CN105688560A - Manufacturing method for improving coal economic value and using coal as dust reduction material - Google Patents

Manufacturing method for improving coal economic value and using coal as dust reduction material Download PDF

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Publication number
CN105688560A
CN105688560A CN201610105820.6A CN201610105820A CN105688560A CN 105688560 A CN105688560 A CN 105688560A CN 201610105820 A CN201610105820 A CN 201610105820A CN 105688560 A CN105688560 A CN 105688560A
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coal
ore
particle
absorption
dust
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侯英翔
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Priority to CN201610105820.6A priority Critical patent/CN105688560A/en
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Priority to CN201710088218.0A priority patent/CN107174867A/en
Priority to CN201710088876.XA priority patent/CN107129849A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D49/00Separating dispersed particles from gases, air or vapours by other methods
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/02Loose filtering material, e.g. loose fibres
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/02Treating solid fuels to improve their combustion by chemical means
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B7/00Respiratory apparatus
    • A62B7/10Respiratory apparatus with filter elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/30Particle separators, e.g. dust precipitators, using loose filtering material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/22Materials not provided for elsewhere for dust-laying or dust-absorbing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0407Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y02A50/2351Atmospheric particulate matter [PM], e.g. carbon smoke microparticles, smog, aerosol particles, dust

Abstract

The invention provides a manufacturing method for improving the coal economic value and using coal as a dust reduction material, and belongs to the technical field of national economic industries, coal industries, metal and non-metallic mine industries, cement production industries, dust polluted places and atmospheric pollution environmental control. The technical problems how to improve the heat productivity and other economic values of coal and how to use coal as the dust reduction material are solved. According to the scheme, coal in one area is used for adsorbing dust produced in the place, coal is prepared into nanometer materials to improve the heat productivity and other economic values of coal and carry out dust reduction, the chemical composition and chemical structure, the atom composition structure and the crystal composition structure of coal and the mixture in the coal are changed, the heat productivity and other economic values of coal are improved, the coal becomes the material capable of reducing dust, the surface property of coal mineral is changed, the heat productivity and other economic values of coal are improved, inherent moisture and ash content in coal are reduced, the volatile component of coal is improved, the carbon essence content in the coal is improved, and the dust reduction effect of coal is improved.

Description

Improve the economic worth of coal and the coal manufacture method as depositing dust material
Technical field: be applied to national economy every profession and trade and be applied to coal industry metallic ore and nonmetallic ore industry manufacture of cement industry atmospheric pollution environmental improvement
After background technology improves the economic worth of coal, national product ability can be effectively improved, gross national product is made to increase substantially, the improvement of current coal industry coal dust is not eradicated, metallic ore and the mine dust of generation in nonmetallic ore recovery process are also without fundamentally solving, under the situation that national economy is growing, building trade is the basic industry of national economy, required cement is in process of production, not only bring harm and potential safety hazard, and be discharged in air and produce atmospheric pollution, in the national economic development, required electric power major part coal generates electricity, coal produces a large amount of dust in power generation process, atmosphere pollution, therefore, it is necessary to find the administering method solving depositing dust problem better。
Summary of the invention 1. a certain area coal adsorbs the coal dust that another area coal produces, reach depositing dust effect, the mine dust produced when the mining of certain metallic ore produces is adsorbed with the coal in a certain area, reach depositing dust effect, adsorb, with a certain area coal, the mine dust produced when certain nonmetallic ore produces, reach depositing dust effect, adsorb, with coal, the dust use that the primary raw material of manufacture of cement produces in process of production, the diameter granule less than or equal to 2.5 microns in coal dust degraded earth atmosphere, reaches to administer air pollution depositing dust effect。
2. coal is made nanometer materials and improves the caloric value of coal and other economic worth of coal, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content, coal is made nanometer materials and carries out depositing dust。Set up the depositing dust character index system of complete coal, the power of the depositing dust character of coal is reflected by the granule size of coal and porosity size, Study on Coal particle diameter is more than the dust-laying effect of more than 1 millimeter coal, Study on Coal particle diameter is less than the dust-laying effect of less than 1 millimeter coal, administer the dust produced in chemical production processes, administer the dust produced in the timber course of processing, administer dirt and dust produced by steamed dumplings stalk。
3. increase porosity and the voidage of coal by artificial means, strengthen the dust-laying effect of coal。
4., when using coal as depositing dust material, according to the coal dust produced for certain areas coal, the mine dust that certain metallic ore produces, the mine dust that certain nonmetallic ore produces, the dust produced during manufacture of cement, need raw coal is carried out washing by the dust-laying effect of the depositing dust of raw coal,
5. change chemical composition and the chemical constitution of coal, improve the caloric value of coal and other economic worth of coal, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content, changing the chemical composition of coal and chemical constitution, making coal become can the material of depositing dust。
6. change the atom composition structure of the coal element of composition coal, change the crystal composition structure of raw coal, or atomic structure and crystal composition structure change, and improve the caloric value of coal and other economic worth of coal simultaneously, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content, change the atom composition structure of the coal element of composition coal, changing the crystal composition structure of raw coal, or atomic structure and crystal form structure and change simultaneously, making coal become can the material of depositing dust。
7. change chemical composition and the chemical constitution of mixture in coal, change the atom composition structure of mixture in coal, change the crystal composition structure of raw coal element, or atomic structure and crystal composition structure change simultaneously, change chemical composition and the chemical constitution of mixture in coal, improve the caloric value of coal and other economic worth of coal, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content, change the atom composition structure of mixture in coal, change the crystal composition structure of raw coal element, or atomic structure and crystal composition structure change simultaneously, making coal become can the material of depositing dust。
8. changing the surface nature of colliery thing, other economic worth of the caloric value and coal that improve coal changes the surface nature of colliery thing, reduces the inherent moisture of coal, reduces pit ash, improve the volatile matter of coal, improve carbon content in coal essence content, strengthens the dust-laying effect of coal。
Detailed description of the invention: 1. transport after a certain area coal being produced, transporting equipment has scratch board conveyor, belt conveyer, skip hoist, Automobile Transportation, train transports, Ship Transportation, means of transportation has highway transportation, railway transportation, water-borne transport, aircraft dispatch, after the coal that a certain area produces is transported to another area, another Areas For Coal is carried out depositing dust at the coal dust produced in process of production, or another area mine dust of producing in process of production of certain metallic ore is carried out depositing dust, or another area mine dust of producing in process of production of certain nonmetallic ore is carried out depositing dust, or the dust produced in another area cement production process is carried out depositing dust, or the dust that chemical materials produced in process of production carries out depositing dust, or the dust produced in steamed dumplings stalk and wood production process is carried out depositing dust, or control atmosphere pollution, administer the dust of PM2.5 in air and carry out depositing dust, can adopt and the place of required depositing dust is sprayed by the coal particle developed or coal dust, or spray, or spray, device therefor can use jetting machine, spraying equipment, spray with aircraft。
2. coal is made nanometer materials can use prior art in factory or experiment indoor production, coal is prepared into nano level superfine material available mechanical comminuting method, gas evaporation method, solwution method, Laser synthesizing method, plasma synthesis method, x ray irradiation x synthetic method, sol-gel process etc., gas evaporation method is a kind of physical method, by coal heating raw materials, evaporation, make atom or molecule, make many atoms or molecule cohesion again, form imperceptible coal nano-particle, evaporation is prepared coal nano-particle and can be divided into, vacuum vapor deposition method, gas evaporation method, by heating evaporation technological means, electrode can be divided into evaporate evaporation, high-frequency induction evaporates, electron beam evaporation, plasma evaporation, laser beam evaporation etc.,
Coal is made nanometer materials by available supercritical fluid method, mainly comprising the following steps of preparation, and first, prepare the alcoholic solution of alkoxide, metering adds water again, so as to hydrolyze to form colloidal sol or gel, and second, the glue made is moved in autoclave, seal and heat up, make solvent reach supercriticality, now release solvent and the water extracted, 3rd, with the solution of the quiet remained on surface of inert blowing gas
Coal is made nanometer materials by using plasma spray body method, utilize plasma torch can produce the feature of 50000K high temperature, the hurried cooling of ejection coal of this spray gun just can be generated coal nanometer materials, plasma jet can realize cracking, synthesis, nitrogenize and react with oxidoreduction etc., if the product of reaction is cooled down suddenly, it is also possible to make ultramicron。
3. the method for coal mineral surface modification has (1) surface coating modification method, namely by adhesion, the method that modifying agent (Organic substance or inorganic matter) is covered in coal mineral particle, is used as the Kaolin of filler, Muscovitum by naturally occurring or synthetic rubber processing, ball clay, or it is coated in coal particle surface with phenolic resin or furane resins, the caking property of coal, many inorganic oxides or hydroxide can be improved, as, TiO2, SiO2, Al (OH)2There is respective zero point pH value。By controlling the pH value of solution, absorption surface activating agent makes coal particle surface modifiy, (2) can also be used with surface chemical modification method, modifying agent and some functional group of mineral surfaces is utilized to carry out chemical reaction or chemisorbed, reach the purpose that coal particle surface is modified, in this kind of method of modifying, it is made by stronger bonding force (such as covalent bond) between coal particle and modifying agent to have an effect, (3) can also be used with mechanical-chemical modification method, namely by pulverizing, grind, the mechanical means such as friction, make mineral lattice structure, crystal formations etc. change, can increase in system, temperature raises, promote particle to melt or decompose or produce free radical or ion, strengthen coal particle surface activity, promote coal particle and other material generation chemical reaction or mutually adhere to, reach the purpose of surface modification, (4) the modified method of available precipitation, during using inorganic matter as modifying agent, the method utilizes the precipitation between modifying agent, coal particle surface deposits one or more layers modified layer, to change coal particle surface character, (5) modified (capsule) method of theca externa, namely at the thin film of coal particle surface bag other material of last layer, , the theca externa wrapped is uniform, shape is capsule such as, it has protection core substance, regulate, release the function of core material, blend compounds encapsulated changes appearance and the character of coal particle, capsule-type prepares method mainly spray coating, spray drying, interfacial polymerization, it is separated and dissolves dispersion cooling method, make the material of capsule wall except organic polymer beyond the region of objective existence, inorganic substances have TiO2, AL2O3, Fe2O3, ZnO and silicates, glue core material has magnesium carbonate, aluminium silicate, sodium hydrosulfite or other gaseous state, liquid。(6) coal particle surface is modified by the means such as the modified method of high energy surface, utilizes plasma, corona discharge, ultraviolet。
Coal surface modification device has (1) bulk material mixer, has mixed stirring device, including container rotating type, (2) high velocity air impact type powder modifying devices such as container fixed pattern and air-flow mixed type, this system is by mixer, metering system, main frame, product collecting device, control system is formed, and main frame is by the rotor of high speed rotating, the parts such as stator and closed circuit form, there are chuck, cooling or heating rotor use between stator and rotor, in rotor, have fin。(3) surface modification is held concurrently reducing mechanism
Evaluation to coal particle surface modified effect, carries out the measurement of some physicochemical properties and surface characteristic to coal particle, compares the change of coal particle depositing dust absorption index after before modified, reaches to evaluate the purpose of modified effect。Basic skills has (1) moist (2) dispersibility (3) infrared spectrum, as long as there is certain functional group or key in coal surface, mineral spectrogram just has corresponding characteristic absorption peak, so, to after before modified and modified after carry out infrared spectrum analysis through the coal particle sample of various process, change according to character pair peak, just can disclose effect and the mechanism of surface modifier。(4) X-ray diffraction, the mixture solid structure of matter in Study on Coal particulate solid material structure and coal, available X-ray diffraction method。Can be used to coal Polycrystalline make Discriminating materials and lattice parameter mensuration, monocrystal X-ray is done structure determination and crystal integrity research (5) heat is analyzed, heat is analyzed and is included differential thermal and calorimetric analysis, differential thermal analysis is used for investigating coal particle in heating process, when reaching certain temperature, due to the heat effect that phase transformation or some chemical reaction produce, analyzing, there is exothermic peak or absworption peak in curve, the size of peak area reflects the power of heat effect, thermogravimetric analysis can measure the change as temperature or the material mass of time function, when carrying out heat and analyzing, generally by two kinds of heat analysis method couplings。(6) solid surface analysis technology is utilized, utilize surface Spectrum Analysis technology, can reveal that the composition of coal particle surface, the much information such as ionic valence condition and chemical bond, combine with scanning detecting probe method by static secondary ion mass spectrum, the absorption specimen of detection coal particle, utilize polyether-type nonionic dispersant, adopt X-ray electronic energy to borrow and add argon ion etching device, measure coal particle and Additive front and rear surfaces characteristic atomic valence state and energy variation, and the feature according to instrument, calculate the thickness of dispersant adsorption film on surface
Coal surface modifier has coupling agent, surfactant, polymer class and Inorganic surface modifiers。
The series such as coupling agent is siliceous or metallic atom organic compound, different by central atom, has a silane system, titanate esters system, Aluminate system, stannic acid ester system, aluminum zirconate system
4. some coals belong to crystal structure, as in Guizhou, Sichuan, the coal particle in some areas in Xinjiang belongs to crystal structure, mechanical force brings out the change of coal mineral crystal structure, coal carries out mechanical force to carry out crushing and grinding to coal, coal solid particle is under mechanical force, produce various physics and chemical phenomenon, not only the size of granule tapers into, specific surface area constantly increases, its internal structure, also correspondingly there is a series of change in physicochemical properties and chemical reactivity, coal particle is in crushing process, under executed mechanical energy effect, coal particle crystal structure also experiences quantitative change to qualitative change process, quantitative change and coal particle are in thinning process, crystalline size constantly diminishes, specific surface area is continually changing, surface and internal flaw, decrystallized progressively aggravate, may finally cause that coal crystalline solid becomes amorphous material, carrying out coal crushing and grind can at Coal Mining Field, coal preparation plant, depositing dust coal production plant or laboratory implement, the equipment that coal uses mechanical force has boulder crusher, jaw crusher, duplex plate Bu Laike disintegrating machine, single toggle crusher, gyratory crusher, coal crushes spendable equipment further have, garden conic crusher, disc type gyratory crusher, Rhonda disintegrating machine, kibbler roll, impact crusher, Ba Make disintegrating machine, roll crusher,
Coal carries out levigate use equipment have, in the process of raw coal mill, plant equipment used has, various grinding machines, rotating cylinder grinding machine, rod mill, ball mill, autogenous tumbling mill, vibrating mill, centrifugal mill, tower mill, Ball-stirring mill, agitated medium sand setting grinding machine, roll squeezer, overhang roll type mill, the change that coal crystal structure and character occur has situations below (1) coal crystal lattice distortion, mechanical impact force, shearing force, pressure all can cause coal crystal deformation, by X-ray diffraction analysis, infrared spectrum, the means such as differential thermal analysis can verify deformation degree, (2) coal particle is decrystallized, effect due to mechanical force, the crystal structure of crystallization coal particle surface is subject to strong destruction and forms amorphous layer, with proceeding of pulverizing, amorphous layer is thickening, finally result in whole crystalline particle amorphization, coal crystal grain amorphization is promoted in mechanical activation comminution effect, its intensity of variation and coal-grinding mode, the coal-grinding time, by relevant (3) the coal crystal conversion of the conditions such as coal-grinding size, coal is at normal temperatures by the effect of mechanically deform power, the transformation of crystal formation can be there is, crystal conversion in crushing process, it is owing to amorphization occurring in pulverizing miniaturization process, middle junction crystalline substance equivalent state, system free energy is made to increase, form unstable phase, simultaneously in compression, shear, bending, under the constantly effect of the power such as extension, when its energy exceedes the crystallization activation energy of phase in version, then complete the transformation of crystal formation, (4) coal crystal structure overall structure deformation, in mechanical milling processes, , due to Mechanosensitive channels, also can make the bulk deformation of colliery thing generation crystal structure, this change occurs mainly in other mixture having in the colliery material of layer structure or together with raw coal, layer structure crystal, in crushing process, owing to the religion of interlayer particle adhesion is weak, then under the effect of shearing force, first cleave out abreast along aspect, become the structure that degree of crystallinity religion is low, if continuing to pulverize, fluorine in coal or other mixture together with raw coal finally lose crystal structure, it is gradually completing integrally-built change。
