混合。
作为上述技术方案的优选，所述催化剂为铂或铑炭催化剂。
作为上述技术方案的优选，所述交联剂为三羟甲基丙烷三(3-吖丙啶基丙酸酯)。
一种环保通用荧光增白剂的制备方法，包括以下步骤：
(1)将4,4’-双(2,4-二磺酸钠苯乙烯基)联苯、二苯乙烯联苯二磺酸钠和去离子水混合搅拌均匀，加入β-环糊精衍生物，交联剂，搅拌均匀后，升温至60-80℃，加入催化剂，反应2-5h，冷却至40-60℃，得到混合液；
(2)将纳米氧化钛、玻璃微珠和去离子水混合搅拌均匀，加入分散剂，500-1000W的功率下超声3-4h，得到均匀分散液；
(3)向步骤(1)得到的混合液中滴加步骤(2)所得的均匀分散液，反应3-6h，冷却至室温，加入2-乙基己基硫酸钠、葡萄糖酸钠，混合搅拌均匀，得到环保通用荧光增白剂。
作为上述技术方案的优选，步骤(1)中，所述反应的条件为：反应温度：75℃，反应时间：4h。
作为上述技术方案的优选，步骤(3)中，所述反应的时间为5h。
本发明具有以下有益效果：
本发明制备的荧光增白剂摩尔消光系数高，可以有效的吸收紫外线，荧光增白效果显著，其最大荧光波长为420-440nm；
且其通用性强，可以用于不同种类织物的增白，分散性好，储存稳定性优异，且具有一定的可生物降解性能，有利于环境保护。
具体实施方式：
为了更好的理解本发明，下面通过实施例对本发明进一步说明，实施例只用于解释本发明，不会对本发明构成任何的限定。
实施例1
一种环保通用荧光增白剂，以重量份计，包括以下组分：
4,4’-双(2,4-二磺酸钠苯乙烯基)联苯10份，
二苯乙烯联苯二磺酸钠15份，
β-环糊精衍生物5份，2-乙基己基硫酸钠3份，
葡萄糖酸钠5份，纳米氧化钛2份，
玻璃微珠0.5份，分散剂0.5份，
交联剂1份，催化剂1.5份，去离子水25份。
其制备方法包括以下步骤：
(1)将4,4’-双(2,4-二磺酸钠苯乙烯基)联苯、二苯乙烯联苯二磺酸钠和去离子水混合搅拌均匀，加入β-环糊精衍生物，交联剂，搅拌均匀后，升温至60℃，加入催化剂，反应2h，冷却至40℃，得到混合液；
(2)将纳米氧化钛、玻璃微珠和去离子水混合搅拌均匀，加入分散剂，500W的功率下超声3h，得到均匀分散液；
(3)向步骤(1)得到的混合液中滴加步骤(2)所得的均匀分散液，反应3h，冷却至室温，加入2-乙基己基硫酸钠、葡萄糖酸钠，混合搅拌均匀，得到环保通用荧光增白剂。
实施例2
一种环保通用荧光增白剂，以重量份计，包括以下组分：
4,4’-双(2,4-二磺酸钠苯乙烯基)联苯20份，
二苯乙烯联苯二磺酸钠20份，
β-环糊精衍生物8份，2-乙基己基硫酸钠7份，
葡萄糖酸钠10份，纳米氧化钛3份，
玻璃微珠1份，分散剂1份，
交联剂2份，催化剂3份，去离子水30份。
其制备方法包括以下步骤：
(1)将4,4’-双(2,4-二磺酸钠苯乙烯基)联苯、二苯乙烯联苯二磺酸钠和去离子水混合搅拌均匀，加入β-环糊精衍生物，交联剂，搅拌均匀后，升温至80℃，加入催化剂，反应5h，冷却至60℃，得到混合液；
(2)将纳米氧化钛、玻璃微珠和去离子水混合搅拌均匀，加入分散剂，1000W的功率下超声4h，得到均匀分散液；
(3)向步骤(1)得到的混合液中滴加步骤(2)所得的均匀分散液，反应6h，冷却至室温，加入2-乙基己基硫酸钠、葡萄糖酸钠，混合搅拌均匀，得到环保通用荧光增白剂。
实施例3
一种环保通用荧光增白剂，以重量份计，包括以下组分：
4,4’-双(2,4-二磺酸钠苯乙烯基)联苯15份，
二苯乙烯联苯二磺酸钠18份，
β-环糊精衍生物6.5份，2-乙基己基硫酸钠5份，
葡萄糖酸钠10份，纳米氧化钛2份，
玻璃微珠0.5份，分散剂1份，
交联剂1.5份，催化剂2份，去离子水30份。
其制备方法包括以下步骤：
(1)将4,4’-双(2,4-二磺酸钠苯乙烯基)联苯、二苯乙烯联苯二磺酸钠和去离子水混合搅拌均匀，加入β-环糊精衍生物，交联剂，搅拌均匀后，升温至65℃，加入催化剂，反应3h，冷却至45℃，得到混合液；
(2)将纳米氧化钛、玻璃微珠和去离子水混合搅拌均匀，加入分散剂，600W的功率下超声3.2h，得到均匀分散液；
(3)向步骤(1)得到的混合液中滴加步骤(2)所得的均匀分散液，反应4h，冷却至室温，加入2-乙基己基硫酸钠、葡萄糖酸钠，混合搅拌均匀，得到环保通用荧光增白剂。
实施例4
一种环保通用荧光增白剂，以重量份计，包括以下组分：
4,4’-双(2,4-二磺酸钠苯乙烯基)联苯12份，
二苯乙烯联苯二磺酸钠16份，
β-环糊精衍生物6份，2-乙基己基硫酸钠4份，
葡萄糖酸钠6份，纳米氧化钛2.2份，
