CN105650363A - Bamboo composite tube and manufacturing method thereof - Google Patents

Bamboo composite tube and manufacturing method thereof Download PDF

Info

Publication number
CN105650363A
CN105650363A CN201610000269.9A CN201610000269A CN105650363A CN 105650363 A CN105650363 A CN 105650363A CN 201610000269 A CN201610000269 A CN 201610000269A CN 105650363 A CN105650363 A CN 105650363A
Authority
CN
China
Prior art keywords
bamboo
layer
enhancement layer
multiple tube
internal layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610000269.9A
Other languages
Chinese (zh)
Inventor
李延军
许斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Forestry University
Original Assignee
Nanjing Forestry University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Forestry University filed Critical Nanjing Forestry University
Priority to CN201610000269.9A priority Critical patent/CN105650363A/en
Publication of CN105650363A publication Critical patent/CN105650363A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/14Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N5/00Manufacture of non-flat articles
    • B27N5/02Hollow articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a non-planar shape
    • B32B1/08Tubular products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/02Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284Application of adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/047Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/02Coating on the layer surface on fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • B32B2262/062Cellulose fibres, e.g. cotton
    • B32B2262/065Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/106Carbon fibres, e.g. graphite fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10Inorganic particles
    • B32B2264/104Oxysalt, e.g. carbonate, sulfate, phosphate or nitrate particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/12Mixture of at least two particles made of different materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/752Corrosion inhibitor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2597/00Tubular articles, e.g. hoses, pipes

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a bamboo composite tube and a manufacturing method thereof. The bamboo composite tube comprises an inner layer, a strengthening layer and an outer wrapping layer which are sequentially manufactured from interior to exterior. According to the bamboo composite tube manufactured through the method, low-grade bamboo wood and machining residues, such as small-caliber bamboo wood, small-caliber-grade sympodial bamboo and bamboo wood machining residues, of the low-grade bamboo wood and waste plastic compositely recycled are used, the outer wall of the strengthening layer is covered with bamboo veneer pasted and covered with non-woven fabric or a bamboo veneer composite material manufactured through longitudinal and transverse combining layer by layer, and therefore the energy-saving and environment-friendly composite tube capable of meeting the strength requirement can be produced. The bamboo composite tube is applied to agricultural irrigation, water supply and drainage, buildings, petrochemical engineering corrosion prevention and other fields.

