CN105693156A - Innovative preparation method of heat-resistant baking-free brick - Google Patents

Innovative preparation method of heat-resistant baking-free brick Download PDF

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Publication number
CN105693156A
CN105693156A CN201610153608.7A CN201610153608A CN105693156A CN 105693156 A CN105693156 A CN 105693156A CN 201610153608 A CN201610153608 A CN 201610153608A CN 105693156 A CN105693156 A CN 105693156A
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China
Prior art keywords
parts
weight
weight portion
ash
heat
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Pending
Application number
CN201610153608.7A
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Chinese (zh)
Inventor
李金顶
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Jinjiang City Min Yi Renewable Resource Co Ltd
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Jinjiang City Min Yi Renewable Resource Co Ltd
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Priority to CN201610153608.7A priority Critical patent/CN105693156A/en
Publication of CN105693156A publication Critical patent/CN105693156A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/10Burned or pyrolised refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08Acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2084Thermal shock resistance
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Civil Engineering (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses an innovative preparation method of a heat-resistant baking-free brick. The method comprises the following steps that 1, ash from a sintering furnace in a power station is smashed to lump materials with the particle size of 5 mm; 2, 32 parts by weight of ash from the sintering furnace in the power station, 22 parts by weight of coal cinder powder, 23 parts by weight of common sand, 7 parts by weight of cement, 5 parts by weight of calcium oxide with the particle size of 5 mm, 4 parts by weight of calcium silicate, 1.2 parts by weight of sodium sulfate, 0.8 part by weight of sodium silicate, 4 parts by weight of water-soluble unsaturated resin and 1.8 parts by weight of turtle powder are added into 12 parts by weight of water to be mixed and stirred into moist material, wherein the particle size of the lump materials of the ash from the sintering furnace in the power station is 5 mm; 3, the moist material is pressed and formed into the baking-free brick through a baking-free brick forming machine under the pressure of 25 MPa; 4, natural drying and maintaining are conducted at the room temperature for four weeks through a water spray method. Compared with the prior art, according to the innovative preparation method of the heat-resistant baking-free brick, the ash from the sintering furnace in the power station serves as the main raw material, the method is beneficial for environmental friendliness, and the prepared baking-free brick has the advantages of being high in strength, high in heat-resistance temperature, high in adiabaticity, small in volume weight, high in specific strength and good in durability.

