CN105686973A - Makeup removing lotion and wet wipe thereof - Google Patents
Makeup removing lotion and wet wipe thereof Download PDFInfo
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- CN105686973A CN105686973A CN201410692634.8A CN201410692634A CN105686973A CN 105686973 A CN105686973 A CN 105686973A CN 201410692634 A CN201410692634 A CN 201410692634A CN 105686973 A CN105686973 A CN 105686973A
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Abstract
The invention discloses a makeup removing lotion and a wet wipe thereof. The makeup removing lotion comprises an oil phase substance, water, glycyrrhizic acid or one or more of glycyrrhizinates, and a surfactant, and the oil phase substance is dispersed in water under the action of the surfactant and the glycyrrhizic acid or one or more of glycyrrhizinates in order to form the transparent or semi-transparent lotion with isotropy and stable thermodynamics. The makeup removing lotion prepared in the above mode has the advantages of lasting stability, improvement of the makeup removing efficiency, and non-greasiness, and the wet wipe has the advantages of simple steps, high efficiency and convenient carrying.
Description
Technical field
The present invention relates to cosmetic product field, particularly relate to a kind of cleaning lotion and wet tissue。
Background technology
Cosmetic composition is improper or resident skin overlong time can increase the weight of skin metabolism burden, skin of releiving must be removed ornaments and formal dress in good time, recover skin vitality, additionally, also require that when changing the makeup that makeup removing series products can quickly and efficiently clean existing color make-up, accept the new look of a woman after make-up for skin and prepare。
Existing makeup removing series products has makeup remover, makeup removing breast and makeup removing liquid three class；The molten oil ability of makeup remover is strong, is suitable for the color make-up composition of removal water proof type, but makeup remover can bring obvious greasy feeling to people while using；It is moderate that although makeup removing breast and the liquid effect water oil component through surfactant of removing ornaments and formal dress compare balance, relatively salubriouser during use, but non-thermodynamics stabilisation systems, it is easy to layering, product lasting stability is poor。Additionally, after above three class makeup removal products uses, be required for rinsing with water, then again clean face with cleansing milk, to remove the oils and fats of face's residual, makeup removing cleaning is cumbersome, if desired goes on business or travels, carrying very inconvenient。
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of cleaning lotion and wet tissue, this cleaning lotion can lasting stability, improve makeup removal efficiency and non-greasy, this wet tissue makeup removing step simple and effective, easy to carry。
For solving above-mentioned technical problem, the technical scheme that the present invention adopts is: provide a kind of cleaning lotion, including more than one in oil phase substance, water, glycyrrhizic acid or glycyrrhetate, surfactant, described oil phase substance is dispersed in described water under the effect of described surfactant and glycyrrhizic acid or glycyrrhetate, and then forms isotropism, thermodynamically stable transparent or semitransparent emulsion。
Wherein, in described cleaning lotion, the weight/mass percentage composition of described oil phase substance is 1%～10%, and more than one the weight/mass percentage composition in described glycyrrhizic acid or glycyrrhetate is 0.05%～5%, and the weight/mass percentage composition of described surfactant is 1%～20%。
Wherein, more than one the weight/mass percentage composition in described glycyrrhizic acid or glycyrrhetate is 0.3%～5%。
Wherein, the quality of described oil phase substance is 1: 1～10 with the mass ratio helping emulsifier, more than one quality sum in the described quality that quality is described surfactant helping emulsifier and described glycyrrhizic acid or glycyrrhetate, the quality of described surfactant is 1～50: 1 with more than one the mass ratio in described glycyrrhizic acid or glycyrrhetate。
Wherein, the quality of described surfactant is 1～25: 1 with more than one the mass ratio in described glycyrrhizic acid or glycyrrhetate。
Wherein, described cleaning lotion also includes skin protectant, and in described cleaning lotion, the weight/mass percentage composition of described skin protectant is 0.1%～10%。
Wherein, described oil phase substance includes polyethenoxy ether and mineral oil。