Some coal particles belong to amorphous mineral, the change of noncrystal coal particle is substantially different from the change of crystal coal particle, under stress effect, dislocation moves and spreads and noncrystalline coal particle solid all can be caused hardening, noncrystalline coal particle dislocation motion can pass through polarized light detection, and the interaction between noncrystalline coal particle oscillating movement and dislocation can cause material unordered or ordering。
Colliery composition granule is in crushing process, mechanical force can be brought out coal particle and be produced the change of series of physical chemical property, (1) change of dispersion, the method characterizing coal particle dispersion is to measure the specific surface area of coal body system, start the dispersion of coal particle during coal-grinding linear with the ore grinding time, the specific surface area of coal particle and ore grinding time exponentially relation afterwards, after again, the dispersion increment of coal particle is negative value, there is the unsaturated field of force and charged construction unit in coal particle surface, coal particle is made to be in the upper state of instability, just reunite under more weak graviational interaction, make granule thicker, fine grinding, crystal structure caused by Ultrafine Grinding, a series of mechanical force and chemical phenomenon such as physicochemical properties and chemical reaction occurs mainly in this stage。(2) dissolubility and rate of dissolution, after the refinement of coal solid particle, the dissolubility of coal increases with rate of dissolution, after coal particle refinement, the mechanical activation effect of coal also there is impact (3) variable density, dry method coal-grinding granule, coal mineral density reduces, wet grinding mill coal particle, coal mineral density reduces, (4) the electrical change of coal particle, Mechanosensitive channels changes coal particle electric conductivity, the absorbability of surface electrical behavior and semiconductor property (5) coal particle surface, coal particle is crushed, the plane of disruption occurs unsaturated bond and charged construction unit, cause that coal particle is in the upper state of instability, thus increasing coal particle activity, improve surface adsorption ability, mechanical activation effect promotes that the raising (6) of colliery thing surface adsorption causes the change (7) of the exchange of coal particle mineral ion or diadochy to cause the change of coal particle surface free energy
5. pair coal solid particle applies light, electricity, magnetic, heat, the energy of the forms such as radiation, cause the change of coal particle chemistries, coal particle molecular structure is caused to change, coal particle atomic structure is caused to change, coal particle crystal structure is caused to change, the coal after change is enable to improve the caloric value of coal and other economic worth of coal, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content, at factory and use for laboratory existing equipment in the present age and instrument, coal solid particle can be applied light, electricity, magnetic, heat, the energy of the forms such as radiation
The coal particle after change is made to have depositing dust character, coal solid particle applying light intensity is reached 10cd and is called for short light intensity with intensity of light, iu is that candela (candela) writes a Chinese character in simplified form cd, coal solid particle is applied electric intensity and reaches 10V/m or more than 10N/C, unit lies prostrate every meter (V/m) or the every storehouse of cattle (N/C), coal solid particle applying magnetic intensity is reached 10GS or more than 10T magnetic induction unit and has Gauss (GS), milli special (mT), tesla (T), coal solid particle applies calorific intensity and reaches more than 100Kcal, or more than 1 (kw), kilocalorie (Kcal), ton evaporation capacity (t), watt (w), kilowatt (kw), coal solid particle is applied radiant intensity and reaches 10W/m2Above, radiant force refers to the total amount of the radiant energy of whole wavelength that object per surface area is launched in the unit interval to half all directions, spherical space, and its conventional unit is W/m2, the equipment that coal applies light intensity has, solid-state gyrolaser, high-pressure microwave plasma exciter, the equipment that to coal, coal is applied electric intensity has, strengthen suspendability charging liquids equipment, the equipment that to coal, coal is applied magnetic intensity has, magnaflux applies method and the circumferential magnetization of magnetic field intensity, the equipment that coal applies calorific intensity has, high frequency firing equipment, high frequency is to utilize electromagnetic field of high frequency to make the intermolecular mutual fierce collision of internal batch produce high temperature, the equipment that coal applies radiant intensity has, change the equipment of the local strength of X-radiation, this equipment includes filling the absorption chamber with ferrofluid with multiple, x-ray filter, absorption chamber, X-radiation direction is stackably arranged。Additionally, x-ray filter includes multiple storage container that can store ferrofluid in it。
6.. coal solid particle is under mechanical force, cause the change of coal particle chemistries, mechanical force and light, electricity, magnetic, heat, the energy of the forms such as radiation is the same, the change of chemistries can also be caused, the chemical reaction of the material that this mechanical force is brought out, it is called mechano-chemical reation, coal carries out mechanical force to carry out crushing and grinding to coal, carrying out coal crushing and grind can at Coal Mining Field, coal preparation plant, depositing dust coal production plant or laboratory implement, the equipment that coal uses mechanical force has boulder crusher, jaw crusher, duplex plate Bu Laike disintegrating machine, single toggle crusher, gyratory crusher, coal crushes spendable equipment further have, garden conic crusher, disc type gyratory crusher, Rhonda disintegrating machine, kibbler roll, impact crusher, Ba Make disintegrating machine, roll crusher, coal carries out levigate use equipment have, in the process of raw coal mill, plant equipment used has, various grinding machines, rotating cylinder grinding machine, rod mill, ball mill, autogenous tumbling mill, vibrating mill, centrifugal mill, tower mill, Ball-stirring mill, agitated medium sand setting grinding machine, roll squeezer, overhang roll type mill,
7. owing to the primordial matter of coal-forming is different with the palegeology condition of coal-forming, difference due to the initial material of coal-forming and the difference of biochemical action and geochemical factor and the micro-composition of coal petrography, composition and the character of the various coal in different regions have very big-difference, coal is uneven mixture, it is made up of organic substance and inorganic substances two parts, composition and the character of coal and other mineral have very big-difference, mineral are the aggregations that in nature, metal or nonmetallic compound are formed, and metallic ore refers to through smelting the mineral products that can therefrom extract metallic element。Such as ferrous metal mineral products: ferrum, manganese, chromium, vanadium, titanium etc. are the mineral products being used as steel and iron industry raw material。Nonferrous metal ore includes: copper, stannum, zinc, nickel, cobalt, tungsten, molybdenum, hydrargyrum etc.。Noble metal includes: platinum, rhodium, gold, silver etc.。Light metal mineral products include: aluminum, magnesium etc.。Rare metal mineral products include: lithium, beryllium, rare earth etc.。The common feature of most mineral metal products is mainly manifested in the aspects such as quality is harder, glossy。Mineral metal products can be divided into 5 kinds by its Matter Composition, character and purposes: ferrous metal mineral products, nonferrous metal ore, noble metal mineral products, title have dispersed elements mineral products, semimetal mineral products, nonmetallic ore is with metallic ore comparatively speaking, there are 91 kinds, are mainly diamond, graphite, crystal, corundum, asbestos, Muscovitum, Gypsum Fibrosum, fluorite, gem, jade, Achates, limestone, dolomite
The character of coal is divided into physical property, chemical composition, processing performance and combustibility etc., when the depositing dust character of Study on Coal, answering the chemical composition of Study on Coal and the atomic structure feature of institute's component, the physical property of coal includes coal petrography composition, color, gloss, density, hardness, electric conductivity, heat conductivity, thermostability, magnetic, granularmetric composition, argillization degree
The chemical composition of coal includes elementary composition and Industrial Analysis, coal is the humatite changed by plant remains, it is elementary composition sufficiently complex, coal is mainly by carbon, oxygen, hydrogen, nitrogen, sulfur, 6 kinds of phosphorus is elementary composition, possibly together with a small amount of fluorine, chlorine, arsenic, boron, plumbous, the elements such as hydrargyrum, and the germanium of trace, gallium, vanadium, the rare elements such as uranium, the Industrial Analysis of coal is in order that understand Coal Quality, judge kind and the processing and utilization approach of coal, including the moisture measuring coal, ash, volatile matter and fixed carbon, , moisture according to coal and ash can substantially understand the percentage composition of wherein organic substance or combustible, moisture and ash such as coal are high, then the content of organic matter is just few, thus caloric value is low, economic worth is little, character organic coal can be substantially recognized from the volatile matter of coal, the height of degree of coalification, the height of close-burning power and caloric value, its degree of coalification can be substantially judged from the fixed carbon content of coal, evaluate its economic worth,
The processing performance of coal includes the cohesiveness of coal, caloric value, chemism, heat stability, grindability, paste-forming properties,
The Industrial Analysis of coal is to understand Coal Quality, judge kind and the processing and utilization approach of coal, including the moisture measuring coal, ash, volatile matter, with 4, fixed carbon, moisture and ash according to coal can substantially understand the percentage composition of organic substance or combustible in coal, moisture and ash such as coal are high, then the content of organic matter is just few, thus caloric value is low, (1) moisture, the moisture of coal has inherent moisture and free moisture two kinds, free moisture refers in exploitation, transport, washing process is attached to the water in coal particle surface and crack, inherent moisture refers to absorption or condenses upon the water in coal particle internal capillary hole, moisture is more high, the economic worth of coal is more low, coal is being stored by the moisture of coal, transport, processing and utilizing all have impact (2) pit ash refer to coal burn completely after the productivity of residue, pit ash is divided into fixed ash and external ash two kinds, fixed ash refers to the dirt that coal is mixed in coalification course, external ash refers to that coal is in exploitation, transport, the dirt being mixed in storage process, i.e. spoil, it can be removed by washing method, pit ash is more high, quality is more poor, caloric value is more low, high processing and the utilization to coal of pit ash has adverse effect (3) volatile matter, the volatile matter of coal refer to coal with the container of air exclusion under certain high temperature, be heated to certain time after, the liquid (steam condition) decomposing out from coal and gas deduct the product after its moisture, the volatile matter of coal is more high, the degree of coalification of coal is more low, burning is more easily lighted (4) fixed carbon, the fixed carbon of coal refer to coal completely cut off air when Organic substance pyrolytic after remaining residual substance deduct its ash after product, main component is carbon, the degree of coalification of coal is may determine that according to fixed carbon content, fixed carbon content is more high, volatile matter is more low, degree of coalification is more high, fixed carbon content is high, the caloric value of coal is also more high, the processing performance of coal includes the cohesiveness of coal, caloric value, chemism, heat stability, grindability, paste-forming properties, the classification of coal, , the classification of coal is adopted different standards by countries in the world, China standard GB/T 5751-2009 " Chinese Coal Classification " is the standard using degree of coalification and processing performance as classification, coal is divided into anthracite, bituminous coal and brown coal three major types, anthracite makes the index of degree of coalification to distinguish anthracitic group with dry ash free basis volatile matter and dry ash free basis hydrogen content, namely smokeless No. one, smokeless No. two and smokeless No. three。
Bituminous coal adopts two parameters to determine classification, a parameter being to characterize bituminous coal degree of coalification, and another is to characterize the close-burning parameter of bituminous coal, the parameter of bituminous coal degree of coalification adopts dry ash free basis volatilization to be allocated as index, and the close-burning parameters selection caking index of bituminous coal and maximum thick ness of plastic layer or Ah's swelling degree difficult to understand distinguish classification as index, i.e. meager coal, meager lean coal, lean coal, coking coal, rich coal, gas rich coal, bottle coal, in glutinous coal, non caking coal, jet coal
The composition and the character that utilize the various coal in different regions have very big-difference, the magnetic of coal particle is different or contrary, the positive magnetic in a certain ribbing, area, another negative magnetic in ribbing, area, or the negative magnetic in ribbing, a certain area, another positive magnetic in ribbing, area, the electrically difference or contrary of coal particle, ribbing, a certain area positive electricity, another ribbing, area negative electricity, or ribbing, a certain area negative electricity, another ribbing, area positive electricity, the coal in a certain area can adsorb another area coal, reach depositing dust effect, obtain a certain area coal and adsorb the coal dust that another area coal produces, shanxi coal transports to the Inner Mongol, coal dust produced by the shungite of shanxi coal absorption Inner Mongol, or Inner Mongol shungite transports to Shanxi, coal dust produced by the shungite absorption shanxi coal of Inner Mongol, shanxi coal transports to Shaanxi, coal dust produced by the coal of shanxi coal absorption Shaanxi, or Shaanxi coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Shaanxi, shanxi coal transports to Xinjiang, coal dust produced by the coal of shanxi coal absorption Xinjiang, or Xinjiang coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Xinjiang, shanxi coal transports to Guizhou, coal dust produced by shanxi coal absorption Guizhou coal, or Guizhou coal transports to Shanxi, coal dust produced by Guizhou coal absorption shanxi coal, shanxi coal transports to Ningxia, coal dust produced by the coal of shanxi coal absorption Ningxia, or Ningxia coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Ningxia, shanxi coal transports to Shandong, coal dust produced by the coal of shanxi coal absorption Shandong, or Shandong coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Shandong, shanxi coal transports to Yunnan, the coal dust that shanxi coal absorption Yunnan coal produces, or Yunnan coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Yunnan, shanxi coal transports to Henan, coal dust produced by the coal of shanxi coal absorption Henan, or Henan coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Henan, shanxi coal transports to Anhui, coal dust produced by the coal of shanxi coal absorption Anhui, or Anhui coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Anhui, shanxi coal transports to Heilungkiang, coal dust produced by the coal of shanxi coal absorption Heilungkiang, or Heilungkiang coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Heilungkiang, Shaanxi transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Shaanxi, Inner Mongol, or Shaanxi coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Shaanxi, Xinjiang transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Xinjiang, Inner Mongol, or Xinjiang coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Xinjiang, Guizhou transported to by Inner Mongol shungite, coal dust produced by the shungite absorption Guizhou coal of Inner Mongol, or Guizhou coal transports to the Inner Mongol, coal dust produced by the shungite of Guizhou coal absorption Inner Mongol, Ningxia transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Ningxia, Inner Mongol, or Ningxia coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Ningxia, Shandong transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Shandong, Inner Mongol, or Shandong coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Shandong, Yunnan transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Yunnan, Inner Mongol, or Yunnan coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Yunnan, Henan transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Henan, Inner Mongol, or Henan coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Henan, Anhui transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Anhui, Inner Mongol, or Anhui coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Anhui, Heilungkiang transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Heilungkiang, Inner Mongol, or Heilungkiang coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Heilungkiang, Shaanxi coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Shaanxi, or Xinjiang coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Xinjiang, Shaanxi coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Shaanxi, or Guizhou coal transports to Shaanxi, coal dust produced by the coal of Guizhou coal absorption Shaanxi, Shaanxi coal transports to Ningxia, coal dust produced by the coal of coal absorption Ningxia, Shaanxi, or Ningxia coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Ningxia, Shaanxi coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Shaanxi, or Shandong coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Shandong, Shaanxi coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Shaanxi, or Shandong coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Shandong, Shaanxi coal transports to Yunnan, coal dust produced by the coal of coal absorption Yunnan, Shaanxi, or Yunnan coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Yunnan, Shaanxi coal transports to Henan, coal dust produced by the coal of coal absorption Henan, Shaanxi, or Henan coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Henan, Shaanxi coal transports to Anhui, coal dust produced by the coal of coal absorption Anhui, Shaanxi, or Anhui coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Anhui, Shaanxi coal transports to Heilungkiang, coal dust produced by the coal of coal absorption Heilungkiang, Shaanxi, or Heilungkiang coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Heilungkiang, Xinjiang coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Xinjiang, or Guizhou coal transports to Xinjiang, coal dust produced by the coal of Guizhou coal absorption Xinjiang, Xinjiang coal transports to Ningxia, coal dust produced by the coal of coal absorption Ningxia, Xinjiang, or Ningxia coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Ningxia, Xinjiang coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Xinjiang, or Shandong coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Shandong, Xinjiang coal transports to Yunnan, coal dust produced by the coal of coal absorption Yunnan, Xinjiang, or Yunnan coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Yunnan, Xinjiang coal transports to Henan, coal dust produced by the coal of coal absorption Henan, Xinjiang, or Henan coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Henan, Xinjiang coal transports to Anhui, coal dust produced by the coal of coal absorption Anhui, Xinjiang, or Anhui coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Anhui, Xinjiang coal transports to Heilungkiang, coal dust produced by the coal of coal absorption Heilungkiang, Xinjiang, or Heilungkiang coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Heilungkiang, Guizhou coal transports to Ningxia, coal dust produced by the coal of Guizhou coal absorption Ningxia, or Ningxia coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Ningxia, Guizhou coal transports to Shandong, coal dust produced by the coal of Guizhou coal absorption Shandong, or Shandong coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Shandong, Guizhou coal transports to Yunnan, coal dust produced by the coal of Guizhou coal absorption Yunnan, or Yunnan coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Yunnan, Guizhou coal transports to Henan, coal dust produced by the coal of Guizhou coal absorption Henan, or Henan coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Henan, Guizhou coal transports to Anhui, coal dust produced by the coal of Guizhou coal absorption Anhui, or Anhui coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Anhui, Guizhou coal transports to Heilungkiang, coal dust produced by the coal of Guizhou coal absorption Heilungkiang, or Heilungkiang coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Heilungkiang, Ningxia coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Ningxia, or Shandong coal transports to Ningxia, coal dust produced by the coal of coal absorption Ningxia, Shan