玻璃微珠0.6份，分散剂0.6份，
交联剂1.2份，催化剂1.7份，去离子水26份。
其制备方法包括以下步骤：
(1)将4,4’-双(2,4-二磺酸钠苯乙烯基)联苯、二苯乙烯联苯二磺酸钠和去离子水混合搅拌均匀，加入β-环糊精衍生物，交联剂，搅拌均匀后，升温至70℃，加入催化剂，反应3.5h，冷却至50℃，得到混合液；
(2)将纳米氧化钛、玻璃微珠和去离子水混合搅拌均匀，加入分散剂，700W的功率下超声3.4h，得到均匀分散液；
(3)向步骤(1)得到的混合液中滴加步骤(2)所得的均匀分散液，反应4.5h，冷却至室温，加入2-乙基己基硫酸钠、葡萄糖酸钠，混合搅拌均匀，得到环保通用荧光增白剂。
实施例5
一种环保通用荧光增白剂，以重量份计，包括以下组分：
4,4’-双(2,4-二磺酸钠苯乙烯基)联苯16份，
二苯乙烯联苯二磺酸钠17份，
β-环糊精衍生物7份，2-乙基己基硫酸钠5份，
葡萄糖酸钠7份，纳米氧化钛2.6份，
玻璃微珠0.7份，分散剂0.8份，
交联剂1.6份，催化剂2份，去离子水28份。
其制备方法包括以下步骤：
(1)将4,4’-双(2,4-二磺酸钠苯乙烯基)联苯、二苯乙烯联苯二磺酸钠和去离子水混合搅拌均匀，加入β-环糊精衍生物，交联剂，搅拌均匀后，升温至75℃，加入催化剂，反应4h，冷却至55℃，得到混合液；
(2)将纳米氧化钛、玻璃微珠和去离子水混合搅拌均匀，加入分散剂，800W的功率下超声3.6h，得到均匀分散液；
(3)向步骤(1)得到的混合液中滴加步骤(2)所得的均匀分散液，反应5h，冷却至室温，加入2-乙基己基硫酸钠、葡萄糖酸钠，混合搅拌均匀，得到环保通用荧光增白剂。
实施例6
一种环保通用荧光增白剂，以重量份计，包括以下组分：
4,4’-双(2,4-二磺酸钠苯乙烯基)联苯16份，
二苯乙烯联苯二磺酸钠18份，
β-环糊精衍生物7.5份，2-乙基己基硫酸钠6份，
葡萄糖酸钠8份，纳米氧化钛2.6份，
玻璃微珠0.8份，分散剂0.9份，
交联剂1.8份，催化剂2.5份，去离子水28份。
其制备方法包括以下步骤：
(1)将4,4’-双(2,4-二磺酸钠苯乙烯基)联苯、二苯乙烯联苯二磺酸钠和去离子水混合搅拌均匀，加入β-环糊精衍生物，交联剂，搅拌均匀后，升温至80℃，加入催化剂，反应4.5h，冷却至55℃，得到混合液；
(2)将纳米氧化钛、玻璃微珠和去离子水混合搅拌均匀，加入分散剂，900W的功率下超声3.8h，得到均匀分散液；
(3)向步骤(1)得到的混合液中滴加步骤(2)所得的均匀分散液，反应5.5h，冷却至室温，加入2-乙基己基硫酸钠、葡萄糖酸钠，混合搅拌均匀，得到环保通用荧光增白剂。
Claims (6)
1.一种环保通用荧光增白剂，其特征在于，以重量份计，包括以下组分：
4,4’-双(2,4-二磺酸钠苯乙烯基)联苯10-20份，
二苯乙烯联苯二磺酸钠15-20份，
β-环糊精衍生物5-8份，
2-乙基己基硫酸钠3-7份，
葡萄糖酸钠5-10份，
纳米氧化钛2份，
玻璃微珠0.5-1份，
分散剂0.5-1份，
交联剂1-2份，
催化剂1.5-3份，
去离子水25-30份；
其中，所述纳米氧化钛的粒径大小为20-25nm；所述玻璃微珠的粒径大小为40-70nm；所述分散剂为油酰甲基牛磺酸钠、C10-15脂肪酸聚氧乙烯酯、span80、吐温60中的一种或多种混合；
其制备方法包括以下步骤：
(1)将4,4’-双(2,4-二磺酸钠苯乙烯基)联苯、二苯乙烯联苯二磺酸钠和去离子水混合搅拌均匀，加入β-环糊精衍生物，交联剂，搅拌均匀后，升温至60-80℃，加入催化剂，反应2-5h，冷却至40-60℃，得到混合液；
(2)将纳米氧化钛、玻璃微珠和去离子水混合搅拌均匀，加入分散剂，500-1000W的功率下超声3-4h，得到均匀分散液；
(3)向步骤(1)得到的混合液中滴加步骤(2)所得的均匀分散液，反应3-6h，冷却至室温，加入2-乙基己基硫酸钠、葡萄糖酸钠，混合搅拌均匀，得到环保通用荧光增白剂。
2.如权利要求1所述的一种环保通用荧光增白剂，其特征在于，以重量份计，包括以下组分：
4,4’-双(2,4-二磺酸钠苯乙烯基)联苯15份，
二苯乙烯联苯二磺酸钠18份，
β-环糊精衍生物6.5份，
2-乙基己基硫酸钠5份，
葡萄糖酸钠10份，
纳米氧化钛2份，
玻璃微珠0.5份，
分散剂1份，
交联剂1.5份，
催化剂2份，
去离子水30份。
3.如权利要求1所述的一种环保通用荧光增白剂，其特征在于，所述催化剂为铂或铑炭催化剂。
4.如权利要求1所述的一种环保通用荧光增白剂，其特征在于，所述交联剂为三羟甲基丙烷三(3-吖丙啶基丙酸酯)。
