CN105609155B - A kind of high-conductivity hard aluminum wire monofilament and preparation method thereof - Google Patents
A kind of high-conductivity hard aluminum wire monofilament and preparation method thereof Download PDFInfo
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- CN105609155B CN105609155B CN201410669016.1A CN201410669016A CN105609155B CN 105609155 B CN105609155 B CN 105609155B CN 201410669016 A CN201410669016 A CN 201410669016A CN 105609155 B CN105609155 B CN 105609155B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 229910052782 aluminium Inorganic materials 0.000 title claims description 78
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 77
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 55
- 229910000737 Duralumin Inorganic materials 0.000 claims abstract description 37
- 238000007670 refining Methods 0.000 claims abstract description 15
- 229910052706 scandium Inorganic materials 0.000 claims abstract description 13
- 239000012535 impurity Substances 0.000 claims abstract description 11
- 229910052742 iron Inorganic materials 0.000 claims abstract description 11
- 238000007872 degassing Methods 0.000 claims abstract description 8
- 229910052796 boron Inorganic materials 0.000 claims abstract description 7
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 41
- 239000000956 alloy Substances 0.000 claims description 41
- 239000004411 aluminium Substances 0.000 claims description 41
- 239000007788 liquid Substances 0.000 claims description 21
- 238000005491 wire drawing Methods 0.000 claims description 11
- 229910052726 zirconium Inorganic materials 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000004080 punching Methods 0.000 claims description 9
- 238000010622 cold drawing Methods 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- 241001062472 Stokellia anisodon Species 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 229910018580 Al—Zr Inorganic materials 0.000 claims description 2
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims 1
- 239000004020 conductor Substances 0.000 abstract description 9
- 239000003795 chemical substances by application Substances 0.000 abstract description 7
- 238000005516 engineering process Methods 0.000 abstract description 5
- 235000010210 aluminium Nutrition 0.000 description 66
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 19
- 238000005275 alloying Methods 0.000 description 14
- 230000005540 biological transmission Effects 0.000 description 10
- 238000005266 casting Methods 0.000 description 9
- 230000005611 electricity Effects 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000000137 annealing Methods 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 5
- FGUJWQZQKHUJMW-UHFFFAOYSA-N [AlH3].[B] Chemical compound [AlH3].[B] FGUJWQZQKHUJMW-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 238000003723 Smelting Methods 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000006698 induction Effects 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001192 hot extrusion Methods 0.000 description 2
- 230000033001 locomotion Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
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- 238000012545 processing Methods 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 229910018191 Al—Fe—Si Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
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- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229910001610 cryolite Inorganic materials 0.000 description 1
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- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
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- 230000005496 eutectics Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- XWHPIFXRKKHEKR-UHFFFAOYSA-N iron silicon Chemical compound [Si].[Fe] XWHPIFXRKKHEKR-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
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Abstract
The invention discloses a kind of conductance >=63%IACS, tensile strength >=163MPa aerial condutor duralumin, hard alumin ium alloy wire monofilament and preparation method thereof, aluminium alloy monofilament, which forms, by mass percentage is：Zr：0.01~0.05%, B：0.01~0.05%, Sc：0.05~0.2%, Fe：0~0.14%, Si：0~0.07%, (V+Ti+Cr+Mn)：0~0.012%, remaining is Al and inevitable trace impurity.The invention also discloses the preparation method of the wire monofilament, employ and be blown into N2Degasification removes the gred, and without adding refining agent, so as to simplify the preparation technology of duralumin, hard alumin ium alloy, the electric wire and cable conductor thus prepared can improve conductance (63%IACS, 20 DEG C) and increase working strength (tensile strength >=163MPa).
Description
【Technical field】
The present invention relates to a kind of transmission line of electricity aerial condutor manufacture method of power industry, a kind of in particular to make somebody a mere figurehead is led
Line duralumin, hard alumin ium alloy monofilament and preparation method thereof.