Utilize the difference of coal and metallic ore composition and character, the composition and the character that utilize the various coal in different regions have very big-difference, the magnetic of coal particle is different from certain metallic ore or contrary, the positive magnetic in a certain ribbing, area, certain metal mine belt bears magnetic, or the negative magnetic in ribbing, a certain area, certain positive magnetic of metal mine belt, coal particle electrically different from certain metallic ore or contrary, ribbing, a certain area positive electricity, certain metallic ore is electronegative, or ribbing, a certain area negative electricity, certain metallic ore positively charged, the mine dust that the coal in a certain area produces when can adsorb the mining of certain metallic ore, reach depositing dust effect, iron mine is adsorbed with shanxi coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Inner Mongol shungite, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Shaanxi coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Xinjiang coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Guizhou coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Ningxia coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Shandong coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Yunnan coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Henan coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Anhui coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Heilungkiang coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect,
Utilize the difference of coal and nonmetallic ore composition and character, the composition and the character that utilize the various coal in different regions have very big-difference, the magnetic of coal particle is different from certain nonmetallic ore or contrary, the positive magnetic in a certain ribbing, area, another certain nonmetal mine belt bears magnetic, or the negative magnetic in ribbing, a certain area, another certain positive magnetic of nonmetal mine belt, coal particle electrically different from certain nonmetallic ore or contrary, ribbing, a certain area positive electricity, another certain nonmetallic ore is electronegative, or ribbing, a certain area negative electricity, another certain nonmetallic ore positively charged, obtain a certain area coal and adsorb the mine dust that certain nonmetallic ore produces, reach depositing dust effect, Diamond Deposit is adsorbed with shanxi coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, with shungite ADSORPTION OF GOLD hard rock ore deposit, Inner Mongol, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Shaanxi coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Xinjiang coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Guizhou coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Ningxia coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Shandong coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Yunnan coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Henan coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Anhui coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Heilungkiang coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, in manufacture of cement, utilize composition and the nature difference of the various coal in different regions, the magnetic of coal particle is different or contrary from the primary raw material magnetic of manufacture of cement, the positive magnetic in a certain ribbing, area, magnetic born by the primary raw material band of manufacture of cement, or the negative magnetic in ribbing, a certain area, the positive magnetic of primary raw material band of manufacture of cement, coal particle is electrically different or contrary from the primary raw material of manufacture of cement, ribbing, a certain area positive electricity, the primary raw material of manufacture of cement is electronegative, or ribbing, a certain area negative electricity, the primary raw material positively charged of manufacture of cement, the coal in a certain area can adsorb the dust that the primary raw material of manufacture of cement produces in process of production, reach depositing dust effect, obtain the dust that the primary raw material of a certain area coal absorption manufacture of cement produces in process of production, the limestone that it is main component with calcium carbonate that calcareous raw material refers to, marl, Chalk and shell etc., limestone is the primary raw material of manufacture of cement, clay raw material mainly provides a small amount of composition in clinker, natural clay raw material has loess, clay, shale, siltstone and river silt etc., wherein loess and clay are with the most use, in addition, also has flyash, the industrial residues such as gangue, clay matter is finely divided sedimentary rock, it is made up of different minerals and other hydrated aluminium silicates, limestone in cement production process is adsorbed with shanxi coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Inner Mongol shungite, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Shaanxi coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Xinjiang coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Guizhou coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Ningxia coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Shandong coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Yunnan coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Henan coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Anhui coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Heilungkiang coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect,
With the diameter granule less than or equal to 2.5 microns in coal dust degraded earth atmosphere, reach to administer air pollution depositing dust effect, with the diameter granule less than or equal to 2.5 microns in coal particle degraded earth atmosphere, reach to administer air pollution depositing dust effect, the diameter of coal dust is less than 1 millimeter, and the diameter of coal particle is more than 1 millimeter。
8. according to claim 3, claim 5, claim 6, claim 7, coal described in claim 8 is as the manufacture method of depositing dust material, coal is made to have depositing dust character, some other material is had adsorption by the depositing dust property list of coal now, the depositing dust character of adsorbing power coal is described, set up the depositing dust character index system of complete coal, the power of the depositing dust character of coal is reflected by the granule size of coal and porosity size, Study on Coal particle diameter is more than the dust-laying effect of more than 1 millimeter coal, Study on Coal particle diameter is less than the dust-laying effect of less than 1 millimeter coal, with coal particle as depositing dust material, coal particle includes the drop in the emulsion made with coal, with the bubble of the liquid that coal is made, the solids of coal, the particle diameter of coal particle is more than more than 1 millimeter, with coal dust body as depositing dust material, coal dust body includes the drop in the emulsion made with coal, with the bubble of the liquid that coal is made, the solids of coal, the particle diameter of coal dust body is less than less than 1 millimeter, coal particle is more little, dissolubility is more big, fusing point is more low, chemical potential is more high, the light of fine Coal granule, electricity, magnetic, peculiar change can be there is in the features such as heat, coal dust body is solid time static, quasi-fluid when being filled with air, there is again when being suspended in gas some character of gas, when making depositing dust material with coal, change the size of coal particle, such as coal particle particle diameter more than 1 millimeter, coal particle particle diameter more than 1.5 millimeters, coal particle particle diameter 2 millimeters is with first-class, the dissolubility of coal, fusing point, the change of the chemical potential impact on the dust-laying effect of coal, change the size of coal dust body, such as coal diameter of particle less than 1 millimeter, coal diameter of particle less than 0.5 millimeter, coal diameter of particle, less than 0.05 millimeter, coal diameter of particle less than 0.01 millimeter, coal diameter of particle, less than 0.001 millimeter, coal diameter of particle, when less than 0.0001 millimeter, the light of coal, electricity, magnetic, the changing features impacts on the dust-laying effect of coal such as heat, change the feature of coal particle diameter and coal dust body, reach to attract each other between coal and coal or adsorb, or attract and adsorb to occur simultaneously, reach to attract each other between mine dust and dust produced by coal and metallic ore or adsorb, or attract and adsorb to occur simultaneously, , reach to attract each other between mine dust and dust produced by coal and nonmetallic ore or adsorb, or attract and adsorb to occur simultaneously, reach to attract each other between dirt and dust produced by coal and steamed dumplings stalk or adsorb, or attract and adsorb to occur simultaneously, attract each other between produced dirt and dust when reaching coal and make cement or adsorb, or attract and adsorb to occur simultaneously, attract each other between produced dirt and dust when reaching coal and make chemical materials or adsorb, or attract and adsorb to occur simultaneously, attract each other between produced dirt and dust when reaching coal and make timber or adsorb, or attract and adsorb to occur simultaneously, attract each other between produced dirt and dust when reaching coal and make other material or adsorb, or attract and adsorb to occur simultaneously。
9. coal is made nanometer materials and improves the caloric value of coal and other economic worth of coal, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content, coal is made nanometer materials and carries out depositing dust, increase porosity and the voidage of coal by artificial means, strengthen the dust-laying effect of coal, when coal is made nanometer materials, add carbon, carbon also makes nanometer materials, make carbon atom make nanometer materials with coal to mix mutually, improve the caloric value of coal, coal nano material refers to that coal particle is of a size of nano level superfine material, its size is between molecule, between atom and bulk material, refer to the small coal pressed powder within the scope of 1 to 100nm, namely this small coal pressed powder size is (10-nRice, n=7) to (10-nRice, n=9) between, coal is prepared into nano level superfine material available mechanical comminuting method, gas evaporation method, solwution method, Laser synthesizing method, plasma synthesis method, x ray irradiation x synthetic method, sol-gel process etc.,
Gas evaporation method is a kind of physical method, by coal heating raw materials, evaporation, make atom or molecule, then make many atoms or molecule cohesion, form imperceptible coal nano-particle, evaporation is prepared coal nano-particle and can be divided into, vacuum vapor deposition method, gas evaporation method, by heating evaporation technological means, electrode can being divided into evaporate evaporation, high-frequency induction evaporates, electron beam evaporation, plasma evaporation, laser beam evaporation etc.
Coal is made nanometer materials by available supercritical fluid method, mainly comprising the following steps of preparation, and first, prepare the alcoholic solution of alkoxide, then metering adds water, so as to hydrolyze to form colloidal sol or gel, second, the glue made is moved in autoclave, seals and heat up, make solvent reach supercriticality, now release solvent and the water extracted, 3rd, with the solution of the quiet remained on surface of inert blowing gas
Coal is made nanometer materials by using plasma spray body method, utilize plasma torch can produce the feature of 50000K high temperature, the hurried cooling of ejection coal of this spray gun just can be generated coal nanometer materials, plasma jet can realize cracking, synthesis, nitrogenizes and reacts with oxidoreduction etc., if cooled down suddenly by the product of reaction, ultramicron can also be made
The ratio of the pore volume of coal and the cumulative volume of coal is called porosity or the porosity, represents with %, it is also possible to the pore volume (cm3/g) that the coal of unit mass comprises represents。The computing formula of porosity,
Porosity=(true density-apparent density)/true density × 100%,
Classify in coal mesopore,
Micropore-its diameter < 10-5mm, it constitutes the absorption volume in coal, (accounting for more than 50%)
Aperture-its diameter=10-5~10-4mm, it constitutes capillary condensation and gas diffusion space;(accounting for more than 28%),
Mesopore-its diameter=10-4~10-3mm, it constitutes the interval of laminar flow infiltration slowly,
Macropore-its diameter=10-3~10-1mm, it constitutes strong laminar flow infiltration interval, and is decided by have the strong surface of fracture destroying structure coal,
Visible hole and crack its diameter > 10-1mm, the interval of its composition laminar flow and turbulent mixture infiltration, and determine macroscopic view (the hard and middle hard coal) surface of fracture of coal,
Infiltration volume: generally the pore volume sum of aperture to visible hole is called infiltration volume,
Total pore size volume: absorption volume is called total pore size volume with infiltration volume sum,
Coal hole and surface area,
Coal is pore-body, wherein contains substantial amounts of surface area。Micropore surface is long-pending to account for more than the 97% of whole surface area, (aperture accounts for 2.5%, and mesopore accounts for 0.2%)
The principal element of coal pore characteristic,
The pore characteristic of coal is closely related with degree of coalification, geology destructiveness and the factor such as crustal stress character and size thereof,
When finding out micropore-its diameter < 10-5mm of different regions coal, the adsorpting characteristic curve of coal and the absorption affinity index of corresponding coal,
Increase porosity and the voidage of coal by artificial means, strengthen the dust-laying effect of coal, may be used under type by artificial means and realize,
Colliery composition granule is in crushing process, mechanical force can be brought out coal particle and be produced the change of series of physical chemical property, (1) change of dispersion, the method characterizing coal particle dispersion is to measure the specific surface area of coal body system, start the dispersion of coal particle during coal-grinding linear with the ore grinding time, the specific surface area of coal particle and ore grinding time exponentially relation afterwards, after again, the dispersion increment of coal particle is negative value, there is the unsaturated field of force and charged construction unit in coal particle surface, coal particle is made to be in the upper state of instability, just reunite under more weak graviational interaction, make granule thicker, fine grinding, crystal structure caused by Ultrafine Grinding, a series of mechanical force and chemical phenomenon such as physicochemical properties and chemical reaction occurs mainly in this stage。(2) dissolubility and rate of dissolution, after the refinement of coal solid particle, the dissolubility of coal increases with rate of dissolution, after coal particle refinement, the mechanical activation effect of coal also there is impact (3) variable density, dry method coal-grinding granule, coal mineral density reduces, wet grinding mill coal particle, coal mineral density reduces, (4) the electrical change of coal particle, Mechanosensitive channels changes coal particle electric conductivity, the absorbability of surface electrical behavior and semiconductor property (5) coal particle surface, coal particle is crushed, the plane of disruption occurs unsaturated bond and charged construction unit, cause that coal particle is in the upper state of instability, thus increasing coal particle activity, improve surface adsorption ability, mechanical activation effect promotes that the raising (6) of colliery thing surface adsorption causes the change (7) of the exchange of coal particle mineral ion or diadochy to cause the change of coal particle surface free energy,
Coal solid particle is under mechanical force, cause the change of coal particle chemistries, mechanical force and light, electricity, magnetic, heat, the energy of the forms such as radiation is the same, the change of chemistries can also be caused, the chemical reaction of the material that this mechanical force is brought out, it is called mechano-chemical reation, coal carries out mechanical force to carry out crushing and grinding to coal, carrying out coal crushing and grind can at Coal Mining Field, coal preparation plant, depositing dust coal production plant or laboratory implement, the equipment that coal uses mechanical force has boulder crusher, jaw crusher, duplex plate Bu Laike disintegrating machine, single toggle crusher, gyratory crusher, coal crushes spendable equipment further have, garden conic crusher, disc type gyratory crusher, Rhonda disintegrating machine, kibbler roll, impact crusher, Ba Make disintegrating machine, roll crusher,
Coal carrying out levigate use equipment have, in the process of raw coal mill, plant equipment used has, various grinding machines, rotating cylinder grinding machine, rod mill, ball mill, autogenous tumbling mill, vibrating mill, centrifugal mill, tower mill, Ball-stirring mill, agitated medium sand setting grinding machine, roll squeezer, overhang roll type mill
Coal solid particle is applied light, electricity, magnetic, heat, the energy of the forms such as radiation, cause the change of coal particle chemistries, coal particle molecular structure is caused to change, cause coal particle atomic structure to change, cause coal particle crystal structure to change, make the coal particle porosity after change increase with voidage and there is depositing dust character。
10. according to coal feature, during with coal as depositing dust material, according to the coal dust produced for certain areas coal, the mine dust that certain metallic ore produces, the mine dust that certain nonmetallic ore produces, the dust produced during manufacture of cement, need raw coal is carried out washing by the dust-laying effect of the depositing dust of raw coal, raw coal has been mixed into various dirt in process of production, exploitation and transportation are inevitably mixed into again rock and other impurity (timber of top board and base plate, metal and cement components), coal is uneven mixture, it is made up of organic substance and inorganic substances two parts, coal separation is the different physics utilizing coal from other material, physical-chemical property, the impurity in raw coal is mechanically removed in coal preparation plant, for reducing the impurity in raw coal, coal is pressed depositing dust quality simultaneously, specification is divided into various product, coal is carried out machining, to adapt to coal to different regions, the depositing dust effect that different minerals (metallic ore and nonmetallic ore) is played, in the shattering process of raw coal, plant equipment used has, disintegrating machine, jaw crusher, duplex plate Bu Laike disintegrating machine, single toggle crusher, gyratory crusher, garden conic crusher, disc type gyratory crusher, Rhonda disintegrating machine, kibbler roll, impact crusher, Ba Make disintegrating machine, roll crusher,
In the process of raw coal mill, plant equipment used has, various grinding machines, rotating cylinder grinding machine, rod mill, ball mill, autogenous tumbling mill, vibrating mill, centrifugal mill, tower mill, Ball-stirring mill, agitated medium sand setting grinding machine, roll squeezer, overhang roll type mill,
Sieve in raw coal screening process has, reciprocating sieve, slanted screen, and glazing bar sieves, horizontal screen, resonance screens, dewatering screen, combination sieve, Mo Gensang sieves, high-frequency screen, regeneration ore pulp sieve, gravity flow screen, bar screen, rotary screen, spiral screen, roller picker, relaxation is sieved, circular vibrating screen, and sieve bend linearly sieves, various compass screen surfaces, compass screen surface fixed by bolt, and tension compass screen surface, from French metal compass screen surface, stretch-draw rubber blanket and polyurethane pad compass screen surface, assemble compass screen surface, woven wire screen compass screen surface
