CN105669999A - 一种含联吡啶型配体的哌酸镉发光材料及其制备方法 - Google Patents
一种含联吡啶型配体的哌酸镉发光材料及其制备方法 Download PDFInfo
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- CN105669999A CN105669999A CN201610231225.7A CN201610231225A CN105669999A CN 105669999 A CN105669999 A CN 105669999A CN 201610231225 A CN201610231225 A CN 201610231225A CN 105669999 A CN105669999 A CN 105669999A
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- cadmium
- piperazine
- acid
- luminescent material
- pyridyl
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- 239000000463 material Substances 0.000 title claims abstract description 66
- 229910052793 cadmium Inorganic materials 0.000 title claims abstract description 26
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 title claims abstract description 26
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000003446 ligand Substances 0.000 title abstract description 6
- WLJNZVDCPSBLRP-UHFFFAOYSA-N pamoic acid Chemical compound C1=CC=C2C(CC=3C4=CC=CC=C4C=C(C=3O)C(=O)O)=C(O)C(C(O)=O)=CC2=C1 WLJNZVDCPSBLRP-UHFFFAOYSA-N 0.000 title abstract 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 39
- UQDBUNOBHAOPPJ-UHFFFAOYSA-N 2,5-dipyridin-4-yl-1,3,4-thiadiazole Chemical group C1=NC=CC(C=2SC(=NN=2)C=2C=CN=CC=2)=C1 UQDBUNOBHAOPPJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000126 substance Substances 0.000 claims abstract description 10
- 150000001661 cadmium Chemical class 0.000 claims abstract description 9
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 6
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 98
- 239000002253 acid Substances 0.000 claims description 49
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- 239000012621 metal-organic framework Substances 0.000 claims description 39
- 238000003756 stirring Methods 0.000 claims description 18
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
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- 229910000831 Steel Inorganic materials 0.000 claims description 6
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- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 claims description 4
- 238000001514 detection method Methods 0.000 claims description 4
- 239000003814 drug Substances 0.000 claims description 4
- 229940079593 drug Drugs 0.000 claims description 4
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- 125000006850 spacer group Chemical group 0.000 claims description 4
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- 238000010537 deprotonation reaction Methods 0.000 claims description 3
- 239000007900 aqueous suspension Substances 0.000 claims description 2
- LHQLJMJLROMYRN-UHFFFAOYSA-L cadmium acetate Chemical group [Cd+2].CC([O-])=O.CC([O-])=O LHQLJMJLROMYRN-UHFFFAOYSA-L 0.000 claims description 2
- XIEPJMXMMWZAAV-UHFFFAOYSA-N cadmium nitrate Inorganic materials [Cd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XIEPJMXMMWZAAV-UHFFFAOYSA-N 0.000 claims description 2
- QCUOBSQYDGUHHT-UHFFFAOYSA-L cadmium sulfate Chemical compound [Cd+2].[O-]S([O-])(=O)=O QCUOBSQYDGUHHT-UHFFFAOYSA-L 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 claims description 2
- NMHMNPHRMNGLLB-UHFFFAOYSA-N phloretic acid Chemical compound OC(=O)CCC1=CC=C(O)C=C1 NMHMNPHRMNGLLB-UHFFFAOYSA-N 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 15
- 238000003786 synthesis reaction Methods 0.000 abstract description 15
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- 229910052751 metal Inorganic materials 0.000 abstract description 6
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- 239000013078 crystal Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229910021645 metal ion Inorganic materials 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
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- 239000000047 product Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- WLZRMCYVCSSEQC-UHFFFAOYSA-N cadmium(2+) Chemical compound [Cd+2] WLZRMCYVCSSEQC-UHFFFAOYSA-N 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000005304 joining Methods 0.000 description 3
- 239000013384 organic framework Substances 0.000 description 3
- 239000013110 organic ligand Substances 0.000 description 3
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- 239000007858 starting material Substances 0.000 description 3
- 238000002411 thermogravimetry Methods 0.000 description 3
