CN105638671B - A kind of high-efficient pesticide composition - Google Patents
A kind of high-efficient pesticide composition Download PDFInfo
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- CN105638671B CN105638671B CN201610089103.9A CN201610089103A CN105638671B CN 105638671 B CN105638671 B CN 105638671B CN 201610089103 A CN201610089103 A CN 201610089103A CN 105638671 B CN105638671 B CN 105638671B
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- Prior art keywords
- fluacrypyrim
- active ingredient
- mite
- pesticide composition
- agent
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- 239000000203 mixture Substances 0.000 title claims abstract description 51
- 239000000575 pesticide Substances 0.000 title claims abstract description 35
- MXWAGQASUDSFBG-RVDMUPIBSA-N fluacrypyrim Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC(C(F)(F)F)=NC(OC(C)C)=N1 MXWAGQASUDSFBG-RVDMUPIBSA-N 0.000 claims abstract description 82
- 239000004480 active ingredient Substances 0.000 claims abstract description 51
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 33
- BOTNFCTYKJBUMU-UHFFFAOYSA-N 2-[4-(2-methylpropyl)piperazin-4-ium-1-yl]-2-oxoacetate Chemical compound CC(C)C[NH+]1CCN(C(=O)C([O-])=O)CC1 BOTNFCTYKJBUMU-UHFFFAOYSA-N 0.000 claims abstract description 25
- XQUXKZZNEFRCAW-UHFFFAOYSA-N fenpropathrin Chemical compound CC1(C)C(C)(C)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 XQUXKZZNEFRCAW-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000000375 suspending agent Substances 0.000 claims description 36
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 241001454293 Tetranychus urticae Species 0.000 claims description 15
- 230000000694 effects Effects 0.000 claims description 15
- 206010018498 Goitre Diseases 0.000 claims description 14
- 241000255967 Helicoverpa zea Species 0.000 claims description 14
- 241000488581 Panonychus citri Species 0.000 claims description 14
- 201000003872 goiter Diseases 0.000 claims description 14
- 239000003094 microcapsule Substances 0.000 claims description 14
- 241001198505 Anarsia lineatella Species 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 11
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims description 9
- 240000003768 Solanum lycopersicum Species 0.000 claims description 9
- 241001517923 Douglasiidae Species 0.000 claims description 8
- 241000488583 Panonychus ulmi Species 0.000 claims description 8
- 241000488533 Tetranychus viennensis Species 0.000 claims description 8
- 241000255969 Pieris brassicae Species 0.000 claims description 7
- 241000344246 Tetranychus cinnabarinus Species 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 7
- 241001619980 Acaphylla theae Species 0.000 claims description 6
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 235000013305 food Nutrition 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000005653 Bifenazate Substances 0.000 abstract description 22
- VHLKTXFWDRXILV-UHFFFAOYSA-N bifenazate Chemical compound C1=C(NNC(=O)OC(C)C)C(OC)=CC=C1C1=CC=CC=C1 VHLKTXFWDRXILV-UHFFFAOYSA-N 0.000 abstract description 22
- 230000002195 synergetic effect Effects 0.000 abstract description 20
- 150000001875 compounds Chemical class 0.000 abstract description 11
- 230000000749 insecticidal effect Effects 0.000 abstract description 3
- 238000001228 spectrum Methods 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 239000003814 drug Substances 0.000 description 37
- 238000012360 testing method Methods 0.000 description 33
- 230000003449 preventive effect Effects 0.000 description 24
- 238000013329 compounding Methods 0.000 description 22
- 230000002265 prevention Effects 0.000 description 19
- 239000004563 wettable powder Substances 0.000 description 19
- 241000238631 Hexapoda Species 0.000 description 17
- 238000002474 experimental method Methods 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000002518 antifoaming agent Substances 0.000 description 14
- 239000002270 dispersing agent Substances 0.000 description 14
- 239000012071 phase Substances 0.000 description 14
- 239000003995 emulsifying agent Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 9
- 229910021641 deionized water Inorganic materials 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- 239000000080 wetting agent Substances 0.000 description 9
- 230000002528 anti-freeze Effects 0.000 description 8
- 231100000820 toxicity test Toxicity 0.000 description 8
- 229910001868 water Inorganic materials 0.000 description 8
- 241000207199 Citrus Species 0.000 description 7
- 206010067482 No adverse event Diseases 0.000 description 7
- 230000010165 autogamy Effects 0.000 description 7
- 235000020971 citrus fruits Nutrition 0.000 description 7
- 229940079593 drug Drugs 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- -1 methoxyl group Esters Chemical class 0.000 description 7
- 235000013339 cereals Nutrition 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000000895 acaricidal effect Effects 0.000 description 5
- 239000000642 acaricide Substances 0.000 description 5
- 239000002574 poison Substances 0.000 description 5
- 231100000614 poison Toxicity 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 206010011732 Cyst Diseases 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 208000031513 cyst Diseases 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 238000013401 experimental design Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000001018 virulence Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 102000002322 Egg Proteins Human genes 0.000 description 3