Wherein, described polyethenoxy ether includes more than one in PPG-15 tristearin alcohol ether, PPG-11 tristearin alcohol ether, PPG-7 lauryl ether, PPG-3 Semen Myristicae alcohol ether, PPG-10 cetyl ether, PPG-14 butyl ether, PPG-5 ceteth-20, PPG-10 oleyl ether, and described mineral oil includes more than one in Fancol ID, 2-Methylpentadecane。
Wherein, described glycyrrhetate includes more than one in the potassium salt of glycyrrhizic acid, sodium salt and ammonium salt。
Wherein, described surfactant to be hydrophile-lipophile balance value be 8～20 a kind of nonionic surfactant or the mixture of two or more nonionic surfactant。
Wherein, described surfactant includes tween 20, Tween-60, tween 80, anhydrous sorbitol laurate, Span60, sorbitan monooleate, alkyl polyglucoside and derivant thereof, PEG-20 sucrose stearate, PEG-5 glyceryl stearate, Cremophor RH40, PEG-60 castor oil hydrogenated, ceteareth-6, ceteareth-25, stereth-2, stereth-21, laureth-4, laureth-23, C12-13 Pareth-3, C12-13 Pareth-4, C12-13 Pareth-23, polyglycereol-4 laurate, two lauryl alcohol Fructus Citri Limoniae esters, PEG-40 tristerin, cetearyl glucoside, more than one in glyceryl stearate citrate。
Wherein, described skin protectant includes more than one in alcohols skin protectant, esters skin protectant, oils skin protectant, macromolecule skin protectant and complementary skin protectant。
Wherein, described alcohols skin protectant includes more than one in propylene glycol, glycerol, butanediol, pentanediol, ethohexadiol, hexadecanol, and described esters skin protectant includes more than one in two PPG-3 myristyl ether adipate esters and two PPG-2 Semen Myristicae oleth-10 adipate esters。
Wherein, described cleaning lotion also includes more than one in preservative, essence, pH adjusting agent, thickening agent。
For solving above-mentioned technical problem, another technical solution used in the present invention is: provide a kind of wet tissue, and including carrier and above-mentioned cleaning lotion, described cleaning lotion applies on the carrier。
Wherein, the quality of described carrier is 1: 1～5 with the mass ratio of described cleaning lotion。
Wherein, described carrier is made up of porous, hydrophilic material。
For solving above-mentioned technical problem, another technical solution used in the present invention is: provide the application a kind of by glycyrrhizic acid or glycyrrhetate, emulsion being carried out solubilising, helping emulsifying aspect。
The invention has the beneficial effects as follows: be different from the situation of prior art, the present invention by surfactant and glycyrrhizic acid or/and the effect of glycyrrhetate, oil phase substance is dispersed in water, form isotropism, thermodynamically stable transparent or semitransparent emulsion, this emulsion is emulsion oil-in-water, the advantage with salubrious non-greasy, simultaneously, due to the effect of surfactant with there is solubilising, help the glycyrrhizic acid of emulsification or the effect of glycyrrhetate, oil phase substance can better be dispersed in water, and long-time stable is not stratified；When the cleaning lotion of the present invention is applied on skin, by the effect of surfactant and glycyrrhizic acid or glycyrrhetate, changes the contact angle between emulsion and skin, make cleaning lotion more uniformly can sprawl at skin surface, improve makeup removal efficiency。
Detailed description of the invention
Embodiment of the present invention provides a kind of cleaning lotion, including more than one in oil phase substance, water, glycyrrhizic acid or glycyrrhetate, surfactant, oil phase substance is dispersed in water under the effect of surfactant and glycyrrhizic acid or glycyrrhetate, and then forms isotropism, thermodynamically stable transparent or semitransparent emulsion。
Oil phase substance refers to the material being not readily dissolved in water, significantly layering can occur when mixing with water or muddiness occur；Oil phase substance can effectively dissolve the lubricant component in cosmetics, plays good makeup removing effect；Surfactant has fixing hydrophilic and lipophilic group, surfactant can reduce the surface tension of oil phase substance and water, make oil phase substance and water dissolve each other and form transparent or semitransparent emulsion, simultaneously, surfactant can also play the effect of emulsifying, cleaning, decontamination in cleaning lotion makeup removing process, improves makeup removal efficiency further；Glycyrrhizic acid is the main active in Radix Glycyrrhizae, two molecule glucose aldehydic acid and a part enoxolone (a