CN105694340A - High-strength ABS-based polymer alloy for FDM (fused deposition modeling) and preparation method of alloy - Google Patents
High-strength ABS-based polymer alloy for FDM (fused deposition modeling) and preparation method of alloy Download PDFInfo
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- CN105694340A CN105694340A CN201610142935.2A CN201610142935A CN105694340A CN 105694340 A CN105694340 A CN 105694340A CN 201610142935 A CN201610142935 A CN 201610142935A CN 105694340 A CN105694340 A CN 105694340A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/068—Ultra high molecular weight polyethylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/10—Peculiar tacticity
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Abstract
The invention relates to an ABS-based polymer alloy for FDM (fused deposition modeling) and a preparation method of the alloy. ABS resin, a linear polymer, a compatibilizer, a plasticizer and an antioxidant are mixed and extruded. The excellent properties of ABS wires are reserved, the linear polymer and other aids are combined, the mechanical properties of existing ABS resin are improved, and the cost of the ABS wires is reduced. The polymer alloy has the characteristics of high tensile strength, good heat resistance and low cost and can be applied to 3D printing of automobile parts, so that automobiles are lightweight and low-carbon, printed automobile parts are lower in brittleness, the surface roughness can meet the requirement, meanwhile, the production cost is greatly reduced, the production process becomes simple, industrial production is better facilitated, and the application and development of the additive manufacturing technology in the automobile field are greatly promoted.
Description
Technical field
The present invention relates to and belong to increasing material manufacture Material Field, be specifically related to a kind of fusion sediment technology high intensity ABS based polyalcohol Alloy And Preparation Method。
Background technology
Along with the development of automotive engineering, the function of automobile is day by day perfect, and the structure of automobile also becomes increasingly complex, and traditional automobile is generally made up of several thousand parts, and modern senior strong car is made up of several ten thousand parts。For meeting vehicle energy saving, environmental protection, safe, comfortable requirement, it is achieved lightweight, high intensity, high performance target, the material and the parts manufacturing technology that constitute automobile also there occurs huge change。Being different from tradition and subtract material manufacturing technology, increasing material manufacturing technology is nearly 30 years emerging a kind of rapid shaping techniques, and it is based on three-dimensional digital model, constructs object by successively increasing material。Increase the free posing ability of material manufacturing technology, it is possible to achieve the quick manufacture of the labyrinth that traditional manufacturing technology has been difficult to, the weight contributing to auto parts and components alleviates significantly。The one that fusion sediment technology (FDM) is the most frequently used increases material manufacturing technology, the operation principle of this technology is to extrude from shower nozzle after thermoplastic, polymeric materials is heated to molten condition, shower nozzle, then according to path movement pre-set in three-dimensional digital model, is formed and has effigurate thin layer。Owing to this know-why material ranges relatively easy, spendable is relatively wide, FDM has become as industrialized a kind of material manufacturing technology that increases, and for the molding of auto parts and components。
Precision and the physical and mechanical properties of FDM profiled member are played decisive role by material。Thermoplastic polymer can the feature such as plasticizing forming rapidly owing to its fluidity of molten is good, after cooling, it is possible to meet the increasing material manufacturing technology requirement to material well。The polymeric material great majority being currently used for FDM technology are thermoplastic polymers, for instance acrylonitrile-butadiene-styrene terpolymer (ABS), polylactic acid, Merlon, nylon etc.。But, exactly because increasing the dependence to thermoplastic polymer of the material manufacturing technology, the material category being successfully applied to FDM technology at present is very limited。Adding FDM technology and pile up the technological principle of material layer by layer, there is the difficult problems such as intensity deficiency, anisotropy of mechanical properties in FDM profiled member。