- 108010000912 Egg Proteins Proteins 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 244000061458 Solanum melongena Species 0.000 description 3
- 235000002597 Solanum melongena Nutrition 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 210000004681 ovum Anatomy 0.000 description 3
- 230000000361 pesticidal effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 235000007516 Chrysanthemum Nutrition 0.000 description 2
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 125000004093 cyano group Chemical group *C#N 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 235000021374 legumes Nutrition 0.000 description 2
- 231100000225 lethality Toxicity 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229940067157 phenylhydrazine Drugs 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- RHDYQUZYHZWTCI-UHFFFAOYSA-N 1-methoxy-4-phenylbenzene Chemical group C1=CC(OC)=CC=C1C1=CC=CC=C1 RHDYQUZYHZWTCI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 241001292007 Chrysopa Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- VSLWUPHHCFQTDB-LJQANCHMSA-N [(3r)-3-(hydroxymethyl)piperidin-1-yl]-[4-[2-(4-methoxyphenyl)ethynyl]phenyl]methanone Chemical compound C1=CC(OC)=CC=C1C#CC1=CC=C(C(=O)N2C[C@H](CO)CCC2)C=C1 VSLWUPHHCFQTDB-LJQANCHMSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- AFVLVVWMAFSXCK-VMPITWQZSA-N alpha-cyano-4-hydroxycinnamic acid Chemical group OC(=O)C(\C#N)=C\C1=CC=C(O)C=C1 AFVLVVWMAFSXCK-VMPITWQZSA-N 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- ONHBDDJJTDTLIR-UHFFFAOYSA-N azocyclotin Chemical compound C1CCCCC1[Sn](N1N=CN=C1)(C1CCCCC1)C1CCCCC1 ONHBDDJJTDTLIR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052956 cinnabar Inorganic materials 0.000 description 1
- 230000002508 compound effect Effects 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
- A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
- A01N55/04—Tin
Abstract
The invention discloses a kind of high-efficient pesticide composition, the composition pesticide containing active components A Yu active ingredient B, active components A is selected from fluacrypyrim, and active ingredient B is selected from any one following compound：Azacyclotin, Bifenazate, fenbutatin oxide, Fenpropathrin, and active components A and the weight ratio of active ingredient B are 1 ︰, 80~60 ︰ 1.The present composition can prevent various pests, and have apparent synergistic effect, expand insecticidal spectrum, and can reduce pesticide usage amount, reduce residual quantity of the pesticide on crop, mitigate environmental pollution.
Description
The application is divisional application, and original application is a kind of patent application " highly effective pesticide of Shaanxi Meibang Pesticide Co., Ltd.
Composition ", the application Wei ︰ 201210138455.0 of original application, original application day 2012.05.05.
Technical field
The invention belongs to technical field of pesticide, are related to a kind of application of high-efficient pesticide composition on crop pest.
Technical background
Fluacrypyrim (Fluacrypyrim) chemical name：Methyl (E) -2- α-[2- isopropoxies -6- (trifluoromethyl) is phonetic
Pyridine -4- phenoxy groups] -0- tolyls } -3- methoxy acrylates, molecular formula：C20H21F3N2O5.Fluacrypyrim is first methoxyl group
Esters of acrylic acid acaricide.With tagging and stomach poison function well, to each feature of evil mite, including ovum, deutonymph, equal into mite
Effectively, and quick-acting is good, and the lasting period is up to 30 days or more.
Azacyclotin (Azocyclotin) chemical name：1- (three cyclohexyl stannyls) -1- hydrogen -1,2,4- triazoles,
Molecular formula：C20H35N3Sn.Azacyclotin is the stronger broad spectrum activity acaricide of action of contace poison.Deutonymph can be killed, into mite and summer egg, to the winter
Ovum is invalid.There is preferable stability to light and rainwater, the longevity of residure is longer.To crop safety under typical concentrations.
Bifenazate (Bifenazate) chemical name：3- (4- methoxyl biphenyl base -3- bases) carbazic acid isopropyl ester, point
Minor：C17H20N2O3.Bifenazate is a kind of new selective foliar spray acaricide, is had to each life stage of mite
Effect.It is minimum on predatory mite influence with ovicidal activity and to knocking down activity into the rapid of mite, it is very suitable for the synthesis of pest
It administers.Plant is not poisoned.
Fenbutatin oxide (Fenbutatin oxide) chemical name：Double [three 2- methylphenyls propyl) tin] oxide, molecule
Formula：C60H78OSn2.Fenbutatin oxide is a kind of non-interior suction acaricide, and the evil mite resistant to organophosphor and organochlorine does not generate it friendship
Mutual resistance.To evil mite based on tagging, starting virulence is slow after spray, and activity starts to increase after 3 days, peaks by 14 days.
The medicine longevity of residure is one kind longer in acaricide, to young mite and stronger into the lethality of mite up to 2-5 months, but to ovum
Lethality is little, all very safe in each growth period use of crop, uses more than effective mite killing concentration one and is showed no poisoning hair again
It is raw, it is very small on such as influences such as Predatory Mites, wooden dipper first and Chrysopa of evil mite natural enemy.