Description

A kind of bamboo multiple tube and manufacture method thereof
Technical field
The invention belongs to pipeline field, be specifically related to a kind of bamboo multiple tube and manufacture method thereof. This pipeline can be applicable to the fields such as agricultural irrigation, plumbing, building and petrochemical industry anticorrosion.
Background technology
In current agricultural irrigation, plumbing and petrochemical industry anticorrosion occasion, conventional pipeline is generally pipe of cement, polyvinyl chloride pipe, polyethylene tube, glass reinforced plastic pipe etc. Confirming by long-term use, above-mentioned conventional pipeline also exists different problems because of the difference of material, and such as conventional cement pipe cost is low, but intensity is low, quality weight, leakage easily occurs due to material problem; The pipeline of synthetic resin material, light weight, corrosion-resistant, but strength and stiffness level is poor, and all adopt petrochemicals manufacture, contaminated environment; The material energy consumption of glass reinforced plastic pipe is too high. For environmental protection and energy-conservation consideration, have increasing need for a kind of energy-conserving and environment-protective, the guaranteed novel pipeline of intensity.
Summary of the invention
It is desirable to provide a kind of method that can produce the bamboo multiple tube meeting strength demand and energy-conserving and environment-protective, i.e. this bamboo multiple tube.
The technical solution adopted in the present invention is: the manufacture method of a kind of bamboo multiple tube, described bamboo multiple tube comprises internal layer, enhancement layer and surrounding layer, comprises the following steps: (one) internal layer manufacture, (two) enhancement layer manufacture, (three) surrounding layer manufacture and (four) pipeline compound:
(1) internal layer manufacture: described internal layer includes the plastic conduit as body and the fiber composite containing bamboo charcoal, the described fiber composite containing bamboo charcoal is covered in the inwall of described plastic conduit, described plastic conduit adopts spray fusing to shape, afterwards the described fiber composite containing bamboo charcoal is pasted described plastic conduit inwall, form described internal layer;
(2) enhancement layer manufacture: described enhancement layer is bamboo composite material, the waste or used plastics pulverized, inorganic filler, technical grade stearic acid, auxiliary agent and the agitated machine of bamboo fiber material is selected to be sufficiently stirred for formation mixed material, it is then fed into twin screw extruder to described mixed material extruding pelletization at 220 DEG C, material after pelletize is dried, put into pipe extruder again, extrude described enhancement layer; Described bamboo fiber material is short-fibre silk and/or bamboo powder, and described short-fibre silk is for utilizing small caliber bamboo wood, small diameter grade Cluster Bamboo, bamboo surplus material of processing, and after being rolled into filamental, cutting is formed, the diameter��1mm of described short-fibre silk, length��2cm;Described bamboo powder is through mechanical activation comminution, grinding by small caliber bamboo wood, small diameter grade Cluster Bamboo, bamboo surplus material of processing, and classification is made 50-500 order and formed;
(3) surrounding layer manufacture: described outer layer is Bamboo veneer composite, use 4-7 setation bamboo, block the bamboo section for 900-3200mm, after de-etiolation goes green grass or young crops, it is 15-25mm that bamboo section is processed into width, the bamboo cane of thickness��8mm, the dried gluing assembly of bamboo cane, form bamboo side, after bamboo side's pressure impregnating, it is dried to surface without obvious water mark, it is again dipped in 50-70 DEG C of warm water and soaks at least 24 hours, obtain softening bamboo block, further according to process requirements, bamboo side after softening is carried out slicing, the thin bamboo thickness��0.5mm of slicing gained, again thin bamboo is put into and veneer dryer is dried to moisture content less than 10%, it is coated with after urea-formaldehyde glue, sticks the non-woven fabrics of bamboo-containing fiber, the thinner bamboo after pasting non-woven fabrics is rolled into outsourcing layer, or sliced bamboo is carried out vertically and horizontally is directly prepared into Bamboo veneer composite after compound roll into outsourcing layer,