Thus, increase the application in more areas of the material manufacturing technology and development, depend on the exploitation of the new material of multiple performance。Relative to the new FDM polymer of synthesis, blend polymer is prepared by blended method in the basis of current material or polymer nanocomposite is the most straightforward procedure preparing FDM polymer new material。Research shows, when, under two components or the good situation of many component materials compatibility, the blended alloy material obtained can maintain the two respective excellent properties of component materials, can give again the performance that material is new on this basis。
ABS resin is the big kind engineering plastics of a kind of high comprehensive performance, and it is because having the excellent processing characteristics of the high intensity of polyacrylonitrile, the impact resistance of polybutadiene, polystyrene, and is widely used in the industries such as machinery, automobile, household electrical appliance。ABS resin is the thermoplastic polymer that a kind of shrinkage factor is less, thus is also one of widely used material of FDM technology, is mainly used in the field such as modelling and automobile exemplar checking。Up to the present, ABS silk material relatively costly, the product of stable performance depends on import；The mechanical performance of profiled member is poor, is only the 50% of moulding, and there is anisotropy；The fragility of ABS silk material is relatively big, and print procedure easily produces the phenomenon of alice, surface roughness and precision and all beats less than instructions for use。The existence of these problems greatly limit ABS silk material and increases material manufacturing technology in the application of automotive field and development。
Summary of the invention
For above-mentioned Problems existing, an object of the present invention is in that to provide a kind of fusion sediment technology high intensity ABS based polyalcohol alloy；
The two of the purpose of the present invention are in that the preparation method providing a kind of fusion sediment technology high intensity ABS based polyalcohol alloy。
To achieve these goals, the technical solution used in the present invention is: a kind of fusion sediment technology high intensity ABS based polyalcohol alloy, is made up of following material by weight:
Above-mentioned linear polymer is any one or any two or more mixing in atactic copolymerized polypropene, isotactic polypropylene, Low Density Polyethylene, ultra-high molecular weight polyethylene。。
Above-mentioned bulking agent is block copolymer styrene-butadiene-styrene resin, one in polypropylene-g-maleic anhydride or two or more mixing。
Above-mentioned antioxidant is the composite antioxidant of any one or the two kinds of proportionings in antioxidant 1010, antioxidant 1076, irgasfos 168。
Above-mentioned plasticizer is phthalic acid ester, adipic acid esters, phosphoric acid ester any one or two or more mixing。
The preparation method of a kind of fusion sediment technology high intensity ABS based polyalcohol alloy, carries out as follows:
1) by the ABS resin of 10～99 parts, the linear polymer of 1～90 part, the bulking agent of 5～10 parts, the nucleator of 0.5～1 part, the antioxidant double screw extruder mixing extruding pelletization of 0.3～0.8 part, 5 sections of temperature of extruder are followed successively by: 160～190 DEG C, 185～205 DEG C, 185～230 DEG C, 185～230 DEG C, 185～230 DEG C。
2) by step 1) in institute's pelletize son drying baker be extruded and processed into the filament of FDM equipment after drying with single screw extrusion machine, diameter error is within 5%, and 5 sections of temperature of extruder are followed successively by 175～185 DEG C, 180～190 DEG C, 180～190 DEG C, 180～190 DEG C, 175～185 DEG C。
Above-mentioned linear polymer is any one or any two or more mixing in atactic copolymerized polypropene, isotactic polypropylene, polyethylene。
Above-mentioned bulking agent is block copolymer styrene-butadiene-styrene resin, one in polypropylene-g-maleic anhydride or two or more mixing。
Above-mentioned antioxidant is the composite antioxidant of any one or the two kinds of proportionings in antioxidant 1010, antioxidant 1076, irgasfos 168。
Above-mentioned plasticizer is phthalic acid ester, adipic acid esters, phosphoric acid ester any one or two or more mixing。