【Background technology】
Overhead transmission line is typically generally using steel-cored aluminium strand as power transmission and distribution wire, in order to solve transmission line of electricity
Reducing energy consumption, transmission of electricity line loss is reduced, is improved the circuit life-span, the general steel-cored aluminium strand prepared using high-conductivity hard aluminum alloy is real
Now transmission line of electricity is energy-saving.There is advantages below using high-conductivity hard aluminum wire on transmission line of electricity：First, energy-conservation：Phase
For conventional wires conductance, the conductance of high-conductivity hard aluminum wire improves about 3%, reduces resistance loss；Second, reduce
Shaft tower is invested：Because wire wind load reduces about 10%, tower weight can reduce about 0.5%；Third, compression width of corridor：500 kilovolts
When common-tower double-return road uses uiform section molded line, width of corridor can reduce 0.5 meter；Fourth, operational reliability is strong：Can relative reduction electricity
Noise caused by corona and line loss.Counted according to the parties concerned, 2010, some local power transmission line path loss electricity are
171000000000 kilowatt hours；By 2015, if 20% transmission line of electricity uses high-conductivity hard aluminum wire, total losses can reduce 10.26 hundred million
Kilowatt hour.Therefore, high-conductivity hard aluminum wire improves transfer efficiency, reduces line loss and fortune to some power network upgradings
Row cost, there is vital effect.High-conductivity hard aluminum wire preparation technology is more complicated in the prior art, and properties of product are not
Stable, product conductance is low, and is both needed in refining process to add refining agent, and one of existing refining agent what is common is that should
It is single with narrow range, function, it can be only achieved different purposes after several different refining agents need to be put into respectively.And often effect is not
It is significant, or Melt parity or environment are harmful to, and varying degree there are problems that it is various.
Chinese patent CN103093855A discloses a kind of high conductivity rare earth hard aluminum conductor, by weight percentage its component
For：Iron 0.0875%~0.145%, the control of iron silicon ratio example is 1.7~2.5, boron 0.01~0.12%, gadolinium 0.01~0.15%,
Remaining is aluminium.The invention also discloses the preparation method of the high conductivity rare earth hard aluminum conductor, aluminium ingot is mainly matched, melting,
The processing such as boronation, refining is carried out again, and conductance 63%IACS, tensile strength 160MPa hard aluminum wire is made.But the system
Preparation Method adds the refining agents such as potassium fluoborate, cryolite, and environmental pollution is larger.
【The content of the invention】
To solve above-mentioned deficiency, in technical scheme provided by the invention, add in micro-alloying elements control alloy
Impurity content, and adjust with Technology for Heating Processing the microstructure of alloy, obtain it is a kind of 20 DEG C at conductance >=63%IACS, anti-
Tensile strength >=163MPa hard aluminum wire monofilament.
The purpose of foregoing invention, is realized with following technical scheme：
A kind of high-conductivity hard aluminum wire monofilament, the hard aluminum wire monofilament is containing following compositions by mass percentage：Zr：
0.01~0.05%, B：0.01~0.05%, Sc：0.05~0.2%, Fe：0~0.14%, Si：0~0.07%, V, Ti, Cr
It is 0~0.012% with tetra- kinds of element mass percent sums of Mn, remaining is Al and inevitable trace impurity.
Preferably, the mass percent of the B is 0.03~0.05%.
