CN105625047A - 一种多色有机硅合成革及制造工艺 - Google Patents

一种多色有机硅合成革及制造工艺 Download PDF

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CN105625047A
CN105625047A CN201610146816.4A CN201610146816A CN105625047A CN 105625047 A CN105625047 A CN 105625047A CN 201610146816 A CN201610146816 A CN 201610146816A CN 105625047 A CN105625047 A CN 105625047A
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silica gel
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polychrome
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黄胜
谢朝辉
杨家昌
吴长林
焦冬生
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Huizhou Sailirone New Material Co Ltd
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Priority to PCT/CN2016/105895 priority patent/WO2017157036A1/zh
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Abstract

本发明公开了一种多色有机硅合成革及制造工艺，包括由上到下依次设置的A颜色硅胶层、B颜色硅胶层以及基材，所述A颜色硅胶层与B颜色硅胶层的颜色不一样，使用两种颜色的有机硅浆料，分别为浆料A和浆料B；浆料A涂布于离型纸上后硫化，涂层厚度为0.01-0.1mm；浆料B则涂布在已经硫化的浆料A上，其涂布次数在一次以上，且除最后一次涂布，前面的涂布的浆料均需硫化后再进行下一次涂布；再进行最后一次涂布后，贴合基材后硫化；剥离离型纸得到多色有机硅合成革。本发明制得的合成革对环境友好，对人体无害，使用性能好。