Description

A kind of heat-resisting non-burning brick innovation preparation method
Technical field
The present invention is the patent No. is 201310014176.8, the applying date is on 01 15th, 2013, name is called the divisional application of the patent of invention of " a kind of non-burning brick formula and preparation method thereof ", relates to a kind of non-burning brick, is specifically related to a kind of heat-resisting non-burning brick innovation preparation method。
Background technology
China is that brick body consumes big country, also it is the big producing country of brick body, common brick is traditional materials for wall, main with being raw material with arable land lower floor clay, after being built into cuboid adobe, in brickkiln, open fire calcination forms, this brick is the most frequently used construction material in current city and rural area, in order to protect the arable land day by day reduced, country has prohibited the production of clay brick, past, also once trial cement brick replaces clay brick, but the production of cement brick and use cost are higher, there is also simultaneously and self estimate one's own ability greatly, it is not suitable with the defect that skyscraper uses, recent year exploitation is a kind of non-burning brick, it is compressing after mainly adopting flyash and cement mixing, there is cost height in compressing non-burning brick of this employing flyash and cement mixing, intensity is low, poor durability, heat resisting temperature is low, anti-freezing property is bad, the defect of brick body weight。
China is the country based on combustion power generation, every year owing to combustion power generation can discharge substantial amounts of waste incineration residue, i.e. refuse-burning plant sintering ash, this garbage power calcium oxide causes serious pollution and harm, and containing the useful component such as part ferrum and calcium oxide in refuse-burning plant sintering ash, if able to recycle, a lot of valuable resource will be saved。
In view of this, drawbacks described above is furtherd investigate by the present inventor, is then produced by this case。
Summary of the invention
The present invention proposes a kind of heat-resisting non-burning brick innovation preparation method, which solves power plant sintering ash processing cost high, the problem being unfavorable for environmental protection, utilize power plant sintering ash containing the brickmaking utility such as a small amount of iron powder and calcium oxide simultaneously, improve the intensity of brick, bridging property and adhesive so that the non-burning brick comprcssive strength made reaches 18.6Mpa, heat resisting temperature is 1016 DEG C, there is intensity height, heat resisting temperature is high, and thermal insulation is strong, and unit weight is little, specific strength is high, the advantage of good endurance。
For reaching above-mentioned purpose, the present invention is achieved by the following technical solutions: a kind of heat-resisting non-burning brick innovation preparation method, comprises the following steps:
One, sintering ash in power plant is pulverized: power plant sintering ash is crushed to the block that particle diameter is 5mm;
Two, dispensing stirring: be 32 parts and power plant that block is 5mm sintering ash and the cinder powder that weight portion is 22 parts by weight portion, weight portion is the normal sands of 23 parts, weight portion is the cement of 7 parts, weight portion is 5 parts and particle diameter is the calcium oxide of 5mm, weight portion is the calcium silicates of 4 parts, weight portion is the sodium sulfate of 1.2 parts, weight portion is the sodium silicate of 0.8 part, and weight portion is the water solublity unsaturated-resin of 4 parts and Testudinis powder that weight portion is 1.8 parts adds the water that weight portion is 12 parts and is mixed into the material of moist shape;
Three, compressing: to use Non-fired brick moulding machine by compressing non-burning brick for the material of above-mentioned moist shape under the pressure of 25MPa;
Four, maintenance: by the spraying surrounding of natural drying maintenance at normal temperatures。
By adopting preceding solution, the invention has the beneficial effects as follows: it adopts power plant sintering ash to be primary raw material, and not only twice laid eliminates the sintering flying dust pollution to environment, is conducive to environmental protection;And containing the brickmaking utility such as a small amount of iron powder and calcium oxide in power plant sintering flying dust, iron powder is favorably improved the intensity of brick, and the sintering time of 6~8 hours can be shortened, calcium oxide can improve bridging property and the adhesive of brick, reduce the weight part ratio of non-burning brick required calcium oxide, reduce material cost;Adding water solublity insatiable hunger water fat in formula, water solublity unsaturated-resin further increases bridging property and the adhesive of brick, effectively reduces the consumption of calcium oxide, reduce further cost, improves intensity;Adding calcium silicates in formula it is modified, make the comprcssive strength of the product of gained reach 18.6Mpa, heat resisting temperature is 1016 DEG C, has heat resisting temperature height, and thermal insulation is strong, and unit weight is little, and specific strength is high, good endurance。
Detailed description of the invention
A kind of heat-resisting non-burning brick innovation preparation method of the present invention, comprises the following steps:
One, sintering ash in power plant is pulverized: power plant sintering ash is crushed to the block that particle diameter is 5mm;
Two, dispensing stirring: be 32 parts and power plant that block is 5mm sintering ash and the cinder powder that weight portion is 22 parts by weight portion, weight portion is the normal sands of 23 parts, weight portion is the cement of 7 parts, weight portion is 5 parts and particle diameter is the calcium oxide of 5mm, weight portion is the calcium silicates of 4 parts, weight portion is the sodium sulfate of 1.2 parts, weight portion is the sodium silicate of 0.8 part, and weight portion is the water solublity unsaturated-resin of 4 parts and Testudinis powder that weight portion is 1.8 parts adds the water that weight portion is 12 parts and is mixed into the material of moist shape;
Three, compressing: to use Non-fired brick moulding machine by compressing non-burning brick for the material of above-mentioned moist shape under the pressure of 25MPa;
Four, maintenance: by the spraying surrounding of natural drying maintenance at normal temperatures。
A kind of heat-resisting non-burning brick innovation preparation method of the present invention, it is with power plant sintering ash for primary raw material, and not only twice laid eliminates the sintering flying dust pollution to environment, is conducive to environmental protection;And containing the brickmaking utility such as a small amount of iron powder and calcium oxide in power plant sintering flying dust, iron powder is favorably improved the intensity of brick, and the sintering time of 6~8 hours can be shortened, calcium oxide can improve bridging property and the adhesive of brick, reduce the weight part ratio of non-burning brick required calcium oxide, reduce material cost;Adding water solublity insatiable hunger water fat in formula, water solublity unsaturated-resin further increases bridging property and the adhesive of brick, effectively reduces the consumption of calcium oxide, reduce further cost, improves intensity;Adding calcium silicates in formula it is modified, make the comprcssive strength of the product of gained reach 18.6Mpa, heat resisting temperature is 1016 DEG C, has heat resisting temperature height, and thermal insulation is strong, and unit weight is little, and specific strength is high, good endurance。