A kind of preparation method of high-conductivity hard aluminum wire monofilament as described above, comprises the steps：
(1) smelt：By the aluminium ingot of purity >=99.7% 720~750 DEG C fusing after, at 730~750 DEG C add B,
Zr, Sc, Fe, Si, V, Ti, Cr and Mn intermediate alloy, aluminum alloy melt is stirred after intermediate alloy is completely melt；
(2) refine：It is passed through N2Degasification, after removing the gred 10~20 minutes, the refining aluminium alloy liquid at 730~750 DEG C, stand 30
~60 minutes；
(3) cast：Aluminum alloy melt obtained by step (2) is cast at 700~720 DEG C and is preheated to 200~250 DEG C of insulations
In cylindrical type mould, duralumin pole is obtained；
(4) bar processed：Duralumin pole is squeezed into aluminium alloy rod after 400~500 DEG C are incubated 0.5~2h, while to squeezing out
Aluminium alloy rod spraying cold water；
(5) wire drawing：Aluminium alloy rod is drawn with punching block through 10~20 passages with 15m/s speed cold drawing with wire drawing machine,
The preferable number that draws is 15 times, obtains duralumin monofilament；
(6) anneal：Duralumin monofilament is annealed, room temperature is air-cooled to after taking-up.
Preferably, the order that intermediate alloy is added in step (1) is that Al-B intermediate alloy boron is added at 730~750 DEG C
Change, after standing 30min, then at 750 DEG C of addition Al-Zr, Al-Sc intermediate alloys.
It is furthermore preferred that in step (4) sprinkling room temperature water 1~3 minute.
Another preferable, duralumin monofilament is annealed 3~6h at 140~180 DEG C in step (6).
Each alloys producing and mechanism in technical scheme is as follows：
Zr：Zirconium atom radius ratio aluminium atom radius is bigger, and zirconium is spread in aluminium with substitute mode, and its diffusion activation energy is high,
Trickle Al is separated out to sub- crystal grain border3Zr phases are not easy agglomeration, higher stability, can prevent the production of recrystallization
It is raw, so as to effectively pin dislocation and crystal boundary, deformation and transgranular and crystal boundary sliding are hindered, is improved intensity.Meanwhile zirconium
The creep-resistant property of aluminium alloy can be improved by adding, and enable aluminum alloy to the creep elongation for also there was only very little at high temperature, therefore, it is possible to
Make spacing increase of the overhead transmission line between tower bar of transmitting electricity, and keep the less pendency degree of aluminium alloy conductor；
B：If impurity element exists with solid solution condition, the influence to electric conductivity is very big, and borax treatment can effectively drop
Low magazine content, i.e., after a certain amount of B element is added in aluminium alloy, it can be sent out with Transition Group Impurities element Cr, Mn, V, Ti etc.
Raw reaction, is allowed to be changed into compound state by solid solution state and is deposited on melt bottom, so as to improve the electric conductivity of aluminium alloy；
Sc：Scandium has good dispersion-strengthened action to aluminium, is the thin agent of the excellent crystal grain of aluminium alloy and well to tie suppression again.
Microamounts of Scandium element is added in aluminium alloy, a large amount of disperses, the secondary Al of coherence can be formed3Sc phase particles, these particles one side
Face can consumingly pinning dislocation and sub boundary, there is very strong stabilization to the substructure in deformed microstructure, alloy is existed
What deformation process was formed occurred in subsequent annealing process to reply by the cellular structure that entanglement dislocation is formed forms Asia
Crystal boundary, and many sub boundaries are made up of the network of dislocation of two dimension, and strong substructure invigoration effect can be played to alloy；Separately
On the one hand these disperses, the secondary A1 of coherence3The tiny particle of Sc phases, the strong pinning dislocation of energy, hinders the motion of dislocation, carries significantly
Shearing stress needed for high dislocation movement by slip, so as to cause alloy strengthening.Meanwhile scandium element can be with the impurity element of some in aluminium alloy
Reaction forms the second phase, so as to which the conductance enabled aluminum alloy to improves；
Fe：Contain a certain amount of iron in aluminium, be a kind of major impurity in fine aluminium.Because the instrument that melting uses with casting
All it is steel or cast iron, iron will be brought into aluminium by these instruments, and in remelting waste material, then can be mixed into iron and iron filings.
