CN105647031A - Anti-skidding shoe material suitable for ice surface and preparation method thereof - Google Patents
Anti-skidding shoe material suitable for ice surface and preparation method thereof Download PDFInfo
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- CN105647031A CN105647031A CN201610162286.2A CN201610162286A CN105647031A CN 105647031 A CN105647031 A CN 105647031A CN 201610162286 A CN201610162286 A CN 201610162286A CN 105647031 A CN105647031 A CN 105647031A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an anti-skidding shoe material suitable for an ice surface. The anti-skidding shoe material is prepared from the following components in parts by weight: 18-30 parts of butyl rubber, 30-45 parts of ethylene propylene rubber, 12-18 parts of ecteola cellulose fine mesh, 3-8 parts of aluminum zirconium dioxide, 4-7 parts of methylprednisolone acetate, 5-10 parts of triethanolamine citrate, 1-5 parts of tert-butyl mercaptan, 2-7 parts of polyethylene wax, 8-12 parts of indene oxide and 0.5-3.5 parts of diisopropyl xanthogen disulfide. The prepared shoe material has excellent anti-skidding performance on smooth road surfaces such as the ice surface; the safety and the stability of walking are improved.
Description
Technical field
The invention belongs to the preparation field of footwear material, particularly to a kind of on-slip shoes material suitable in the use of ice face and preparation method thereof.
Background technology
Why people can on the way walk the existence being because between sole and ground frictional force. People, in the process of daily walking, often step a step, and the bottom of shoes once will rub with ground, thus, often decline at the locomotor activity of smooth road people under normal circumstances, it is not easy to walk surely, walk soon and arbitrarily change direction; Stronger at the locomotor activity of shaggy road surface people. In northern China, owing to weather is comparatively severe, the severe cold weather that snows often makes road surface easily freeze, and common shoes non-skid property on this smooth ice face is poor, effecting reaction cannot be made when running into emergency case or emergency in time, be the problem needing to solve thus for the non-skid property how making shoes also show excellence on relatively smooth ground.
Summary of the invention
For the above technical problem existed in prior art, the invention provides a kind of on-slip shoes material suitable in the use of ice face and preparation method thereof, to solve problem poor in ice face shoes non-skid property at present.
Technical scheme: a kind of on-slip shoes material used suitable in ice face, each component including following percentage by weight: butyl rubber 18-30 part, ethylene propylene monomer 30-45 part, cross-links alcohol amine cellulose 12-18 part, zirconium dioxide aluminum 3-8 part, methylprednisolone acetate 4-7 part, triethanolamine citrate 5-10 part, tert-butyl mercaptan 1-5 part, Tissuemat E 2-7 part, oxidation indenes 8-12 part, dithiodiisopropyl xanthate 0.5-3.5 part.
Preferably, described butyl rubber 24-28 part, ethylene propylene monomer 35-40 part, cross-links alcohol amine cellulose 15-18 part, zirconium dioxide aluminum 4-6 part, methylprednisolone acetate 4-6 part, triethanolamine citrate 6-9 part, tert-butyl mercaptan 2-3.5 part, Tissuemat E 3-6 part, oxidation indenes 9-12 part, dithiodiisopropyl xanthate 1-2.5 part.
Preferably, described butyl rubber 26 parts, ethylene propylene monomer 38 parts, cross-link alcohol amine cellulose 17 parts, 5 parts of zirconium dioxide aluminum, methylprednisolone acetate 5 parts, triethanolamine citrate 8 parts, tert-butyl mercaptan 3 parts, Tissuemat E 4 parts, aoxidizes indenes 10 parts, dithiodiisopropyl xanthate 2 parts.
