CN105669048A - 一种单向透视低辐射玻璃 - Google Patents
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Abstract
本发明公开了一种单向透视低辐射玻璃,包括玻璃基板、沿玻璃基板的厚度方向依次设置的复合电介质层、第一金属反射层、阻止金属氧化层、中间复合介质层、第二金属反射层、光吸收层及复合介质保护层,其中,复合电介质层的厚度为4-50nm,第一金属反射层的厚度为10-30nm,阻止金属氧化层的厚度为0.5-10nm,中间复合介质层的厚度为30-90nm,第二金属反射层的厚度为5-20nm,光吸收层的厚度为0.5-20nm,复合介质保护层的厚度为10-60nm。该单向透视低辐射玻璃结构牢固、紧凑、简单,能提高观察对象面光线的反射率,减低观察面光线的反射率,减少观察干扰,兼具单向透视和低辐射性能。
Description
技术领域
本发明涉及一种单向透视低辐射玻璃。
背景技术
现有技术中,单向透视的玻璃往往不具有低辐射的功能,而具有低辐射性能的玻璃又不具有单向透视的功能,也就是说无法兼具单向透视与低辐射的双重功能。
发明内容
本发明的目的是提供一种兼具单向***与低辐射性能的玻璃。
为达到上述目的,本发明采用的技术方案是:一种单向透视低辐射玻璃,所述玻璃包括玻璃基板、沿所述玻璃基板的厚度方向依次设置的复合电介质层、第一金属反射层、阻止金属氧化层、中间复合介质层、第二金属反射层、光吸收层及复合介质保护层,其中,所述复合电介质层的厚度为4-50nm,所述第一金属反射层的厚度为10-30nm,所述阻止金属氧化层的厚度为0.5-10nm,所述中间复合介质层的厚度为30-90nm,所述第二金属反射层的厚度为5-20nm,所述光吸收层的厚度为0.5-20nm,所述复合介质保护层的厚度为10-60nm。
优选地,所述复合电介质层/中间复合介质层/复合介质保护层为SiNx层、SnO2层、ZnSnOx层、TiOx层、ZnO层中任一层。
优选地,所述复合电介质层/中间复合介质层/复合介质保护层为SiNx层、SnO2层、ZnSnOx层、TiOx层、ZnO层中的至少两层叠加而成。
优选地,所述第一金属反射层/第二金属反射层为Ag层、Al层、Cr层或Cu层。
优选地,所述阻止金属氧化层为NiCr层、Nb层或Cr层。
优选地,所述的光吸收层为NiCr层、Nb层或Cr层。
作为一种具体的实施方式,所述玻璃由ZnSnO层、Ag层、NiCr层、ZnSnO层、Ag层、NiCr层及Si3N4层依次层叠在所述玻璃基板而成。
作为另一种具体的实施方式,所述玻璃由ZnSnO层、Ag层与Cu层复合层、NiCr层、ZnSnO层、Ag层、NiCr层及Si3N4层依次层叠在所述玻璃基板而成。
优选地,所述玻璃基板为普通玻璃或钢化玻璃。
由于上述技术方案的运用,本发明与现有技术相比具有下列优点:本发明中的单向透视低辐射玻璃,其中通过在玻璃基板上依次镀设复合电介质层、第一金属反射层、阻止金属氧化层、中间复合介质层、第二金属反射层、光吸收层及复合介质保护层,并对各层的厚度进行配置,能提高单向玻璃观察对象面光线的反射率,减低观察面光线的反射率,减少观察干扰,兼具单向透视和低辐射性能。
附图说明
附图1为本发明实施例1的截面结构示意图;
附图2为本发明实施例2的截面结构示意图。
1、玻璃基板;2、复合电介质层;3、第一金属反射层;31、Ag层;32、Cu层;4、阻止金属氧化层;5、中间复合介质层;6、第二金属反射层;7、光吸收层;8、复合介质保护层。