In coal classification process, plant equipment used has, and uses all kinds of grader, hydraulic classifier, horizontal mipmap machine, cone classifier, mechanical classifier, cake formula grader, spiral classifier, hydrocyclone,
Utilizing gravity separation method to process raw coal, device therefor has jigging machine, with the coal grain raw coal with religion weight spoil composition that dissociates, with point contracting chute and separating cone, with spiral chute, shaking table, air table, double-deck ore separators, centrifugal ore separator, coal preparation method has, coal jigging, heavy media coal separation, coal floatation, table separation, hydrocyclone coal separation, inclined trough washing, helicla flute coal separation, hindered bed separator coal separation, combined type dry coal separation。
11. change chemical composition and the chemical constitution of coal, improve the caloric value of coal and other economic worth of coal, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content,
Coal adds carbon atom, carbon atom is made to combine with other element in coal particle, improve the caloric value of coal, change chemical composition and the chemical constitution of coal, strengthen the magnetic of coal particle, electrically, adsorptivity, increase the porosity of coal and voidage, make coal become can the material of depositing dust, coal texture mainly includes the content of two aspects: one is the molecular structure of the chemical constitution of coal and coal;Two is the physical arrangement of coal and intermolecular stacking provisions and pore structure, change carbon content in coal, oxygen, hydrogen, nitrogen, sulfur, chemical composition that 6 kinds of elements of phosphorus combine each other and chemical constitution, change fluorine a small amount of in coal, chlorine, arsenic, boron, plumbous, chemical composition that the elements such as hydrargyrum form each other and chemical constitution, change fluorine a small amount of in coal, chlorine, arsenic, boron, plumbous, the elements such as hydrargyrum and carbon, oxygen, hydrogen, nitrogen, sulfur, chemical composition that 6 kinds of elements of phosphorus combine each other and chemical constitution, change the germanium of formed trace in coal, gallium, vanadium, chemical composition that the rare elements such as uranium are mutual and chemical constitution, change the germanium of formed trace in coal, gallium, vanadium, the rare elements such as uranium and carbon, oxygen, hydrogen, nitrogen, sulfur, chemical composition that 6 kinds of elements of phosphorus combine each other and chemical constitution, change the germanium of formed trace in coal, gallium, vanadium, the fluorine that the rare elements such as uranium are a small amount of with coal, chlorine, arsenic, boron, plumbous, chemical composition that the elements such as hydrargyrum combine each other and chemical constitution,
Colliery composition granule is in crushing process, mechanical force can be brought out coal particle and be produced the change of series of physical chemical property, (1) change of dispersion, the method characterizing coal particle dispersion is to measure the specific surface area of coal body system, start the dispersion of coal particle during coal-grinding linear with the ore grinding time, the specific surface area of coal particle and ore grinding time exponentially relation afterwards, after again, the dispersion increment of coal particle is negative value, there is the unsaturated field of force and charged construction unit in coal particle surface, coal particle is made to be in the upper state of instability, just reunite under more weak graviational interaction, make granule thicker, fine grinding, crystal structure caused by Ultrafine Grinding, a series of mechanical force and chemical phenomenon such as physicochemical properties and chemical reaction occurs mainly in this stage。(2) dissolubility and rate of dissolution, after the refinement of coal solid particle, the dissolubility of coal increases with rate of dissolution, after coal particle refinement, the mechanical activation effect of coal also there is impact (3) variable density, dry method coal-grinding granule, coal mineral density reduces, wet grinding mill coal particle, coal mineral density reduces, (4) the electrical change of coal particle, Mechanosensitive channels changes coal particle electric conductivity, the absorbability of surface electrical behavior and semiconductor property (5) coal particle surface, coal particle is crushed, the plane of disruption occurs unsaturated bond and charged construction unit, cause that coal particle is in the upper state of instability, thus increasing coal particle activity, improve surface adsorption ability, mechanical activation effect promotes that the raising (6) of colliery thing surface adsorption causes the change (7) of the exchange of coal particle mineral ion or diadochy to cause the change of coal particle surface free energy
Coal solid particle is under mechanical force, cause the change of coal particle chemistries, mechanical force and light, electricity, magnetic, heat, the energy of the forms such as radiation is the same, the change of chemistries can also be caused, the chemical reaction of the material that this mechanical force is brought out, it is called mechano-chemical reation, coal carries out mechanical force to carry out crushing and grinding to coal, carrying out coal crushing and grind can at Coal Mining Field, coal preparation plant, depositing dust coal production plant or laboratory implement, the equipment that coal uses mechanical force has boulder crusher, jaw crusher, duplex plate Bu Laike disintegrating machine, single toggle crusher, gyratory crusher, coal crushes spendable equipment further have, garden conic crusher, disc type gyratory crusher, Rhonda disintegrating machine, kibbler roll, impact crusher, Ba Make disintegrating machine, roll crusher,
Coal carrying out levigate use equipment have, in the process of raw coal mill, plant equipment used has, various grinding machines, rotating cylinder grinding machine, rod mill, ball mill, autogenous tumbling mill, vibrating mill, centrifugal mill, tower mill, Ball-stirring mill, agitated medium sand setting grinding machine, roll squeezer, overhang roll type mill
Coal solid particle is applied light, electricity, magnetic, heat, the energy of the forms such as radiation, cause the change of coal particle chemistries, coal particle molecular structure is caused to change, coal particle atomic structure is caused to change, coal particle crystal structure is caused to change, the coal particle after change is made to have depositing dust character, coal solid particle applying light intensity is reached 10cd and is called for short light intensity with intensity of light, iu is that candela (candela) writes a Chinese character in simplified form cd, coal solid particle is applied electric intensity and reaches 10V/m or more than 10N/C, unit lies prostrate every meter (V/m) or the every storehouse of cattle (N/C), coal solid particle applying magnetic intensity is reached 10GS or more than 10T magnetic induction unit and has Gauss (GS), milli special (mT), tesla (T), coal solid particle applies calorific intensity and reaches more than 100Kcal, or more than 1 (kw), kilocalorie (Kcal), ton evaporation capacity (t), watt (w), kilowatt (kw), coal solid particle is applied radiant intensity and reaches 10W/m2Above, radiant force refers to the total amount of the radiant energy of whole wavelength that object per surface area is launched in the unit interval to half all directions, spherical space, and its conventional unit is W/m2, the equipment that coal applies light intensity has, solid-state gyrolaser, high-pressure microwave plasma exciter, the equipment that to coal, coal is applied electric intensity has, strengthen suspendability charging liquids equipment, the equipment that to coal, coal is applied magnetic intensity has, magnaflux applies method and the circumferential magnetization of magnetic field intensity, the equipment that coal applies calorific intensity has, high frequency firing equipment, high frequency is to utilize electromagnetic field of high frequency to make the intermolecular mutual fierce collision of internal batch produce high temperature, the equipment that coal applies radiant intensity has, change the equipment of the local strength of X-radiation, this equipment includes filling the absorption chamber with ferrofluid with multiple, x-ray filter, absorption chamber, X-radiation direction is stackably arranged。Additionally, x-ray filter includes multiple storage container that can store ferrofluid in it。
12. according to coal characteristic, change the atom composition structure of the coal element of composition coal, change the crystal composition structure of coal element, improve the caloric value of coal and other economic worth of coal, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content
Coal adds carbon, carbon atom is made to combine with other element in coal particle, improve the caloric value of coal, according to coal characteristic, change the atom composition structure of the coal element of composition coal, change the crystal composition structure of coal element, strengthen the magnetic of coal particle, electrically, adsorptivity, increase porosity and the voidage of coal, making coal become can the material of depositing dust, change carbon content in coal, oxygen, hydrogen, nitrogen, sulfur, atomic structure or crystal that 6 kinds of elements of phosphorus combine each other form structure, or atomic structure and crystal composition structure change simultaneously, change fluorine a small amount of in coal, chlorine, arsenic, boron, plumbous, atomic structure or crystal that the elements such as hydrargyrum form each other form structure, or atomic structure and crystal composition structure change simultaneously, change fluorine a small amount of in coal, chlorine, arsenic, boron, plumbous, the elements such as hydrargyrum and carbon, oxygen, hydrogen, nitrogen, sulfur, atomic structure or crystal that 6 kinds of elements of phosphorus combine each other form structure, or atomic structure and crystal composition structure change simultaneously, change the germanium of formed trace in coal, gallium, vanadium, atomic structure or crystal that the rare elements such as uranium are mutual form structure, or atomic structure and crystal composition structure change simultaneously, change the germanium of formed trace in coal, gallium, vanadium, the rare elements such as uranium and carbon, oxygen, hydrogen, nitrogen, sulfur, atomic structure or crystal that 6 kinds of elements of phosphorus combine each other form structure, or atomic structure and crystal composition structure change simultaneously, change the germanium of formed trace in coal, gallium, vanadium, the fluorine that the rare elements such as uranium are a small amount of with coal, chlorine, arsenic, boron, plumbous, atomic structure or crystal that the elements such as hydrargyrum combine each other form structure, or atomic structure and crystal composition structure change simultaneously,
Colliery composition granule is in crushing process, mechanical force can be brought out coal particle and be produced the change of series of physical chemical property, (1) change of dispersion, the method characterizing coal particle dispersion is to measure the specific surface area of coal body system, start the dispersion of coal particle during coal-grinding linear with the ore grinding time, the specific surface area of coal particle and ore grinding time exponentially relation afterwards, after again, the dispersion increment of coal particle is negative value, there is the unsaturated field of force and charged construction unit in coal particle surface, coal particle is made to be in the upper state of instability, just reunite under more weak graviational interaction, make granule thicker, fine grinding, crystal structure caused by Ultrafine Grinding, a series of mechanical force and chemical phenomenon such as physicochemical properties and chemical reaction occurs mainly in this stage (2) dissolubility and rate of dissolution, after the refinement of coal solid particle, the dissolubility of coal increases with rate of dissolution, after coal particle refinement, the mechanical activation effect of coal also there is impact (3) variable density, dry method coal-grinding granule, coal mineral density reduces, wet grinding mill coal particle, coal mineral density reduces, (4) the electrical change of coal particle, Mechanosensitive channels changes coal particle electric conductivity, the absorbability of surface electrical behavior and semiconductor property (5) coal particle surface, coal particle is crushed, the plane of disruption occurs unsaturated bond and charged construction unit, cause that coal particle is in the upper state of instability, thus increasing coal particle activity, improve surface adsorption ability, mechanical activation effect promotes that the raising (6) of colliery thing surface adsorption causes the change (7) of the exchange of coal particle mineral ion or diadochy to cause the change of coal particle surface free energy,
Coal solid particle is under mechanical force, cause the change of coal particle chemistries, mechanical force and light, electricity, magnetic, heat, the energy of the forms such as radiation is the same, the change of chemistries can also be caused, the chemical reaction of the material that this mechanical force is brought out, it is called mechano-chemical reation, coal carries out mechanical force to carry out crushing and grinding to coal, carrying out coal crushing and grind can at Coal Mining Field, coal preparation plant, depositing dust coal production plant or laboratory implement, the equipment that coal uses mechanical force has boulder crusher, jaw crusher, duplex plate Bu Laike disintegrating machine, single toggle crusher, gyratory crusher, coal crushes spendable equipment further have, garden conic crusher, disc type gyratory crusher, Rhonda disintegrating machine, kibbler roll, impact crusher, Ba Make disintegrating machine, roll crusher,
Coal carrying out levigate use equipment have, in the process of raw coal mill, plant equipment used has, various grinding machines, rotating cylinder grinding machine, rod mill, ball mill, autogenous tumbling mill, vibrating mill, centrifugal mill, tower mill, Ball-stirring mill, agitated medium sand setting grinding machine, roll squeezer, overhang roll type mill
Coal solid particle is applied light, electricity, magnetic, heat, the energy of the forms such as radiation, cause the change of coal particle chemistries, coal particle molecular structure is caused to change, coal particle atomic structure is caused to change, coal particle crystal structure is caused to change, the coal particle after change is made to have depositing dust character, coal solid particle applying light intensity is reached 10cd and is called for short light intensity with intensity of light, iu is that candela (candela) writes a Chinese character in simplified form cd, coal solid particle is applied electric intensity and reaches 10V/m or more than 10N/C, unit lies prostrate every meter (V/m) or the every storehouse of cattle (N/C), coal solid particle applying magnetic intensity is reached 10GS or more than 10T magnetic induction unit and has Gauss (GS), milli special (mT), tesla (T), coal solid particle applies calorific intensity and reaches more than 100Kcal, or more than 1 (kw), kilocalorie (Kcal), ton evaporation capacity (t), watt (w), kilowatt (kw), coal solid particle is applied radiant intensity and reaches 10W/m2Above, radiant force refers to the total amount of the radiant energy of whole wavelength that object per surface area is launched in the unit interval to half all directions, spherical space, and its conventional unit is W/m2, the equipment that coal applies light intensity has, solid-state gyrolaser, high-pressure microwave plasma exciter, the equipment that to coal, coal is applied electric intensity has, strengthen suspendability charging liquids equipment, the equipment that to coal, coal is applied magnetic intensity has, magnaflux applies method and the circumferential magnetization of magnetic field intensity, the equipment that coal applies calorific intensity has, high frequency firing equipment, high frequency is to utilize electromagnetic field of high frequency to make the intermolecular mutual fierce collision of internal batch produce high temperature, the equipment that coal applies radiant intensity has, change the equipment of the local strength of X-radiation, this equipment includes filling the absorption chamber with ferrofluid with multiple, x-ray filter, absorption chamber, X-radiation direction is stackably arranged。Additionally, x-ray filter includes multiple storage container that can store ferrofluid in it。
13. according to coal characteristic, change chemical composition and the chemical constitution of mixture in coal, change the atom composition structure of mixture in coal, change the crystal composition structure of coal element, or atomic structure and crystal composition structure change simultaneously, improve the caloric value of coal and other economic worth of coal, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content
Coal adds carbon, makes carbon atom combine with other element in coal particle or combine with other element of mixture in coal, improve the caloric value of coal, according to coal characteristic, change chemical composition and the chemical constitution of mixture in coal, change the atom composition structure of mixture in coal, change the crystal composition structure of coal element, or atomic structure and crystal composition structure change simultaneously, strengthen the magnetic of coal particle, electrically, adsorptivity, increasing the porosity of coal and voidage, making coal become can the material of depositing dust。The heterogeneity mixture that coal material is made up of the organic compound of many complexity, inorganic mineral, metallo-organic complex etc., changes mixture in coal, as, spoil, the molecular structure in yellow ferrum sulfur ore deposit, atomic structure, crystal structure, improve the dust-laying effect of coal, change the chemical constitution of coal and the molecular structure of coal, the physical arrangement of change coal and intermolecular stacking provisions and pore structure, make coal become depositing dust material, improve the dust-laying effect of coal
In colliery composition granule and coal, mixture is in crushing process, mechanical force can be brought out mixture in coal particle and coal and be produced the change of series of physical chemical property, (1) change of dispersion, the method characterizing coal particle dispersion is to measure the specific surface area of coal body system, start the dispersion of coal particle during coal-grinding linear with the ore grinding time, the specific surface area of coal particle and ore grinding time exponentially relation afterwards, after again, the dispersion increment of coal particle is negative value, there is the unsaturated field of force and charged construction unit in coal particle surface, coal particle is made to be in the upper state of instability, just reunite under more weak graviational interaction, make granule thicker, fine grinding, crystal structure caused by Ultrafine Grinding, a series of mechanical force and chemical phenomenon such as physicochemical properties and chemical reaction occurs mainly in this stage。(2) dissolubility and rate of dissolution, after the refinement of coal solid particle, the dissolubility of coal increases with rate of dissolution, after coal particle refinement, the mechanical activation effect of coal also there is impact (3) variable density, dry method coal-grinding granule, coal mineral density reduces, wet grinding mill coal particle, coal mineral density reduces, (4) the electrical change of coal particle, Mechanosensitive channels changes coal particle electric conductivity, the absorbability of surface electrical behavior and semiconductor property (5) coal particle surface, coal particle is crushed, the plane of disruption occurs unsaturated bond and charged construction unit, cause that coal particle is in the upper state of instability, thus increasing coal particle activity, improve surface adsorption ability, mechanical activation effect promotes that the raising (6) of colliery thing surface adsorption causes the change (7) of the exchange of coal particle mineral ion or diadochy to cause the change of coal particle surface free energy,
In coal solid particle and coal, mixture is under mechanical force, cause the change of blend chemistry in coal particle and coal, mechanical force and light, electricity, magnetic, heat, the energy of the forms such as radiation is the same, the change of chemistries can also be caused, the chemical reaction of the material that this mechanical force is brought out, it is called mechano-chemical reation, coal carries out mechanical force to carry out crushing and grinding to coal, carrying out coal crushing and grind can at Coal Mining Field, coal preparation plant, depositing dust coal production plant or laboratory implement, the equipment that coal uses mechanical force has boulder crusher, jaw crusher, duplex plate Bu Laike disintegrating machine, single toggle crusher, gyratory crusher, coal crushes spendable equipment further have, garden conic crusher, disc type gyratory crusher, Rhonda disintegrating machine, kibbler roll, impact crusher, Ba Make disintegrating machine, roll crusher,