Fenpropathrin (Fenpropathrin) chemical name：Alpha-cyano -3- phenoxy benzyl -2,2,3,3- tetramethyl-rings
Propane carbonyl acid ester, molecular formula：C22H23NO3.Fenpropathrin is a kind of pyrethroid insecticides, and insecticidal spectrum is wide, and the longevity of residure is long,
It is its maximum feature to have good result to a variety of tetranychids, but this product is without interior suction, fumigation action.
The content of the invention
Fluacrypyrim, azacyclotin, Bifenazate, fenbutatin oxide, the long-time service of Fenpropathrin single dose may bring resistance generation, medicine
The problems such as effect declines, composition pesticide proposed by the present invention contain active components A and live with active ingredient B and suitable surface
Property agent and carrier.
A kind of high-efficient pesticide composition, containing active components A and active ingredient B, active components A and active ingredient B weight
Than for 1 ︰, 80~60 ︰ 1, the active components A is selected from fluacrypyrim, active ingredient B be selected from azacyclotin, Bifenazate, fenbutatin oxide,
One of Fenpropathrin kind；Active components A is 1 ︰, 60~40 ︰ 1 with the preferred weight ratios of active ingredient B；More preferably fluacrypyrim
Weight ratio with azacyclotin is 1 ︰, 25~10 ︰ 1；The weight ratio of fluacrypyrim and Bifenazate is 1 ︰, 30~10 ︰ 1；Fluacrypyrim and benzene
The weight ratio of fourth tin is 1 ︰, 30~10 ︰ 1；The weight ratio of fluacrypyrim and Fenpropathrin is 1 ︰, 20~10 ︰ 1.
The composition pesticide can be made into wettable powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, water and milk
Agent, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
The composition pesticide is made for preventing cereal crop, fruit tree, vegetables, fibre crops, ornamental plant, beans
The application of insect pest on object.
The pest include Tetranychus urticae, red spider, Panonychus citri, small heart-eating peach worm, tetranychus viennensis, tetranychid, knurl tick,
Blister mite, leaf miner, bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, section type tetranychid, acaphylla theae, tealeaves mite, tomato goitre mite, dark greyish green
Worm.
The amount of application when content of active ingredient depends on being used alone in the present composition, also depends on a kind of chemical combination
Object and another mixed ratio of compound and synergistic effect degree, at the same it is also related with target pest.In usual composition
The weight percentage of active ingredient is the 2%~90% of total weight, is preferably 5%~80%.According to different preparation classes
Type, active component content scope are different.In general, liquid preparation contains by weight 1%~60% active material, preferably
Ground is 5%~50%；Solid pharmaceutical preparation contains by weight 5%~80% active material, and preferably 10%~80%.
At least containing a kind of surfactant in the Pesticidal combination of the present invention, so that active component is in water during application
It is scattered.Surface-active contents are the 2%~30% of total formulation weight, and surplus is solid or liquid diluent.
Surfactant selected by the Pesticidal combination of the present invention is known in those skilled in the art：It can be selected from
One or more of dispersant, wetting agent, thickener or antifoaming agent.According to different dosage forms, this field can also be contained in preparation
Stabilizer, antifreeze well known to technical staff etc..
The Pesticidal combination of the present invention can be used through dilution or directly before use by user.Its preparation can be by ability
Prepared by the processing method well known to field technique personnel, i.e., after active ingredient is mixed with liquid flux or solid carrier, add
Surfactant such as one or more of dispersant, stabilizer, wetting agent, binding agent, antifoaming agent etc..
Comprising following component and content when wettable powder is made in composition：Active components A 1%~60%, active ingredient
B1%~80%, dispersant 1%~12%, wetting agent 1%~8%, filler surplus.
Composition includes following component and content when water dispersible granules are made：Active components A 1%~60%, active ingredient
B1%~80%, dispersant 1%~12%, wetting agent 1%~8%, disintegrant 1%~10%, binding agent 0~8%, more than filler
Amount.
Composition includes following component and content when suspending agent is made：Active components A 1%~50%, active ingredient B1%
~50%, dispersant 1%~10%, wetting agent 1%~10%, antifoaming agent 0.01%~2%, thickener 0~2%, antifreeze 0
~8%, deionized water adds to 100%.
Composition includes following component and content when suspension emulsion is made：Active components A 1%~50%, active ingredient B1%
~50%, emulsifier 1%~10%, dispersant 1%~10%, solvent 0~20%, antifoaming agent 0.01%~2%, thickener 0
~2%, antifreeze 0~8%, stabilizer 0~3%, deionized water add to 100%.
Composition includes following component and content when microemulsion is made：Active components A 1%~50%, active ingredient B1%
~50%, emulsifier 3%~25%, solvent 1%~10%, antifreeze 0~8%, stabilizer 0~3%, antifoaming agent 0.01%~
2%th, deionized water adds to 100%.
Composition includes following component and content when aqueous emulsion is made：Active components A 1%~50%, active ingredient B1%
~50%, solvent 1%~20%, emulsifier 1%~12%, antifreeze 0~8%, antifoaming agent 0.01%~2%, thickener 0~
2%th, deionized water adds to 100%.