5.如权利要求1所述的一种环保通用荧光增白剂，其特征在于，步骤(1)中，所述反应的条件为：反应温度：75℃，反应时间：4h。
6.如权利要求1所述的一种环保通用荧光增白剂，其特征在于，步骤(3)中，所述反应的时间为5h。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610101477.8A CN105696327B (zh) | 2016-02-25 | 2016-02-25 | 一种环保通用荧光增白剂及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610101477.8A CN105696327B (zh) | 2016-02-25 | 2016-02-25 | 一种环保通用荧光增白剂及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105696327A CN105696327A (zh) | 2016-06-22 |
| CN105696327B true CN105696327B (zh) | 2018-02-02 |
Family
ID=56222534
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610101477.8A Expired - Fee Related CN105696327B (zh) | 2016-02-25 | 2016-02-25 | 一种环保通用荧光增白剂及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105696327B (zh) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243777A (zh) * | 2016-08-15 | 2016-12-21 | 泉州市山水电脑耗材有限公司 | 中温型活性染料195艳红色浆稳定性配方及其制备方法 |
| CN106758132B (zh) * | 2016-12-01 | 2019-05-03 | 湖北鸿鑫化工有限公司 | 一种荧光增白浆液及其制备方法 |
| CN109457539A (zh) * | 2018-11-28 | 2019-03-12 | 夏勇 | 一种造纸用环保荧光增白剂及其制备方法 |
| CN111389296A (zh) * | 2020-04-16 | 2020-07-10 | 浙江弘毅化学有限公司 | 一种制备环保型荧光增白剂的装置及其制备方法 |
| CN111535010A (zh) * | 2020-05-23 | 2020-08-14 | 嵊州市天美助剂厂 | 一种高日晒牢度棉用荧光增白剂组合物 |
| CN112409821B (zh) * | 2020-11-20 | 2022-05-31 | 湖北海汇化工科技有限公司 | 一种水溶性荧光增白剂及其制备方法 |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4841473B1 (zh) * | 1962-11-21 | 1973-12-06 | ||
| JPS4993677A (zh) * | 1973-01-16 | 1974-09-05 | ||
| CN101338152A (zh) * | 2007-07-20 | 2009-01-07 | 潘东海 | 道路反光标线涂料 |
| CN102354473A (zh) * | 2011-10-31 | 2012-02-15 | 安徽海盛纳米新材料科技有限公司 | 一种高亮度长余辉发光标牌及其制备方法 |
| CN104589751A (zh) * | 2015-01-01 | 2015-05-06 | 宁波帝杨电子科技有限公司 | 一种户外荧光薄膜及其制备方法 |
| CN104693892A (zh) * | 2015-02-16 | 2015-06-10 | 陕西师范大学 | 一种文物隐形编码标识液 |
| CN104840977A (zh) * | 2015-03-23 | 2015-08-19 | 济南大学 | 一种磁性荧光复合纳米药物载体的制备方法 |
| CN104862120A (zh) * | 2015-04-09 | 2015-08-26 | 广州立白企业集团有限公司 | 一种洗涤剂用荧光增白剂水溶液的制备方法 |
-
2016
