CN105671615B - A kind of process of surface treatment for realizing electronic product 3D effect - Google Patents

A kind of process of surface treatment for realizing electronic product 3D effect Download PDF

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Publication number
CN105671615B
CN105671615B CN201610024551.0A CN201610024551A CN105671615B CN 105671615 B CN105671615 B CN 105671615B CN 201610024551 A CN201610024551 A CN 201610024551A CN 105671615 B CN105671615 B CN 105671615B
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product
product surface
effect
oxide film
carried out
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CN201610024551.0A
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CN105671615A (en
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陆任锋
侯体波
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Guangdong Oppo Mobile Telecommunications Corp Ltd
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Guangdong Oppo Mobile Telecommunications Corp Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/12Anodising more than once, e.g. in different baths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/22Removing surface-material, e.g. by engraving, by etching
    • B44C1/221Removing surface-material, e.g. by engraving, by etching using streams of abrasive particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/22Removing surface-material, e.g. by engraving, by etching
    • B44C1/228Removing surface-material, e.g. by engraving, by etching by laser radiation
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/16Pretreatment, e.g. desmutting
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/18After-treatment, e.g. pore-sealing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Optics & Photonics (AREA)
  • Toxicology (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)

Abstract

The present invention relates to technical field of electronic equipment, more particularly to a kind of process of surface treatment for realizing electronic product 3D effect.A kind of process of surface treatment for realizing electronic product 3D effect, by carrying out laser carving to product surface subregion or Zone Full, so that product surface is in 3D stereoeffects, and the product surface after laser carving is carried out anodic oxidation to form the anode oxide film with resistance to corrosion and adsorption capacity.By the way that the subregion of product surface or Zone Full are carried out after laser carving, the product surface with 3D structures is obtained, and further does anodic oxidation, the anodic oxidation product of 3D stereoeffects is obtained.Product implementation is enriched, reaches and pursues ultimate attainment effect.The PROCESS FOR TREATMENT of anodic oxidation twice so that product surface maintains preferable smoothness and flatness, with good resistance to corrosion, improves the quality of product.