Mixture in coal and coal carrying out levigate use equipment have, in the process of raw coal mill, plant equipment used has, various grinding machines, rotating cylinder grinding machine, rod mill, ball mill, autogenous tumbling mill, vibrating mill, centrifugal mill, tower mill, Ball-stirring mill, agitated medium sand setting grinding machine, roll squeezer, overhang roll type mill
Mixture in coal solid particle and coal is applied light, electricity, magnetic, heat, the energy of the forms such as radiation, cause the change of blend chemistry in coal particle and coal, mixture molecular structure in coal particle and coal is caused to change, mixture atomic structure in coal particle and coal is caused to change, mixture crystal structure in coal particle and coal is caused to change, make the coal particle after change and in coal mixture there is depositing dust character, coal solid particle applying light intensity is reached 10cd and is called for short light intensity with intensity of light, iu is that candela (candela) writes a Chinese character in simplified form cd, coal solid particle is applied electric intensity and reaches 10V/m or more than 10N/C, unit lies prostrate every meter (V/m) or the every storehouse of cattle (N/C), coal solid particle applying magnetic intensity is reached 10GS or more than 10T magnetic induction unit and has Gauss (GS), milli special (mT), tesla (T), coal solid particle applies calorific intensity and reaches more than 100Kcal, or more than 1 (kw), kilocalorie (Kcal), ton evaporation capacity (t), watt (w), kilowatt (kw), coal solid particle is applied radiant intensity and reaches 10W/m2Above, radiant force refers to the total amount of the radiant energy of whole wavelength that object per surface area is launched in the unit interval to half all directions, spherical space, and its conventional unit is W/m2, the equipment that coal applies light intensity has, solid-state gyrolaser, high-pressure microwave plasma exciter, the equipment that to coal, coal is applied electric intensity has, strengthen suspendability charging liquids equipment, the equipment that to coal, coal is applied magnetic intensity has, magnaflux applies method and the circumferential magnetization of magnetic field intensity, the equipment that coal applies calorific intensity has, high frequency firing equipment, high frequency is to utilize electromagnetic field of high frequency to make the intermolecular mutual fierce collision of internal batch produce high temperature, the equipment that coal applies radiant intensity has, change the equipment of the local strength of X-radiation, this equipment includes filling the absorption chamber with ferrofluid with multiple, x-ray filter, absorption chamber, X-radiation direction is stackably arranged。Additionally, x-ray filter includes multiple storage container that can store ferrofluid in it。
14. according to coal characteristic, change the surface nature of colliery thing, improve the caloric value of coal and other economic worth of coal, by the method for coal mineral surface modification and modifying agent, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content
Coal adds carbon, carbon atom is made to be combined the caloric value improving coal with modified coal facies, according to coal characteristic, change the surface nature of colliery thing, strengthen the magnetic of coal particle, electrically, adsorptivity, increase porosity and the voidage of coal, strengthen coal and coal produces the dust-laying effect between coal dust, strengthen the dust-laying effect between the mine dust of coal and the generation of certain metallic ore, strengthen the dust-laying effect between the mine dust of coal and the generation of certain nonmetallic ore, strengthen the dust-laying effect between the dust produced in coal and cement production process, strengthen the diameter granule less than or equal to 2.5 microns in coal dust degraded earth atmosphere, reach to administer air pollution depositing dust effect higher, reduction along with coal particle degree, then coal particle surface activity also improves therewith, it is many-sided that coal micronized particles has high surface, there is high chemical reactivity, high absorption capacity, high coherency, the adsorption property of Study on Coal micronized particles, Study on Coal granular solids and the adsorption property on solid two-phase interface, coal particle solid claims adsorbent, other adsorbed solid particles claim adsorbate, absorption is divided into physical absorption and chemisorbed, both essential distinctions are with or without electron transfer between adsorbate and adsorbent, the physical absorption of Study on Coal granule and chemisorbed, Study on Coal particle surface modification, coal particle absorption affinity is made to strengthen, develop coal particle surface modifying agent, the granule modified method of Study on Coal, develop coal particle reforming apparatus, utilize mental retardation primary particle, as, photon, electronics, ion, interact with coal particle surface, produce scattering or launch secondary, by analyzing the power spectrum of ejecting particle, mass spectrum or spectrum, the surface information that coal particle is relevant can be obtained, utilize surface Spectrum Analysis technology, can reveal that the composition of coal particle surface, the much information such as ionic valence condition and chemical bond, combine with scanning detecting probe method by static secondary ion mass spectrum, the absorption specimen of detection coal particle, utilize polyether-type nonionic dispersant, adopt X-ray electronic energy to borrow and add argon ion etching device, measure coal particle and Additive front and rear surfaces characteristic atomic valence state and energy variation, and the feature according to instrument, calculate the thickness of dispersant adsorption film on surface,
The method of coal mineral surface modification has (1) surface coating modification method, namely by adhesion, the method that modifying agent (Organic substance or inorganic matter) is covered in coal mineral particle, is used as the Kaolin of filler, Muscovitum by naturally occurring or synthetic rubber processing, ball clay, or it is coated in coal particle surface with phenolic resin or furane resins, the caking property of coal, many inorganic oxides or hydroxide can be improved, as, TiO2, SiO2, Al (OH)2There is respective zero point pH value。By controlling the pH value of solution, absorption surface activating agent makes coal particle surface modifiy, (2) can also be used with surface chemical modification method, modifying agent and some functional group of mineral surfaces is utilized to carry out chemical reaction or chemisorbed, reach the purpose that coal particle surface is modified, in this kind of method of modifying, it is made by stronger bonding force (such as covalent bond) between coal particle and modifying agent to have an effect, (3) can also be used with mechanical-chemical modification method, namely by pulverizing, grind, the mechanical means such as friction, make mineral lattice structure, crystal formations etc. change, can increase in system, temperature raises, promote particle to melt or decompose or produce free radical or ion, strengthen coal particle surface activity, promote coal particle and other material generation chemical reaction or mutually adhere to, reach the purpose of surface modification, (4) the modified method of available precipitation, during using inorganic matter as modifying agent, the method utilizes the precipitation between modifying agent, coal particle surface deposits one or more layers modified layer, to change coal particle surface character, (5) modified (capsule) method of theca externa, namely at the thin film of coal particle surface bag other material of last layer, , the theca externa wrapped is uniform, shape is capsule such as, it has protection core substance, regulate, release the function of core material, blend compounds encapsulated changes appearance and the character of coal particle, capsule-type prepares method mainly spray coating, spray drying, interfacial polymerization, it is separated and dissolves dispersion cooling method, make the material of capsule wall except organic polymer beyond the region of objective existence, inorganic substances have TiO2, AL2O3, Fe2O3, ZnO and silicates, glue core material has magnesium carbonate, aluminium silicate, sodium hydrosulfite or other gaseous state, liquid。(6) coal particle surface is modified by the means such as the modified method of high energy surface, utilizes plasma, corona discharge, ultraviolet,
Coal surface modification device has (1) bulk material mixer, has mixed stirring device, including container rotating type, (2) high velocity air impact type powder modifying devices such as container fixed pattern and air-flow mixed type, this system is by mixer, metering system, main frame, product collecting device, control system is formed, and main frame is by the rotor of high speed rotating, the parts such as stator and closed circuit form, there are chuck, cooling or heating rotor use between stator and rotor, in rotor, have fin。(3) surface modification is held concurrently reducing mechanism,
Evaluation to coal particle surface modified effect, carries out the measurement of some physicochemical properties and surface characteristic to coal particle, compares the change of coal particle depositing dust absorption index after before modified, reaches to evaluate the purpose of modified effect。Basic skills has (1) moist (2) dispersibility (3) infrared spectrum, as long as there is certain functional group or key in coal surface, mineral spectrogram just has corresponding characteristic absorption peak, so, to after before modified and modified after carry out infrared spectrum analysis through the coal particle sample of various process, change according to character pair peak, just effect and the mechanism of surface modifier can be disclosed, (4) X-ray diffraction, the mixture solid structure of matter in Study on Coal particulate solid material structure and coal, available X-ray diffraction method。Can be used to coal Polycrystalline make Discriminating materials and lattice parameter mensuration, monocrystal X-ray is done structure determination and crystal integrity research (5) heat is analyzed, heat is analyzed and is included differential thermal and calorimetric analysis, differential thermal analysis is used for investigating coal particle in heating process, when reaching certain temperature, due to the heat effect that phase transformation or some chemical reaction produce, analyzing, there is exothermic peak or absworption peak in curve, the size of peak area reflects the power of heat effect, thermogravimetric analysis can measure the change as temperature or the material mass of time function, when carrying out heat and analyzing, generally by two kinds of heat analysis method couplings。(6) solid surface analysis technology is utilized, utilize surface Spectrum Analysis technology, can reveal that the composition of coal particle surface, the much information such as ionic valence condition and chemical bond, combine with scanning detecting probe method by static secondary ion mass spectrum, the absorption specimen of detection coal particle, utilize polyether-type nonionic dispersant, adopt X-ray electronic energy to borrow and add argon ion etching device, measure coal particle and Additive front and rear surfaces characteristic atomic valence state and energy variation, and the feature according to instrument, calculate the thickness of dispersant adsorption film on surface
Coal surface modifier has coupling agent, surfactant, polymer class and Inorganic surface modifiers,
The series such as coupling agent is siliceous or metallic atom organic compound, different by central atom, has a silane system, titanate esters system, Aluminate system, stannic acid ester system, aluminum zirconate system。

Claims (8)

1. owing to the primordial matter of coal-forming is different with the palegeology condition of coal-forming, difference due to the initial material of coal-forming and the difference of biochemical action and geochemical factor and the micro-composition of coal petrography, composition and the character of the various coal in different regions have very big-difference, coal is uneven mixture, it is made up of organic substance and inorganic substances two parts, composition and the character of coal and other mineral have very big-difference, mineral are the aggregations that in nature, metal or nonmetallic compound are formed, and metallic ore refers to through smelting the mineral products that can therefrom extract metallic element。Such as ferrous metal mineral products: ferrum, manganese, chromium, vanadium, titanium etc. are the mineral products being used as steel and iron industry raw material。Nonferrous metal ore includes: copper, stannum, zinc, nickel, cobalt, tungsten, molybdenum, hydrargyrum etc.。Noble metal includes: platinum, rhodium, gold, silver etc.。Light metal mineral products include: aluminum, magnesium etc.。Rare metal mineral products include: lithium, beryllium, rare earth etc.。The common feature of most mineral metal products is mainly manifested in the aspects such as quality is harder, glossy。Mineral metal products can be divided into 5 kinds by its Matter Composition, character and purposes: ferrous metal mineral products, nonferrous metal ore, noble metal mineral products, title have dispersed elements mineral products, semimetal mineral products, nonmetallic ore is with metallic ore comparatively speaking, there are 91 kinds, are mainly diamond, graphite, crystal, corundum, asbestos, Muscovitum, Gypsum Fibrosum, fluorite, gem, jade, Achates, limestone, dolomite
The character of coal is divided into physical property, chemical composition, processing performance and combustibility etc., when the depositing dust character of Study on Coal, answering the chemical composition of Study on Coal and the atomic structure feature of institute's component, the physical property of coal includes coal petrography composition, color, gloss, density, hardness, electric conductivity, heat conductivity, thermostability, magnetic, granularmetric composition, argillization degree
The chemical composition of coal includes elementary composition and Industrial Analysis, coal is the humatite changed by plant remains, it is elementary composition sufficiently complex, coal is mainly by carbon, oxygen, hydrogen, nitrogen, sulfur, 6 kinds of phosphorus is elementary composition, possibly together with a small amount of fluorine, chlorine, arsenic, boron, plumbous, the elements such as hydrargyrum, and the germanium of trace, gallium, vanadium, the rare elements such as uranium, the Industrial Analysis of coal is in order that understand Coal Quality, judge kind and the processing and utilization approach of coal, including the moisture measuring coal, ash, volatile matter and fixed carbon, , moisture according to coal and ash can substantially understand the percentage composition of wherein organic substance or combustible, moisture and ash such as coal are high, then the content of organic matter is just few, thus caloric value is low, economic worth is little, character organic coal can be substantially recognized from the volatile matter of coal, the height of degree of coalification, the height of close-burning power and caloric value, its degree of coalification can be substantially judged from the fixed carbon content of coal, evaluate its economic worth,
The processing performance of coal includes the cohesiveness of coal, caloric value, chemism, heat stability, grindability, paste-forming properties,
The Industrial Analysis of coal is to understand Coal Quality, judge kind and the processing and utilization approach of coal, including the moisture measuring coal, ash, volatile matter, with 4, fixed carbon, moisture and ash according to coal can substantially understand the percentage composition of organic substance or combustible in coal, moisture and ash such as coal are high, then the content of organic matter is just few, thus caloric value is low, (1) moisture, the moisture of coal has inherent moisture and free moisture two kinds, free moisture refers in exploitation, transport, washing process is attached to the water in coal particle surface and crack, inherent moisture refers to absorption or condenses upon the water in coal particle internal capillary hole, moisture is more high, the economic worth of coal is more low, coal is being stored by the moisture of coal, transport, processing and utilizing all have impact (2) pit ash refer to coal burn completely after the productivity of residue, pit ash is divided into fixed ash and external ash two kinds, fixed ash refers to the dirt that coal is mixed in coalification course, external ash refers to that coal is in exploitation, transport, the dirt being mixed in storage process, i.e. spoil, it can be removed by washing method, pit ash is more high, quality is more poor, caloric value is more low, high processing and the utilization to coal of pit ash has adverse effect (3) volatile matter, the volatile matter of coal refer to coal with the container of air exclusion under certain high temperature, be heated to certain time after, the liquid (steam condition) decomposing out from coal and gas deduct the product after its moisture, the volatile matter of coal is more high, the degree of coalification of coal is more low, burning is more easily lighted (4) fixed carbon, the fixed carbon of coal refer to coal completely cut off air when Organic substance pyrolytic after remaining residual substance deduct its ash after product, main component is carbon, the degree of coalification of coal is may determine that according to fixed carbon content, fixed carbon content is more high, volatile matter is more low, degree of coalification is more high, fixed carbon content is high, the caloric value of coal is also more high, the processing performance of coal includes the cohesiveness of coal, caloric value, chemism, heat stability, grindability, paste-forming properties,
The classification of coal, the classification of coal is adopted different standards by countries in the world, China standard GB/T 5751-2009 " Chinese Coal Classification " is the standard using degree of coalification and processing performance as classification, coal is divided into anthracite, bituminous coal and brown coal three major types, and anthracite makes the index of degree of coalification to distinguish anthracitic group with dry ash free basis volatile matter and dry ash free basis hydrogen content, namely smokeless No. one, smokeless No. two and smokeless No. three。
Bituminous coal adopts two parameters to determine classification, a parameter being to characterize bituminous coal degree of coalification, and another is to characterize the close-burning parameter of bituminous coal, the parameter of bituminous coal degree of coalification adopts dry ash free basis volatilization to be allocated as index, and the close-burning parameters selection caking index of bituminous coal and maximum thick ness of plastic layer or Ah's swelling degree difficult to understand distinguish classification as index, i.e. meager coal, meager lean coal, lean coal, coking coal, rich coal, gas rich coal, bottle coal, in glutinous coal, non caking coal, jet coal