- 2016-02-25 CN CN201610101477.8A patent/CN105696327B/zh not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4841473B1 (zh) * | 1962-11-21 | 1973-12-06 | ||
| JPS4993677A (zh) * | 1973-01-16 | 1974-09-05 | ||
| CN101338152A (zh) * | 2007-07-20 | 2009-01-07 | 潘东海 | 道路反光标线涂料 |
| CN102354473A (zh) * | 2011-10-31 | 2012-02-15 | 安徽海盛纳米新材料科技有限公司 | 一种高亮度长余辉发光标牌及其制备方法 |
| CN104589751A (zh) * | 2015-01-01 | 2015-05-06 | 宁波帝杨电子科技有限公司 | 一种户外荧光薄膜及其制备方法 |
| CN104693892A (zh) * | 2015-02-16 | 2015-06-10 | 陕西师范大学 | 一种文物隐形编码标识液 |
| CN104840977A (zh) * | 2015-03-23 | 2015-08-19 | 济南大学 | 一种磁性荧光复合纳米药物载体的制备方法 |
| CN104862120A (zh) * | 2015-04-09 | 2015-08-26 | 广州立白企业集团有限公司 | 一种洗涤剂用荧光增白剂水溶液的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105696327A (zh) | 2016-06-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105696327B (zh) | 一种环保通用荧光增白剂及其制备方法 | |
| CN103993504B (zh) | 一种多功能碳量子点作为荧光增白剂的应用 | |
| DE2238734C2 (de) | Bis-benzofuranyl-Verbindungen und deren Verwendung als optische Aufheller | |
| KR102501334B1 (ko) | 써모플라스틱 화합물을 레이저 마킹하기 위한 안티몬 비함유 조성물 | |
| CN109505167A (zh) | 一种稀土金属骨架多功能染色荧光棉织物的制备方法 | |
| Nakamura et al. | Photophysical properties of various regioisomers of [60] fullerene-o-quinodimethane bisadducts | |
| JP2005529245A (ja) | 繊維材料を増白させる方法 | |
| CN107674670A (zh) | 一种高耐光型荧光增白剂的制备方法 | |
| Allen et al. | Spectroscopic analysis of organic contaminants in terephthalic acid: colour implications in poly (ethylene terephthalate) manufacture | |
| EP0935691B1 (de) | Optischer aufheller | |
| CA2832775C (en) | A novel fwa formulation used for the papermaking process | |
| Adam et al. | Cyclic peroxides. 59. On the mechanism of the rubrene-enhanced chemiluminescence of. alpha.-peroxylactones | |
| US3416945A (en) | Process for the optical brightening of fibers containing terephthalic acid polyesters | |
| US3784569A (en) | V-triazolyl coumarins | |
| CN108164817A (zh) | 一种透明度高的塑料编织袋的生产工艺 | |