Description

一种多色有机硅合成革及制造工艺
技术领域
本发明涉及一种有机硅合成革双色制造工艺，属于合成革技术领域。
背景技术
目前，国内外合成革产业主要以聚氨酯(PU),聚氯乙烯(PVC)为主，其在制造及使用过程中都会含有大量的二甲基甲酰胺，丁酮，甲苯等有害物质，且其废弃物回收处理时又会产生氯化氢，二噁英，氰化氢等对环境和生物有害的分解产物。
PU和PVC合成革在日常使用时还有不耐老化，不耐温，易水解，易沾污，透气性差等缺点。
有机硅合成革可克服上述缺点，但由于有机硅橡胶的特殊性，目前市面的有机硅合成革均为单色系列，花色较为单一。
发明内容
本发明针对上述问题的不足，提出一种多色有机硅合成革及制造工艺，本发明对环境友好，对人体无害，使用性能好。
本发明为解决上述技术问题提出的技术方案是：
一种多色有机硅合成革，包括由上到下依次设置的A颜色硅胶层、B颜色硅胶层以及基材，所述A颜色硅胶层与B颜色硅胶层的颜色不一样。
优选的：所述A颜色硅胶层、B颜色硅胶层以及基材依次复合连接在一起。
优选的：所述A颜色硅胶层厚度为0.01-0.1mm，所述B颜色硅胶层的厚度为0.1-0.3mm。
优选的：所述B颜色硅胶层包括一种以上的颜色的硅胶层复合而成。
优选的：所述A颜色硅胶层包括一种以上的颜色的硅胶层复合而成。
优选的：所述基材为超细纤维，无纺布，机织布，玻璃纤维，碳纤维或塑料模。
一种多色有机硅合成革的制造工艺，使用两种颜色的有机硅浆料，分别为浆料A和浆料B；浆料A涂布于离型纸上后硫化，涂层厚度为0.01-0.1mm；浆料B则涂布在已经硫化的浆料A上，其涂布次数在一次以上，且除最后一次涂布，前面的涂布的浆料均需硫化后再进行下一次涂布；再进行最后一次涂布后，贴合基材后硫化；剥离离型纸得到多色有机硅合成革。
优选的：所述浆料A与浆料B的色浆添加比例如下：
浆料A0.1-1％
浆料B5-15％。
优选的：所述浆料A固含量为10-70％，浆料B固含量为100％。
优选的：所述浆料A所用稀释剂为沸点60-150℃可挥发无毒无污染溶剂。
优选的：所述硫化温度为80-150℃，硫化时间为1-20分钟。
具体的，包括以下步骤：
步骤1，配制不同颜色不同固含量的有机硅浆料A和浆料B；
步骤2，将浆料A涂布于离型纸上，涂层厚度为0.01-0.1mm，并送入80-150℃烘道烘烤1-10分钟固化；
步骤3，将浆料B涂布于已固化的浆料A涂层上，浆料B涂布次数可为一次以上，浆料B的总涂布厚度为0.1-0.3mm；除最后一次涂布，前面的涂布的浆料均需硫化后再进行下一次涂布；硫化温度80-150℃，单次硫化时间1-10分钟；
步骤4，将基材与最后一次涂布的浆料B贴合，并送入80-150℃烘道烘烤1-20分钟固化；
步骤5，将合成革与离型纸剥离。
本发明的一种多色有机硅合成革及制造工艺，相比现有技术，具有以下有益效果：
工艺简单且可连续生产，效率高，整个过程无有害物质无污染物，制备的有机硅皮革环保无毒，双色层次感鲜明。
附图说明
图1是有机硅合成革双色制造工艺图，
图2是本发明的结构示意图。
其中，1为涂布台一，2为涂布台二，3为涂布台三，4为离型纸，5为涂头一，6为涂头二，7为涂头三，8为贴合辊，9为基材，10为烘道一，11为烘道二，12为烘道三，21为A颜色硅胶层，22为B颜色硅胶层。
具体实施方式
附图非限制性地公开了本发明一个优选实施例的结构示意图，以下将结合附图详细地说明本发明的技术方案。
实施例1
本实施例的一种多色有机硅合成革，包括由上到下依次复合连接在一起的A颜色硅胶层、B颜色硅胶层以及基材，所述A颜色硅胶层与B颜色硅胶层的颜色不一样。
所述A颜色硅胶层厚度为0.01-0.2mm，所述B颜色硅胶层的厚度为0.1-0.3mm。
所述基材为超细纤维，无纺布，机织布，玻璃纤维，碳纤维或塑料模。
一种多色有机硅合成革的制造工艺，使用两种颜色的有机硅浆料，分别为浆料A和浆料B；浆料A涂布于离型纸上后硫化，涂层厚度为0.01-0.2mm；浆料B则涂布在已经硫化的浆料A上，其涂布次数在一次以上，且除最后一次涂布，前面的涂布的浆料均需硫化后再进行下一次涂布；进行最后一次涂布后，贴合基材后硫化；剥离离型纸得到多色有机硅合成革。
所述浆料A与浆料B的色浆添加比例如下：
浆料A0.1-1％
浆料B5-15％。
所述浆料A固含量为10-70％，浆料B固含量为100％。
所述浆料A所用稀释剂为沸点60-150℃可挥发无毒无污染溶剂。
所述硫化温度为80-150℃，硫化时间为1-20分钟。
有机硅液体加成型硅橡胶配制：将1000克端乙烯基硅油(黏度10000厘斯)，300克疏水性气相白炭黑(比表面积200)，充分混匀，再加入20克含氢硅油(含氢量0.75；黏度100厘斯)，0.4克甲基丁炔醇，4克铂催化剂(Pt浓度3000ppm),混匀即得
a，将30克有机硅液体加成型硅橡胶中加入70克六甲基二硅氧烷，0.5克黑色色浆，充分混匀作为浆料A。90克有机硅液体加成型硅橡胶中加入10克咖啡色色浆，充分混匀作为浆料B。
b，将浆料A涂布于皮革纹路AR-133离型纸上，涂布厚度0.05mm,送入120℃烘道硫化5分钟后继续涂布浆料B，涂布厚度0.15mm，送入120℃烘道硫化5分钟。继续进行浆料B第二次涂布，涂布厚度0.1mm，并贴合厚度0.6mm超细纤维基材，送入120℃烘道硫化10分钟，将硫化完的合成革与离型纸分离，得到黑色/咖啡多色有机硅合成革。
实施例2
本实施例与实施例1的区别之处在于：将浆料A涂布于皮革纹路AR-133离型纸上的涂布厚度0.01mm；送入120℃烘道硫化5分钟后继续涂布浆料B，涂布厚度0.1mm，并贴合厚度0.6mm超细纤维基材，送入120℃烘道硫化10分钟。
实施例3
本实施例与实施例1的区别之处在于：将浆料A涂布于皮革纹路AR-133离型纸上的涂布厚度0.1mm,送入120℃烘道硫化5分钟后继续涂布浆料B，涂布厚度0.05mm，送入120℃烘道硫化5分钟。继续进行浆料B第二次涂布，涂布厚度0.3mm，送入120℃烘道硫化5分钟，继续进行浆料B第二次涂布，涂布厚度0.1mm，并贴合厚度0.6mm超细纤维基材，送入120℃烘道硫化10分钟。
实施例4
本实施例与实施例1的区别在于:A浆料的色浆添加量改为0.1克，B浆料的色浆添加量改为5克。
实施例5
本实施例与实施例2的区别在于：A浆料的色浆添加量改为1克，B浆料的色浆添加量改为15克。
实施例6
本实施例与实施例1的区别在于：所述B颜色硅胶层两种颜色的硅胶层复合而成，这两种颜色的硅胶层分别为B1颜色硅胶层和B2颜色硅胶层，其制作方法与实施例1类似，在此不必赘述。这样得到的B颜色硅胶层与A颜色硅胶层在进行复合，其得到的三色革层次感鲜明，颜色富有变化。同理，B颜色硅胶层可由更多种颜色的硅胶层复合而成，其得到的色彩层次更强烈，颜色更富有变化。同理可值得同样的A颜色硅胶层。
比较例1
本比较例与实施例1的区别之处在于：不涂布浆料A，得到咖啡单色合成革。
比较例2
本实施例与实施例1的区别在于:A浆料的色浆添加量改为2克，涂层厚度0.2mm,B浆料的色浆添加量改为3克,涂层厚度0.05mm。
实施例1-6均可得到层次感不一的双色合成革,而比较例1-2只能得到单色合成革，其色彩单一，僵硬。
上面结合附图所描述的本发明优选具体实施例仅用于说明本发明的实施方式，而不是作为对前述发明目的和所附权利要求内容和范围的限制，凡是依据本发明的技术实质对以上实施例所做的任何简单修改、等同变化与修饰，均仍属本发明技术和权利保护范畴。