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- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
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- 239000002994 raw material Substances 0.000 description 2
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- 150000003852 triazoles Chemical class 0.000 description 2
- DPVRAKPVTIJJKP-UHFFFAOYSA-N CCC.N1N=CN=C1 Chemical compound CCC.N1N=CN=C1 DPVRAKPVTIJJKP-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
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- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
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- 239000012535 impurity Substances 0.000 description 1
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- 239000000696 magnetic material Substances 0.000 description 1
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- 239000011148 porous material Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
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- 230000000171 quenching effect Effects 0.000 description 1
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- 239000011701 zinc Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000013094 zinc-based metal-organic framework Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/008—Supramolecular polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/14—Macromolecular compounds
- C09K2211/1441—Heterocyclic
- C09K2211/1466—Heterocyclic containing nitrogen as the only heteroatom
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/14—Macromolecular compounds
- C09K2211/1441—Heterocyclic
- C09K2211/1483—Heterocyclic containing nitrogen and sulfur as heteroatoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/188—Metal complexes of other metals not provided for in one of the previous groups
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Plural Heterocyclic Compounds (AREA)
- Luminescent Compositions (AREA)
Abstract
Description
Claims (7)
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CN201610231225.7A CN105669999B (zh) | 2016-04-14 | 2016-04-14 | 一种含联吡啶型配体的哌酸镉发光材料及其制备方法 |
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CN201610231225.7A CN105669999B (zh) | 2016-04-14 | 2016-04-14 | 一种含联吡啶型配体的哌酸镉发光材料及其制备方法 |
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CN105669999A true CN105669999A (zh) | 2016-06-15 |
CN105669999B CN105669999B (zh) | 2018-03-16 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106366329A (zh) * | 2016-09-12 | 2017-02-01 | 桂林理工大学 | 对苯二甲酸双核镉聚合物及其制备方法 |
CN110016044A (zh) * | 2019-05-13 | 2019-07-16 | 淮南师范学院 | 一种含多酸-咪唑型构件的镉基荧光探针化合物及其制备方法和应用 |
CN113201146A (zh) * | 2021-05-18 | 2021-08-03 | 郑州大学 | 一种含噻二唑/羧基的铜配位聚合物及其制备方法和应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103588797A (zh) * | 2013-11-22 | 2014-02-19 | 淮南师范学院 | 一种新型***类荧光配位聚合物及其制备方法和应用 |
CN103772420A (zh) * | 2014-02-12 | 2014-05-07 | 淮南师范学院 | 一种取代吡啶配合物及其制备方法以及作为近紫外光致发光材料的应用 |
CN105237472A (zh) * | 2015-10-30 | 2016-01-13 | 淮南师范学院 | 一种取代吡啶配合物及其制备方法以及作为非线性光学材料、铁电材料和荧光材料的应用 |
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2016
- 2016-04-14 CN CN201610231225.7A patent/CN105669999B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103588797A (zh) * | 2013-11-22 | 2014-02-19 | 淮南师范学院 | 一种新型***类荧光配位聚合物及其制备方法和应用 |
CN103772420A (zh) * | 2014-02-12 | 2014-05-07 | 淮南师范学院 | 一种取代吡啶配合物及其制备方法以及作为近紫外光致发光材料的应用 |
CN105237472A (zh) * | 2015-10-30 | 2016-01-13 | 淮南师范学院 | 一种取代吡啶配合物及其制备方法以及作为非线性光学材料、铁电材料和荧光材料的应用 |
Non-Patent Citations (3)
Title |
---|
GUI-LIN WEN,ET AL.: ""A Distorted pcu Topological Heterometallic Metal-Organic Framework with Right- and Left Chiral Covalent Layers"", 《Z. ANORG. ALLG. CHEM.》 * |
GUI-LIN WEN,ET AL.: ""Two 3D cupric metal–organic frameworks based on the biphenyl-2,3,30,50-tetracarboxylate ligand and possessing 1D nanosized channels"", 《INORGANICA CHIMICA ACTA》 * |
刘道富,等: ""八种具有荧光性能的新型配合物的合成与性能研究"", 《化学世界》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106366329A (zh) * | 2016-09-12 | 2017-02-01 | 桂林理工大学 | 对苯二甲酸双核镉聚合物及其制备方法 |
CN110016044A (zh) * | 2019-05-13 | 2019-07-16 | 淮南师范学院 | 一种含多酸-咪唑型构件的镉基荧光探针化合物及其制备方法和应用 |
CN110016044B (zh) * | 2019-05-13 | 2021-05-14 | 淮南师范学院 | 一种含多酸-咪唑型构件的镉基荧光探针化合物及其制备方法和应用 |
CN113201146A (zh) * | 2021-05-18 | 2021-08-03 | 郑州大学 | 一种含噻二唑/羧基的铜配位聚合物及其制备方法和应用 |
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CN105669999B (zh) | 2018-03-16 |
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