CN105603343B - Gas permeability copper air-conditioner foil and preparation method thereof - Google Patents
Gas permeability copper air-conditioner foil and preparation method thereof Download PDFInfo
- Publication number
- CN105603343B CN105603343B CN201510962967.2A CN201510962967A CN105603343B CN 105603343 B CN105603343 B CN 105603343B CN 201510962967 A CN201510962967 A CN 201510962967A CN 105603343 B CN105603343 B CN 105603343B
- Authority
- CN
- China
- Prior art keywords
- copper
- copper foil
- foil
- hole
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 134
- 239000010949 copper Substances 0.000 title claims abstract description 48
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 48
- 239000011888 foil Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 230000035699 permeability Effects 0.000 title claims abstract description 22
- 239000011889 copper foil Substances 0.000 claims abstract description 84
- 239000000463 material Substances 0.000 claims abstract description 49
- 238000000034 method Methods 0.000 claims abstract description 25
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 16
- 239000002131 composite material Substances 0.000 claims abstract description 13
- DOVLHZIEMGDZIW-UHFFFAOYSA-N [Cu+3].[O-]B([O-])[O-] Chemical compound [Cu+3].[O-]B([O-])[O-] DOVLHZIEMGDZIW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000010148 water-pollination Effects 0.000 claims abstract description 6
- 238000005097 cold rolling Methods 0.000 claims description 45
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 39
- 239000000741 silica gel Substances 0.000 claims description 39
- 229910002027 silica gel Inorganic materials 0.000 claims description 39
- 238000000137 annealing Methods 0.000 claims description 32
- 238000000498 ball milling Methods 0.000 claims description 29
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 26
- 239000007789 gas Substances 0.000 claims description 22
- 239000003513 alkali Substances 0.000 claims description 20
- 238000003490 calendering Methods 0.000 claims description 20
- 238000004140 cleaning Methods 0.000 claims description 17
- 238000005530 etching Methods 0.000 claims description 15
- 239000000853 adhesive Substances 0.000 claims description 14
- 230000001070 adhesive effect Effects 0.000 claims description 14
- 238000005096 rolling process Methods 0.000 claims description 14
- 239000012300 argon atmosphere Substances 0.000 claims description 13
- 238000005406 washing Methods 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- 239000004519 grease Substances 0.000 claims description 9
- 230000009467 reduction Effects 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 7
- 238000005245 sintering Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 239000003792 electrolyte Substances 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- -1 polyethylene Polymers 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- 238000003825 pressing Methods 0.000 claims description 5
- 239000010959 steel Substances 0.000 claims description 5
- 239000002585 base Substances 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- 238000003780 insertion Methods 0.000 claims 1
- 230000037431 insertion Effects 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 238000004378 air conditioning Methods 0.000 abstract description 7
- 241001124569 Lycaenidae Species 0.000 abstract description 5
- 235000014987 copper Nutrition 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 229910000881 Cu alloy Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000003723 Smelting Methods 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 210000001161 mammalian embryo Anatomy 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 238000005476 soldering Methods 0.000 description 2
- 238000005482 strain hardening Methods 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- 239000000956 alloy Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/08—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon
-
- B22F1/0003—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
- B22F2009/043—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling by ball milling
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2255/00—Heat exchanger elements made of materials having special features or resulting from particular manufacturing processes
- F28F2255/06—Heat exchanger elements made of materials having special features or resulting from particular manufacturing processes composite, e.g. polymers with fillers or fibres
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of preparation method of gas permeability copper air-conditioner foil, the Copper Foil by copper borate whisker and T2 coppers into, the present invention distinguishes composite hydrophilic film and hydrophobic film on the two sides of gas permeability Copper Foil, the air-conditioner foil product that material of the present invention and method are obtained, its tensile strength is more than 8% up to 140 160Mpa, elongation percentage.There is excellent hydrophily and hydrophobicity simultaneously, greatly improve air-conditioning heat exchange efficiency, prevent frosting.
Description
Technical field
The present invention relates to copper product and its manufacture craft.It is more particularly related to which a kind of be applied to air-conditioning heat exchange
Gas permeability copper air-conditioner foil of piece and preparation method thereof.