The composition and the character that utilize the various coal in different regions have very big-difference, the magnetic of coal particle is different or contrary, the positive magnetic in a certain ribbing, area, another negative magnetic in ribbing, area, or the negative magnetic in ribbing, a certain area, another positive magnetic in ribbing, area, the electrically difference or contrary of coal particle, ribbing, a certain area positive electricity, another ribbing, area negative electricity, or ribbing, a certain area negative electricity, another ribbing, area positive electricity, the coal in a certain area can adsorb another area coal, reach depositing dust effect, obtain a certain area coal and adsorb the coal dust that another area coal produces, shanxi coal transports to the Inner Mongol, coal dust produced by the shungite of shanxi coal absorption Inner Mongol, or Inner Mongol shungite transports to Shanxi, coal dust produced by the shungite absorption shanxi coal of Inner Mongol, shanxi coal transports to Shaanxi, coal dust produced by the coal of shanxi coal absorption Shaanxi, or Shaanxi coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Shaanxi, shanxi coal transports to Xinjiang, coal dust produced by the coal of shanxi coal absorption Xinjiang, or Xinjiang coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Xinjiang, shanxi coal transports to Guizhou, coal dust produced by shanxi coal absorption Guizhou coal, or Guizhou coal transports to Shanxi, coal dust produced by Guizhou coal absorption shanxi coal, shanxi coal transports to Ningxia, coal dust produced by the coal of shanxi coal absorption Ningxia, or Ningxia coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Ningxia, shanxi coal transports to Shandong, coal dust produced by the coal of shanxi coal absorption Shandong, or Shandong coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Shandong, shanxi coal transports to Yunnan, the coal dust that shanxi coal absorption Yunnan coal produces, or Yunnan coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Yunnan, shanxi coal transports to Henan, coal dust produced by the coal of shanxi coal absorption Henan, or Henan coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Henan, shanxi coal transports to Anhui, coal dust produced by the coal of shanxi coal absorption Anhui, or Anhui coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Anhui, shanxi coal transports to Heilungkiang, coal dust produced by the coal of shanxi coal absorption Heilungkiang, or Heilungkiang coal transports to Shanxi, coal dust produced by the coal absorption shanxi coal of Heilungkiang, Shaanxi transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Shaanxi, Inner Mongol, or Shaanxi coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Shaanxi, Xinjiang transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Xinjiang, Inner Mongol, or Xinjiang coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Xinjiang, Guizhou transported to by Inner Mongol shungite, coal dust produced by the shungite absorption Guizhou coal of Inner Mongol, or Guizhou coal transports to the Inner Mongol, coal dust produced by the shungite of Guizhou coal absorption Inner Mongol, Ningxia transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Ningxia, Inner Mongol, or Ningxia coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Ningxia, Shandong transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Shandong, Inner Mongol, or Shandong coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Shandong, Yunnan transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Yunnan, Inner Mongol, or Yunnan coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Yunnan, Henan transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Henan, Inner Mongol, or Henan coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Henan, Anhui transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Anhui, Inner Mongol, or Anhui coal transports to the Inner Mongol, coal dust produced by the shungite of coal absorption Inner Mongol, Anhui, Heilungkiang transported to by Inner Mongol shungite, coal dust produced by the coal of shungite absorption Heilungkiang, Inner Mongol, or Heilungkiang coal transports to the Inner Mongol,
Coal dust produced by the shungite of coal absorption Inner Mongol, Heilungkiang, Shaanxi coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Shaanxi, or Xinjiang coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Xinjiang, Shaanxi coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Shaanxi, or Guizhou coal transports to Shaanxi, coal dust produced by the coal of Guizhou coal absorption Shaanxi, Shaanxi coal transports to Ningxia, coal dust produced by the coal of coal absorption Ningxia, Shaanxi, or Ningxia coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Ningxia, Shaanxi coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Shaanxi, or Shandong coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Shandong, Shaanxi coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Shaanxi, or Shandong coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Shandong, Shaanxi coal transports to Yunnan, coal dust produced by the coal of coal absorption Yunnan, Shaanxi, or Yunnan coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Yunnan, Shaanxi coal transports to Henan, coal dust produced by the coal of coal absorption Henan, Shaanxi, or Henan coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Henan, Shaanxi coal transports to Anhui, coal dust produced by the coal of coal absorption Anhui, Shaanxi, or Anhui coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Anhui, Shaanxi coal transports to Heilungkiang, coal dust produced by the coal of coal absorption Heilungkiang, Shaanxi, or Heilungkiang coal transports to Shaanxi, coal dust produced by the coal of coal absorption Shaanxi, Heilungkiang, Xinjiang coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Xinjiang, or Guizhou coal transports to Xinjiang, coal dust produced by the coal of Guizhou coal absorption Xinjiang, Xinjiang coal transports to Ningxia, coal dust produced by the coal of coal absorption Ningxia, Xinjiang, or Ningxia coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Ningxia, Xinjiang coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Xinjiang, or Shandong coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Shandong, Xinjiang coal transports to Yunnan, coal dust produced by the coal of coal absorption Yunnan, Xinjiang, or Yunnan coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Yunnan, Xinjiang coal transports to Henan, coal dust produced by the coal of coal absorption Henan, Xinjiang, or Henan coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Henan, Xinjiang coal transports to Anhui, coal dust produced by the coal of coal absorption Anhui, Xinjiang, or Anhui coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Anhui, Xinjiang coal transports to Heilungkiang, coal dust produced by the coal of coal absorption Heilungkiang, Xinjiang, or Heilungkiang coal transports to Xinjiang, coal dust produced by the coal of coal absorption Xinjiang, Heilungkiang, Guizhou coal transports to Ningxia, coal dust produced by the coal of Guizhou coal absorption Ningxia, or Ningxia coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Ningxia, Guizhou coal transports to Shandong, coal dust produced by the coal of Guizhou coal absorption Shandong, or Shandong coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Shandong, Guizhou coal transports to Yunnan, coal dust produced by the coal of Guizhou coal absorption Yunnan, or Yunnan coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Yunnan, Guizhou coal transports to Henan, coal dust produced by the coal of Guizhou coal absorption Henan, or Henan coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Henan, Guizhou coal transports to Anhui, coal dust produced by the coal of Guizhou coal absorption Anhui, or Anhui coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Anhui, Guizhou coal transports to Heilungkiang, coal dust produced by the coal of Guizhou coal absorption Heilungkiang, or Heilungkiang coal transports to Guizhou, coal dust produced by the coal absorption Guizhou coal of Heilungkiang, Ningxia coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Ningxia, or Shandong coal transports to Ningxia, coal dust produced by the coal of coal absorption Ningxia, Shandong, Ningxia coal transports to Yunnan, coal dust produced by the coal of coal absorption Yunnan, Ningxia, or Yunnan coal transports to Ningxia, coal dust produced by the coal of coal absorption Ningxia, Yunnan, Ningxia coal transports to Henan, coal dust produced by the coal of coal absorption Henan, Ningxia, or Henan coal transports to Ningxia, coal dust produced by the coal of coal absorption Ningxia, Henan, Ningxia coal transports to Anhui, coal dust produced by the coal of coal absorption Anhui, Ningxia, or Anhui coal transports to Ningxia, coal dust produced by the coal of coal absorption Ningxia, Anhui, Ningxia coal transports to Heilungkiang, coal dust produced by the coal of coal absorption Heilungkiang, Ningxia, or Heilungkiang coal transports to Ningxia, coal dust produced by the coal of coal absorption Ningxia, Heilungkiang, Shandong coal transports to Yunnan, coal dust produced by the coal of coal absorption Yunnan, Shandong, or Yunnan coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Yunnan, Shandong coal transports to Yunnan, coal dust produced by the coal of coal absorption Yunnan, Shandong, or Yunnan coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Yunnan, Shandong coal transports to Henan, coal dust produced by the coal of coal absorption Henan, Shandong, or Henan coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Henan, Shandong coal transports to Anhui, coal dust produced by the coal of coal absorption Anhui, Shandong, or Anhui coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Anhui, Shandong coal transports to Heilungkiang, coal dust produced by the coal of coal absorption Heilungkiang, Shandong, or Heilungkiang coal transports to Shandong, coal dust produced by the coal of coal absorption Shandong, Heilungkiang, Yunnan coal transports to Henan, coal dust produced by the coal of coal absorption Henan, Yunnan, or Henan coal transports to Yunnan, coal dust produced by the coal of coal absorption Yunnan, Henan, Yunnan coal transports to Anhui, coal dust produced by the coal of coal absorption Anhui, Yunnan, or Anhui coal transports to Yunnan, coal dust produced by the coal of coal absorption Yunnan, Anhui, Yunnan coal transports to Heilungkiang, coal dust produced by the coal of coal absorption Heilungkiang, Yunnan, or Heilungkiang coal transports to Yunnan, coal dust produced by the coal of coal absorption Yunnan, Heilungkiang, Henan coal transports to Anhui, coal dust produced by the coal of coal absorption Anhui, Henan, or Anhui coal transports to Henan, coal dust produced by the coal of coal absorption Henan, Anhui, Henan coal transports to Heilungkiang, coal dust produced by the coal of coal absorption Heilungkiang, Henan, or Heilungkiang coal transports to Henan, coal dust produced by the coal of coal absorption Henan, Heilungkiang, Anhui coal transports to Heilungkiang, coal dust produced by the coal of coal absorption Heilungkiang, Anhui, or Heilungkiang coal transports to Anhui, coal dust produced by the coal of coal absorption Anhui, Heilungkiang,
Utilize the difference of coal and metallic ore composition and character, the composition and the character that utilize the various coal in different regions have very big-difference, the magnetic of coal particle is different from certain metallic ore or contrary, the positive magnetic in a certain ribbing, area, certain metal mine belt bears magnetic, or the negative magnetic in ribbing, a certain area, certain positive magnetic of metal mine belt, coal particle electrically different from certain metallic ore or contrary, ribbing, a certain area positive electricity, certain metallic ore is electronegative, or ribbing, a certain area negative electricity, certain metallic ore positively charged, the mine dust that the coal in a certain area produces when can adsorb the mining of certain metallic ore, reach depositing dust effect, iron mine is adsorbed with shanxi coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Inner Mongol shungite, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Shaanxi coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Xinjiang coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Guizhou coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Ningxia coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Shandong coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Yunnan coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Henan coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Anhui coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect, iron mine is adsorbed with Heilungkiang coal, manganese ore, chrome ore, navajoite, titanium ore, copper mine, cassiterite, zinc ore, nickel minerals, cobalt ore, tungsten ore, molybdenum ore, hydrargyrum ore deposit, platinum ore, rhodium ore deposit, gold mine, silver ore, lithium ore deposit, beryllium ore deposit, mine dust produced by Rare Earth Mine, reach depositing dust effect,
Utilize the difference of coal and nonmetallic ore composition and character, the composition and the character that utilize the various coal in different regions have very big-difference, the magnetic of coal particle is different from certain nonmetallic ore or contrary, the positive magnetic in a certain ribbing, area, another certain nonmetal mine belt bears magnetic, or the negative magnetic in ribbing, a certain area, another certain positive magnetic of nonmetal mine belt, coal particle electrically different from certain nonmetallic ore or contrary, ribbing, a certain area positive electricity, another certain nonmetallic ore is electronegative, or ribbing, a certain area negative electricity, another certain nonmetallic ore positively charged, obtain a certain area coal and adsorb the mine dust that certain nonmetallic ore produces, reach depositing dust effect, Diamond Deposit is adsorbed with shanxi coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, with shungite ADSORPTION OF GOLD hard rock ore deposit, Inner Mongol, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Shaanxi coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Xinjiang coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Guizhou coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Ningxia coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Shandong coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Yunnan coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Henan coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Anhui coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, Diamond Deposit is adsorbed with Heilungkiang coal, graphite ore, crystal ore deposit, corundum ore deposit, asbestos deposit, MICA, Gypsum Mine, fluorite ore, gem ore deposit, jade ore deposit, Achates ore deposit, limestone deposit, 91 kinds of nonmetal mine dusts such as dolomite ore deposit, reach depositing dust effect, in manufacture of cement, utilize composition and the nature difference of the various coal in different regions, the magnetic of coal particle is different or contrary from the primary raw material magnetic of manufacture of cement, the positive magnetic in a certain ribbing, area, magnetic born by the primary raw material band of manufacture of cement, or the negative magnetic in ribbing, a certain area, the positive magnetic of primary raw material band of manufacture of cement, coal particle is electrically different or contrary from the primary raw material of manufacture of cement, ribbing, a certain area positive electricity, the primary raw material of manufacture of cement is electronegative, or ribbing, a certain area negative electricity, the primary raw material positively charged of manufacture of cement, the coal in a certain area can adsorb the dust that the primary raw material of manufacture of cement produces in process of production, reach depositing dust effect, obtain the dust that the primary raw material of a certain area coal absorption manufacture of cement produces in process of production, the limestone that it is main component with calcium carbonate that calcareous raw material refers to, marl, Chalk and shell etc., limestone is the primary raw material of manufacture of cement, clay raw material mainly provides a small amount of composition in clinker, natural clay raw material has loess, clay, shale, siltstone and river silt etc., wherein loess and clay are with the most use, in addition, also has flyash, the industrial residues such as gangue, clay matter is finely divided sedimentary rock, it is made up of different minerals and other hydrated aluminium silicates, limestone in cement production process is adsorbed with shanxi coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Inner Mongol shungite, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Shaanxi coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Xinjiang coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Guizhou coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Ningxia coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Shandong coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Yunnan coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Henan coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Anhui coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect, limestone in cement production process is adsorbed with Heilungkiang coal, marl, Chalk and shell, loess, clay, shale, siltstone and river silt, flyash, gangue, Kaolin, montmorillonite, dirt produced by hydromica, reach depositing dust effect,
With the diameter granule less than or equal to 2.5 microns in coal dust degraded earth atmosphere, reach to administer air pollution depositing dust effect, with the diameter granule less than or equal to 2.5 microns in coal particle degraded earth atmosphere, reach to administer air pollution depositing dust effect, the diameter of coal dust is less than 1 millimeter, and the diameter of coal particle is more than 1 millimeter。
2. according to claim 3, claim 5, claim 6, claim 7, coal described in claim 8 is as the manufacture method of depositing dust material, coal is made to have depositing dust character, some other material is had adsorption by the depositing dust property list of coal now, the depositing dust character of adsorbing power coal is described, set up the depositing dust character index system of complete coal, the power of the depositing dust character of coal is reflected by the granule size of coal and porosity size, Study on Coal particle diameter is more than the dust-laying effect of more than 1 millimeter coal, Study on Coal particle diameter is less than the dust-laying effect of less than 1 millimeter coal, with coal particle as depositing dust material, coal particle includes the drop in the emulsion made with coal, with the bubble of the liquid that coal is made, the solids of coal, the particle diameter of coal particle is more than more than 1 millimeter, with coal dust body as depositing dust material, coal dust body includes the drop in the emulsion made with coal, with the bubble of the liquid that coal is made, the solids of coal, the particle diameter of coal dust body is less than less than 1 millimeter, coal particle is more little, dissolubility is more big, fusing point is more low, chemical potential is more high, the light of fine Coal granule, electricity, magnetic, peculiar change can be there is in the features such as heat, coal dust body is solid time static, quasi-fluid when being filled with air, there is again when being suspended in gas some character of gas, when making depositing dust material with coal, change the size of coal particle, such as coal particle particle diameter more than 1 millimeter, coal particle particle diameter more than 1.5 millimeters, coal particle particle diameter 2 millimeters is with first-class, the dissolubility of coal, fusing point, the change of the chemical potential impact on the dust-laying effect of coal, change the size of coal dust body, such as coal diameter of particle less than 1 millimeter, coal diameter of particle less than 0.5 millimeter, coal diameter of particle, less than 0.05 millimeter, coal diameter of particle less than 0.01 millimeter, coal diameter of particle, less than 0.001 millimeter, coal diameter of particle, when less than 0.0001 millimeter, the light of coal, electricity, magnetic, the changing features impacts on the dust-laying effect of coal such as heat, change the feature of coal particle diameter and coal dust body, reach to attract each other between coal and coal or adsorb, or attract and adsorb to occur simultaneously, reach to attract each other between mine dust and dust produced by coal and metallic ore or adsorb, or attract and adsorb to occur simultaneously, , reach to attract each other between mine dust and dust produced by coal and nonmetallic ore or adsorb, or attract and adsorb to occur simultaneously, reach to attract each other between dirt and dust produced by coal and steamed dumplings stalk or adsorb, or attract and adsorb to occur simultaneously, attract each other between produced dirt and dust when reaching coal and make cement or adsorb, or attract and adsorb to occur simultaneously, attract each other between produced dirt and dust when reaching coal and make chemical materials or adsorb, or attract and adsorb to occur simultaneously, attract each other between produced dirt and dust when reaching coal and make timber or adsorb, or attract and adsorb to occur simultaneously, attract each other between produced dirt and dust when reaching coal and make other material or adsorb, or attract and adsorb to occur simultaneously。
3. coal is made nanometer materials and improves the caloric value of coal and other economic worth of coal, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content,
Coal is made nanometer materials and carries out depositing dust, increase porosity and the voidage of coal by artificial means, strengthen the dust-laying effect of coal, when coal is made nanometer materials, adding carbon, carbon also makes nanometer materials, make carbon atom make nanometer materials with coal to mix mutually, improve the caloric value of coal
Coal nano material refers to that coal particle is of a size of nano level superfine material, and its size, between molecule, atom and bulk material, refers to the small coal pressed powder within the scope of 1 to 100nm, and namely this small coal pressed powder size is (10-nRice, n=7) arrive (10-nRice, n=9) between, coal is prepared into nano level superfine material available mechanical comminuting method, gas evaporation method, solwution method, Laser synthesizing method, plasma synthesis method, x ray irradiation x synthetic method, sol-gel process etc.,
Gas evaporation method is a kind of physical method, by coal heating raw materials, evaporation, make atom or molecule, then make many atoms or molecule cohesion, form imperceptible coal nano-particle, evaporation is prepared coal nano-particle and can be divided into, vacuum vapor deposition method, gas evaporation method, by heating evaporation technological means, electrode can being divided into evaporate evaporation, high-frequency induction evaporates, electron beam evaporation, plasma evaporation, laser beam evaporation etc.