Description

A kind of process of surface treatment for realizing electronic product 3D effect
Technical field
The present invention relates to technical field of electronic equipment, more particularly to a kind of surface treatment work for realizing electronic product 3D effect Skill.
Background technology
The autoxidation aluminium on aluminum products surface was not only soft but also thin, and corrosion resistance is poor, it is impossible to be more not suitable for as effective overcoat Color.Therefore can be in product surface manufacturing artificial oxygenerating film, as product surface diaphragm, relative to nature in modern industry Aluminum oxide, good corrosion resistance, hardness is good, and thickness is big, colours.
The artificial oxygenerating film is mainly applied chemistry oxidation and anodic oxidation.Chemical oxidation is exactly aluminum products in weak base In property or weakly acidic solution, part of matrix metal reacts, make the natural oxide film on its surface thicken or produce it is some other The processing procedure of passivating film.
Chemical oxide film is compared with anode oxide film, film much thinner, and corrosion stability and hardness ratio are relatively low, and not easy coloring, Light resistance after coloring is poor, so metal aluminium coloring can preferentially use anodization.Aluminium alloy is done after anodic oxidation, Ke Yicheng Existing very strong metal-like, and color is varied.
As electronic equipment is developed rapidly and is popularized, requirement of the consumer to electronic product be no longer simple function and Structure, but diversity and a variety of ways of presentation are needed from the section bar of whole product, the manufacture craft of common anode oxidation Flow is typically all to carry out anodized after polishing, grinding, sandblasting, and what the product so made was presented is all plane Effect, it is impossible to make 3D stereoeffects.
The content of the invention
It is an object of the invention to propose a kind of process of surface treatment for realizing electronic product 3D effect, by product table The subregion in face or Zone Full are carried out after laser carving, obtain the product surface with 3D structures, and further do anodic oxidation, Obtain the anodic oxidation product of 3D stereoeffects.Product implementation is enriched, reaches and pursues ultimate attainment effect.
For up to this purpose, the present invention uses following technical scheme:
A kind of process of surface treatment for realizing electronic product 3D effect, by product surface subregion or Zone Full Carry out laser carving so that product surface is in 3D stereoeffects, and have to the product surface progress anodic oxidation after laser carving to be formed The anode oxide film of resistance to corrosion and adsorption capacity.
As one of the preferred embodiments of the present invention, comprise the following steps:
Step 1: plane lapping:Plane lapping is carried out to the surface of product, with remove fault unnecessary on product surface and Cut, reaches the flatness of setting;
Step 2: oil removing:Oil removing is carried out to product surface using alkaline solution, can by animal oil and vegetable oil stinging formation Dissolubility soap and except degreasing;
Step 3: alkali is stung:The flash of product surface is removed by industrial soda, adjust workpiece surface material thickness, it is uniform, Bright dark degree, so that the change of this material is smooth;
Thrown Step 4: changing:Product surface is polished using phosphoric acid solution or phosphosulfate mixed liquor;
Step 5: an anodic oxidation:Anodized is carried out to product surface using sulfuric acid solution, to be compared Product surface has more preferable resistance to corrosion and the anode oxide film of adsorption capacity;
Step 6: laser carving:The high-strength focused laser beam launched using laser so that product surface is according to industrial design Requirement different levels and structure is presented;
Step 7: sandblasting:Blasting treatment is carried out to the product surface structure after laser carving, the sandblasting is zircon sand, glass Sand or steel ball;
Step 8: strip:Strip processing is carried out to product surface by decoating liquid, with the sun formed in removal process five Pole oxide-film;
Step 9: two-step anodization:Anodized is carried out to product surface using sulfuric acid so that with 3D effect Product surface on produce the anode oxide film with resistance to corrosion and adsorption capacity.
As one of the preferred embodiments of the present invention, the temperature that processing is thrown in the change in step 4 is 95-105 DEG C, processing Time 20-120 second.
As one of the preferred embodiments of the present invention, the pressure of sandblasting is 2kg/cm in the step 72, the rule of sandblasting Lattice are 150-210 mesh.
As one of the preferred embodiments of the present invention, the concentration of sulfuric acid is 180-220g/l in step 5 and step 9, Voltage is 8-15V, and temperature is 18-22 DEG C, and the time is 20-60M.
As one of the preferred embodiments of the present invention, in addition to Step 10: dyeing:Using chemical staining agent to step 9 In oxide-film dyed.
As one of the preferred embodiments of the present invention, in addition to Step 11: sealing pores:Anode oxide film is sunk Product has the micropore sealing pores of dyestuff, to keep fast colours degree.
As one of the preferred embodiments of the present invention, sealing pores are carried out to anode oxide film using nickel acetate.
Beneficial effect:By the way that the subregion of product surface or Zone Full are carried out after laser carving, obtain with 3D structures Product surface, and further do anodic oxidation, obtain the anodic oxidation product of 3D stereoeffects.Enrich product realization side Formula, reaches and pursues ultimate attainment effect.
Embodiment
Technical scheme is further illustrated below by embodiment.
Embodiment 1
The autoxidation aluminium on aluminum products surface was not only soft but also thin, and corrosion resistance is poor, it is impossible to be more not suitable for as effective overcoat Color.Therefore can be in product surface manufacturing artificial oxygenerating film, as product surface diaphragm, relative to nature in modern industry Aluminum oxide, good corrosion resistance, hardness is good, and thickness is big, colours.
Aluminium alloy is done after anodic oxidation, and very strong metal-like can be presented, and color is varied.However, common The product surface that anodic oxidation is made all is the effect that plane is presented, and coloring is more single and stiff, and product is just without more Sample.
Therefore the invention provides a kind of process of surface treatment for realizing electronic product 3D effect, by product table face Subregion or Zone Full carry out laser carving so that product surface is in 3D stereoeffects, and carries out sun to the product surface after laser carving Pole aoxidizes to form the anode oxide film with resistance to corrosion and adsorption capacity.