kind of pentacyclic triterpenoid) are combined into, and glycyrrhetate is the salt of glycyrrhizic acid；Embodiment of the present invention can be used alone glycyrrhizic acid or be used alone glycyrrhetate, it is possible to glycyrrhizic acid and glycyrrhetate is mixed and uses；Glycyrrhizic acid and glycyrrhetate mainly play solubilising in embodiments of the present invention, help emulsification, the surface tension of solution can be reduced, thus reducing the consumption of surfactant, change the hydrophile-lipophile balance of surfactant, participate in forming micelle, adjust the polarity of water and oil phase substance, finally affect phase and the phase character of the system of oil phase substance and water, make the transparent or semitransparent uniform emulsion of System forming of oil phase substance and water；The isotropism of embodiment of the present invention, thermodynamically stable transparent or semitransparent emulsion are actually oil-in-water microemulsion, and the diameter of its dispersant liquid drop is less than 1 micron。
Embodiment of the present invention by surfactant and glycyrrhizic acid or/and the effect of glycyrrhetate, oil phase substance is dispersed in water, form isotropism, thermodynamically stable transparent or semitransparent emulsion, this emulsion is emulsion oil-in-water, the advantage with salubrious non-greasy, simultaneously as the effect of surfactant and there is solubilising, help the glycyrrhizic acid of emulsification or the effect of glycyrrhetate, oil phase substance can better be dispersed in water, and long-time stable is not stratified；Simultaneously as glycyrrhizic acid or glycyrrhetate have solubilising, help emulsification, it is possible to reduce the consumption of surfactant in cleaning lotion, it is to avoid because of the tight problem with stimulation of skin brought containing substantial amounts of surfactant in cleaning lotion；When the cleaning lotion of the present invention is applied on skin, by the effect of surfactant and glycyrrhizic acid or glycyrrhetate, changes the contact angle between emulsion and skin, make cleaning lotion more uniformly can sprawl at skin surface, improve makeup removal efficiency。
The surfactant of embodiment of the present invention is that HLB value (hydrophile-lipophile balance value of surfactant) ranges for the single nonionic surfactant of 8～20 or the mixture of two or more nonionic surfactant, and the HLB value of this surfactant can be 8, 14 or 20 etc., nonionic surfactant does not exist with ionic condition in emulsion, and stability is high, and it has cleaning, the effect of decontamination, the surfactant of embodiment of the present invention includes tween 20, Tween-60, tween 80, anhydrous sorbitol laurate, Span60, sorbitan monooleate, alkyl polyglucoside and derivant thereof, PEG-20 sucrose stearate, PEG-5 glyceryl stearate, Cremophor RH40, PEG-60 castor oil hydrogenated, ceteareth-6, ceteareth-25, stereth-2, stereth-21, laureth-4, laureth-23, C12-13 Pareth-3, C12-13 Pareth-4, C12-13 Pareth-23, polyglycereol-4 laurate, two lauryl alcohol Fructus Citri Limoniae esters, PEG-40 tristerin, cetearyl glucoside, more than one in glyceryl stearate citrate。
Further, in embodiment of the present invention, glycyrrhetate includes more than one in the potassium salt of glycyrrhizic acid, sodium salt and ammonium salt, and the glycyrrhizic acid of embodiment of the present invention and the general structure of glycyrrhetate be:
Wherein, when R1, R2 and R3 are H, this general structure represents glycyrrhizic acid。When in R1, R2 and R3, any one is K, when other two is H, this general structure represents glycyrrhizic acid one potassium；When in R1, R2 and R3, any two is K, all the other one when being H, this general structure represents glycyrrhizic acid dipotassium；When R1, R2 and R3 are K, this general structure represents tripotassium glycyrrhetate。When in R1, R2 and R3, any one is Na, when other two is H, this general structure represents glycyrrhizic acid one sodium；When in R1, R2 and R3, any two is Na, all the other one when being H, this general structure represents disodium glycyrrhizinate；When R1, R2 and R3 are Na, this general structure represents trisodium glycyrrhetinate。When in R1, R2 and R3, any one is NH4, when other two is H, this general structure represents glycyrrhizic acid one ammonium；When in R1, R2 and R3, any two is NH4, all the other one when being H, this general structure represents diammonium glycyrrhizinate；When R1, R2 and R3 are NH4Time, this general structure represents glycyrrhizic acid three ammonium。