Composition includes following component and content when microcapsule suspending agent is made：Active components A 1%~50%, active ingredient
B1%~50%, macromolecule cyst material 1%~10%, dispersant 2%~10%, solvent 1%~10%, emulsifier 1%~
7%th, pH adjusting agent 0.01%~5%, antifoaming agent 0.01%~2%, deionized water add to 100%.
Composition includes following component and content when microcapsule suspension-suspendinagent agent is made：Active components A 1%~50%, activity
Ingredient B1%~50%, macromolecule cyst material 1%~12%, dispersant 1%-12%, wetting agent 1%-8%, solvent 1%~
15%th, emulsifier 1%~8%, antifoaming agent 0.01%~2%, thickener 0~2%, pH adjusting agent 0.01%~5%, deionization
Water adds to 100%.
The wettable powder the key technical indexes of the present invention：
The water dispersible granules the key technical indexes of the present invention：
The suspending agent the key technical indexes of the present invention：
The suspension emulsion the key technical indexes of the present invention：
The microemulsion the key technical indexes of the present invention：
The aqueous emulsion the key technical indexes of the present invention：
The microcapsule suspending agent the key technical indexes of the present invention：
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention：
The advantage of the invention is that：
(1) present composition has good synergy and lasting effect within the specific limits, and preventive effect is higher than single dose；(2) agriculture
Medicinal dose is reduced, and is reduced residual quantity of the pesticide on crop, is mitigated environmental pollution；(3) insecticidal spectrum is expanded, Cereal is made
Object, fruit tree, vegetables, fibre crops, ornamental plant, the Tetranychus urticae on legume crop, red spider, Panonychus citri, small heart-eating peach worm,
Tetranychus viennensis, tetranychid, knurl tick, blister mite, leaf miner, bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, section type tetranychid, tea goitre
Mite, tealeaves mite, tomato goitre mite, cabbage caterpillar have greater activity；(4) to safety of human and livestock, Environmental compatibility is good；And preparation is adhered
Power enhances, resistance of rainwater washing against.
Specific embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The present invention is not limited thereto.
Application Example one
1~12 wettable powder of example
Fluacrypyrim, active ingredient B, dispersant, wetting agent, filler are mixed, are uniformly mixed in mixed cylinder, through air-flow powder
Broken machine remixes uniformly after crushing, you can wettable powder product of the present invention is made.Specifically it is shown in Table 1.
1 example of table, 1~12 each component and content
13~24 water dispersible granules of example
Fluacrypyrim, active ingredient B, dispersant, wetting agent, binding agent, disintegrant, filler are obtained together through air-flow crushing
The grain size needed obtains granulation materials.Item is quantified and is sent into fluidized bed granulating dryer after granulation and drying, is made
Water dispersible granules product of the present invention.Specifically it is shown in Table 2.
2 example of table, 13~24 each component and content
25~36 suspending agent of example
Dispersant, wetting agent, antifoaming agent, thickener, antifreeze are uniformly mixed by high speed shear, addition fluacrypyrim,
Active ingredient B, surplus are supplied with deionized water, when ball milling 2~3 is small in the ball mill, make diameter of particle all below 5 μm,
Suspending agent product of the present invention is made.Specifically it is shown in Table 3.
3 example of table, 25~36 each component and content
37~48 suspension emulsion of example
By dispersant in above-mentioned formulation material, antifoaming agent, thickener, antifreeze, stabilizer, mix by high speed shear it is equal
It is even, fluacrypyrim is added in, when ball milling 2~3 is small in the ball mill, makes diameter of particle all below 5 μm, fluacrypyrim is made and suspends
Then agent directly emulsifies active ingredient B, solvent, emulsifier and various auxiliary agents in suspending agent with high speed agitator, this is made
The invention suspension emulsion product.Specifically it is shown in Table 4,5.
4 example of table, 37~42 each component and content
5 example of table, 43~48 each component and content
49~53 microemulsion of example
Fluacrypyrim, active ingredient B are dissolved in the homogenizer equipped with solvent, by emulsifier, antifreeze, antifoaming agent, steady
Determine agent to be added in the homogenizer equipped with above-mentioned solution, surplus is mixed and homogenized strongly after being supplied with deionized water, finally
Obtain the transparent microemulsion product of the present invention of clear appearance.Specifically it is shown in Table 6.
6 example of table, 49~53 each component and content
54~65 aqueous emulsion of example
Fluacrypyrim, active ingredient B, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase；By deionized water, resist
Jelly agent, thickener, antifoaming agent mix, into homogeneous water phase.Under high velocity agitation, water is added to oil phase, this hair is made
The bright aqueous emulsion product.Specifically it is shown in Table 7,8.
7 example of table, 54~59 each component and content
8 example of table, 60~65 each component and content
Azacyclotin, Bifenazate, fenbutatin oxide, Fenpropathrin in table 1- tables 8 are exchanged, novel formulation can be made.
66~68 microcapsule suspending agent of example
Fluacrypyrim, active ingredient B, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, in shearing bar
Under part, by oil phase be added to containing emulsifier, pH adjusting agent, dispersant, antifoaming agent aqueous phase solution in, surplus deionized water
It supplies, two kinds of materials react in oil-water interfaces, form high score ascus wall, the well dispersed micro-capsule of the present composition is made
Suspending agent product.Specifically it is shown in Table 9.