The processing of the laser carving is the high-strength focused laser beam product irradiation surface launched by using laser, causes production Corresponding Chemical Physics change occurs for the material on product surface, so that by planning of the planar structure of product surface according to industrial design Form the three-dimensional structure with different levels.
As one of the preferred embodiments of the present invention, comprise the following steps:
Step 1: plane lapping:The vestige of processing or mould can be left when product surface is untreated, in its plane, Plane lapping is carried out to the surface of product, to remove fault unnecessary on product surface and cut, the flatness of setting is reached.
Step 2: oil removing:Oil removing is carried out to product surface using alkaline solution, can by animal oil and vegetable oil stinging formation Dissolubility soap and except degreasing;Because greasy dirt can reduce the adhesive force of anode oxide film, the entirety of anode oxide film is had an effect on Quality, so must clean up.In order that oil removing ratio is more thoroughly, cleaning way carries out oil removing twice for use preferably.
Step 3: alkali is stung:The flash of product surface is removed by industrial soda, adjust workpiece surface material thickness, it is uniform, Bright dark degree, so that the change of this material is smooth;Alkali sting be chemical polishing another important pretreatment mode, alkali is stung can With the thickness for adjusting workpiece surface material, uniform, bright dark degree, not pretreated aluminium is to be unable to anodic oxidation and coloring 's.
In addition, aluminium and its alloy surface are readily generated one layer of very thin pellumina in atmosphere, (thickness is about 0.01- 0.02um), there is certain resistance to corrosion in an atmosphere, but this oxide-film is loose porous, uneven, resistance to corrosion is not By force, stain is becomed easily infected by.Meanwhile, product surface production when around can produce flash, the oxygen of aluminium can be removed by alkali lye Change film and flash.
Thrown Step 4: changing:Product surface is polished using phosphoric acid solution or phosphosulfate mixed liquor;To obtain bloom The temperature that processing is thrown in change in the surface of brightness, step 4 is 95-105 DEG C, processing time 20-120 second.
Step 5: an anodic oxidation:Anodized is carried out to product surface using sulfuric acid solution, to be compared Product surface has more preferable resistance to corrosion and the anode oxide film of adsorption capacity;The oxidation for the aluminium that anodizing process with sulfuric acid as major salt is obtained Film layer appearance colorless is transparent, and thickness is 5-20um, and hardness is high, and hole is more, and adsorptivity is strong, is conducive to dyeing, after Seal treatment, With higher resistance to corrosion, it is mainly used in protection and decorative purpose, the process of film forming is water electrolysis process.
The concentration of sulfuric acid is 180-220g/l in step 5, and voltage is 8-15V, and temperature is 18-22 DEG C, and the time is 20- 60M.The oxide-film that anodic oxidation is formed is interim oxide-film, for preventing that product surface is certainly in process of production So aoxidize or be easier to be stained.
Step 6: laser carving:The high-strength focused laser beam launched using laser so that product surface is according to industrial design Requirement different levels and structure is presented;The beam distribution and energy size of the generating laser, can be according to specific industry Design requirement is adjusted accordingly.
Step 7: sandblasting:Blasting treatment is carried out to the product surface structure after laser carving, made using the impact of high speed sand flow With the surface for clearing up and being roughened product, impact and shear action due to abrasive material to workpiece surface make the surface of workpiece obtain one Fixed cleannes and different roughness, making the mechanical performance of workpiece surface is improved, therefore improves the antifatigue of workpiece Property, its adhesive force between coating is added, the durability of film is extended, the levelling and decoration of coating is also beneficial to.
The sandblasting is zircon sand, glass sand or steel ball;The pressure of sandblasting is 2kg/cm in the step 72, the rule of sandblasting Lattice are 150-210 mesh.
Step 8: strip:Strip processing is carried out to product surface by decoating liquid, with facing formed in removal process five The anode oxide film of when property and because of the technique of sandblasting and laser carving self-assembling formation oxide-film;In order to passed through in product surface Go through after step 6 and step 7, complete after 3D shaping structures, further obtain complete anode oxide film.
Step 9: two-step anodization:Anodized is carried out to product surface using sulfuric acid so that with 3D effect Product surface on produce the anode oxide film with resistance to corrosion and adsorption capacity.The aluminium that anodizing process with sulfuric acid as major salt is obtained Oxidation film layer appearance colorless is transparent, and thickness is 5-20um, and hardness is high, and hole is more, and adsorptivity is strong, is conducive to dyeing.
As one of the preferred embodiments of the present invention, in addition to Step 11: sealing pores:Anode oxide film is sunk Product has the micropore sealing pores of dyestuff, to keep fast colours degree.But also can have workpiece prevents fat from printing, color spot and oil The ability that fat is contaminated.It is further that sealing pores are carried out to anode oxide film using nickel acetate.
In summary, by the way that the subregion of product surface or Zone Full are carried out after laser carving, obtain with 3D structures Product surface, and further do anodic oxidation, obtain the anodic oxidation product of 3D stereoeffects.Enrich product realization side Formula, reaches and pursues ultimate attainment effect.The PROCESS FOR TREATMENT of anodic oxidation twice so that product surface maintain preferable smoothness and Flatness, with good resistance to corrosion, improves the quality of product.
The technical principle of the present invention is described above in association with specific embodiment.These descriptions are intended merely to explain the present invention's Principle, and limiting the scope of the invention can not be construed in any way.Based on explanation herein, the technology of this area Personnel, which would not require any inventive effort, can associate other embodiments of the present invention, and these modes are fallen within Within protection scope of the present invention.