Further, in cleaning lotion, the weight/mass percentage composition of oil phase substance is 1%～10%, such as 1%, 5% or 10% etc., more than one weight/mass percentage composition in glycyrrhizic acid or glycyrrhetate is 0.05%～5%, such as 0.05%, 2% or 5% etc., the weight/mass percentage composition of surfactant is 1%～20%, such as 1%, 10% or 20% etc., weight/mass percentage composition refers to that this material mass accounts for the percentage ratio of cleaning lotion gross mass, more than one in glycyrrhizic acid or glycyrrhetate refer to glycyrrhizic acid, the mixture of glycyrrhetate or glycyrrhizic acid and glycyrrhetate, in cleaning lotion, residue content part is the content of water；The cleaning lotion of embodiment of the present invention adopt in the oil phase substance of suitable proportioning, surfactant, glycyrrhizic acid or glycyrrhetate more than one, water, cleaning lotion can be made to reach well to remove ornaments and formal dress effect, stability of emulsion is high simultaneously, can long storage time not stratified。In another embodiment of the present invention, more than one weight/mass percentage composition in glycyrrhizic acid or glycyrrhetate is 0.3%～5%, such as 0.3%, 0.6% or 5% etc., experiment proves, when more than one the weight/mass percentage composition in glycyrrhizic acid or glycyrrhetate is 0.3%～5%, its to the solubilising of emulsion, help emulsifying effect especially pronounced, the consumption of surfactant in cleaning lotion can be greatly reduced, reduce the cleaning lotion tight problem with stimulation of skin because bringing containing exhibiting high surface activating agent。
Further, the quality of oil phase substance is 1: 1～10 with the mass ratio helping emulsifier, such as 1: 1, 1: 5 or 1: 10 etc., help emulsifier is more than one the general designation in surfactant and glycyrrhizic acid or glycyrrhetate herein, namely more than one the quality sum in the quality that quality is surfactant of emulsifier and glycyrrhizic acid or glycyrrhetate is helped, the quality of surfactant is 1～50: 1 with more than one the mass ratio in glycyrrhizic acid or glycyrrhetate, such as 1: 1, 20: 1 or 50: 1 etc., embodiment of the present invention adopts the oil phase substance of proper proportion and helps emulsifier, oil phase substance can be made to be dispersed stably in water, form transparent or semitransparent emulsion。
Further, the quality of surfactant is 1～25: 1 with more than one the mass ratio in glycyrrhizic acid or glycyrrhetate, such as 1: 1,10: 1 or 25: 1 etc., the use of a small amount of glycyrrhizic acid or glycyrrhetate, the consumption of surfactant can be significantly reduced, it is to avoid the tight problem with stimulation skin of skin that the use of exhibiting high surface activating agent brings。
Further, cleaning lotion also includes skin protectant, and in cleaning lotion, the weight/mass percentage composition of skin protectant is 0.1%～10%, for instance 0.1%, 5% or 10% etc.。
The skin protectant of embodiment of the present invention is after skin is removed ornaments and formal dress by cleaning lotion, the effect of moist skin care can be played, the discomfort such as dry tight after cleaning lotion uses, skin brought can be reduced, eliminate the step also smearing skin care item in prior art after makeup removing further, effectively simplify makeup removing cleaning, makeup removing cleaning efficiency and property easy to use can be improved。
The skin protectant of embodiment of the present invention includes more than one in alcohols skin protectant, esters skin protectant, oils skin protectant, macromolecule skin protectant and complementary skin protectant, alcohols skin protectant includes more than one in propylene glycol, glycerol, butanediol, pentanediol, ethohexadiol, hexadecanol, these alcohols skin protectant also have solubilising and help the effect of emulsifying, can help to form microemulsion, reduce the consumption of surfactant further；Esters skin protectant includes more than one in dicaprylyl carbonate, caprylic/capric triglyceride, isopropyl myristate, isopropyl palmitate, two PPG-3 myristyl ether adipate esters, two PPG-2 Semen Myristicae oleth-10 adipate esters；In another embodiment of the present invention, esters skin protectant is more than one in two PPG-3 myristyl ether adipate esters and two PPG-2 Semen Myristicae oleth-10 adipate esters, both esters skin protectant also have solubilising and help the effect of emulsifying, can help to form microemulsion, reduce the consumption of surfactant further；Oils skin protectant includes more than one in Jojoba oil (being again Jojoba oil), olive oil, mineral oil, Oleum Ricini, lanoline, macromolecule skin protectant includes more than one in hyaluronic acid, collagen protein, and complementary skin protectant includes more than one in bisabolol, Radix Hamamelidis Mollis extracting solution, Flos Matricariae chamomillae extracting solution, oat beta-glucan, Aloe。