Iron is harmful to the mechanical property for casting aluminium, because it generally occurs with a thick crystal, or with Al-Fe-Si compound shapes
Formula is present, and they all improve the hardness of aluminium to a certain extent, but reduce the plasticity of aluminium.It recent studies have shown that, iron can carry
High aluminium conductor intensity, does not significantly reduce its electric conductivity.But also there is data to show in actual production, the Fe/Si in aluminium conductor
It is too high than should be 1.3~1.5, its resistivity can be made significantly to raise, so it should also be noted that the content of control iron；
Si：Element silicon is a kind of major impurity element in fine aluminium.As Si contents raise, the electrical conductivity of alloy declines.
This is due to improve Si contents in alloy, and Si quantity of dissociating in aluminum substrate increase, Si is semiconductor, high compared with the resistivity of aluminum substrate
Much, so the raising of Si contents reduces effective conductive cross-sectional area of aluminum substrate, low-alloyed electrical conductivity drops.Therefore, in duralumin
It should be tried one's best in alloy and reduce Si contents；
Cr, Mn, V and Ti are the impurity element in alloy.This several element has crystal grain thinning, improves aluminium alloy room temperature
Tensile strength and the effect for improving heat resistance, but they in aluminium conductor to be dissolved in the presence of state, it is easy to absorb conductor material
Free electron in material and fill their incomplete electronic shell, the reduction of this conduction number of electrons result in aluminium conductor conduction
The reduction of property.Research shows that every 1% (Cr+Mn+V+Ti) illeffects is to the 5 of aluminium electric conductivity illeffects per 1%Si
Times.So it need to strictly control the content of this several element.
In the preparation method of nonheat-treatable heat-resisting aluminium alloy monofilament provided by the invention, first smelt, when fine aluminium ingot is complete
Each alloying element is sequentially placed into after fusing, wherein B and Al has eutectic reaction, and alloying element is easier to dissolve, in fusion process
It can be directly added into aluminum melt；For Zr, Sc element because fusing point is higher, dissolving is very slow, it is necessary to which larger overheat can be just completely dissolved.
Aluminium liquid is stirred with mixer, makes alloying element full and uniformization；Dehydrogenation is carried out to aluminium liquid using nitrogen, except Slag treatment.
Mould is heated, prevents mold temperature has big difference to cause with temperature of aluminum liquid from causing shrinkage cavity, mould in aluminium liquid casting cycle
200~250 DEG C of 60~90min of insulation are heated to, aluminium liquid casting is then carried out, is cast into 45 × 100mm of Ф duralumin pole.Adopt
Ф 9.5mm circle aluminium bar is extruded into the mode of hot extrusion, then carries out wire drawing.With 15m/s speed on wire drawing machine it is cold
Wire drawing, drawn by punching block multi-pass, the final monofilament for obtaining Ф 3.05mm.Adjusted by 140~180 DEG C of 3~6h of annealing
Integrate the performance of gold.
With immediate prior art ratio, beneficial effects of the present invention：Technical scheme provided by the invention, due in duralumin
Minor Sc is with the addition of in alloy, can either reduce impurity content has Grain Refinement Effect again, is ensureing duralumin, hard alumin ium alloy tool
Aluminium alloy has preferable mechanical property while having high conductivity；Used when technical scheme is as a result of hot extrusion
The method of cold water chilling duralumin round bar, avoids the appearance with precipitated phase；Only with being blown into technical scheme
N2Degasification is removed the gred, and without adding refining agent, so as to simplify the preparation technology of duralumin, hard alumin ium alloy, the electric wire thus prepared is led
Body can improve conductance (63%IACS, 20 DEG C) and increase working strength (tensile strength >=163MPa).
【Embodiment】
Unless otherwise stated, all embodiments are all to use existing smelting and extrusion equipment.