(4) pipeline compound: be coated with waterproofing agent and preservative at described internal layer inwall, insert among the tubular space that described enhancement layer inwall is formed after outer wall spraying water proof type adhesive, utilize special-shaped heating press, apply pressure and make described internal layer and the bonding of described enhancement layer, at described enhancement layer outer wall coated with resins adhesive after bonding, the thin bamboo being covered with non-woven fabrics after impregnation is successively attached to described enhancement layer outer wall, and the interface between adjacent two layers staggers, until thickness meets needs; The multiple tube of first one-step forming is sent in drying equipment, is warmed to 60-140 DEG C, carries out cured; Last spraying waterproofing agent and preservative on the outermost layer of described surrounding layer.
The material of described plastic conduit is selected from polyethylene, polypropylene, polrvinyl chloride, polystyrene.
Described waste or used plastics includes the waste polyvinyl chloride of recovery, polyethylene, polypropylene; Described inorganic filler is selected from one or more in calcium carbonate, wollastonite, Kaolin, Pulvis Talci; Described auxiliary agent is antifungus agent and/or fire retardant.
The liquid used in described bamboo side impregnating by pressure is water or the aqueous solution containing penetrating agent or softening agent.
The adhesive and the described thin bamboo institute impregnation that are coated with outside described enhancement layer are the one in Lauxite, unsaturated polyester resin, epoxy resin, phenolic resin or polyurethane resin.
Present invention also offers a kind of bamboo multiple tube, comprise internal layer, enhancement layer and surrounding layer, described internal layer includes the plastic conduit as body and the fiber composite containing bamboo charcoal, the described fiber composite containing bamboo charcoal is covered in the inwall of described plastic conduit, described enhancement layer is bamboo composite material, described internal layer inwall coating waterproofing agent and preservative, the outermost layer of described surrounding layer sprays waterproofing agent and preservative.
The material of described plastic conduit is selected from polyethylene, polypropylene, polrvinyl chloride, polystyrene.
Described waste or used plastics includes the waste polyvinyl chloride of recovery, polyethylene, polypropylene; Described inorganic filler is selected from one or more in calcium carbonate, wollastonite, Kaolin, Pulvis Talci; Described auxiliary agent is antifungus agent and/or fire retardant.
The adhesive and the described thin bamboo institute impregnation that are coated with outside described enhancement layer are the one in Lauxite, unsaturated polyester resin, epoxy resin, phenolic resin or polyurethane resin.
Described Bamboo veneer composite is thickness��0.5mm bamboo fibre thin bamboo of slicing gained, after being coated with urea-formaldehyde glue, stick the non-woven fabrics of bamboo-containing fiber, the thin bamboo after pasting non-woven fabrics is rolled into outsourcing layer again, or sliced bamboo is carried out vertically and horizontally is directly prepared into Bamboo veneer composite after compound rolls into outsourcing layer.
Present invention comprises the bamboo multiple tube manufactured by said method, include internal layer, enhancement layer, surrounding layer successively from inside to outside.
It is an advantage of the current invention that: make full use of the various advantages of bamboo wood, in conjunction with waste or used plastics, form the pipeline meeting requirement of strength. The material such as the residue of bamboo processing, bamboo branch can be made full use of on the one hand, on the other hand, waste or used plastics be turned waste into wealth, make full use of the advantage of various material.
Accompanying drawing explanation
The process chart of Fig. 1 present invention.
Fig. 2 is the profile according to the bamboo multiple tube of the present invention.
Detailed description of the invention
Flow chart as shown in Figure 1, the manufacture method of the bamboo multiple tube of the present invention, it is sequentially prepared internal layer from inside to outside, enhancement layer, surrounding layer, specifically comprises the following steps that
Internal layer manufactures: internal layer is the plastic conduit that inwall pastes the fiber composite containing bamboo charcoal, and this plastic conduit adopts spray fusing to shape, and the fiber composite containing bamboo charcoal pastes plastic conduit inwall afterwards, forms internal layer;