Further, oil phase substance includes polyethenoxy ether and mineral oil, and namely oil phase substance is at least include the compound oily components of polyethenoxy ether and mineral oil, and mineral oil is alkanes oily matter。The oily matter of embodiment of the present invention has diversification oily components, and different color make-up compositions has the effects such as moistening, dispersion, softening, dissolving；Polyethenoxy ether or mineral oil are all oils and fats and the good solvent of wax class, also can make opaque and pigment wetting and disperse；In addition, polyethenoxy ether is fatty alcohol and epoxypropane polymer, except the lubricant component in color make-up is had excellent dissolution, also has good intermiscibility for the film forming polymer being difficult in the mascara of removal, can soft polymer granule, make polymeric chain swelling loose；After unwinding, the oil components such as wax class, opaque, coloring agent easily depart from from polymer molecule, dissolved by mineral oil and remaining polyethenoxy ether oil-based solvent subsequently, plus the emulsifying solubilization of surfactant and glycyrrhizic acid or glycyrrhetate, can the color make-up composition in removal film-forming type waterproof mascara effectively up hill and dale。
The polyethenoxy ether of embodiment of the present invention includes more than one in PPG-15 tristearin alcohol ether, PPG-11 tristearin alcohol ether, PPG-7 lauryl ether, PPG-3 Semen Myristicae alcohol ether, PPG-10 cetyl ether, PPG-14 butyl ether, PPG-5 ceteth-20, PPG-10 oleyl ether, and mineral oil includes having more than one in the Fancol ID of low melting point highly branched chain structure, 2-Methylpentadecane。
Further, the cleaning lotion of embodiment of the present invention also includes more than one in preservative, essence, pH adjusting agent, thickening agent, this preservative, essence, pH adjusting agent, thickening agent are aqueous phase substance soluble in water, and this preservative, essence, pH adjusting agent, thickening agent select the preservative of this area routine, essence, pH adjusting agent, thickening agent。
Another embodiment of the present invention provides a kind of wet tissue, and including the cleaning lotion of carrier and above-mentioned embodiment, cleaning lotion is applied on carrier。
Cleaning lotion can adopt spray, impregnating this area routinely on carrier the mode of coating solution be applied on carrier；The carrier object that can be used for scrape skin for ease of carrying and use, such as napkin, cloth products, it can absorb a certain amount of liquid of preservation。
Above-mentioned cleaning lotion is applied on carrier by embodiment of the present invention, by carrier scrape skin, cleaning lotion is made to transfer on skin, and then skin is removed ornaments and formal dress, this wet tissue is easy to use, can in cleaning lotion makeup removing process, by the wiping of carrier, the oils and fats remained on skin is removed, eliminate the step cleaned further with water, simultaneously because containing skin protectant in cleaning lotion, may also function as the effect of skin protection, relative to tradition the makeup removing makeup removing of process, cleaning, skin protection step, the makeup removing step of embodiment of the present invention obtains great simplification。
Further, the quality of carrier is 1: 1～5 with the mass ratio of cleaning lotion, for instance 1: 1,1: 3 or 1: 5 etc., the mass ratio suitable by controlling carrier and cleaning lotion, is added to equably on carrier by cleaning lotion, to make wet tissue。
Further, carrier is made up of porous, hydrophilic material, and porous, hydrophilic material is strong with water binding ability, can be effectively improved the retention ratio of cleaning lotion, and the color make-up composition of removal can be made to be effectively retained in carrier；The carrier of embodiment of the present invention can be non-woven fabrics, the wet napkin etc. that religion is high by force。
Another embodiment of the present invention also provides for a kind of by glycyrrhizic acid or glycyrrhetate, emulsion being carried out solubilising, helps the application of emulsifying aspect。