Embodiment 1
The 63%IACS conductance hard aluminum wire monofilament of following components and its mass percent is prepared,：
By the aluminium ingot that purity is 99.7% in medium frequency induction melting furnace, melted at 720 DEG C, when rising to 730 DEG C, in
Between alloy mode, add aluminium boron intermediate alloy boronation, stand 30 minutes after, at 750 DEG C, add Zr, Sc alloying element, make
Its final content is reached respectively, and alloying element is added in the form of intermediate alloy, is sufficiently stirred after intermediate alloy is completely melt；
It is passed through N2Degasification, slagging-off 10 minutes, the refining aluminium alloy liquid at 750 DEG C, cast after standing 40min.It is before casting that cylindrical type is low
Carbon Steel Die, which is put into batch-type furnace, is heated to 200 DEG C, is incubated 20min, and temperature of aluminum liquid is down into 720 DEG C, then falls aluminium liquid
Enter in mould, prepare the duralumin pole that size is 45 × 300mm of Ф length.Duralumin pole is squeezing after 450 DEG C are incubated 1 hour
It is squeezed into Ф 9.5mm aluminium alloy rod on press, while the cold water 2 minutes of room temperature is sprayed to the aluminium alloy rod squeezed out.By aluminium
Rod of metal alloy carries out cold drawing with 15m/s speed on high speed wiredrawing bench, is drawn using punching block by 15 passages, finally obtains Ф
3.05mm duralumin monofilament.By aluminium alloy monofilament in 180 DEG C of batch annealing 3 hours, room temperature is air-cooled to after taking-up.Through inspection
Survey, gained duralumin monofilament conductance is 63.01%IACS, and test intensity is 163.15MPa, elongation percentage 2.13%.
Embodiment 2
Prepare the 63%IACS conductance hard aluminum wire monofilament of following components and its mass percent：
By the aluminium ingot that purity is 99.7% in smelting furnace, after 720 DEG C of fusings, 740 DEG C are warming up to, with intermediate alloy
Mode, aluminium boron intermediate alloy boronation is added, after standing 30 minutes, at 750 DEG C, Zr, Sc alloying element, made final up to its respectively
Content, alloying element are added in the form of intermediate alloy, are sufficiently stirred after intermediate alloy is completely melt；It is passed through N2Degasification,
Slagging-off 15 minutes, the refining aluminium alloy liquid at 750 DEG C, cast after standing 40min.Cylindrical type low-carbon steel mold is put into before casting
200 DEG C are heated in batch-type furnace, is incubated 20min, and temperature of aluminum liquid is down to 720 DEG C, then pours into aluminium liquid in mould, is prepared
Go out the duralumin pole that size is 45 × 300mm of Ф length.Duralumin pole is squeezed into Ф after 450 DEG C are incubated 1 hour on extruder
9.5mm aluminium alloy rod, while spray to the aluminium alloy rod that squeezes out the cold water 2 minutes of room temperature.By aluminium alloy rod with 15m/s's
Speed carries out cold drawing on high speed wiredrawing bench, is drawn using punching block by 15 passages, the final duralumin list for obtaining Ф 3.05mm
Silk.By aluminium alloy monofilament in 160 DEG C of batch annealing 4 hours, room temperature is air-cooled to after taking-up.After testing, gained duralumin list
Silk conductance is 63.07%IACS, and test intensity is 163.52MPa, elongation percentage 2.07%.