Claims (7)

1. a kind of process of surface treatment for realizing electronic product 3D effect, it is characterised in that by product surface subregion Or Zone Full carries out laser carving so that product surface is in 3D stereoeffects, and carries out anodic oxidation to the product surface after laser carving To form the anode oxide film with resistance to corrosion and adsorption capacity, following steps are specifically included:
Step 1: plane lapping:Plane lapping is carried out to the surface of product, to remove fault unnecessary on product surface and draw Trace, reaches the flatness of setting;
Step 2: oil removing:Oil removing is carried out to product surface using alkaline solution, animal oil and the formation of stinging of vegetable oil is soluble Soap and except degreasing;
Step 3: alkali is stung:The flash of product surface is removed by industrial soda, the thickness, uniform, bright dark of workpiece surface material is adjusted Degree so that this material become it is smooth;
Thrown Step 4: changing:Product surface is polished using phosphoric acid solution or phosphosulfate mixed liquor;
Step 5: an anodic oxidation:Anodized is carried out to product surface using sulfuric acid solution, product is compared to obtain Surface has more preferable resistance to corrosion and the anode oxide film of adsorption capacity;
Step 6: laser carving:The high-strength focused laser beam launched using laser so that product surface will according to industrial design Ask presentation different levels and structure;
Step 7: sandblasting:To after laser carving product surface structure carry out blasting treatment, the sandblasting be zircon sand, glass sand or Steel ball;
Step 8: strip:Strip processing is carried out to product surface by decoating liquid, with provisional formed in removal process five Anode oxide film and because of the technique of sandblasting and laser carving self-assembling formation oxide-film;
Step 9: two-step anodization:Anodized is carried out to product surface using sulfuric acid so that the production with 3D effect The anode oxide film with resistance to corrosion and adsorption capacity is produced on product surface.
2. the process of surface treatment according to claim 1 for realizing electronic product 3D effect, it is characterised in that in step 4 Change throw processing temperature be 95-105 DEG C, processing time 20-120 second.
3. the process of surface treatment according to claim 1 for realizing electronic product 3D effect, it is characterised in that the step The pressure of sandblasting is 2kg/cm in seven2, the specification of sandblasting is 150-210 mesh.
4. the process of surface treatment according to claim 1 for realizing electronic product 3D effect, it is characterised in that step 5 and The concentration of sulfuric acid is 180-220g/L in step 9, and voltage is 8-15V, and temperature is 18-22 DEG C, and the time is 20-60M.
5. 3D effect process of surface treatment according to claim 1, it is characterised in that also including Step 10: dyeing:Using Chemical staining agent is dyed to the oxide-film in step 9.
6. 3D effect process of surface treatment according to claim 5, it is characterised in that also including Step 11: at sealing of hole Reason:There are the micropore sealing pores of dyestuff to the deposition of anode oxide film, to keep fast colours degree.
7. 3D effect process of surface treatment according to claim 6, it is characterised in that using nickel acetate to anode oxide film Carry out sealing pores.
CN201610024551.0A 2016-01-13 2016-01-13 A kind of process of surface treatment for realizing electronic product 3D effect Expired - Fee Related CN105671615B (en)

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