Claims (1)

1. a heat-resisting non-burning brick innovation preparation method, it is characterised in that: comprise the following steps:
One, sintering ash in power plant is pulverized: power plant sintering ash is crushed to the block that particle diameter is 5mm;
Two, dispensing stirring: be 32 parts and power plant that block is 5mm sintering ash and the cinder powder that weight portion is 22 parts by weight portion, weight portion is the normal sands of 23 parts, weight portion is the cement of 7 parts, weight portion is 5 parts and particle diameter is the calcium oxide of 5mm, weight portion is the calcium silicates of 4 parts, weight portion is the sodium sulfate of 1.2 parts, weight portion is the sodium silicate of 0.8 part, and weight portion is the water solublity unsaturated-resin of 4 parts and Testudinis powder that weight portion is 1.8 parts adds the water that weight portion is 12 parts and is mixed into the material of moist shape;
Three, compressing: to use Non-fired brick moulding machine by compressing non-burning brick for the material of above-mentioned moist shape under the pressure of 25MPa;
Four, maintenance: by the spraying surrounding of natural drying maintenance at normal temperatures。
CN201610153608.7A 2013-01-15 2013-01-15 Innovative preparation method of heat-resistant baking-free brick Pending CN105693156A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610153608.7A CN105693156A (en) 2013-01-15 2013-01-15 Innovative preparation method of heat-resistant baking-free brick

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610153608.7A CN105693156A (en) 2013-01-15 2013-01-15 Innovative preparation method of heat-resistant baking-free brick
CN201310014176.8A CN103922688B (en) 2013-01-15 2013-01-15 A kind of non-burning brick and making method

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CN105693156A true CN105693156A (en) 2016-06-22

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CN201610178055.0A Pending CN105859196A (en) 2013-01-15 2013-01-15 Method for preparing heat-resistant baking-free bricks
CN201310014176.8A Expired - Fee Related CN103922688B (en) 2013-01-15 2013-01-15 A kind of non-burning brick and making method

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Publication number Priority date Publication date Assignee Title
CN104402355A (en) * 2014-10-31 2015-03-11 福建省南安市荣达建材有限公司 Inorganic ceramic tile powder
CN106380115B (en) * 2016-08-30 2018-12-04 贵州安顺家喻新型材料股份有限公司 A kind of environmental protection brick and preparation method thereof
CN107129244A (en) * 2017-05-06 2017-09-05 安徽绿风环保节能材料有限公司 A kind of anti-ant grass-planting brick
CN109293309B (en) * 2018-10-26 2020-12-08 固克节能科技股份有限公司 Treatment method for production waste of water-based paint and heat-insulation decorative integrated plate
CN110540407B (en) * 2019-09-20 2022-04-15 鞍钢集团矿业有限公司 Porous water permeable brick fired by carbonate-containing iron tailings and firing method thereof

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CN101468905A (en) * 2007-12-28 2009-07-01 刘贵堂 Red mud unburned brick and preparation thereof
CN101486550A (en) * 2008-01-16 2009-07-22 新立基(北京)建材有限公司 Domestic garbage prefabricated part and method of manufacturing the same

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CN101289297A (en) * 2008-06-03 2008-10-22 钱海华 Process for making bricks by waste residue of smelting chromium irons
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Publication number Priority date Publication date Assignee Title
CN1226528A (en) * 1998-12-21 1999-08-25 李桓宇 Lightweight non-sintered bricks made from coal cinders
CN101468905A (en) * 2007-12-28 2009-07-01 刘贵堂 Red mud unburned brick and preparation thereof
CN101486550A (en) * 2008-01-16 2009-07-22 新立基(北京)建材有限公司 Domestic garbage prefabricated part and method of manufacturing the same

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CN103922688A (en) 2014-07-16
CN105859196A (en) 2016-08-17
CN103922688B (en) 2016-03-30

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