9 example of table, 66~68 each component and content
69~71 microcapsule suspension-suspendinagent agent of example
Active ingredient B, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, by oil phase in shearing condition
Under be added to containing emulsifier, pH adjusting agent aqueous phase solution in, well dispersed microcapsule suspending agent is made.By dispersant, wet
Profit agent, antifoaming agent, thickener are uniformly mixed by high speed shear, are added in fluacrypyrim, when ball milling 2~3 is small in the ball mill, are made micro-
Grain grain size all below 5 μm, is made suspending agent, then suspending agent is added in the aqueous phase solution of micro-capsule suspension, is gone
Ionized water supplies surplus, and the well dispersed microcapsule suspension-suspendinagent agent product of the present composition is made.Specifically it is shown in Table 10.
10 example of table, 69~71 each component and content
The embodiment of the present invention is the method being combined using Toxicity Determination and field trial.First pass through indoor virulence survey
It is fixed, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient (CTC), CTC ＜ 80 are antagonism, 80≤CTC≤120
For summation action, CTC ＞ 120 are synergistic effect, on this basis, then carry out field trial.
Test method：The mother liquor of each mixed agent is diluted to five series concentrations respectively during experiment, is respectively placed in beaker
It is spare.Using the first leaching leaf method that is followed by worm, by not in contact with the blade of the same size of any medicament in the liquid configured
It takes out, naturally dry, is put into insect box after immersion 5s, then connect for examination larva, raised under the conditions of 25 DEG C, often handle 3
Secondary repetition, it is 50 often to repeat test worm number used, while sets blank control, checks dead borer population in 72h, calculates the death rate and correction
The death rate acquires virulence regression equation and calculates LC50Value.If compareing the death rate is more than 10%, it is considered as invalid experiment.It calculates public
Formula is as follows：
Pest corrected mortality is converted into probit value (y), concentration for the treatment of (μ g/ml) is converted into numerical value (x), with minimum
Square law draws virulence regression equation, and thus calculates the value of each medicament.Common poison system is calculated according to the abundant equations of Sun Yun
Number CTC.Calculation formula is following (using fluacrypyrim as standard agent, toxicity index 100)：
In formula：M is the mixture of different ratio
PEffective active composition BFor effective active composition B shared ratios in the composition
PFluacrypyrimFor fluacrypyrim shared ratio in the composition
B is selected from one of azacyclotin, Bifenazate, fenbutatin oxide, Fenpropathrin kind.
Application Example two：
For trying pest：Citrus red mite.
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Effective cause of fluacrypyrim and azacyclotin active compound and the two different ratio mixture is determined by pilot study
Dead concentration range.
Toxicity test result
11 fluacrypyrim of table compounds the toxicity test analysis of results table to citrus red mite with azacyclotin
As shown in Table 11, fluacrypyrim compounds the proportioning for preventing citrus red mite in 1 80~60 ︰ 1 of ︰ with azacyclotin, altogether poison
Coefficient is all higher than 120, illustrates that the two mixture in the range of 1 ︰, 80~60 ︰ 1 shows synergistic effect, when fluacrypyrim and azacyclotin
Proportioning in 1 25~10 ︰ 1 of ︰, synergistic effect is more prominent, and co-toxicity coefficient is all higher than 210.Wherein when fluacrypyrim and azacyclotin
Co-toxicity coefficient is maximum when weight ratio is 2 ︰ 5, and synergistic effect is the most apparent.It is tested through applicant and finds matching somebody with somebody for fluacrypyrim and azacyclotin
Than for 10：1、5：1、4：1、3：1、2：1、1：1、1：2、2：5、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：10、1：15、1：
20、1：When 25, fluacrypyrim is compounded with azacyclotin to Tetranychus urticae, red spider, Panonychus citri, small heart-eating peach worm, tetranychus viennensis, leaf
Mite, knurl tick, blister mite, leaf miner, bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, cut type tetranychid, acaphylla theae, tealeaves mite, kind
The prevention of eggplant goitre mite, cabbage caterpillar has apparent synergistic effect, and co-toxicity coefficient is all higher than 120.
Application Example three：
For trying pest：Apple Tetranychus urticae.
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：The effective of fluacrypyrim and Bifenazate active compound and the two different ratio mixture is determined by pilot study
Lethasl concentration scope.