It is an object of the invention under the premise not sacrificing existing ABS silk material performance, ABS composite wire material is prepared by adding second component polymer, thus the cost of thread material is greatly lowered while improving printing parts toughness, finally realize the extensive use in automotive light weight technology of new material and FDM technology。The second component polymer selected in the present invention is linear polymer, this is because polyethylene or polypropylene are all the thermoplastic synthetic resins of function admirable, there is the advantages such as density processing little, nontoxic, easy, intensity height, chemical stability and electrical insulation capability are good, and cheap, the application in automotive trim and parts is relatively broad。But owing to its degree of crystallinity is significantly high, material shrinkage factor in forming process is very big, and linear polymer application in increasing material manufacturing technology is restricted。
Therefore, polypropylene or polyethylene are added in ABS resin by the present invention, form a kind of plastic alloy, to improve the mechanical property of existing ABS resin, to reduce the cost of ABS silk material。The feature that preparation-obtained ABS base composite resin has hot strength height, heat resistance is good。
Beneficial effect: the present invention retains ABS silk material premium properties, carries out general character in conjunction with linear polymer and other auxiliary agents, improves the mechanical property of existing ABS resin, reduces the cost of ABS silk material；There is hot strength height, heat resistance is good, cost is low feature, can be used for the 3D of auto parts and components to print thus automobile lightweight, low carbonization, the auto parts and components fragility printed is bigger, and surface roughness does not reach requirement, production cost is substantially reduced simultaneously, production process becomes simply to be easier to industrialized production, is greatly facilitated and increases material manufacturing technology in the application of automotive field and development。
Detailed description of the invention
Embodiment 1
Weigh respectively isotactic polypropylene 100g, phthalic acid ester 5g, styrene-butadiene-styrene resin 25g, primary antioxidant 1010 and auxiliary anti-oxidant 1680.5g, ABS resin 300g be added sequentially in double screw extruder mix, plasticizing, extrusion, pelletize。The 5 sections of temperature melt extruded respectively 185 DEG C, 190 DEG C, 190 DEG C, 190 DEG C, 185 DEG C, screw speed is 80 revs/min。Then with single screw extrusion machine by gained pellet wire-drawing shape。5 sections of temperature of single screw extrusion machine respectively 180 DEG C, 185 DEG C, 185 DEG C, 185 DEG C, 180 DEG C。The consumptive material of rolling, after vacuum drying, seals and preserves。
Embodiment 2
Weigh isotactic polypropylene 100g respectively, phthalic acid ester 5g, styrene-butadiene-styrene resin 25g, antioxidant 0.5g, ABS resin 300g are added sequentially in double screw extruder to mix, plasticizing, extrusion, pelletize。The 5 sections of temperature melt extruded respectively 185 DEG C, 190 DEG C, 190 DEG C, 190 DEG C, 185 DEG C, screw speed is 80 revs/min。Then with single screw extrusion machine by gained pellet wire-drawing shape。5 sections of temperature of single screw extrusion machine respectively 180 DEG C, 185 DEG C, 185 DEG C, 185 DEG C, 180 DEG C。The consumptive material of rolling, after vacuum drying, seals and preserves。
Embodiment 3
Weigh respectively atactic copolymerized polypropene 100g, phthalic acid ester 1g, styrene-butadiene-styrene resin 25g, primary antioxidant 1010 and auxiliary anti-oxidant 1680.5g, ABS resin 300g be added sequentially in double screw extruder mix, plasticizing, extrusion, pelletize。The 5 sections of temperature melt extruded respectively 180 DEG C, 185 DEG C, 185 DEG C, 185 DEG C, 180 DEG C, screw speed is 80 revs/min。Then with single screw extrusion machine by gained pellet wire-drawing shape。5 sections of temperature of single screw extrusion machine respectively 180 DEG C, 185 DEG C, 185 DEG C, 185 DEG C, 180 DEG C。The consumptive material of rolling, after vacuum drying, seals and preserves。
Embodiment 4
Weigh any one or two or more mixing 10g, the block copolymer styrene-butadiene-styrene resin in any one or any two or more mixing 90g, phthalic acid ester, adipic acid esters, the phosphoric acid esters in atactic copolymerized polypropene, isotactic polypropylene, polyethylene respectively, one in polypropylene-g-maleic anhydride or two kinds of 10g, antioxidant 1010,1076,168 any one or two kinds of 0.8g, ABS resin 99g are added sequentially in double screw extruder to mix, plasticizing, extrusion, pelletize。The 5 sections of temperature melt extruded respectively 190 DEG C, 205 DEG C, 230 DEG C, 230 DEG C, 230 DEG C, screw speed is 80 revs/min。Then with single screw extrusion machine by gained pellet wire-drawing shape。5 sections of temperature of single screw extrusion machine respectively 185 DEG C, 190 DEG C, 190 DEG C, 190 DEG C, 185 DEG C。The consumptive material of rolling, after vacuum drying, seals and preserves。