Coal is made nanometer materials by available supercritical fluid method, mainly comprising the following steps of preparation, and first, prepare the alcoholic solution of alkoxide, then metering adds water, so as to hydrolyze to form colloidal sol or gel, second, the glue made is moved in autoclave, seals and heat up, make solvent reach supercriticality, now release solvent and the water extracted, 3rd, with the solution of the quiet remained on surface of inert blowing gas
Coal is made nanometer materials by using plasma spray body method, utilize plasma torch can produce the feature of 50000K high temperature, the hurried cooling of ejection coal of this spray gun just can be generated coal nanometer materials, plasma jet can realize cracking, synthesis, nitrogenizes and reacts with oxidoreduction etc., if cooled down suddenly by the product of reaction, ultramicron can also be made
The ratio of the pore volume of coal and the cumulative volume of coal is called porosity or the porosity, represents with %, it is also possible to the pore volume (cm3/g) that the coal of unit mass comprises represents。The computing formula of porosity,
Porosity=(true density-apparent density)/true density × 100%,
Classify in coal mesopore,
Micropore-its diameter < 10-5mm, it constitutes the absorption volume in coal, (accounting for more than 50%)
Aperture-its diameter=10-5~10-4mm, it constitutes capillary condensation and gas diffusion space;(accounting for more than 28%),
Mesopore-its diameter=10-4~10-3mm, it constitutes the interval of laminar flow infiltration slowly,
Macropore-its diameter=10-3~10-1mm, it constitutes strong laminar flow infiltration interval, and is decided by have the strong surface of fracture destroying structure coal,
Visible hole and crack its diameter > 10-1mm, the interval of its composition laminar flow and turbulent mixture infiltration, and determine macroscopic view (the hard and middle hard coal) surface of fracture of coal,
Infiltration volume: generally the pore volume sum of aperture to visible hole is called infiltration volume,
Total pore size volume: absorption volume is called total pore size volume with infiltration volume sum,
Coal hole and surface area,
Coal is pore-body, wherein contains substantial amounts of surface area。Micropore surface is long-pending to account for more than the 97% of whole surface area, (aperture accounts for 2.5%, and mesopore accounts for 0.2%)
The principal element of coal pore characteristic,
The pore characteristic of coal is closely related with degree of coalification, geology destructiveness and the factor such as crustal stress character and size thereof,
When finding out micropore one its diameter < 10-5mm of different regions coal, the adsorpting characteristic curve of coal and the absorption affinity index of corresponding coal,
Increase porosity and the voidage of coal by artificial means, strengthen the dust-laying effect of coal, may be used under type by artificial means and realize,
Colliery composition granule is in crushing process, mechanical force can be brought out coal particle and be produced the change of series of physical chemical property, (1) change of dispersion, the method characterizing coal particle dispersion is to measure the specific surface area of coal body system, start the dispersion of coal particle during coal-grinding linear with the ore grinding time, the specific surface area of coal particle and ore grinding time exponentially relation afterwards, after again, the dispersion increment of coal particle is negative value, there is the unsaturated field of force and charged construction unit in coal particle surface, coal particle is made to be in the upper state of instability, just reunite under more weak graviational interaction, make granule thicker, fine grinding, crystal structure caused by Ultrafine Grinding, a series of mechanical force and chemical phenomenon such as physicochemical properties and chemical reaction occurs mainly in this stage。(2) dissolubility and rate of dissolution, after the refinement of coal solid particle, the dissolubility of coal increases with rate of dissolution, after coal particle refinement, the mechanical activation effect of coal also there is impact (3) variable density, dry method coal-grinding granule, coal mineral density reduces, wet grinding mill coal particle, coal mineral density reduces, (4) the electrical change of coal particle, Mechanosensitive channels changes coal particle electric conductivity, the absorbability of surface electrical behavior and semiconductor property (5) coal particle surface, coal particle is crushed, the plane of disruption occurs unsaturated bond and charged construction unit, cause that coal particle is in the upper state of instability, thus increasing coal particle activity, improve surface adsorption ability, mechanical activation effect promotes that the raising (6) of colliery thing surface adsorption causes the change (7) of the exchange of coal particle mineral ion or diadochy to cause the change of coal particle surface free energy,
Coal solid particle is under mechanical force, cause the change of coal particle chemistries, mechanical force and light, electricity, magnetic, heat, the energy of the forms such as radiation is the same, the change of chemistries can also be caused, the chemical reaction of the material that this mechanical force is brought out, it is called mechano-chemical reation, coal carries out mechanical force to carry out crushing and grinding to coal, carrying out coal crushing and grind can at Coal Mining Field, coal preparation plant, depositing dust coal production plant or laboratory implement, the equipment that coal uses mechanical force has boulder crusher, jaw crusher, duplex plate Bu Laike disintegrating machine, single toggle crusher, gyratory crusher, coal crushes spendable equipment further have, garden conic crusher, disc type gyratory crusher, Rhonda disintegrating machine, kibbler roll, impact crusher, Ba Make disintegrating machine, roll crusher,
Coal carrying out levigate use equipment have, in the process of raw coal mill, plant equipment used has, various grinding machines, rotating cylinder grinding machine, rod mill, ball mill, autogenous tumbling mill, vibrating mill, centrifugal mill, tower mill, Ball-stirring mill, agitated medium sand setting grinding machine, roll squeezer, overhang roll type mill
Coal solid particle is applied light, electricity, magnetic, heat, the energy of the forms such as radiation, cause the change of coal particle chemistries, coal particle molecular structure is caused to change, cause coal particle atomic structure to change, cause coal particle crystal structure to change, make the coal particle porosity after change increase with voidage and there is depositing dust character。
4. according to coal feature, during with coal as depositing dust material, according to the coal dust produced for certain areas coal, the mine dust that certain metallic ore produces, the mine dust that certain nonmetallic ore produces, the dust produced during manufacture of cement, need raw coal is carried out washing by the dust-laying effect of the depositing dust of raw coal, raw coal has been mixed into various dirt in process of production, exploitation and transportation are inevitably mixed into again rock and other impurity (timber of top board and base plate, metal and cement components), coal is uneven mixture, it is made up of organic substance and inorganic substances two parts, coal separation is the different physics utilizing coal from other material, physical-chemical property, the impurity in raw coal is mechanically removed in coal preparation plant, for reducing the impurity in raw coal, coal is pressed depositing dust quality simultaneously, specification is divided into various product, coal is carried out machining, to adapt to coal to different regions, the depositing dust effect that different minerals (metallic ore and nonmetallic ore) is played,
In the shattering process of raw coal, plant equipment used has, disintegrating machine, jaw crusher, duplex plate Bu Laike disintegrating machine, single toggle crusher, gyratory crusher, garden conic crusher, disc type gyratory crusher, Rhonda disintegrating machine, kibbler roll, impact crusher, Ba Make disintegrating machine, roll crusher
In the process of raw coal mill, plant equipment used has, various grinding machines, rotating cylinder grinding machine, rod mill, ball mill, autogenous tumbling mill, vibrating mill, centrifugal mill, tower mill, Ball-stirring mill, agitated medium sand setting grinding machine, roll squeezer, overhang roll type mill,
Sieve in raw coal screening process has, reciprocating sieve, slanted screen, and glazing bar sieves, horizontal screen, resonance screens, dewatering screen, combination sieve, Mo Gensang sieves, high-frequency screen, regeneration ore pulp sieve, gravity flow screen, bar screen, rotary screen, spiral screen, roller picker, relaxation is sieved, circular vibrating screen, and sieve bend linearly sieves, various compass screen surfaces, compass screen surface fixed by bolt, and tension compass screen surface, from French metal compass screen surface, stretch-draw rubber blanket and polyurethane pad compass screen surface, assemble compass screen surface, woven wire screen compass screen surface
In coal classification process, plant equipment used has, and uses all kinds of grader, hydraulic classifier, horizontal mipmap machine, cone classifier, mechanical classifier, cake formula grader, spiral classifier, hydrocyclone,
Utilizing gravity separation method to process raw coal, device therefor has jigging machine, with the coal grain raw coal with religion weight spoil composition that dissociates, with point contracting chute and separating cone, with spiral chute, shaking table, air table, double-deck ore separators, centrifugal ore separator, coal preparation method has, coal jigging, heavy media coal separation, coal floatation, table separation, hydrocyclone coal separation, inclined trough washing, helicla flute coal separation, hindered bed separator coal separation, combined type dry coal separation。
5. change chemical composition and the chemical constitution of coal, improve the caloric value of coal and other economic worth of coal, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content,
Coal adds carbon atom, carbon atom is made to combine with other element in coal particle, improve the caloric value of coal, change chemical composition and the chemical constitution of coal, strengthen the magnetic of coal particle, electrically, adsorptivity, increase the porosity of coal and voidage, make coal become can the material of depositing dust, coal texture mainly includes the content of two aspects: one is the molecular structure of the chemical constitution of coal and coal;Two is the physical arrangement of coal and intermolecular stacking provisions and pore structure, change carbon content in coal, oxygen, hydrogen, nitrogen, sulfur, chemical composition that 6 kinds of elements of phosphorus combine each other and chemical constitution, change fluorine a small amount of in coal, chlorine, arsenic, boron, plumbous, chemical composition that the elements such as hydrargyrum form each other and chemical constitution, change fluorine a small amount of in coal, chlorine, arsenic, boron, plumbous, the elements such as hydrargyrum and carbon, oxygen, hydrogen, nitrogen, sulfur, chemical composition that 6 kinds of elements of phosphorus combine each other and chemical constitution, change the germanium of formed trace in coal, gallium, vanadium, chemical composition that the rare elements such as uranium are mutual and chemical constitution, change the germanium of formed trace in coal, gallium, vanadium, the rare elements such as uranium and carbon, oxygen, hydrogen, nitrogen, sulfur, chemical composition that 6 kinds of elements of phosphorus combine each other and chemical constitution, change the germanium of formed trace in coal, gallium, vanadium, the fluorine that the rare elements such as uranium are a small amount of with coal, chlorine, arsenic, boron, plumbous, chemical composition that the elements such as hydrargyrum combine each other and chemical constitution,
Colliery composition granule is in crushing process, mechanical force can be brought out coal particle and be produced the change of series of physical chemical property, (1) change of dispersion, the method characterizing coal particle dispersion is to measure the specific surface area of coal body system, start the dispersion of coal particle during coal-grinding linear with the ore grinding time, the specific surface area of coal particle and ore grinding time exponentially relation afterwards, after again, the dispersion increment of coal particle is negative value, there is the unsaturated field of force and charged construction unit in coal particle surface, coal particle is made to be in the upper state of instability, just reunite under more weak graviational interaction, make granule thicker, fine grinding, crystal structure caused by Ultrafine Grinding, a series of mechanical force and chemical phenomenon such as physicochemical properties and chemical reaction occurs mainly in this stage。(2) dissolubility and rate of dissolution, after the refinement of coal solid particle, the dissolubility of coal increases with rate of dissolution, after coal particle refinement, the mechanical activation effect of coal also there is impact (3) variable density, dry method coal-grinding granule, coal mineral density reduces, wet grinding mill coal particle, coal mineral density reduces, (4) the electrical change of coal particle, Mechanosensitive channels changes coal particle electric conductivity, the absorbability of surface electrical behavior and semiconductor property (5) coal particle surface, coal particle is crushed, the plane of disruption occurs unsaturated bond and charged construction unit, cause that coal particle is in the upper state of instability, thus increasing coal particle activity, improve surface adsorption ability, mechanical activation effect promotes that the raising (6) of colliery thing surface adsorption causes the change (7) of the exchange of coal particle mineral ion or diadochy to cause the change of coal particle surface free energy
Coal solid particle is under mechanical force, cause the change of coal particle chemistries, mechanical force and light, electricity, magnetic, heat, the energy of the forms such as radiation is the same, the change of chemistries can also be caused, the chemical reaction of the material that this mechanical force is brought out, it is called mechano-chemical reation, coal carries out mechanical force to carry out crushing and grinding to coal, carrying out coal crushing and grind can at Coal Mining Field, coal preparation plant, depositing dust coal production plant or laboratory implement, the equipment that coal uses mechanical force has boulder crusher, jaw crusher, duplex plate Bu Laike disintegrating machine, single toggle crusher, gyratory crusher, coal crushes spendable equipment further have, garden conic crusher, disc type gyratory crusher, Rhonda disintegrating machine, kibbler roll, impact crusher, Ba Make disintegrating machine, roll crusher,
Coal carrying out levigate use equipment have, in the process of raw coal mill, plant equipment used has, various grinding machines, rotating cylinder grinding machine, rod mill, ball mill, autogenous tumbling mill, vibrating mill, centrifugal mill, tower mill, Ball-stirring mill, agitated medium sand setting grinding machine, roll squeezer, overhang roll type mill
Coal solid particle is applied light, electricity, magnetic, heat, the energy of the forms such as radiation, cause the change of coal particle chemistries, cause coal particle molecular structure to change, cause coal particle atomic structure to change, cause coal particle crystal structure to change, make the coal particle after change have depositing dust character, coal solid particle is applied light intensity and reaches 10cdIt is called for short light intensity with intensity of light, iu is that candela (candela) writes a Chinese character in simplified form cd, coal solid particle is applied electric intensity and reaches 10V/m or more than 10N/C, unit lies prostrate every meter (V/m) or the every storehouse of cattle (N/C), coal solid particle applying magnetic intensity is reached 10GS or more than 10T magnetic induction unit and has Gauss (GS), milli special (mT), tesla (T), coal solid particle applies calorific intensity and reaches more than 100Kcal, or more than 1 (kw), kilocalorie (Kcal), ton evaporation capacity (t), watt (w), kilowatt (kw), coal solid particle is applied radiant intensity and reaches 10W/m2Above, radiant force refers to the total amount of the radiant energy of whole wavelength that object per surface area is launched in the unit interval to half all directions, spherical space, and its conventional unit is W/m2, the equipment that coal applies light intensity has, solid-state gyrolaser, high-pressure microwave plasma exciter, the equipment that to coal, coal is applied electric intensity has, strengthen suspendability charging liquids equipment, the equipment that to coal, coal is applied magnetic intensity has, magnaflux applies method and the circumferential magnetization of magnetic field intensity, the equipment that coal applies calorific intensity has, high frequency firing equipment, high frequency is to utilize electromagnetic field of high frequency to make the intermolecular mutual fierce collision of internal batch produce high temperature, the equipment that coal applies radiant intensity has, change the equipment of the local strength of X-radiation, this equipment includes filling the absorption chamber with ferrofluid with multiple, x-ray filter, absorption chamber, X-radiation direction is stackably arranged。Additionally, x-ray filter includes multiple storage container that can store ferrofluid in it。
6. according to coal characteristic, change the atom composition structure of the coal element of composition coal, change the crystal composition structure of coal element, improve the caloric value of coal and other economic worth of coal, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content
Coal adds carbon, carbon atom is made to combine with other element in coal particle, improve the caloric value of coal, according to coal characteristic, change the atom composition structure of the coal element of composition coal, change the crystal composition structure of coal element, strengthen the magnetic of coal particle, electrically, adsorptivity, increase porosity and the voidage of coal, making coal become can the material of depositing dust, change carbon content in coal, oxygen, hydrogen, nitrogen, sulfur, atomic structure or crystal that 6 kinds of elements of phosphorus combine each other form structure, or atomic structure and crystal composition structure change simultaneously, change fluorine a small amount of in coal, chlorine, arsenic, boron, plumbous, atomic structure or crystal that the elements such as hydrargyrum form each other form structure, or atomic structure and crystal composition structure change simultaneously, change fluorine a small amount of in coal, chlorine, arsenic, boron, plumbous, the elements such as hydrargyrum and carbon, oxygen, hydrogen, nitrogen, sulfur, atomic structure or crystal that 6 kinds of elements of phosphorus combine each other form structure, or atomic structure and crystal composition structure change simultaneously, change the germanium of formed trace in coal, gallium, vanadium, atomic structure or crystal that the rare elements such as uranium are mutual form structure, or atomic structure and crystal composition structure change simultaneously, change the germanium of formed trace in coal, gallium, vanadium, the rare elements such as uranium and carbon, oxygen, hydrogen, nitrogen, sulfur, atomic structure or crystal that 6 kinds of elements of phosphorus combine each other form structure, or atomic structure and crystal composition structure change simultaneously, change the germanium of formed trace in coal, gallium, vanadium, the fluorine that the rare elements such as uranium are a small amount of with coal, chlorine, arsenic, boron, plumbous, atomic structure or crystal that the elements such as hydrargyrum combine each other form structure, or atomic structure and crystal composition structure change simultaneously,
Colliery composition granule is in crushing process, mechanical force can be brought out coal particle and be produced the change of series of physical chemical property, (1) change of dispersion, the method characterizing coal particle dispersion is to measure the specific surface area of coal body system, start the dispersion of coal particle during coal-grinding linear with the ore grinding time, the specific surface area of coal particle and ore grinding time exponentially relation afterwards, after again, the dispersion increment of coal particle is negative value, there is the unsaturated field of force and charged construction unit in coal particle surface, coal particle is made to be in the upper state of instability, just reunite under more weak graviational interaction, make granule thicker, fine grinding, crystal structure caused by Ultrafine Grinding, a series of mechanical force and chemical phenomenon such as physicochemical properties and chemical reaction occurs mainly in this stage (2) dissolubility and rate of dissolution, after the refinement of coal solid particle, the dissolubility of coal increases with rate of dissolution, after coal particle refinement, the mechanical activation effect of coal also there is impact (3) variable density, dry method coal-grinding granule, coal mineral density reduces, wet grinding mill coal particle, coal mineral density reduces, (4) the electrical change of coal particle, Mechanosensitive channels changes coal particle electric conductivity, the absorbability of surface electrical behavior and semiconductor property (5) coal particle surface, coal particle is crushed, the plane of disruption occurs unsaturated bond and charged construction unit, cause that coal particle is in the upper state of instability, thus increasing coal particle activity, improve surface adsorption ability, mechanical activation effect promotes that the raising (6) of colliery thing surface adsorption causes the change (7) of the exchange of coal particle mineral ion or diadochy to cause the change of coal particle surface free energy,