Toxicity test result
12 fluacrypyrim of table compounds the toxicity test analysis of results table to apple Tetranychus urticae with Bifenazate
As shown in Table 12, fluacrypyrim compounds the proportioning for preventing apple Tetranychus urticae in 1 80~60 ︰ 1 of ︰ with Bifenazate,
Co-toxicity coefficient is all higher than 120, illustrates that the two mixture in the range of 1 ︰, 80~60 ︰ 1 shows synergistic effect, when fluacrypyrim and connection
For the proportioning of phenylhydrazine ester in 1 30~10 ︰ 1 of ︰, synergistic effect is more prominent, and co-toxicity coefficient is all higher than 220.Wherein when fluacrypyrim with
Co-toxicity coefficient is maximum when Bifenazate weight ratio is 1 ︰ 3, and synergistic effect is the most apparent.It is tested through applicant and finds fluacrypyrim and connection
The proportioning of phenylhydrazine ester is 10：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：10、
1：15、1：20、1：25、1：When 30, fluacrypyrim is compounded with Bifenazate to Tetranychus urticae, red spider, Panonychus citri, the small food heart of peach
Worm, tetranychus viennensis, tetranychid, knurl tick, blister mite, leaf miner, bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, section type tetranychid, tea
The prevention of goitre mite, tealeaves mite, tomato goitre mite, cabbage caterpillar has apparent synergistic effect, and co-toxicity coefficient is all higher than 120.
Application Example four：
For trying pest：Citrus blister mite.
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Effective cause of fluacrypyrim and fenbutatin oxide active compound and the two different ratio mixture is determined by pilot study
Dead concentration range.
Toxicity test result
13 fluacrypyrim of table compounds the toxicity test analysis of results table to citrus blister mite with fenbutatin oxide
As shown in Table 13, fluacrypyrim compounds the proportioning for preventing citrus blister mite in 1 80~60 ︰ 1 of ︰ with fenbutatin oxide, altogether poison
Coefficient is all higher than 120, illustrates that the two mixture in the range of 1 ︰, 80~60 ︰ 1 shows synergistic effect, when fluacrypyrim and fenbutatin oxide
Proportioning in 1 30~10 ︰ 1 of ︰, synergistic effect is more prominent, and co-toxicity coefficient is all higher than 220.Wherein when fluacrypyrim and fenbutatin oxide
Co-toxicity coefficient is maximum when weight ratio is 1 ︰ 3, and synergistic effect is the most apparent.It is tested through applicant and finds matching somebody with somebody for fluacrypyrim and fenbutatin oxide
Than for 10：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：10、1：15、1：20、
1：25、1：When 30, fluacrypyrim is compounded with fenbutatin oxide to Tetranychus urticae, red spider, Panonychus citri, small heart-eating peach worm, tetranychus viennensis, leaf
Mite, knurl tick, blister mite, leaf miner, bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, cut type tetranychid, acaphylla theae, tealeaves mite, kind
The prevention of eggplant goitre mite, cabbage caterpillar has apparent synergistic effect, and co-toxicity coefficient is all higher than 120.
Application Example five：
For trying pest：Cotton boll worm.
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：The effective of fluacrypyrim and Fenpropathrin active compound and the two different ratio mixture is determined by pilot study
Lethasl concentration scope.
Toxicity test result
14 fluacrypyrim of table compounds the toxicity test analysis of results table to cotton boll worm with Fenpropathrin
As shown in Table 14, fluacrypyrim compounds the proportioning for preventing cotton boll worm in 1 80~60 ︰ 1 of ︰ with Fenpropathrin, altogether
Malicious coefficient is all higher than 120, illustrates that the two mixture in the range of 1 ︰, 80~60 ︰ 1 shows synergistic effect, when fluacrypyrim and first cyanogen
For the proportioning of chrysanthemum ester in 1 20~10 ︰ 1 of ︰, synergistic effect is more prominent, and co-toxicity coefficient is all higher than 210.Wherein when fluacrypyrim and first
Co-toxicity coefficient is maximum when Cyano chrysanthemate weight ratio is 1 ︰ 2, and synergistic effect is the most apparent.It is tested through applicant and finds fluacrypyrim and first cyanogen
The proportioning of chrysanthemum ester is 10：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：10、1：
15、1：When 20, fluacrypyrim is compounded with Fenpropathrin to Tetranychus urticae, red spider, Panonychus citri, small heart-eating peach worm, tetranychus viennensis, leaf
Mite, knurl tick, blister mite, leaf miner, bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, cut type tetranychid, acaphylla theae, tealeaves mite, kind
The prevention of eggplant goitre mite, cabbage caterpillar has apparent synergistic effect, and co-toxicity coefficient is all higher than 120.
Six fluacrypyrim of Application Example and active ingredient B and its compounding prevention tomato goitre mite test of pesticide effectiveness
This experiment is arranged in Xian District, Shanxi Province suburban area, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided,
30% fluacrypyrim suspending agent (autogamy) of comparison medicament, 25% azacyclotin wettable powder (purchased in market), 43% Bifenazate suspending agent
(purchased in market), 50% fenbutatin oxide suspending agent (purchased in market), 20% Fenpropathrin wettable powder (purchased in market).
Tomato goitre acarid evil index is investigated before medicine, in insect pest early period of origination dispenser, 1 day after dispenser, investigates insect pest within 3 days, 7 days
Index simultaneously calculates preventive effect.Result of the test is as follows：
15 fluacrypyrim of table and active ingredient B and its compounding prevention tomato goitre mite test of pesticide effectiveness
As can be seen from Table 15, for fluacrypyrim with can effectively prevent tomato goitre mite after active ingredient B compoundings, control effect is excellent
In the preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in experiment scope of medication to target crop.