In existing technology, glycyrrhizic acid and glycyrrhetate are all widely used at food, medicine, daily use chemicals and cosmetic field。But presently known, glycyrrhizic acid and glycyrrhetate are mainly used as sweeting agent, flavoring agent, flavor potentiator, sports drink kalium replenishment agent in food service industry。In medicine, daily use chemicals and cosmetic field, glycyrrhizic acid and glycyrrhetate mainly play antiinflammatory, antioxidation, antibacterial, treatment wound, antiallergic, prevention histamine release, effectively remove superoxide ion and hydroxyl radical free radical, significantly inhibit the effects such as liposome peroxidation thing。But in embodiments of the present invention, glycyrrhizic acid and glycyrrhetate mainly play solubilising, help emulsification, the surface tension of solution can be reduced, thus reducing the consumption of surfactant, change the hydrophile-lipophile balance of surfactant, participate in forming micelle, adjust the polarity of water and oil phase substance, final phase and the phase character affecting emulsion system, makes the transparent or semitransparent uniform microemulsion of System forming。
Below by detailed description of the invention, the present invention will be further described:
Embodiment 1
Present embodiment mainly investigate glycyrrhizic acid or glycyrrhetate to the solubilising of emulsion, help emulsification。
Present embodiment adds the glycyrrhizic acid dipotassium that mass fraction is 0.1%, 0.2%, 0.25%, 0.3%, 0.4%, 0.4% and 0.6% respectively in conventional emulsions seven groups identical, use the 8th group of identical conventional emulsions not adding glycyrrhizic acid dipotassium as reference simultaneously, being respectively added on non-woven fabrics by above-mentioned eight groups of emulsions with identical amount, the turbidity after liquid dilution twice and the change of solution particle diameter before and after interpolation glycyrrhizic acid dipotassium are extruded in test from non-woven fabrics。
Table 1 is the addition of glycyrrhizic acid dipotassium and the relation of turbidity after extruding liquid dilution twice from non-woven fabrics。
Table 1
| Glycyrrhizic acid dipotassium % | Emulsion cross non-woven fabrics after turbidity (diluting 2 times) |
| 0 | 665 |
| 0.1 | 444 |
| 0.2 | 226 |
| 0.25 | 143 |
| 0.3 | 23 |
| 0.4 | 31.8 |
| 0.5 | 29.9 |
| 0.6 | 27.9 |
As can be seen from Table 1, after emulsion adds a small amount of glycyrrhizic acid dipotassium, the turbidity of emulsion can substantially reduce, illustrate that glycyrrhizic acid dipotassium can play solubilising, help the effect of emulsifying, when add glycyrrhizic acid dipotassium be emulsion content more than or equal to 0.3% time, the turbidity of emulsion significantly reduces, and illustrates that this ranges for reducing emulsion turbidity and use one of glycyrrhizic acid dipotassium preferably content range。
Table 2 is add the change of solution particle diameter before and after glycyrrhizic acid dipotassium。
Table 2
Wherein, the size distribution curve that D10, D50, D90 are recorded by laser diffractometry draws, D10 represents that in emulsion, particle diameter accounts for the 10% of total particle number more than the granule of this numerical value, D50 represents that in emulsion, particle diameter accounts for the 50% of total particle number more than the granule of this numerical value, and D90 represents that in emulsion, particle diameter accounts for the 90% of total particle number more than the granule of this numerical value。
From Table 2, it can be seen that after adding glycyrrhizic acid dipotassium, the particle diameter of emulsion can diminish；From the appearance the turbidity of emulsion can increase along with the addition of glycyrrhizic acid dipotassium and constantly reduce, and when reaching a certain particular value, emulsion will be eventually become transparent color by milky, and namely glycyrrhizic acid dipotassium has solubilising, helps the effect of emulsifying。Because the characteristic of each emulsification system is different, the addition of the glycyrrhizic acid dipotassium needed for formation transparent micro emulsion, need to be adjusted as the case may be。
Further, present embodiment also selects the glycyrrhizic acid dipotassium respectively accounting for quality of the emulsion mark 0.3% and Common surface active agent tween-20 to join in same emulsion system, use one group of emulsion not adding glycyrrhizic acid dipotassium and tween 20 as comparison simultaneously, assessed both solubilizing effects by the outward appearance of the turbidity of test emulsion, observation emulsion。
Table 3 is glycyrrhizic acid dipotassium and the tween 20 contrast to emulsion solubilizing effect。