Enhancement layer manufactures: for bamboo-plastic combined layer, utilizes small caliber bamboo wood, small diameter grade Cluster Bamboo, bamboo surplus material of processing, and after being rolled into filamental, cutting forms short-fibre silk, the diameter��1mm of described short-fibre silk, length��2cm; Or small caliber bamboo wood, small diameter grade Cluster Bamboo, bamboo surplus material of processing are made through mechanical activation comminution, grinding, classification the bamboo powder of 50-500 order, standby; Select waste or used plastics, modifying agent, technical grade stearic acid, auxiliary agent, it is sufficiently stirred for after mixing with the agitated machine of short-fibre silk or bamboo powder, send into twin screw extruder material extruding pelletization at 220 DEG C to just mixing, material after pelletize is dried, put into pipe extruder again, extrude enhancement layer;
Surrounding layer manufactures: use 4-7 setation bamboo, block the bamboo section for 900-3200mm, after de-etiolation goes green grass or young crops, bamboo section cuts open into width is: 15-25mm, the bamboo cane of thickness��8mm, the dried gluing assembly of bamboo cane, form bamboo side, after bamboo side's pressure impregnating, it is dried to surface without obvious water mark, it is again dipped in 50-70 DEG C of warm water and soaks at least 24 hours, obtain softening bamboo block, further according to process requirements, bamboo side after softening is carried out slicing, the thin bamboo thickness��0.5mm of slicing gained, again thin bamboo is put into and veneer dryer is dried to moisture content less than 10%, the non-woven fabrics of bamboo-containing fiber is sticked after gluing, further according to needing the thin bamboo after pasting non-woven fabrics or the Bamboo veneer composite vertically and horizontally made after compound are successively covered enhancement layer outer wall, or make the thin bamboo after pasting non-woven fabrics form thin bamboo cane, post outside enhancement layer by the mode being wound around, form outsourcing layer,
After three layers has each manufactured, being combined into compound pipeline complex pipeline, combination step is as follows:
Waterproofing agent and preservative it is coated with at internal layer inwall, insert among the tubular space that enhancement layer inwall is formed after outer wall spraying water proof type adhesive, utilize special-shaped heating press, apply pressure and make internal layer and enhancement layer bonding, at enhancement layer outer wall coated with resins adhesive after bonding, the thin bamboo layers being covered with non-woven fabrics after impregnation is successively attached to enhancement layer outer wall, and the interface between adjacent two layers staggers, until thickness meets needs; Or utilize slewing, rotate the internal layer after bonding and enhancement layer, simultaneously by after impregnation and post the thin bamboo cane of non-woven fabrics and be successively wound into enhancement layer outer wall, until thickness meets needs; The pipeline of first one-step forming is sent in drying equipment, is warmed to 60-140 DEG C, carries out cured;
Last spraying waterproofing agent and preservative on outer layer.
The material of the plastic conduit wherein adopted in internal layer manufacture is selected from polyethylene, polypropylene, polrvinyl chloride, polystyrene.
The waste or used plastics used in enhancement layer manufacture includes the waste polyvinyl chloride of recovery, polyethylene, polypropylene; Selected inorganic filler is selected from: one or more in calcium carbonate, wollastonite, Kaolin, Pulvis Talci; Selected auxiliary agent is antifungus agent or fire retardant.
The liquid of bamboo side's impregnating by pressure is water, aqueous solution containing penetrating agent or softening agent.
The adhesive and the thin bamboo layers institute impregnation that are coated with outside enhancement layer are the one in Lauxite, unsaturated polyester resin, epoxy resin, phenolic resin or polyurethane resin.
The fiber composite containing bamboo charcoal used in internal layer manufacture is prepared as follows: select 4-7 setation bamboo, after carbonization becomes bamboo charcoal, preliminary in bulk footpath of pulverizing is the fritter of 4-6cm, fritter bamboo charcoal carries out three times again pulverize, obtain the bamboo charcoal powder about 800 orders, take that the bamboo charcoal powder of 30-35% is blended with the terylene chips of 65-70% according to mass ratio and conventional method carries out mixing, wire drawing and then prepared bamboo carbon fiber, then by bamboo carbon fiber by the weaving manner formation fiber composite containing bamboo charcoal. Fiber composite containing bamboo charcoal can need to arrange one or more layers according to use, thickness in monolayer��1mm.