Embodiment 5
Weigh any one or two or more mixing 5g, the block copolymer styrene-butadiene-styrene resin in any one or any two or more mixing 1g, phthalic acid ester, adipic acid esters, the phosphoric acid esters in atactic copolymerized polypropene, isotactic polypropylene, polyethylene respectively, one in polypropylene-g-maleic anhydride or two kinds of 5g, antioxidant 1010,1076,168 any one or two kinds of 0.3g, ABS resin 10g are added sequentially in double screw extruder to mix, plasticizing, extrusion, pelletize。The 5 sections of temperature melt extruded respectively 160 DEG C, 185 DEG C, 185 DEG C, 185 DEG C, 185 DEG C, screw speed is 80 revs/min。Then with single screw extrusion machine by gained pellet wire-drawing shape。5 sections of temperature of single screw extrusion machine respectively 175 DEG C, 180 DEG C, 180 DEG C, 180 DEG C, 175 DEG C。The consumptive material of rolling, after vacuum drying, seals and preserves。
Embodiment 6
Weigh any one or two or more mixing 8g, the block copolymer styrene-butadiene-styrene resin in any one or any two or more mixing 50g, phthalic acid ester, adipic acid esters, the phosphoric acid esters in atactic copolymerized polypropene, isotactic polypropylene, polyethylene respectively, one in polypropylene-g-maleic anhydride or two kinds of 8g, antioxidant 1010,1076,168 any one or two kinds of 0.5g, ABS resin 66g are added sequentially in double screw extruder to mix, plasticizing, extrusion, pelletize。The 5 sections of temperature melt extruded respectively 180 DEG C, 200 DEG C, 210 DEG C, 210 DEG C, 205 DEG C, screw speed is 80 revs/min。Then with single screw extrusion machine by gained pellet wire-drawing shape。5 sections of temperature of single screw extrusion machine respectively 180 DEG C, 185 DEG C, 185 DEG C, 185 DEG C, 180 DEG C。The consumptive material of rolling, after vacuum drying, seals and preserves。
Embodiment 7
Weigh any one or two or more mixing 9g, the block copolymer styrene-butadiene-styrene resin in any one or any two or more mixing 80g, phthalic acid ester, adipic acid esters, the phosphoric acid esters in atactic copolymerized polypropene, isotactic polypropylene, polyethylene respectively, one in polypropylene-g-maleic anhydride or two kinds of 8g, antioxidant 1010,1076,168 any one or two kinds of 0.7g, ABS resin 89g are added sequentially in double screw extruder to mix, plasticizing, extrusion, pelletize。The 5 sections of temperature melt extruded respectively 180 DEG C, 185 DEG C, 185 DEG C, 185 DEG C, 180 DEG C, screw speed is 80 revs/min。Then with single screw extrusion machine by gained pellet wire-drawing shape。5 sections of temperature of single screw extrusion machine respectively 180 DEG C, 185 DEG C, 185 DEG C, 185 DEG C, 180 DEG C。The consumptive material of rolling, after vacuum drying, seals and preserves。
Claims (10)
1. a fusion sediment technology high intensity ABS based polyalcohol alloy, is made up of following material by weight:
。
2. a kind of fusion sediment technology high intensity ABS based polyalcohol alloy according to claim 1, it is characterised in that: described linear polymer is any one or any two or more mixing in atactic copolymerized polypropene, isotactic polypropylene, Low Density Polyethylene, ultra-high molecular weight polyethylene。
3. a kind of fusion sediment technology high intensity ABS based polyalcohol alloy according to claim 1, it is characterized in that: described bulking agent is block copolymer styrene-butadiene-styrene resin, one in polypropylene-g-maleic anhydride or two or more mixing。
4. a kind of fusion sediment technology high intensity ABS based polyalcohol alloy according to claim 1, it is characterised in that: described antioxidant is the composite antioxidant of any one or the two kinds of proportionings in antioxidant 1010, antioxidant 1076, irgasfos 168。
5. a kind of fusion sediment technology high intensity ABS based polyalcohol alloy according to claim 1, it is characterised in that: described plasticizer is any one or two or more mixing in phthalic acid ester, adipic acid esters, phosphoric acid ester。
6. a preparation method for fusion sediment technology high intensity ABS based polyalcohol alloy as claimed in claim 1, carries out as follows:
1) by the ABS resin of 10～99 parts, the linear polymer of 1～90 part, the bulking agent of 5～10 parts, the plasticizer of 5～10 parts, the antioxidant double screw extruder mixing extruding pelletization of 0.3～0.8 part, 5 sections of temperature of extruder are followed successively by: 160～190 DEG C, 185～205 DEG C, 185～230 DEG C, 185～230 DEG C, 185～230 DEG C。
2) by step 1) in institute's pelletize son drying baker be extruded and processed into the filament of FDM equipment after drying with single screw extrusion machine, diameter error is within 5%, and 5 sections of temperature of extruder are followed successively by 175～185 DEG C, 180～190 DEG C, 180～190 DEG C, 180～190 DEG C, 175～185 DEG C。
7. the preparation method of a kind of fusion sediment technology high intensity ABS based polyalcohol alloy according to claim 6, it is characterised in that: described linear polymer is any one or any two or more mixing in atactic copolymerized polypropene, isotactic polypropylene, Low Density Polyethylene, ultra-high molecular weight polyethylene。
8. the preparation method of a kind of fusion sediment technology high intensity ABS based polyalcohol alloy according to claim 1, it is characterized in that: described bulking agent is block copolymer styrene-butadiene-styrene resin, one in polypropylene-g-maleic anhydride or two or more mixing。
9. the preparation method of a kind of fusion sediment technology high intensity ABS based polyalcohol alloy according to claim 1, it is characterised in that: described antioxidant is the composite antioxidant of any one or the two kinds of proportionings in antioxidant 1010, antioxidant 1076, irgasfos 168。
10. the preparation method of a kind of fusion sediment technology high intensity ABS based polyalcohol alloy according to claim 1, it is characterised in that: described plasticizer is any one or two or more mixing in phthalic acid ester, adipic acid esters, phosphoric acid ester。
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109080701A (en) * | 2018-08-27 | 2018-12-25 | 四川中物红宇科技有限公司 | A kind of alloy material and vehicle bridge frame for vehicle bridge frame surface |
| CN110177636A (en) * | 2016-11-15 | 2019-08-27 | 霍加纳斯股份有限公司 | Raw material for increasing material manufacturing method, the increasing material manufacturing method using it and the product obtained by it |
| CN114921049A (en) * | 2022-05-26 | 2022-08-19 | 中国重汽集团济南动力有限公司 | ABS (acrylonitrile butadiene styrene) modified material for large-size FDM (frequency-division multiplexing) printing as well as preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150125682A1 (en) * | 2013-11-01 | 2015-05-07 | Kraton Polymers U.S. Llc | Fuse molded three dimensional article and a method for making the same |
| CN104845032A (en) * | 2015-05-26 | 2015-08-19 | 江苏浩宇电子科技有限公司 | Preparation method of toughened 3D (three-dimensional) printing consumables |
| CN104974461A (en) * | 2015-06-30 | 2015-10-14 | 深圳光华伟业股份有限公司 | ABS alloy material, and preparation method thereof |
| TW201542610A (en) * | 2014-02-19 | 2015-11-16 | 巴斯夫歐洲公司 | Polymers as support material for use in fused filament fabrication |
| CN105331064A (en) * | 2015-11-05 | 2016-02-17 | 张晓军 | Colorful FDM 3D printing material and preparation method thereof |
-
2016
- 2016-03-14 CN CN201610142935.2A patent/CN105694340A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150125682A1 (en) * | 2013-11-01 | 2015-05-07 | Kraton Polymers U.S. Llc | Fuse molded three dimensional article and a method for making the same |
| TW201542610A (en) * | 2014-02-19 | 2015-11-16 | 巴斯夫歐洲公司 | Polymers as support material for use in fused filament fabrication |
| CN104845032A (en) * | 2015-05-26 | 2015-08-19 | 江苏浩宇电子科技有限公司 | Preparation method of toughened 3D (three-dimensional) printing consumables |
| CN104974461A (en) * | 2015-06-30 | 2015-10-14 | 深圳光华伟业股份有限公司 | ABS alloy material, and preparation method thereof |
| CN105331064A (en) * | 2015-11-05 | 2016-02-17 | 张晓军 | Colorful FDM 3D printing material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110177636A (en) * | 2016-11-15 | 2019-08-27 | 霍加纳斯股份有限公司 | Raw material for increasing material manufacturing method, the increasing material manufacturing method using it and the product obtained by it |
| CN110177636B (en) * | 2016-11-15 | 2021-12-21 | 霍加纳斯股份有限公司 | Raw material for additive manufacturing process, additive manufacturing process using the same, and articles obtained therefrom |
| CN109080701A (en) * | 2018-08-27 | 2018-12-25 | 四川中物红宇科技有限公司 | A kind of alloy material and vehicle bridge frame for vehicle bridge frame surface |
| CN114921049A (en) * | 2022-05-26 | 2022-08-19 | 中国重汽集团济南动力有限公司 | ABS (acrylonitrile butadiene styrene) modified material for large-size FDM (frequency-division multiplexing) printing as well as preparation method and application thereof |
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