Table 3
As can be seen from Table 3, under identical addition, the solution turbidity adding glycyrrhizic acid dipotassium is decreased obviously, and outward appearance is become transparent from milky, and adding the emulsion of tween 20, turbidity does not have significant change, and outward appearance also remains as milky, namely the solubilizing effect of glycyrrhizic acid dipotassium is substantially better than tween 20, therefore adds a certain amount of glycyrrhizic acid dipotassium in formula system and can reduce the consumption of required surfactant when forming microemulsion。The addition of glycyrrhizic acid dipotassium can reduce equivalent oil phase component amount of required surfactant when emulsifying, solubilising formation microemulsion, thus avoiding the tight problem with stimulation of skin because bringing in formula liquid containing substantial amounts of surfactant。
The glycyrrhizic acid dipotassium of present embodiment is an example of glycyrrhizic acid or glycyrrhetate, because the structure of glycyrrhizic acid or glycyrrhetate and the structure of glycyrrhizic acid dipotassium are identical, it also has the character identical with glycyrrhizic acid dipotassium, and glycyrrhizic acid and glycyrrhetate can play solubilising, help the effect of emulsifying。
Embodiment 2
Present embodiment is the preparation of cleaning lotion and wet tissue。
Preparation emulsion:
(1) add water to, in allotment bucket, whipping process add propylene glycol；
(2) Arlamol E and tween 20 are added in the first keg, be uniformly mixed；Two PPG-3 myristyl ether adipate esters, 2-Methylpentadecane, laureth-4 and tween 20 are joined in the second keg, and is uniformly mixed；Solution in second keg is joined in the first keg, and after being uniformly mixed, joins in allotment bucket；
(3) complementary to glycyrrhizic acid dipotassium and preservative, pH adjusting agent etc. composition is added in allotment bucket, and continue stirring and be completely dissolved to it and obtain cleaning lotion。
Prepare wet tissue:
The cleaning lotion prepared and carrier are added carrier in mass ratio at 2.5: 1, then cuts into required size and can be prepared by required wet tissue。
In above-mentioned cleaning lotion, the content of each component is in Table 4, and wherein content refers to that each constituent mass accounts for the percentage ratio of total cleaning lotion quality。
Table 4
| Sequence number | Composition | Content % (w/w) |
| 1 | Pure water | Surplus |
| 2 | Propylene glycol | 5 |
| 3 | Arlamol E | 1.5 |
| 4 | Tween 20 | 4.0 |
| 5 | Two PPG-3 myristyl ether adipate esters | 0.5 |
| 6 | 2-Methylpentadecane | 1.6 |
| 7 | Laureth-4 | 4.13 |
| 8 | Tween 20 | 0.85 |
| 9 | Glycyrrhizic acid dipotassium | 1.50 |
| 10 | The complementary composition such as preservative, pH adjusting agent | In right amount |
Embodiment 3
Present embodiment is the preparation of cleaning lotion and wet tissue。
Preparation emulsion:
(1) add water to, in allotment bucket, whipping process add butanediol；
(2) PPG-3 Semen Myristicae alcohol ether and Cremophor RH40 are added in the first keg, be uniformly mixed；Two PPG-2 Semen Myristicae oleth-10 adipate esters, 2-Methylpentadecane, C12-13 Pareth-4 and tween 20 are joined in the second keg, and is uniformly mixed；Solution in second keg is joined in the first keg, and after being uniformly mixed, joins in allotment bucket；
(3) complementary to collagen protein, glycyrrhizic acid dipotassium and preservative, pH adjusting agent etc. composition is added in allotment bucket, and continue stirring and be completely dissolved to it and obtain cleaning lotion。
Prepare wet tissue:
The cleaning lotion prepared and carrier are added carrier in mass ratio at 3.5: 1, then cuts into required size and can be prepared by required wet tissue。
In above-mentioned cleaning lotion, the content of each component is in Table 5, and wherein content refers to that each constituent mass accounts for the percentage ratio of total cleaning lotion quality。
Table 5
The foregoing is only embodiments of the present invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure utilizing description of the present invention to make or equivalence flow process conversion; or directly or indirectly it is used in other relevant technical field, all in like manner include in the scope of patent protection of the present invention。
Claims (18)
1. a cleaning lotion, it is characterized in that, including more than one in oil phase substance, water, glycyrrhizic acid or glycyrrhetate, surfactant, described oil phase substance is dispersed in described water under the effect of described surfactant and glycyrrhizic acid or glycyrrhetate, and then forms isotropism, thermodynamically stable transparent or semitransparent emulsion。