The preparation method of a kind of on-slip shoes material used suitable in ice face, comprises the steps of:
(1) by butyl rubber 18-30 part heating-up temperature to 40-75 DEG C, insulation reaction 10-15min;It is subsequently added methylprednisolone acetate 4-7 part and Tissuemat E 2-7 part, stirring reaction 5-20min, obtains A material;
(2) ethylene propylene monomer 30-45 part is heated to temperature 50-65 DEG C, insulation reaction 5-10min; It is subsequently added crosslinking alcohol amine cellulose 12-18 part, triethanolamine citrate 5-10 part and tert-butyl mercaptan 1-5 part, stirring reaction 10-15min, obtains B material;
(3) zirconium dioxide aluminum 3-8 part and oxidation indenes 8-12 part are added in dithiodiisopropyl xanthate 0.5-3.5 part, stirring reaction 10-15min at temperature 30-40 DEG C, obtain C material;
(4) B material described in the material of A described in step (1), step (2) and C material described in step (3) are mixed in a kettle., stirring reaction 20-30min at keeping temperature 60-70 DEG C, can obtain the described on-slip shoes material being applicable to the use of ice face after discharging, cooling.
Preferably, temperature described in step (1) is 65 DEG C, and the time of described insulation reaction is 15min, and the time of stirring reaction is 10min, and the speed of stirring is 200r/min.
Preferably, temperature described in step (2) is 58 DEG C, and the time of described insulation reaction is 8min, and the time of stirring reaction is 10min, and the speed of stirring is 250r/min.
Preferably, temperature described in step (3) is 35 DEG C, and the time of stirring reaction is 12min, and the speed of stirring is 250r/min.
Preferably, temperature described in step (4) is 62 DEG C, and the time of stirring reaction is 25min, and the speed of stirring is 350r/min.
Beneficial effect:
A kind of on-slip shoes material suitable in the use of ice face of the present invention and preparation method thereof, by adding portion raw material in footwear material preparation process, improve the non-skid property, the particularly non-skid property in smooth road such as ice face of footwear material, meet the demand that people walk on brilliance road surface. Preparation method of the present invention is easy, easily operate. Prepared by the present invention, the static friction factor of footwear material is up to 0.73-0.96, and dynamic friction factor is up to 0.45-0.62.
Detailed description of the invention
Embodiment 1
(1) by 18 parts of heating-up temperatures of butyl rubber to 40 DEG C, insulation reaction 10min; It is subsequently added methylprednisolone acetate 4 parts and Tissuemat E 2 parts, with speed 200r/min stirring reaction 5min, obtains A material;
(2) by ethylene propylene monomer 30 parts heating to temperature 50 C, insulation reaction 5min; It is subsequently added crosslinking alcohol amine cellulose 12 parts, triethanolamine citrate 5 parts and tert-butyl mercaptan 1 part, with 250r/min speed stirring reaction 10min, obtains B material;
(3) 3 parts of zirconium dioxide aluminum and oxidation indenes 8 parts are added in dithiodiisopropyl xanthate 0.5 part, at temperature 30 DEG C, with speed 250r/min stirring reaction 10min, obtain C material;
(4) B material described in the material of A described in step (1), step (2) and C material described in step (3) are mixed in a kettle., keep under temperature 60 C, with speed 350r/min stirring reaction 20min, the described on-slip shoes material being applicable to the use of ice face can be obtained after discharging, cooling.
Embodiment 2
(1) by 30 parts of heating-up temperatures of butyl rubber to 75 DEG C, insulation reaction 15min; It is subsequently added methylprednisolone acetate 7 parts and Tissuemat E 7 parts, with speed 200r/min stirring reaction 20min, obtains A material;
(2) by ethylene propylene monomer 45 parts heating to temperature 65 DEG C, insulation reaction 10min; It is subsequently added crosslinking alcohol amine cellulose 18 parts, triethanolamine citrate 10 parts and tert-butyl mercaptan 5 parts, with 250r/min speed stirring reaction 15min, obtains B material;
(3) 8 parts of zirconium dioxide aluminum and oxidation indenes 12 parts are added in dithiodiisopropyl xanthate 3.5 parts, at temperature 40 DEG C, with speed 250r/min stirring reaction 15min, obtain C material;
(4) B material described in the material of A described in step (1), step (2) and C material described in step (3) are mixed in a kettle., keep under temperature 70 C, with speed 350r/min stirring reaction 30min, the described on-slip shoes material being applicable to the use of ice face can be obtained after discharging, cooling.