The mass ratio of each main component of enhancement layer is, short-fibre silk or bamboo powder: waste or used plastics: modifying agent: technical grade stearic acid: auxiliary agent=60��90:30��60:12-20:5��10:5��10. When extrusion processing, each section of temperature difference of pipe extruder, first paragraph temperature is 90 DEG C, and two-stage nitration temperature is 160 DEG C, and three sections of temperature are 200 DEG C, and engine speed is 60r/min.
In outer layer manufactures, outer of bamboo Huang can use traditional cutting or frosted mode to remove, traditional cutting way, comparatively wastes material, but goes blue or green de-etiolation speed fast; Frosted mode comparatively saves material, and the bamboo powder that grinding is got off can collect recycling. Pressure impregnating desirable pressure is 0.4-1.0MPa, and the time is 24-72h. Slicing thin bamboo out can use melamine resin adehsive stick, modified urea-formaldehyde resin glue to paste non-woven fabrics. Before thin bamboo layers is stacked to enhancement layer outer wall, or before being wound on enhancement layer outer wall, side, the bamboo face coated with resins of thin bamboo layers to be made, in order to laminating between layers.
Waterproofing agent and preservative it is coated with at internal layer inwall, insert among the tubular space that enhancement layer inwall is formed after outer wall spraying water proof type adhesive, utilize special-shaped heating press, apply pressure and make internal layer and enhancement layer bonding, at enhancement layer outer wall coated with resins adhesive after bonding, the thin bamboo layers being covered with non-woven fabrics after impregnation is successively attached to enhancement layer outer wall, and the interface between adjacent two layers staggers, until thickness meets needs; Or utilize slewing, rotate the internal layer after bonding and enhancement layer, simultaneously just after impregnation and post the thin bamboo cane of non-woven fabrics and be successively wound into enhancement layer outer wall, until thickness meets needs; The pipeline of first one-step forming is sent in drying equipment, is warmed to 60-140 DEG C, carries out cured;
Last spraying waterproofing agent and preservative on outer layer.
The waterproofing agent adopted in anabolic process is waterproofing agent of organosilicon, and preservative is modified chitosan metal composite preservative, and water proof type adhesive is phenol-formaldehyde resin modified or neoprene resin.So that thin bamboo layers can fit tightly molding with enhancement layer, can be inserted in the cavity that internal layer is formed steel-made internal mould and on surrounding layer outer sheath steel external mold, and pressurize on internal mold and external mold simultaneously, help sizing.
The application further comprises the bamboo multiple tube prepared by said method, such as Fig. 2, include successively including internal layer 1, enhancement layer 2 and surrounding layer 3 from inside to outside. Described internal layer 1 includes the plastic conduit as body and the fiber composite containing bamboo charcoal, the described fiber composite containing bamboo charcoal is covered in the inwall of described plastic conduit, described enhancement layer 2 is bamboo composite material, surrounding layer 3 is Bamboo veneer composite, described internal layer inwall coating waterproofing agent and preservative, the outermost layer of described surrounding layer sprays waterproofing agent and preservative.
The material of described plastic conduit is selected from polyethylene, polypropylene, polrvinyl chloride, polystyrene.
Described waste or used plastics includes the waste polyvinyl chloride of recovery, polyethylene, polypropylene; Described inorganic filler is selected from one or more in calcium carbonate, wollastonite, Kaolin, Pulvis Talci; Described auxiliary agent is antifungus agent and/or fire retardant.
The adhesive and the described thin bamboo institute impregnation that are coated with outside described enhancement layer are the one in Lauxite, unsaturated polyester resin, epoxy resin, phenolic resin or polyurethane resin.
Described Bamboo veneer composite is thickness��0.5mm bamboo fibre thin bamboo of slicing gained, after being coated with urea-formaldehyde glue, stick the non-woven fabrics of bamboo-containing fiber, the thin bamboo after pasting non-woven fabrics is rolled into outsourcing layer again, or sliced bamboo is carried out vertically and horizontally is directly prepared into Bamboo veneer composite after compound rolls into outsourcing layer.
Although the present invention describes in detail above, it is clear that be understood by, the technical staff in the field that the present invention is correlated with can improve in the case of without departing from the spirit of the present invention.