Embodiment 3
Prepare the 63%IACS conductance hard aluminum wire monofilament of following components and its mass percent：
By the aluminium ingot that purity is 99.7 in smelting furnace, melted at 720 DEG C, when rising to 730 DEG C, with the side of intermediate alloy
Formula, aluminium boron intermediate alloy boronation is added, after standing 30 minutes, at 750 DEG C, add Zr, Sc alloying element, make to reach it most respectively
Whole content, alloying element are added in the form of intermediate alloy, are sufficiently stirred after intermediate alloy is completely melt；It is passed through N2Remove
Gas, slagging-off 20 minutes, the refining aluminium alloy liquid at 730 DEG C, cast after standing 60 minutes.Low-carbon steel mold is put into case before casting
220 DEG C are heated in formula stove, 700 DEG C of aluminum alloy melt is cast in the cylindrical type mould, prepare size for Ф 45 ×
The duralumin pole of 300mm length；Duralumin pole is squeezed into Ф 9.5mm aluminium alloy after 500 DEG C are incubated 40 minutes on extruder
Bar, while the cold water 3 minutes of room temperature is sprayed to the aluminium alloy rod that squeezes out, to avoid with precipitated phase precipitation.By aluminium alloy rod
Cold drawing is carried out on wire drawing machine with 15m/s speed, is drawn using punching block by 15 passages, finally obtains a diameter of 3.05mm
Duralumin monofilament；By aluminium alloy monofilament in 140 DEG C of batch annealing 6h, room temperature is air-cooled to after taking-up.After testing, gained is hard
Aluminium monofilament conductance is 63.05%IACS, and test intensity is 163.36MPa, elongation percentage 2.18%.
Embodiment 4
Prepare the 63%IACS conductance hard aluminum wire monofilament of following components and its mass percent：
The aluminium ingot that purity is 99.7% is added in medium frequency induction melting furnace, 720 DEG C is kept the temperature at and melts fine aluminium,
When temperature rises to 730 DEG C, start in a manner of intermediate alloy, add aluminium boron intermediate alloy boronation, after standing 30 minutes,
750 DEG C, Zr, Sc alloying element are added, the final content for making them is as it appears from the above, alloying element is in the form of intermediate alloy
Add, aluminum alloy melt is sufficiently stirred after intermediate alloy is completely melt；It is passed through N2Degasification, slagging-off 10 minutes, at 750 DEG C
Lower refining aluminium alloy liquid, cast after standing 40min.Cylindrical type low-carbon steel mold is put into batch-type furnace before casting and is heated to
210 DEG C, be incubated 20min, and temperature of aluminum liquid be down to 700 DEG C, then pour into aluminium liquid in mould, prepare size for Ф 45 ×
The duralumin pole of 300mm length.After 480 DEG C are incubated 1.5 hours, the aluminium that Ф 9.5mm are squeezed on extruder closes duralumin pole
Golden bar, while spray to the aluminium alloy rod that squeezes out the cold water 3 minutes of room temperature.By aluminium alloy rod with 15m/s speed at a high speed
Cold drawing is carried out on wire drawing machine, is drawn using punching block by 15 passages, the final duralumin monofilament for obtaining Ф 3.05mm.By aluminium alloy
Monofilament is air-cooled to room temperature in 140 DEG C of batch annealing 6 hours after taking-up.After testing, gained duralumin monofilament conductance is
63.02%IACS, test intensity are 163.05MPa, elongation percentage 2.08%.
Embodiment 5
Prepare the 63%IACS conductance hard aluminum wire monofilament of following components and its mass percent：
The aluminium ingot that purity is 99.7% is added in medium frequency induction melting furnace, 730 DEG C is kept the temperature at and melts fine aluminium,
When temperature rises to 740 DEG C, start in a manner of intermediate alloy, add aluminium boron intermediate alloy boronation, after standing 30 minutes,
Zr, Sc alloying element at 750 DEG C, the final content for making them are as it appears from the above, alloying element is added in the form of intermediate alloy
Enter, aluminum alloy melt is sufficiently stirred after intermediate alloy is completely melt；It is passed through N2Degasification, slagging-off 25 minutes, at 750 DEG C
Refining aluminium alloy liquid, cast after standing 40min.Cylindrical type low-carbon steel mold is put into batch-type furnace before casting and is heated to
200 DEG C, be incubated 20min, and temperature of aluminum liquid be down to 710 DEG C, then pour into aluminium liquid in mould, prepare size for Ф 45 ×
The duralumin pole of 300mm length.Duralumin pole is squeezed into Ф 9.5mm aluminium alloy after 420 DEG C are incubated 1 hour on extruder
Bar, while spray to the aluminium alloy rod that squeezes out the cold water 1 minute of room temperature.Aluminium alloy rod is drawn with 15m/s speed in high speed
Cold drawing is carried out on silk machine, is drawn using punching block by 15 passages, the final duralumin monofilament for obtaining Ф 3.05mm.By aluminium alloy single
Silk is air-cooled to room temperature in 150 DEG C of batch annealing 5 hours after taking-up.After testing, gained duralumin monofilament conductance is
63.03%IACS, test intensity are 163.09MPa, elongation percentage 2.12%.