Embodiment 3
(1) by 24 parts of heating-up temperatures of butyl rubber to 60 DEG C, insulation reaction 10min; It is subsequently added methylprednisolone acetate 4 parts and Tissuemat E 3 parts, with speed 200r/min stirring reaction 10min, obtains A material;
(2) by ethylene propylene monomer 35 parts heating to temperature 55 DEG C, insulation reaction 10min; It is subsequently added crosslinking alcohol amine cellulose 15 parts, triethanolamine citrate 6 parts and tert-butyl mercaptan 2 parts, with 250r/min speed stirring reaction 10min, obtains B material;
(3) 4 parts of zirconium dioxide aluminum and oxidation indenes 9 parts are added in dithiodiisopropyl xanthate 1 part, at temperature 40 DEG C, with speed 250r/min stirring reaction 15min, obtain C material;
(4) B material described in the material of A described in step (1), step (2) and C material described in step (3) are mixed in a kettle., keep under temperature 70 C, with speed 350r/min stirring reaction 30min, the described on-slip shoes material being applicable to the use of ice face can be obtained after discharging, cooling.
Embodiment 4
(1) by 28 parts of heating-up temperatures of butyl rubber to 70 DEG C, insulation reaction 15min; It is subsequently added methylprednisolone acetate 6 parts and Tissuemat E 6 parts, with speed 200r/min stirring reaction 15min, obtains A material;
(2) by ethylene propylene monomer 40 parts heating to temperature 60 C, insulation reaction 15min; It is subsequently added crosslinking alcohol amine cellulose 18 parts, triethanolamine citrate 9 parts and tert-butyl mercaptan 3.5 parts, with 250r/min speed stirring reaction 15min, obtains B material;
(3) 6 parts of zirconium dioxide aluminum and oxidation indenes 12 parts are added in dithiodiisopropyl xanthate 2.5 parts, at temperature 35 DEG C, with speed 250r/min stirring reaction 10min, obtain C material;
(4) B material described in the material of A described in step (1), step (2) and C material described in step (3) are mixed in a kettle., keep at temperature 65 DEG C, with speed 350r/min stirring reaction 25min, the described on-slip shoes material being applicable to the use of ice face can be obtained after discharging, cooling.
Embodiment 5
(1) by 26 parts of heating-up temperatures of butyl rubber to 65 DEG C, insulation reaction 15min; It is subsequently added methylprednisolone acetate 5 parts and Tissuemat E 4 parts, with speed 200r/min stirring reaction 10min, obtains A material;
(2) by ethylene propylene monomer 38 parts heating to temperature 58 DEG C, insulation reaction 8min; It is subsequently added crosslinking alcohol amine cellulose 17 parts, triethanolamine citrate 8 parts and tert-butyl mercaptan 3 parts, with 250r/min speed stirring reaction 10min, obtains B material;
(3) 5 parts of zirconium dioxide aluminum and oxidation indenes 10 parts are added in dithiodiisopropyl xanthate 2 parts, at temperature 35 DEG C, with speed 250r/min stirring reaction 12min, obtain C material;
(4) B material described in the material of A described in step (1), step (2) and C material described in step (3) are mixed in a kettle., keep at temperature 62 DEG C, with speed 350r/min stirring reaction 25min, the described on-slip shoes material being applicable to the use of ice face can be obtained after discharging, cooling.