Background technology
At present copper alloy is typically used for producing air-conditioner foil.But the radiating effect of copper alloy is well below copper alloy
Radiating effect, therefore prepare air-conditioner foil using Cu alloy material and increased much with respect to power consumption for copper alloy, smoothness
In addition, as each class standard is to the requirement more and more higher in terms of air conditioner energy-saving, also the energy-conservation to air-conditioner foil is special
Property propose higher requirement, air-conditioner foil includes hydrophily paper tinsel and hydrophobicity paper tinsel, and wherein hydrophily paper tinsel surface has stronger parent
It is aqueous.The quality of hydrophilicity is adhered to the angular dimension formed after copper foil surface by water and determined, the smaller then hydrophilicity in a angles
It is better, on the contrary then hydrophilicity is poorer.In general, a angles are less than 35 °, that is, belong to hydrophilicity, and its major function is to make hot sky
Moisture in gas is easily spread out and flowed away downwards along sheet material when the globule is condensed on heat exchanger fin.It can so avoid because changing
The globule " bridging " between backing and influence the ventilation effect of heat exchanger, so as to improve the rate of heat exchange of air-conditioning, freezing on an equal basis
Electric energy can also be saved under conditions of amount.
Hydrophobicity paper tinsel is called repellency paper tinsel, its surface property and hydrophily paper tinsel contrast.I.e. condensed water is agglomerated to the copper
It is larger with contact angle formed by Copper Foil during paper tinsel surface, typically more than 75 °.The more big then hydrophobic performance of angle is better.Use hydrophobic
The final purpose of property paper tinsel is identical with hydrophily paper tinsel, i.e., do not allow condensed water to remain between heat exchanger fin.Difference is, hydrophobicity
Paper tinsel is the contact angle by increasing condensed water and heat exchanger fin, condensed water formation is easy to the globule of landing and is reached removal heat exchanger fin
Between condensed water purpose.
When winter turns on the aircondition because air-conditioning internal machine is heated, outer machine reforms into cold scattering, after temperature reaches certain temperature,
The condenser of outer machine will defrost, now interior machine blower failure, outer machine blower failure, compressor operating, four-way valve commutation, commutation
The frost of outer machine is melted to outer mechanism heat afterwards, steam is just had and water is produced, now simple hydrophobicity air-conditioner foil or hydrophilic
Property air-conditioner foil all effectively steam and water can not be removed.
The content of the invention
It is an object of the invention to solve at least the above, and provide the advantage that at least will be described later.
It is a still further object of the present invention to provide a kind of thickness is thinner, mechanical performance is more excellent, while so that air conditioning energy consumption
Lower air-conditioner foil.
In order to realize according to object of the present invention and further advantage there is provided a kind of gas permeability copper air-conditioner foil, its
The hydrophilic material and hydrophobic material for being compounded in its two sides by Copper Foil and respectively are constituted；
Wherein, the densely covered through hole of the copper foil surface, its thickness is 0.01-0.02mm, and the quantity of the through hole reaches
5000-9000/m2, the diameter of the pin hole is less than 0.03mm；
Wherein, the hydrophilic material is eptfe film, and its thickness is 0.01-0.02mm；
Wherein, the hydrophobic material is the mixture of porous silica gel and carborundum, the porous silica gel and carborundum
Volume ratio is 1:1.25, the consumption of the porous silica gel is 1g/m2, the fineness of the porous silica gel and carbon dust is between 1250-
Between 2500 mesh.