具体实施方式
下面结合附图和具体实施例来对本发明的技术方案作进一步的阐述。
参见图1、图2所示,本发明的单向透视低辐射玻璃,该玻璃包括玻璃基板1、沿玻璃基板1的厚度方向依次设置的复合电介质层2、第一金属反射层3、阻止金属氧化层4、中间复合介质层5、第二金属反射层6、光吸收层7及复合介质保护层8,其中玻璃基板1可采用普通玻璃或者钢化玻璃,也可以为本领域内常用的其他类型的玻璃。玻璃基板1的一侧表面设置有上述的各层,另一侧面为该单向透视玻璃的外表面,也为观察对象面。
复合电介质层2能有效地加强玻璃基板1与第一金属反射层3的结合强度,同时还可以通过该复合电介质层2的颜色调节,降低光线的透过率,从而降低光线从玻璃基板1射向第一金属反射层3的强度。该复合电介质层2可为SiNx层、SnO2层、ZnSnOx层、TiOx层、ZnO层中任一层,也可以为SiNx层、SnO2层、ZnSnOx层、TiOx层、ZnO层中至少两层叠加而成。该复合电介质层2的厚度优选地为4-50nm。
第一金属反射层3能够将从玻璃基板1射来的光反射,使玻璃基板1即管材对象面无法透视到相对面,该第一金属反射层3为Ag层、Al层、Cr层或Cu层,或者由为Ag层、Al层、Cr层及Cu层中的至少两层叠加而成,该第一金属反射层3的厚度优选地为10-30nm。
阻止金属氧化层4叠加设置在第一金属反射层3的表面,能有效地组织第一金属反射层3与空气接触而发生氧化,保证了第一金属反射层3的可透视性和反光性能。该阻止金属氧化层4为NiCr层、Nb层或Cr层,其厚度优选地为0.5-10nm。
中间复合介质层5可为SiNx层、SnO2层、ZnSnOx层、TiOx层、ZnO层中任一层,也可以为SiNx层、SnO2层、ZnSnOx层、TiOx层、ZnO层中至少两层叠加而成。其厚度优选地为30-90nm。
第二金属反射层6用于增强单向透视玻璃的低辐射性能,该第二金属反射层6为Ag层、Al层、Cr层或Cu层,或者由为Ag层、Al层、Cr层及Cu层中的至少两层叠加而成,其厚度优选地为5-20nm。
光吸收层7能有效地使光线在其界面发生折射,降低光线的反射率,并使光在穿透该光吸收层7的过程中被吸收,从而降低该单向透视玻璃与玻璃基板1相对的外表面(亦即观察面)光线的反射率,实现透视效果,并减少观察干扰。该光吸收层7可为NiCr层、Nb层或Cr层,其厚度为0.5-20nm。
复合介质保护层8能够有效地对光吸收层7起到保护作用,使得该单向透视玻璃耐用,不易损坏,同时还可以通过该复合介质保护层8的颜色调节,提高光线的透过率。该复合介质保护层8可以为SiNx层、SnO2层、ZnSnOx层、TiOx层、ZnO层中任一层,也可以为SiNx层、SnO2层、ZnSnOx层、TiOx层、ZnO层中至少两层叠加而成,其厚度优选地为10-60nm。
以下以具体的实施例来说明本发明的单向透视玻璃的性能:
实施例1:
参见图1所示,该单向透视玻璃的结构为普通白玻璃基板/ZnSnO层/Ag层/NiCr层/ZnSnO层/Ag层/NiCr层/Si3N4层,各层的厚度依次为6mm/33.5nm/25.0nm/7.7nm/76.2nm/11.1nm/1.3nm/21.4nm。可通过磁控溅射工艺依次将各层膜层镀设在玻璃基板1上,其中使用14个交流旋转阴极,5个直流平面阴极,共19个阴极进行生产。
产品的性能测试如下:
玻面(观察对象面)的光反射率:56%,透过颜色:a*=-3.9,b*=-0.09;