Comparative example 1
(1) by 18 parts of heating-up temperatures of butyl rubber to 40 DEG C, insulation reaction 10min; It is subsequently added Tissuemat E 2 parts, with speed 200r/min stirring reaction 5min, obtains A material;
(2) by ethylene propylene monomer 30 parts heating to temperature 50 C, insulation reaction 5min; It is subsequently added triethanolamine citrate 5 parts and tert-butyl mercaptan 1 part, with 250r/min speed stirring reaction 10min, obtains B material;
(3) 3 parts of zirconium dioxide aluminum is added in dithiodiisopropyl xanthate 0.5 part, at temperature 30 DEG C, with speed 250r/min stirring reaction 10min, obtain C material;
(4) B material described in the material of A described in step (1), step (2) and C material described in step (3) are mixed in a kettle., under maintenance temperature 60 C, with speed 350r/min stirring reaction 20min, footwear material can be obtained after discharging, cooling.
Comparative example 2
(1) by 30 parts of heating-up temperatures of butyl rubber to 75 DEG C, insulation reaction 15min; It is subsequently added Tissuemat E 7 parts, with speed 200r/min stirring reaction 20min, obtains A material;
(2) by ethylene propylene monomer 45 parts heating to temperature 65 DEG C, insulation reaction 10min; It is subsequently added triethanolamine citrate 10 parts and tert-butyl mercaptan 5 parts, with 250r/min speed stirring reaction 15min, obtains B material;
(3) 8 parts of zirconium dioxide aluminum is added in dithiodiisopropyl xanthate 3.5 parts, at temperature 40 DEG C, with speed 250r/min stirring reaction 15min, obtain C material;
(4) B material described in the material of A described in step (1), step (2) and C material described in step (3) are mixed in a kettle., under maintenance temperature 70 C, with speed 350r/min stirring reaction 30min, footwear material can be obtained after discharging, cooling.
To the footwear material of each embodiment and comparative example according to " GB/T3903.6 2005 footwear GENERAL EXPERIMENTATION non-skid property " detector non-skid property, result is as follows:
| Project | Static friction factor | Dynamic friction factor |
| Comparative example 1 | 0.41 | 0.24 |
| Comparative example 2 | 0.43 | 0.28 |
| Embodiment 1 | 0.73 | 0.45 |
| Embodiment 2 | 0.75 | 0.49 |
| Embodiment 3 | 0.81 | 0.51 |
| Embodiment 4 | 0.83 | 0.58 |
| Embodiment 5 | 0.96 | 0.62 |
Claims (8)
1. one kind is applicable to the on-slip shoes material that ice face uses, it is characterized in that, including each component of following percentage by weight: butyl rubber 18-30 part, ethylene propylene monomer 30-45 part, crosslinking alcohol amine cellulose 12-18 part, zirconium dioxide aluminum 3-8 part, methylprednisolone acetate 4-7 part, triethanolamine citrate 5-10 part, tert-butyl mercaptan 1-5 part, Tissuemat E 2-7 part, aoxidizes indenes 8-12 part, dithiodiisopropyl xanthate 0.5-3.5 part.
2. a kind of on-slip shoes material used suitable in ice face according to claim 1, it is characterized in that, described butyl rubber 24-28 part, ethylene propylene monomer 35-40 part, crosslinking alcohol amine cellulose 15-18 part, zirconium dioxide aluminum 4-6 part, methylprednisolone acetate 4-6 part, triethanolamine citrate 6-9 part, tert-butyl mercaptan 2-3.5 part, Tissuemat E 3-6 part, aoxidizes indenes 9-12 part, dithiodiisopropyl xanthate 1-2.5 part.
3. a kind of on-slip shoes material used suitable in ice face according to claim 1, it is characterized in that, described butyl rubber 26 parts, ethylene propylene monomer 38 parts, crosslinking alcohol amine cellulose 17 parts, 5 parts of zirconium dioxide aluminum, methylprednisolone acetate 5 parts, triethanolamine citrate 8 parts, tert-butyl mercaptan 3 parts, Tissuemat E 4 parts, aoxidizes indenes 10 parts, dithiodiisopropyl xanthate 2 parts.