It is the data of embodiment in form.
| Embodiment | Conductance (%IACS) | Tensile strength (MPa) | Elongation percentage (%) |
| 1 | 63.01 | 163.15 | 2.13 |
| 2 | 63.07 | 163.52 | 2.07 |
| 3 | 63.05 | 163.36 | 2.18 |
| 4 | 63.02 | 163.05 | 2.08 |
| 5 | 63.03 | 163.09 | 2.12 |
It is only the detailed description carried out to presently preferred embodiments of the present invention above, but the present invention is not limited to above reality
Apply example.It should be understood that in the case of the spirit and scope of claims hereof are not departed from, those skilled in the art
The various modifications made, still fall within the scope of the present invention.
Claims (4)
1. a kind of high-conductivity hard aluminum wire monofilament, it is characterised in that the hard aluminum wire monofilament is following containing by mass percentage
Composition：Zr：0.01~0.05%, B：0.01~0.05%, Sc：0.05~0.2%, Fe：0~0.14%, Si：0~0.07%,
V+Ti+Cr+Mn：0~0.012%, remaining is Al and inevitable trace impurity；
The preparation method of described high-conductivity hard aluminum wire monofilament, comprises the steps：
(1) smelt：By the aluminium ingot of purity >=99.7% after 720~750 DEG C of fusings, B, Zr, Sc are added at 730~750 DEG C
Intermediate alloy, stir aluminum alloy melt after intermediate alloy is completely melt；
(2) refine：It is blown into N2Degasification, after removing the gred 10~20 minutes, the refining aluminium alloy liquid at 730~750 DEG C, stand 30~60
Minute；
(3) cast：Temperature of aluminum liquid obtained by step (2) is down to 700~720 DEG C, is cast to and is preheated to 200~250 DEG C of insulations
In mould, duralumin pole is made；
(4) bar processed：Duralumin pole is squeezed into aluminium alloy rod after 400~500 DEG C are incubated 0.5~2h, while to the aluminium squeezed out
Rod of metal alloy spray water；
(5) wire drawing：Aluminium alloy rod is drawn through 10~20 passages using punching block, obtained with 15m/s speed cold drawing with wire drawing machine
Duralumin monofilament；
(6) anneal：Duralumin monofilament is annealed, room temperature is air-cooled to after taking-up；
The order that intermediate alloy is added in step (1) is that Al-B intermediate alloy boronations are added at 730~750 DEG C, stands 30min
Afterwards, Al-Zr, Al-Sc intermediate alloy are added at 750 DEG C；
Spray water 1~3 minute in step (4).
2. hard aluminum wire monofilament as claimed in claim 1, it is characterised in that the mass percent of the B be 0.03~
0.05%.
3. high-conductivity hard aluminum wire monofilament as claimed in claim 1, it is characterised in that the drawing in step (5) in punching block
Number is 15 times.
4. high-conductivity hard aluminum wire monofilament as claimed in claim 1, it is characterised in that in step (6) at 140~180 DEG C
Anneal 3~6h.
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| CN113862525A (en) * | 2021-07-27 | 2021-12-31 | 国网江苏省电力有限公司 | High-conductivity aluminum alloy monofilament for overhead conductor and preparation method thereof |
| CN113957301B (en) * | 2021-10-28 | 2022-11-08 | 全球能源互联网研究院有限公司 | Aluminum alloy monofilament and preparation method thereof |
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