| Liu et al. | Thermal and fluorescent properties of optical brighteners and their whitening effect for pelletization of cycloolefin copolymers | |
| Ouchi et al. | Increasing the dyeability of polyester fabrics by photochemical treatment at room-temperature using H 2 O 2 in air | |
| Tang et al. | Flexible polyarylene ether nitrile containing pendant carboxyl groups/Eu (III) fluorescent films with high thermal stability and mechanical strength | |
| KR101048905B1 (ko) | 양모섬유가공용 티타늄하이드로졸, 양모섬유용 복합가공제 및 이를 이용한 양모섬유의 복합가공방법 | |
| Saron et al. | Effects of bismuth vandate and anthraquinone dye on the photodegradation of polycarbonate | |
| US3708475A (en) | Process for the production of chlorine-containing v-triazole compounds | |
| US3565890A (en) | Novel di-arylene azolyl-styrene compound and the use thereof | |
| CN110373045B (zh) | 一种分散翠蓝s-gb200%染料组合物及其应用 | |
| CA2832776C (en) | Fluorescent brighter #71 used for the papermaking process | |
| US739071A (en) | Process of dyeing brown. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Wenqing Inventor before: Wei Tiantang |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20171227 Address after: 523000 Guangdong province Dongguan Songshan Lake high tech Industrial Development Zone Productivity building 406 Applicant after: Dongguan Lianzhou intellectual property operation management Co.,Ltd. Address before: No. 153, tree garden road, Dong Zhu Town, Suzhou high tech Zone, Jiangsu Province Applicant before: SUZHOU SANHE KAITAI COLORED THREAD WEAVING Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190621 Address after: 435406 Makou Niushan, Tianzhen, Wuxue City, Huanggang City, Hubei Province Patentee after: WUXUE ODYSSEY CHEMICALS CO.,LTD. Address before: 523000 productivity building 406, Songshan Hu high tech Industrial Development Zone, Dongguan, Guangdong Patentee before: Dongguan Lianzhou Intellectual Property Operation Management Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180202 |