4. the preparation method being applicable to the on-slip shoes material that ice face uses, it is characterised in that comprise the steps of:
(1) by butyl rubber 18-30 part heating-up temperature to 40-75 DEG C, insulation reaction 10-15min; It is subsequently added methylprednisolone acetate 4-7 part and Tissuemat E 2-7 part, stirring reaction 5-20min, obtains A material;
(2) ethylene propylene monomer 30-45 part is heated to temperature 50-65 DEG C, insulation reaction 5-10min; It is subsequently added crosslinking alcohol amine cellulose 12-18 part, triethanolamine citrate 5-10 part and tert-butyl mercaptan 1-5 part, stirring reaction 10-15min, obtains B material;
(3) zirconium dioxide aluminum 3-8 part and oxidation indenes 8-12 part are added in dithiodiisopropyl xanthate 0.5-3.5 part, stirring reaction 10-15min at temperature 30-40 DEG C, obtain C material;
(4) B material described in the material of A described in step (1), step (2) and C material described in step (3) are mixed in a kettle., stirring reaction 20-30min at keeping temperature 60-70 DEG C, can obtain the described on-slip shoes material being applicable to the use of ice face after discharging, cooling.
5. the preparation method of a kind of on-slip shoes material used suitable in ice face according to claim 4, it is characterized in that, temperature described in step (1) is 65 DEG C, and the time of described insulation reaction is 15min, the time of stirring reaction is 10min, and the speed of stirring is 200r/min.
6. the preparation method of a kind of on-slip shoes material used suitable in ice face according to claim 4, it is characterized in that, temperature described in step (2) is 58 DEG C, and the time of described insulation reaction is 8min, the time of stirring reaction is 10min, and the speed of stirring is 250r/min.
7. the preparation method of a kind of on-slip shoes material used suitable in ice face according to claim 4, it is characterised in that temperature described in step (3) is 35 DEG C, and the time of stirring reaction is 12min, and the speed of stirring is 250r/min.
8. the preparation method of a kind of on-slip shoes material used suitable in ice face according to claim 4, it is characterised in that temperature described in step (4) is 62 DEG C, and the time of stirring reaction is 25min, and the speed of stirring is 350r/min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610162286.2A CN105647031A (en) | 2016-03-22 | 2016-03-22 | Anti-skidding shoe material suitable for ice surface and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610162286.2A CN105647031A (en) | 2016-03-22 | 2016-03-22 | Anti-skidding shoe material suitable for ice surface and preparation method thereof |
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| CN105647031A true CN105647031A (en) | 2016-06-08 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084370A (en) * | 2016-06-30 | 2016-11-09 | 嘉兴市哈妮鞋业有限公司 | The preparation method of high rigidity sole sizing material |
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| CN102964645A (en) * | 2012-11-29 | 2013-03-13 | 泰亚鞋业股份有限公司 | Ice surface anti-slip rubber sports shoe soles and manufacturing method thereof |
| CN104292554A (en) * | 2014-08-07 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | Ice-surface dynamic anti-slip rubber sole and production method thereof |
| CN104804248A (en) * | 2015-04-26 | 2015-07-29 | 青岛保利康新材料有限公司 | Non-skid rubber soles |
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2016
- 2016-03-22 CN CN201610162286.2A patent/CN105647031A/en active Pending
Patent Citations (4)
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| EP1664169B1 (en) * | 2003-09-15 | 2009-05-13 | Basf Se | Expandable thermoplastic polyurethane blends |
| CN102964645A (en) * | 2012-11-29 | 2013-03-13 | 泰亚鞋业股份有限公司 | Ice surface anti-slip rubber sports shoe soles and manufacturing method thereof |
| CN104292554A (en) * | 2014-08-07 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | Ice-surface dynamic anti-slip rubber sole and production method thereof |
| CN104804248A (en) * | 2015-04-26 | 2015-07-29 | 青岛保利康新材料有限公司 | Non-skid rubber soles |
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| CN106084370A (en) * | 2016-06-30 | 2016-11-09 | 嘉兴市哈妮鞋业有限公司 | The preparation method of high rigidity sole sizing material |
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