Seven fluacrypyrim of Application Example and active ingredient B and its compounding prevention cotton boll worm test of pesticide effectiveness
This experiment is arranged in Shaanxi Province Weinan City Dali County, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., carried
For 30% fluacrypyrim suspending agent (autogamy) of comparison medicament, 25% azacyclotin wettable powder (purchased in market), 43% Bifenazate suspend
Agent (purchased in market), 50% fenbutatin oxide suspending agent (purchased in market), 20% Fenpropathrin wettable powder (purchased in market).
Cotton boll pests index is investigated before medicine, in insect pest early period of origination dispenser, 1 day after dispenser, investigates worm within 3 days, 7 days
Evil index simultaneously calculates preventive effect.Result of the test is as follows：
16 fluacrypyrim of table and active ingredient B and its compounding prevention cotton boll worm test of pesticide effectiveness
As can be seen from Table 16, for fluacrypyrim with can effectively prevent cotton boll worm after active ingredient B compoundings, control effect is equal
Better than the preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in experiment scope of medication to target crop.
Eight fluacrypyrim of Application Example and active ingredient B and its compounding prevention apple Tetranychus urticae test of pesticide effectiveness
This experiment is arranged in Xianyang, Shanxi province city, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, control
30% fluacrypyrim suspending agent (autogamy) of medicament, 25% azacyclotin wettable powder (purchased in market), 43% Bifenazate suspending agent (city
Purchase), 50% fenbutatin oxide suspending agent (purchased in market), 20% Fenpropathrin wettable powder (purchased in market).
Apple Tetranychus urticae insect pest index is investigated before medicine, in insect pest early period of origination dispenser, 1 day after dispenser, is investigated within 3 days, 7 days
Insect pest index simultaneously calculates preventive effect.Result of the test is as follows：
17 fluacrypyrim of table and active ingredient B and its compounding prevention apple Tetranychus urticae test of pesticide effectiveness
As can be seen from Table 17, fluacrypyrim after active ingredient B compoundings with can effectively prevent apple Tetranychus urticae, control effect
The preventive effect of single dose is superior to, and preventive effect phase is long.It has no adverse effects in experiment scope of medication to target crop.
Nine fluacrypyrim of Application Example and active ingredient B and its compounding prevention citrus red mite test of pesticide effectiveness
This experiment is arranged in Hanzhong city, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, comparison medicine
30% fluacrypyrim suspending agent (autogamy) of agent, 25% azacyclotin wettable powder (purchased in market), 43% Bifenazate suspending agent (purchased in market),
50% fenbutatin oxide suspending agent (purchased in market), 20% Fenpropathrin wettable powder (purchased in market).
Citrus red mite insect pest index is investigated before medicine, in insect pest early period of origination dispenser, 1 day after dispenser, investigates worm within 3 days, 7 days
Evil index simultaneously calculates preventive effect.Result of the test is as follows：
18 fluacrypyrim of table and active ingredient B and its compounding prevention citrus red mite test of pesticide effectiveness
As can be seen from Table 18, for fluacrypyrim with can effectively prevent citrus red mite after active ingredient B compoundings, control effect is equal
Better than the preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in experiment scope of medication to target crop.
Ten fluacrypyrim of Application Example and active ingredient B and its compounding prevention apple small heart-eating peach worm test of pesticide effectiveness
This experiment is arranged in Xianyang, Shanxi province city, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, control
30% fluacrypyrim suspending agent (autogamy) of medicament, 25% azacyclotin wettable powder (purchased in market), 43% Bifenazate suspending agent (city
Purchase), 50% fenbutatin oxide suspending agent (purchased in market), 20% Fenpropathrin wettable powder (purchased in market).
Apple small heart-eating peach worm insect pest index is investigated before medicine, in insect pest early period of origination dispenser, 1 day after dispenser, is adjusted within 3 days, 7 days
It looks into insect pest index and calculates preventive effect.Result of the test is as follows：
19 fluacrypyrim of table and active ingredient B and its compounding prevention apple small heart-eating peach worm test of pesticide effectiveness
As can be seen from Table 19, fluacrypyrim is with can effectively prevent apple small heart-eating peach worm, prevention effect after active ingredient B compoundings
Fruit is superior to the preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in experiment scope of medication to target crop.
11 fluacrypyrim of Application Example and active ingredient B and its compounding prevention citrus blister mite test of pesticide effectiveness
This experiment is arranged in Shaanxi Province's Hanzhong City, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, control
30% fluacrypyrim suspending agent (autogamy) of medicament, 25% azacyclotin wettable powder (purchased in market), 43% Bifenazate suspending agent (city
Purchase), 50% fenbutatin oxide suspending agent (purchased in market), 20% Fenpropathrin wettable powder (purchased in market).
Citrus blister mite insect pest index is investigated before medicine, in insect pest early period of origination dispenser, 3 days after dispenser, is investigated within 7 days, 15 days
Insect pest index simultaneously calculates preventive effect.Result of the test is as follows：
20 fluacrypyrim of table and active ingredient B and its compounding prevention citrus blister mite test of pesticide effectiveness
As can be seen from Table 20, for fluacrypyrim with can effectively prevent citrus blister mite after active ingredient B compoundings, control effect is equal
Better than the preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in experiment scope of medication to target crop.