Claims (10)

1.一种多色有机硅合成革，其特征在于：包括由上到下依次设置的A颜色硅胶层、B颜色硅胶层以及基材，所述A颜色硅胶层与B颜色硅胶层的颜色不一样。
2.根据权利要求1所述的多色有机硅合成革，其特征在于：所述A颜色硅胶层、B颜色硅胶层以及基材依次复合连接在一起。
3.根据权利要求1所述的多色有机硅合成革，其特征在于：所述A颜色硅胶层厚度为0.01-0.1mm，所述B颜色硅胶层的厚度为0.1-0.3mm。
4.根据权利要求1所述的多色有机硅合成革，其特征在于：所述B颜色硅胶层包括一种以上的颜色的硅胶层复合而成。
5.根据权利要求1所述的多色有机硅合成革，其特征在于：所述A颜色硅胶层包括一种以上的颜色的硅胶层复合而成。
6.一种基于权利要求1所述的多色有机硅合成革的制造工艺，其特征在于：使用两种颜色的有机硅浆料，分别为浆料A和浆料B；浆料A涂布于离型纸上后硫化，涂层厚度为0.01-0.1mm；浆料B则涂布在已经硫化的浆料A上，其涂布次数在一次以上，且除最后一次涂布，前面的涂布的浆料均需硫化后再进行下一次涂布；再进行最后一次涂布后，贴合基材后硫化；剥离离型纸得到多色有机硅合成革。
7.根据权利要求5所述的多色有机硅合成革的制造工艺，其特征在于：所述浆料A与浆料B的色浆添加比例如下：
浆料A0.1-1％
浆料B5-15％。
8.根据权利要求5所述的多色有机硅合成革的制造工艺，其特征在于：所述浆料A固含量为10-70％，浆料B固含量为100％。
9.根据权利要求5所述的多色有机硅合成革的制造工艺，其特征在于：所述浆料A所用稀释剂为沸点60-150℃可挥发无毒无污染溶剂。
10.根据权利要求5所述的多色有机硅合成革的制造工艺，其特征在于，包括以下步骤：
步骤1，配制不同颜色不同固含量的有机硅浆料A和浆料B；
步骤2，将浆料A涂布于离型纸上，涂层厚度为0.01-0.1mm，并送入80-150℃烘道烘烤1-10分钟固化；
步骤3，将浆料B涂布于已固化的浆料A涂层上，浆料B涂布次数可为一次以上，浆料B的总涂布厚度为0.1-0.3mm；除最后一次涂布，前面的涂布的浆料均需硫化后再进行下一次涂布；硫化温度80-150℃，单次硫化时间1-10分钟；
步骤4，将基材与最后一次涂布的浆料B贴合，并送入80-150℃烘道烘烤1-20分钟固化；
步骤5，将合成革与离型纸剥离。
CN201610146816.4A 2016-03-15 2016-03-15 一种多色有机硅合成革及制造工艺 Pending CN105625047A (zh)

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