膜面(观察面)的光反射率:18%,反射颜色:a*=-15,b*=-33;
观察面的光透过率:24%;
辐射率:0.02。
实施例2:
参见图2所示,该单向透视玻璃的结构为普通白玻璃基板/ZnSnO层/Ag层/Cu层/NiCr层/ZnSnO层/Ag层/NiCr层/Si3N4层,其中,每层的厚度为6mm/17.2nm/19.0nm/6.3nm/4.4nm/82.6nm/15.6nm/0.7nm/33.4nm,该单向透视玻璃中采用Ag层31与Cu层32叠加形成第一金属反射层3。可通过磁控溅射工艺依次将各层膜层镀设在玻璃基板1上,其中使用12个交流旋转阴极,6个直流平面阴极,共18个阴极进行生产。
产品的性能测试如下:
玻面(观察对象面)的光反射率:50%,透过颜色:a*=-0.28,b*=-3.26;
膜面(观察面)的光反射率:14%,反射颜色:a*=3.5,b*=-13;
观察面的光透过率:30%。
辐射率:0.02。
综上,可以看出,该单向透视低辐射玻璃结构牢固、紧凑、简单,能提高观察对象面光线的反射率,减低观察面光线的反射率,减少观察干扰,兼具单向透视和低辐射性能。
上述实施例只为说明本发明的技术构思及特点,其目的在于让熟悉此项技术的人士能够了解本发明的内容并据以实施,并不能以此限制本发明的保护范围。凡根据本发明精神实质所作的等效变化或修饰,都应涵盖在本发明的保护范围之内。
Claims (9)
1.一种单向透视低辐射玻璃,其特征在于:所述玻璃包括玻璃基板、沿所述玻璃基板的厚度方向依次设置的复合电介质层、第一金属反射层、阻止金属氧化层、中间复合介质层、第二金属反射层、光吸收层及复合介质保护层,其中,所述复合电介质层的厚度为4-50nm,所述第一金属反射层的厚度为10-30nm,所述阻止金属氧化层的厚度为0.5-10nm,所述中间复合介质层的厚度为30-90nm,所述第二金属反射层的厚度为5-20nm,所述光吸收层的厚度为0.5-20nm,所述复合介质保护层的厚度为10-60nm。
2.根据权利要求1所述的单向透视低辐射玻璃,其特征在于:所述复合电介质层/中间复合介质层/复合介质保护层为SiNx层、SnO2层、ZnSnOx层、TiOx层、ZnO层中任一层。
3.根据权利要求1所述的单向透视低辐射玻璃,其特征在于:所述复合电介质层/中间复合介质层/复合介质保护层为SiNx层、SnO2层、ZnSnOx层、TiOx层、ZnO层中的至少两层叠加而成。
4.根据权利要求1所述的单向透视低辐射玻璃,其特征在于:所述第一金属反射层/第二金属反射层为Ag层、Al层、Cr层或Cu层。
5.根据权利要求1所述的单向透视低辐射玻璃,其特征在于:所述阻止金属氧化层为NiCr层、Nb层或Cr层。
6.根据权利要求1所述的单向透视低辐射玻璃,其特征在于:所述的光吸收层为NiCr层、Nb层或Cr层。
7.根据权利要求1所述的单向透视低辐射玻璃,其特征在于:所述玻璃由ZnSnO层、Ag层、NiCr层、ZnSnO层、Ag层、NiCr层及Si3N4层依次层叠在所述玻璃基板而成。
8.根据权利要求1所述的单向透视低辐射玻璃,其特征在于:所述玻璃由ZnSnO层、Ag层与Cu层复合层、NiCr层、ZnSnO层、Ag层、NiCr层及Si3N4层依次层叠在所述玻璃基板而成。
9.根据权利要求1所述的单向透视低辐射玻璃,其特征在于:所述玻璃基板为普通玻璃或钢化玻璃。
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