Claims (10)

1. a manufacture method for bamboo multiple tube, described bamboo multiple tube comprises internal layer, enhancement layer and surrounding layer, comprises the following steps: (one) internal layer manufacture, (two) enhancement layer manufacture, (three) surrounding layer manufacture and (four) pipeline compound, it is characterised in that:
(1) internal layer manufacture: described internal layer includes the plastic conduit as body and the fiber composite containing bamboo charcoal, the described fiber composite containing bamboo charcoal is covered in the inwall of described plastic conduit, described plastic conduit adopts spray fusing to shape, afterwards the described fiber composite containing bamboo charcoal is pasted described plastic conduit inwall, form described internal layer;
(2) enhancement layer manufacture: described enhancement layer is bamboo composite material, the waste or used plastics pulverized, inorganic filler, technical grade stearic acid, auxiliary agent and the agitated machine of bamboo fiber material is selected to be sufficiently stirred for formation mixed material, it is then fed into twin screw extruder to described mixed material extruding pelletization at 220 DEG C, material after pelletize is dried, put into pipe extruder again, extrude described enhancement layer; Described bamboo fiber material is short-fibre silk and/or bamboo powder, and described short-fibre silk is for utilizing small caliber bamboo wood, small diameter grade Cluster Bamboo, bamboo surplus material of processing, and after being rolled into filamental, cutting is formed, the diameter��1mm of described short-fibre silk, length��2cm; Described bamboo powder is through mechanical activation comminution, grinding by small caliber bamboo wood, small diameter grade Cluster Bamboo, bamboo surplus material of processing, and classification is made 50-500 order and formed;
(3) surrounding layer manufacture: described outer layer is Bamboo veneer composite, use 4-7 setation bamboo, block the bamboo section for 900-3200mm, after de-etiolation goes green grass or young crops, it is 15-25mm that bamboo section is processed into width, the bamboo cane of thickness��8mm, the dried gluing assembly of bamboo cane, form bamboo side, after bamboo side's pressure impregnating, it is dried to surface without obvious water mark, it is again dipped in 50-70 DEG C of warm water and soaks at least 24 hours, obtain softening bamboo block, further according to process requirements, bamboo side after softening is carried out slicing, the thin bamboo thickness��0.5mm of slicing gained, again thin bamboo is put into and veneer dryer is dried to moisture content less than 10%,It is coated with after urea-formaldehyde glue, sticks the non-woven fabrics of bamboo-containing fiber, the thinner bamboo after pasting non-woven fabrics is rolled into outsourcing layer, or sliced bamboo is carried out vertically and horizontally is directly prepared into Bamboo veneer composite after compound roll into outsourcing layer;
(4) pipeline compound: be coated with waterproofing agent and preservative at described internal layer inwall, insert among the tubular space that described enhancement layer inwall is formed after outer wall spraying water proof type adhesive, utilize special-shaped heating press, apply pressure and make described internal layer and the bonding of described enhancement layer, at described enhancement layer outer wall coated with resins adhesive after bonding, the thin bamboo being covered with non-woven fabrics after impregnation is successively attached to described enhancement layer outer wall, and the interface between adjacent two layers staggers, until thickness meets needs; The multiple tube of first one-step forming is sent in drying equipment, is warmed to 60-140 DEG C, carries out cured; Last spraying waterproofing agent and preservative on the outermost layer of described surrounding layer.
2. the manufacture method of bamboo multiple tube according to claim 1, it is characterised in that: the material of described plastic conduit is selected from polyethylene, polypropylene, polrvinyl chloride, polystyrene.
3. the manufacture method of bamboo multiple tube according to claim 2, it is characterised in that: waste polyvinyl chloride that described waste or used plastics includes reclaiming, polyethylene, polypropylene; Described inorganic filler is selected from one or more in calcium carbonate, wollastonite, Kaolin, Pulvis Talci; Described auxiliary agent is antifungus agent and/or fire retardant.
4. the manufacture method of bamboo multiple tube according to claim 3, it is characterised in that: the liquid used in described bamboo side impregnating by pressure is water or the aqueous solution containing penetrating agent or softening agent.
5. the manufacture method of bamboo multiple tube according to claim 4, it is characterised in that: outside described enhancement layer, the adhesive of coating and described thin bamboo institute impregnation are the one in Lauxite, unsaturated polyester resin, epoxy resin, phenolic resin or polyurethane resin.
6. a bamboo multiple tube, comprise internal layer, enhancement layer and surrounding layer, it is characterized in that: described internal layer includes the plastic conduit as body and the fiber composite containing bamboo charcoal, the described fiber composite containing bamboo charcoal is covered in the inwall of described plastic conduit, described enhancement layer is bamboo composite material, described outer layer is Bamboo veneer composite, and described internal layer inwall is coated with waterproofing agent and preservative, and the outermost layer of described surrounding layer sprays waterproofing agent and preservative.
7. bamboo multiple tube according to claim 6, it is characterised in that: the material of described plastic conduit is selected from polyethylene, polypropylene, polrvinyl chloride, polystyrene.
8. bamboo multiple tube according to claim 6, it is characterised in that: waste polyvinyl chloride that described waste or used plastics includes reclaiming, polyethylene, polypropylene; Described inorganic filler is selected from one or more in calcium carbonate, wollastonite, Kaolin, Pulvis Talci; Described auxiliary agent is antifungus agent and/or fire retardant.
9. bamboo multiple tube according to claim 6, it is characterised in that: outside described enhancement layer, the adhesive of coating and described thin bamboo institute impregnation are the one in Lauxite, unsaturated polyester resin, epoxy resin, phenolic resin or polyurethane resin.
10. bamboo multiple tube according to claim 6, it is characterized in that: described Bamboo veneer composite is thickness��0.5mm bamboo fibre thin bamboo of slicing gained, after being coated with urea-formaldehyde glue, stick the non-woven fabrics of bamboo-containing fiber, the thin bamboo after pasting non-woven fabrics is rolled into outsourcing layer again, or sliced bamboo is carried out vertically and horizontally is directly prepared into Bamboo veneer composite after compound rolls into outsourcing layer.
CN201610000269.9A 2016-01-03 2016-01-03 Bamboo composite tube and manufacturing method thereof Pending CN105650363A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610000269.9A CN105650363A (en) 2016-01-03 2016-01-03 Bamboo composite tube and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610000269.9A CN105650363A (en) 2016-01-03 2016-01-03 Bamboo composite tube and manufacturing method thereof