2. cleaning lotion according to claim 1, it is characterized in that, in described cleaning lotion, the weight/mass percentage composition of described oil phase substance is 1%～10%, more than one weight/mass percentage composition in described glycyrrhizic acid or glycyrrhetate is 0.05%～5%, and the weight/mass percentage composition of described surfactant is 1%～20%。
3. cleaning lotion according to claim 2, it is characterised in that more than one the weight/mass percentage composition in described glycyrrhizic acid or glycyrrhetate is 0.3%～5%。
4. cleaning lotion according to claim 2, it is characterized in that, the quality of described oil phase substance is 1: 1～10 with the mass ratio helping emulsifier, more than one quality sum in the described quality that quality is described surfactant helping emulsifier and described glycyrrhizic acid or glycyrrhetate, the quality of described surfactant is 1～50: 1 with more than one the mass ratio in described glycyrrhizic acid or glycyrrhetate。
5. cleaning lotion according to claim 4, it is characterised in that the quality of described surfactant is 1～25: 1 with more than one the mass ratio in described glycyrrhizic acid or glycyrrhetate。
6. cleaning lotion according to claim 2, it is characterised in that described cleaning lotion also includes skin protectant, in described cleaning lotion, the weight/mass percentage composition of described skin protectant is 0.1%～10%。
7. the cleaning lotion according to any one of claim 1～6, it is characterised in that described oil phase substance includes polyethenoxy ether and mineral oil。
8. cleaning lotion according to claim 7, it is characterized in that, described polyethenoxy ether includes more than one in PPG-15 tristearin alcohol ether, PPG-11 tristearin alcohol ether, PPG-7 lauryl ether, PPG-3 Semen Myristicae alcohol ether, PPG-10 cetyl ether, PPG-14 butyl ether, PPG-5 ceteth-20, PPG-10 oleyl ether, and described mineral oil includes more than one in Fancol ID, 2-Methylpentadecane。
9. the cleaning lotion according to any one of claim 1～6, it is characterised in that described glycyrrhetate includes more than one in the potassium salt of glycyrrhizic acid, sodium salt and ammonium salt。
10. the cleaning lotion according to any one of claim 1～6, it is characterised in that described surfactant is hydrophile-lipophile balance value be 8～20 a kind of nonionic surfactant or the mixture of two or more nonionic surfactant。
11. cleaning lotion according to claim 10, it is characterized in that, described surfactant includes tween 20, Tween-60, tween 80, anhydrous sorbitol laurate, Span60, sorbitan monooleate, alkyl polyglucoside and derivant thereof, PEG-20 sucrose stearate, PEG-5 glyceryl stearate, Cremophor RH40, PEG-60 castor oil hydrogenated, ceteareth-6, ceteareth-25, stereth-2, stereth-21, laureth-4, laureth-23, C12-13 Pareth-3, C12-13 Pareth-4, C12-13 Pareth-23, polyglycereol-4 laurate, two lauryl alcohol Fructus Citri Limoniae esters, PEG-40 tristerin, cetearyl glucoside, more than one in glyceryl stearate citrate。
12. cleaning lotion according to claim 6, it is characterised in that described skin protectant includes more than one in alcohols skin protectant, esters skin protectant, oils skin protectant, macromolecule skin protectant and complementary skin protectant。
13. cleaning lotion according to claim 12, it is characterized in that, described alcohols skin protectant includes more than one in propylene glycol, glycerol, butanediol, pentanediol, ethohexadiol, hexadecanol, and described esters skin protectant includes more than one in two PPG-3 myristyl ether adipate esters and two PPG-2 Semen Myristicae oleth-10 adipate esters。
14. cleaning lotion according to claim 1, it is characterised in that described cleaning lotion also includes more than one in preservative, essence, pH adjusting agent, thickening agent。
15. a wet tissue, it is characterised in that include the cleaning lotion according to any one of carrier and claim 1～14, described cleaning lotion applies on the carrier。
16. wet tissue according to claim 15, it is characterised in that the mass ratio of the quality of described carrier and described cleaning lotion is 1: 1～5。
17. wet tissue according to claim 15, it is characterised in that described carrier is made up of porous, hydrophilic material。
18. emulsion is carried out solubilising by glycyrrhizic acid or glycyrrhetate, helps the application of emulsifying aspect by one kind。
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