12 fluacrypyrim of Application Example and active ingredient B and its compounding prevention tealeaves mite test of pesticide effectiveness
This experiment is arranged in Sichuan Province Ya'an, and test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, control
30% fluacrypyrim suspending agent (autogamy) of medicament, 25% azacyclotin wettable powder (purchased in market), 43% Bifenazate suspending agent (city
Purchase), 50% fenbutatin oxide suspending agent (purchased in market), 20% Fenpropathrin wettable powder (purchased in market).
Tealeaves acarid evil index is investigated before medicine, in insect pest early period of origination dispenser, 1 day after dispenser, insect pest is investigated and refers within 3 days, 7 days
It counts and calculates preventive effect.Result of the test is as follows：
21 fluacrypyrim of table and active ingredient B and its compounding prevention tealeaves mite test of pesticide effectiveness
As can be seen from Table 21, with can effectively prevent tealeaves mite after active ingredient B compoundings, control effect is superior to fluacrypyrim
The preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in experiment scope of medication to target crop.
The experiment by different places throughout the country is drawn afterwards, fluacrypyrim and azacyclotin, Bifenazate, fenbutatin oxide, first
To the Tetranychus urticae, red spider, complete on cereal crops, fruit tree, vegetables, flowers, fibre crops, legume crop after Cyano chrysanthemate compounding
Pawl mite, small heart-eating peach worm, tetranychus viennensis, tetranychid, knurl tick, blister mite, leaf miner, bollworm, Shenmu-Yanan railway, cinnabar leaf
The preventive effect of the common pests such as mite, section type tetranychid, acaphylla theae, tealeaves mite, tomato goitre mite, cabbage caterpillar is more than 95%, better than list
Agent preventive effect, synergistic effect are apparent.
Claims (10)
1. a kind of high-efficient pesticide composition, it is characterised in that：Effective active composition is active components A and active ingredient B, activity into
Point A and active ingredient B weight ratios are 1 ︰, 80~60 ︰ 1, and the active components A is fluacrypyrim, active ingredient B be selected from azacyclotin,
One of fenbutatin oxide, Fenpropathrin kind.
2. high-efficient pesticide composition according to claim 1, it is characterised in that：Active components A and the weight of active ingredient B
Than for 1 ︰, 60~40 ︰ 1.
3. high-efficient pesticide composition according to claim 2, it is characterised in that：The weight ratio of fluacrypyrim and azacyclotin is 1 ︰
25~10 ︰ 1.
4. high-efficient pesticide composition according to claim 2, it is characterised in that：The weight ratio of fluacrypyrim and fenbutatin oxide is 1 ︰
30~10 ︰ 1.
5. high-efficient pesticide composition according to claim 2, it is characterised in that：The weight ratio of fluacrypyrim and Fenpropathrin is
1 ︰, 20~10 ︰ 1.
6. the high-efficient pesticide composition according to any one in claim 3 to 5, it is characterised in that：Composition is made can
Wet powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
7. high-efficient pesticide composition according to claim 6 is used to prevent the application of crop pests.
8. application according to claim 7, it is characterised in that：The pest includes red spider, Panonychus citri, the small food heart of peach
Worm, knurl tick, blister mite, leaf miner, bollworm, acaphylla theae, tomato goitre mite, cabbage caterpillar.
9. application according to claim 7, it is characterised in that：The pest includes tetranychid.
10. application according to claim 7, it is characterised in that：The pest includes Tetranychus urticae, tetranychus viennensis, god
Ze Shi tetranychids, Tetranychus cinnabarinus cut type tetranychid, tealeaves mite.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5367093A (en) * | 1991-11-22 | 1994-11-22 | Uniroyal Chemical Company, Inc. | Insecticidal phenylhydrazine derivatives |
| CN1911033A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. high efficiency cypermethrin and pyrimidifen and its application |
| CN1911018A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. fluacrypyrim and vermectins or methyl amino Avermectins benzoate, and its application Avermectins |
| CN101228876A (en) * | 2007-12-27 | 2008-07-30 | 华南农业大学 | Nicouline and fluacrypyrim blending agrochemical |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004196718A (en) * | 2002-12-19 | 2004-07-15 | Shiro Seiyama | Microencapsulated agrochemical preparation and method for producing the same |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5367093A (en) * | 1991-11-22 | 1994-11-22 | Uniroyal Chemical Company, Inc. | Insecticidal phenylhydrazine derivatives |
| CN1911033A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. high efficiency cypermethrin and pyrimidifen and its application |
| CN1911018A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. fluacrypyrim and vermectins or methyl amino Avermectins benzoate, and its application Avermectins |
| CN101228876A (en) * | 2007-12-27 | 2008-07-30 | 华南农业大学 | Nicouline and fluacrypyrim blending agrochemical |
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Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Patentee after: SHAANXI MEIBANG PHARMACEUTICAL GROUP Co.,Ltd. Address before: 715500 Shaanxi Pucheng Weinan County agricultural base industrial park Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
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