Publications (1)

Publication Number Publication Date
CN105650363A true CN105650363A (en) 2016-06-08

Family

ID=56491262

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610000269.9A Pending CN105650363A (en) 2016-01-03 2016-01-03 Bamboo composite tube and manufacturing method thereof

Country Status (1)

Country Link
CN (1) CN105650363A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107791342A (en) * 2016-08-30 2018-03-13 湖北福汉木业有限公司 A kind of wooden cable hank and its production method
CN108131504A (en) * 2018-02-09 2018-06-08 安徽华奇管业有限公司 A kind of superpower measuring body bamboo with bell socket slights spiral composite pipe
CN108340453A (en) * 2018-02-09 2018-07-31 安徽华奇管业有限公司 A kind of bamboo processing treatment technology of manufacture bamboo winding composite pressure pipe
CN109304778A (en) * 2018-10-19 2019-02-05 浙江农林大学暨阳学院 A kind of manufacturing method and products thereof of high-performance bamboo fiber reinforced plastics
CN110039743A (en) * 2019-05-10 2019-07-23 浙江峰源新材料科技股份有限公司 A kind of preparation method of bamboo carbon fibre Reinforced PVC hose
CN111231040A (en) * 2020-03-20 2020-06-05 南京林业大学 Novel degradable fiber straw and manufacturing method thereof
CN112454590A (en) * 2020-11-12 2021-03-09 澳莆(上海)环保科技有限公司 Preparation method of double-layer flat-pressing arc-shaped bamboo cylinder for architectural decoration
CN113028193A (en) * 2021-03-09 2021-06-25 天津日腾飞管业有限公司 Anti-blocking ventilation pipe for henhouse and preparation process
WO2021129295A1 (en) * 2019-12-23 2021-07-01 浙江鑫宙竹基复合材料科技有限公司 Bamboo-based winding composite pipe and manufacturing method therefor
CN113878681A (en) * 2020-12-17 2022-01-04 龙竹科技集团股份有限公司 Bamboo straw processing method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5423933A (en) * 1993-05-19 1995-06-13 Horian; Richard C. Fabrication of plastic and wood veneer composite
CN102259450A (en) * 2011-06-02 2011-11-30 南京林业大学 Self-abrasion-resisting wood composite material and manufacturing method thereof
CN104260422A (en) * 2014-08-27 2015-01-07 南京林业大学 Wood-based composite pipe and preparation method thereof
CN104948848A (en) * 2015-05-11 2015-09-30 杭州金培科技有限公司 Energy-saving and environment-friendly composite tube and manufacturing method thereof
US20150273804A1 (en) * 2014-03-31 2015-10-01 Jiangsu Kentier Wood Co., Ltd. Wood composite product