Coal solid particle is under mechanical force, cause the change of coal particle chemistries, mechanical force and light, electricity, magnetic, heat, the energy of the forms such as radiation is the same, the change of chemistries can also be caused, the chemical reaction of the material that this mechanical force is brought out, it is called mechano-chemical reation, coal carries out mechanical force to carry out crushing and grinding to coal, carrying out coal crushing and grind can at Coal Mining Field, coal preparation plant, depositing dust coal production plant or laboratory implement, the equipment that coal uses mechanical force has boulder crusher, jaw crusher, duplex plate Bu Laike disintegrating machine, single toggle crusher, gyratory crusher, coal crushes spendable equipment further have, garden conic crusher, disc type gyratory crusher, Rhonda disintegrating machine, kibbler roll, impact crusher, Ba Make disintegrating machine, roll crusher,
Coal carrying out levigate use equipment have, in the process of raw coal mill, plant equipment used has, various grinding machines, rotating cylinder grinding machine, rod mill, ball mill, autogenous tumbling mill, vibrating mill, centrifugal mill, tower mill, Ball-stirring mill, agitated medium sand setting grinding machine, roll squeezer, overhang roll type mill
Coal solid particle is applied light, electricity, magnetic, heat, the energy of the forms such as radiation, cause the change of coal particle chemistries, cause coal particle molecular structure to change, cause coal particle atomic structure to change, cause coal particle crystal structure to change, make the coal particle after change have depositing dust character, coal solid particle is applied light intensity and reaches 10cdIt is called for short light intensity with intensity of light, iu is that candela (candela) writes a Chinese character in simplified form cd, coal solid particle is applied electric intensity and reaches 10V/m or more than 10N/C, unit lies prostrate every meter (V/m) or the every storehouse of cattle (N/C), coal solid particle applying magnetic intensity is reached 10GS or more than 10T magnetic induction unit and has Gauss (GS), milli special (mT), tesla (T), coal solid particle applies calorific intensity and reaches more than 100Kcal, or more than 1 (kw), kilocalorie (Kcal), ton evaporation capacity (t), watt (w), kilowatt (kw), coal solid particle is applied radiant intensity and reaches 10W/m2Above, radiant force refers to the total amount of the radiant energy of whole wavelength that object per surface area is launched in the unit interval to half all directions, spherical space, and its conventional unit is W/m2, the equipment that coal applies light intensity has, solid-state gyrolaser, high-pressure microwave plasma exciter, the equipment that to coal, coal is applied electric intensity has, strengthen suspendability charging liquids equipment, the equipment that to coal, coal is applied magnetic intensity has, magnaflux applies method and the circumferential magnetization of magnetic field intensity, the equipment that coal applies calorific intensity has, high frequency firing equipment, high frequency is to utilize electromagnetic field of high frequency to make the intermolecular mutual fierce collision of internal batch produce high temperature, the equipment that coal applies radiant intensity has, change the equipment of the local strength of X-radiation, this equipment includes filling the absorption chamber with ferrofluid with multiple, x-ray filter, absorption chamber, X-radiation direction is stackably arranged。Additionally, x-ray filter includes multiple storage container that can store ferrofluid in it。
7. according to coal characteristic, change chemical composition and the chemical constitution of mixture in coal, change the atom composition structure of mixture in coal, change the crystal composition structure of coal element, or atomic structure and crystal composition structure change simultaneously, improve the caloric value of coal and other economic worth of coal, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content
Coal adds carbon, makes carbon atom combine with other element in coal particle or combine with other element of mixture in coal, improve the caloric value of coal, according to coal characteristic, change chemical composition and the chemical constitution of mixture in coal, change the atom composition structure of mixture in coal, change the crystal composition structure of coal element, or atomic structure and crystal composition structure change simultaneously, strengthen the magnetic of coal particle, electrically, adsorptivity, increasing the porosity of coal and voidage, making coal become can the material of depositing dust。The heterogeneity mixture that coal material is made up of the organic compound of many complexity, inorganic mineral, metallo-organic complex etc., changes mixture in coal, as, spoil, the molecular structure in yellow ferrum sulfur ore deposit, atomic structure, crystal structure, improve the dust-laying effect of coal, change the chemical constitution of coal and the molecular structure of coal, the physical arrangement of change coal and intermolecular stacking provisions and pore structure, make coal become depositing dust material, improve the dust-laying effect of coal
In colliery composition granule and coal, mixture is in crushing process, mechanical force can be brought out mixture in coal particle and coal and be produced the change of series of physical chemical property, (1) change of dispersion, the method characterizing coal particle dispersion is to measure the specific surface area of coal body system, start the dispersion of coal particle during coal-grinding linear with the ore grinding time, the specific surface area of coal particle and ore grinding time exponentially relation afterwards, after again, the dispersion increment of coal particle is negative value, there is the unsaturated field of force and charged construction unit in coal particle surface, coal particle is made to be in the upper state of instability, just reunite under more weak graviational interaction, make granule thicker, fine grinding, crystal structure caused by Ultrafine Grinding, a series of mechanical force and chemical phenomenon such as physicochemical properties and chemical reaction occurs mainly in this stage。(2) dissolubility and rate of dissolution, after the refinement of coal solid particle, the dissolubility of coal increases with rate of dissolution, after coal particle refinement, the mechanical activation effect of coal also there is impact (3) variable density, dry method coal-grinding granule, coal mineral density reduces, wet grinding mill coal particle, coal mineral density reduces, (4) the electrical change of coal particle, Mechanosensitive channels changes coal particle electric conductivity, the absorbability of surface electrical behavior and semiconductor property (5) coal particle surface, coal particle is crushed, the plane of disruption occurs unsaturated bond and charged construction unit, cause that coal particle is in the upper state of instability, thus increasing coal particle activity, improve surface adsorption ability, mechanical activation effect promotes that the raising (6) of colliery thing surface adsorption causes the change (7) of the exchange of coal particle mineral ion or diadochy to cause the change of coal particle surface free energy,
In coal solid particle and coal, mixture is under mechanical force, cause the change of blend chemistry in coal particle and coal, mechanical force and light, electricity, magnetic, heat, the energy of the forms such as radiation is the same, the change of chemistries can also be caused, the chemical reaction of the material that this mechanical force is brought out, it is called mechano-chemical reation, coal carries out mechanical force to carry out crushing and grinding to coal, carrying out coal crushing and grind can at Coal Mining Field, coal preparation plant, depositing dust coal production plant or laboratory implement, the equipment that coal uses mechanical force has boulder crusher, jaw crusher, duplex plate Bu Laike disintegrating machine, single toggle crusher, gyratory crusher, coal crushes spendable equipment further have, garden conic crusher, disc type gyratory crusher, Rhonda disintegrating machine, kibbler roll, impact crusher, Ba Make disintegrating machine, roll crusher,
Mixture in coal and coal carrying out levigate use equipment have, in the process of raw coal mill, plant equipment used has, various grinding machines, rotating cylinder grinding machine, rod mill, ball mill, autogenous tumbling mill, vibrating mill, centrifugal mill, tower mill, Ball-stirring mill, agitated medium sand setting grinding machine, roll squeezer, overhang roll type mill
Mixture in coal solid particle and coal is applied light, electricity, magnetic, heat, the energy of the forms such as radiation, cause the change of blend chemistry in coal particle and coal, cause mixture molecular structure in coal particle and coal to change, cause mixture atomic structure in coal particle and coal to change, cause mixture crystal structure in coal particle and coal to change, make the coal particle after change and in coal mixture there is depositing dust character, to coal solid particle apply light intensity reach 10cdIt is called for short light intensity with intensity of light, iu is that candela (candela) writes a Chinese character in simplified form cd, coal solid particle is applied electric intensity and reaches 10V/m or more than 10N/C, unit lies prostrate every meter (V/m) or the every storehouse of cattle (N/C), coal solid particle applying magnetic intensity is reached 10GS or more than 10T magnetic induction unit and has Gauss (GS), milli special (mT), tesla (T), coal solid particle applies calorific intensity and reaches more than 100Kcal, or more than 1 (kw), kilocalorie (Kcal), ton evaporation capacity (t), watt (w), kilowatt (kw), coal solid particle is applied radiant intensity and reaches 10W/m2Above, radiant force refers to the total amount of the radiant energy of whole wavelength that object per surface area is launched in the unit interval to half all directions, spherical space, and its conventional unit is W/m2, the equipment that coal applies light intensity has, solid-state gyrolaser, high-pressure microwave plasma exciter, the equipment that to coal, coal is applied electric intensity has, strengthen suspendability charging liquids equipment, the equipment that to coal, coal is applied magnetic intensity has, magnaflux applies method and the circumferential magnetization of magnetic field intensity, the equipment that coal applies calorific intensity has, high frequency firing equipment, high frequency is to utilize electromagnetic field of high frequency to make the intermolecular mutual fierce collision of internal batch produce high temperature, the equipment that coal applies radiant intensity has, change the equipment of the local strength of X-radiation, this equipment includes filling the absorption chamber with ferrofluid with multiple, x-ray filter, absorption chamber, X-radiation direction is stackably arranged。Additionally, x-ray filter includes multiple storage container that can store ferrofluid in it。
8. according to coal characteristic, change the surface nature of colliery thing, improve the caloric value of coal and other economic worth of coal, by the method for coal mineral surface modification and modifying agent, reduce the inherent moisture of coal, reduce pit ash, improve the volatile matter of coal, improve carbon content in coal essence content
Coal adds carbon, carbon atom is made to be combined with modified coal facies, improve the caloric value of coal, according to coal characteristic, change the surface nature of colliery thing, strengthen the magnetic of coal particle, electrically, adsorptivity, increase porosity and the voidage of coal, strengthen coal and coal produces the dust-laying effect between coal dust, strengthen the dust-laying effect between the mine dust of coal and the generation of certain metallic ore, strengthen the dust-laying effect between the mine dust of coal and the generation of certain nonmetallic ore, strengthen the dust-laying effect between the dust produced in coal and cement production process, strengthen the diameter granule less than or equal to 2.5 microns in coal dust degraded earth atmosphere, reach to administer air pollution depositing dust effect higher, reduction along with coal particle degree, then coal particle surface activity also improves therewith, it is many-sided that coal micronized particles has high surface, there is high chemical reactivity, high absorption capacity, high coherency, the adsorption property of Study on Coal micronized particles, Study on Coal granular solids and the adsorption property on solid two-phase interface, coal particle solid claims adsorbent, other adsorbed solid particles claim adsorbate, absorption is divided into physical absorption and chemisorbed, both essential distinctions are with or without electron transfer between adsorbate and adsorbent, the physical absorption of Study on Coal granule and chemisorbed, Study on Coal particle surface modification, coal particle absorption affinity is made to strengthen, develop coal particle surface modifying agent, the granule modified method of Study on Coal, develop coal particle reforming apparatus, utilize mental retardation primary particle, as, photon, electronics, ion, interact with coal particle surface, produce scattering or launch secondary, by analyzing the power spectrum of ejecting particle, mass spectrum or spectrum, the surface information that coal particle is relevant can be obtained, utilize surface Spectrum Analysis technology, can reveal that the composition of coal particle surface, the much information such as ionic valence condition and chemical bond, combine with scanning detecting probe method by static secondary ion mass spectrum, the absorption specimen of detection coal particle, utilize polyether-type nonionic dispersant, adopt X-ray electronic energy to borrow and add argon ion etching device, measure coal particle and Additive front and rear surfaces characteristic atomic valence state and energy variation, and the feature according to instrument, calculate the thickness of dispersant adsorption film on surface,
The method of coal mineral surface modification has (1) surface coating modification method, namely by adhesion, the method that modifying agent (Organic substance or inorganic matter) is covered in coal mineral particle, is used as the Kaolin of filler, Muscovitum by naturally occurring or synthetic rubber processing, ball clay, or it is coated in coal particle surface with phenolic resin or furane resins, the caking property of coal, many inorganic oxides or hydroxide can be improved, as, TiO2, SiO2, Al (OH)2There is respective zero point pH value。By controlling the pH value of solution, absorption surface activating agent makes coal particle surface modifiy, (2) can also be used with surface chemical modification method, modifying agent and some functional group of mineral surfaces is utilized to carry out chemical reaction or chemisorbed, reach the purpose that coal particle surface is modified, in this kind of method of modifying, it is made by stronger bonding force (such as covalent bond) between coal particle and modifying agent to have an effect, (3) can also be used with mechanical-chemical modification method, namely by pulverizing, grind, the mechanical means such as friction, make mineral lattice structure, crystal formations etc. change, can increase in system, temperature raises, promote particle to melt or decompose or produce free radical or ion, strengthen coal particle surface activity, promote coal particle and other material generation chemical reaction or mutually adhere to, reach the purpose of surface modification, (4) the modified method of available precipitation, during using inorganic matter as modifying agent, the method utilizes the precipitation between modifying agent, coal particle surface deposits one or more layers modified layer, to change coal particle surface character, (5) modified (capsule) method of theca externa, namely at the thin film of coal particle surface bag other material of last layer, , the theca externa wrapped is uniform, shape is capsule such as, it has protection core substance, regulate, release the function of core material, blend compounds encapsulated changes appearance and the character of coal particle, capsule-type prepares method mainly spray coating, spray drying, interfacial polymerization, it is separated and dissolves dispersion cooling method, make the material of capsule wall except organic polymer beyond the region of objective existence, inorganic substances have TiO2, AL2O3, Fe2O3, ZnO and silicates, glue core material has magnesium carbonate, aluminium silicate, sodium hydrosulfite or other gaseous state, liquid。(6) coal particle surface is modified by the means such as the modified method of high energy surface, utilizes plasma, corona discharge, ultraviolet,
Coal surface modification device has (1) bulk material mixer, has mixed stirring device, including container rotating type, (2) high velocity air impact type powder modifying devices such as container fixed pattern and air-flow mixed type, this system is by mixer, metering system, main frame, product collecting device, control system is formed, and main frame is by the rotor of high speed rotating, the parts such as stator and closed circuit form, there are chuck, cooling or heating rotor use between stator and rotor, in rotor, have fin。(3) surface modification is held concurrently reducing mechanism,
Evaluation to coal particle surface modified effect, carries out the measurement of some physicochemical properties and surface characteristic to coal particle, compares the change of coal particle depositing dust absorption index after before modified, reaches to evaluate the purpose of modified effect。Basic skills has (1) moist (2) dispersibility (3) infrared spectrum, as long as there is certain functional group or key in coal surface, mineral spectrogram just has corresponding characteristic absorption peak, so, to after before modified and modified after carry out infrared spectrum analysis through the coal particle sample of various process, change according to character pair peak, just effect and the mechanism of surface modifier can be disclosed, (4) X-ray diffraction, the mixture solid structure of matter in Study on Coal particulate solid material structure and coal, available X-ray diffraction method。Can be used to coal Polycrystalline make Discriminating materials and lattice parameter mensuration, monocrystal X-ray is done structure determination and crystal integrity research (5) heat is analyzed, heat is analyzed and is included differential thermal and calorimetric analysis, differential thermal analysis is used for investigating coal particle in heating process, when reaching certain temperature, due to the heat effect that phase transformation or some chemical reaction produce, analyzing, there is exothermic peak or absworption peak in curve, the size of peak area reflects the power of heat effect, thermogravimetric analysis can measure the change as temperature or the material mass of time function, when carrying out heat and analyzing, generally by two kinds of heat analysis method couplings。(6) solid surface analysis technology is utilized, utilize surface Spectrum Analysis technology, can reveal that the composition of coal particle surface, the much information such as ionic valence condition and chemical bond, combine with scanning detecting probe method by static secondary ion mass spectrum, the absorption specimen of detection coal particle, utilize polyether-type nonionic dispersant, adopt X-ray electronic energy to borrow and add argon ion etching device, measure coal particle and Additive front and rear surfaces characteristic atomic valence state and energy variation, and the feature according to instrument, calculate the thickness of dispersant adsorption film on surface
Coal surface modifier has coupling agent, surfactant, polymer class and Inorganic surface modifiers,
The series such as coupling agent is siliceous or metallic atom organic compound, different by central atom, has a silane system, titanate esters system, Aluminate system, stannic acid ester system, aluminum zirconate system。
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