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5423933A (en) * 1993-05-19 1995-06-13 Horian; Richard C. Fabrication of plastic and wood veneer composite
CN102259450A (en) * 2011-06-02 2011-11-30 南京林业大学 Self-abrasion-resisting wood composite material and manufacturing method thereof
US20150273804A1 (en) * 2014-03-31 2015-10-01 Jiangsu Kentier Wood Co., Ltd. Wood composite product
CN104260422A (en) * 2014-08-27 2015-01-07 南京林业大学 Wood-based composite pipe and preparation method thereof
CN104948848A (en) * 2015-05-11 2015-09-30 杭州金培科技有限公司 Energy-saving and environment-friendly composite tube and manufacturing method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
许斌 等: "竹材通过端部压注处理进行防裂及防蛀的研究", 《竹子研究汇刊》 *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107791342A (en) * 2016-08-30 2018-03-13 湖北福汉木业有限公司 A kind of wooden cable hank and its production method
CN108131504A (en) * 2018-02-09 2018-06-08 安徽华奇管业有限公司 A kind of superpower measuring body bamboo with bell socket slights spiral composite pipe
CN108340453A (en) * 2018-02-09 2018-07-31 安徽华奇管业有限公司 A kind of bamboo processing treatment technology of manufacture bamboo winding composite pressure pipe
CN109304778A (en) * 2018-10-19 2019-02-05 浙江农林大学暨阳学院 A kind of manufacturing method and products thereof of high-performance bamboo fiber reinforced plastics
CN110039743A (en) * 2019-05-10 2019-07-23 浙江峰源新材料科技股份有限公司 A kind of preparation method of bamboo carbon fibre Reinforced PVC hose
WO2021129295A1 (en) * 2019-12-23 2021-07-01 浙江鑫宙竹基复合材料科技有限公司 Bamboo-based winding composite pipe and manufacturing method therefor
CN111231040A (en) * 2020-03-20 2020-06-05 南京林业大学 Novel degradable fiber straw and manufacturing method thereof
CN112454590A (en) * 2020-11-12 2021-03-09 澳莆(上海)环保科技有限公司 Preparation method of double-layer flat-pressing arc-shaped bamboo cylinder for architectural decoration
CN113878681A (en) * 2020-12-17 2022-01-04 龙竹科技集团股份有限公司 Bamboo straw processing method
WO2022126853A1 (en) * 2020-12-17 2022-06-23 龙竹科技集团股份有限公司 Bamboo straw processing method
CN113878681B (en) * 2020-12-17 2023-05-23 龙竹科技集团股份有限公司 Bamboo straw processing method
CN113028193A (en) * 2021-03-09 2021-06-25 天津日腾飞管业有限公司 Anti-blocking ventilation pipe for henhouse and preparation process

Similar Documents

Publication Publication Date Title
CN105650363A (en) Bamboo composite tube and manufacturing method thereof
CN101532592B (en) Environmental protection glass-reinforced plastic pipe and production method thereof
CN104948848B (en) Energy-saving and environment-friendly composite tube and manufacturing method thereof
CN105715882B (en) A kind of small-bore bamboo coiled composite tube and its manufacturing method
CN104896211B (en) High-performance wood base composite pressure delivery pipe and preparation method
CN101832430A (en) Glass-steel reinforced plastic pipe and manufacturing method thereof
CN103557378A (en) High-stiffness composite tube formed through fixed length winding and manufacturing method thereof
CN101992555A (en) Processing method of net framework enhanced plastic composite pipe and manufactured composite pipe
CN103434156A (en) Production technology of composite cable duct with adhesive layer
CN104057678A (en) High wear-resistant waterproof moisture-proof composite board and preparation method and application thereof
CN204361643U (en) Composite cable protection pipe
CN102825646B (en) The making method of a kind of cellulosic bobbin
CN204665313U (en) Bamboo is wound around composite chimney
CN104260422B (en) Wood base composite pipe and preparation method
CN104044276B (en) The manufacture method of glass reinforced plastic pipe
WO2009154946A3 (en) Structurally supported insert and process for producing the same
CN102328464A (en) Honeycomb core plate of composite plate and manufacturing process thereof
CN103486347A (en) Heat-preservation compound glass steel tube and forming process thereof
CN205724730U (en) A kind of high strength glass fiber reinforced plastics cable duct tube
CN201294209Y (en) Fiberglass insulation tube
CN100560942C (en) The preparation method of integral organic glass fiber reinforced plastic wind pipe
CN206154787U (en) Bamboo winding composite product
CN103507279A (en) Corrugated hollow plate and manufacturing method thereof
CN202242128U (en) Alveolate core plate of composite plate
CN102563233A (en) Multifunctional mining combined pipe and manufacturing method for same

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160608