Present invention also offers a kind of preparation method of gas permeability copper air-conditioner foil, the Copper Foil by T2 coppers into, including
Following steps：
S1, preparation meet the Copper Foil of thickness, and the Copper Foil is etched, and make the copper of the densely covered through hole of Copper Foil
Paper tinsel, the thickness of the Copper Foil is 0.01-0.02mm, and the quantity of the through hole reaches 5000-9000/m2, the through hole
Diameter is less than 0.03mm；
S2, the one side of eptfe film and step the S1 Copper Foil prepared is combined using adhesive, its
In, the thickness of the eptfe film is 0.01-0.02mm, and the composite pressure used is 3kg/cm3, it is combined temperature
Spend for 80 DEG C, hauling speed is 2m/s, and the consumption of adhesive is 6g/m2；
S3, the another side coating polyethylene alcohol by Copper Foil, are combined with porous silica gel and carborundum, wherein, it is described micro-
The volume ratio of hole silica gel and carborundum is 1:1.25, the consumption of the porous silica gel is 1g/m2, the porous silica gel and carborundum
Fineness be 1250-2500 mesh, the composite pressure used is 8kg/cm3, combined temp is 85 DEG C, and hauling speed is 1m/
S, the consumption of adhesive is 5g/m2。
Preferably, the preparation method of the Copper Foil in the step S1 is：By copper borate whisker and T2 copper powders in mass ratio
For 1:20 carry out mixing and ball milling, by the powder isostatic cool pressing after ball milling into cylindrical blank, by the cylindrical blank in argon gas
Sintered under protective atmosphere, the blank after sintering is pressed again, blank of the blank after multiple pressure after argon atmosphere resintering, resintering
Sheet material is hot extruded into, sheet material carries out Ageing Treatment under argon atmosphere, the sheet material through Wetted constructures is continued into rolling is
It may be adapted to the blank of cold rolling 3.5 ± 0.5mm thickness, by 2 cold rolling calenderings and an etching process, obtain 0.01-
The ventilative Copper Foil of the densely covered through hole in the surface of 0.02mm thickness.
Preferably, relative air humidity is less than 1% in melting.
Preferably, the concrete operations of the mixing and ball milling include：Ball milling parameter is ratio of grinding media to material 8:1, steel ball by sphere diameter from
Totally eight kinds of specifications are loaded in mixture 10mm-80mm, drum's speed of rotation 200r/min, and ball mill working method is shut down to rotate forward 900s
30s, then inverts 900s, shuts down 30s, so circulation, Ball-milling Time is 4h.
Preferably, the concrete operations of 2 cold rolling calenderings include：Carried out once under the conditions of blank temperature is less than 80 DEG C
Cold rolling, each passage uses 25-35% pass reductions, by the cold rolling calendering of 6-7 passages, is rolling to 0.4 ± 0.05mm thickness, turns
Annealing furnace carries out first time intermediate annealing；Cold rolling blank after first time intermediate annealing is subjected to secondary cold-rolling, each passage is used
35-45% pass reductions, by the cold rolling calendering of 4-5 passages, are rolling to 0.01-0.02mm thickness.
Preferably, the concrete operations of the etching process step include：To the blank by secondary cold-rolling using containing
The aqueous solution of 3wt% hydrochloric acid is as electrolyte, with 80 DEG C of liquid temperature and current density 0.42A/cm2Implemented by direct current etching,
This results in the Copper Foil with through hole, the quantity of the through hole up to 5000-9000/m2, the diameter of the through hole
Less than 0.03mm.
Preferably, the concrete operations of the annealing steps include：Annealing temperature of the Copper Foil of process at 350 DEG C will be rolled through paper tinsel
Lower insulation 8h, then it is incubated 10h under 250 DEG C of annealing temperature.
Preferably, also need to carry out the operation except grease before the step 2：Alkali is carried out by alkaline bath at 60 DEG C
Wash, the grease of copper foil surface prepared by cleaning step S1；Wherein alkali lye pH value is 11-13；After alkali cleaning terminates, enter back into tank and enter
Row high temperature is washed, and cleaning copper rolls up the alkali lye of remained on surface, and high temperature washing temperature is 50-60 DEG C, after washing terminates, at 180 DEG C
Copper Foil is dried.
The present invention at least includes following beneficial effect：
1st, the present invention is processed using T2 copper, and T2 copper has good conduction, heat conduction, anti-corrosion and processing characteristics, can weld
Connect and soldering.The impurity of the electrical and thermal conductivity containing reduction is less have after processing it is indeformable, film is easy for colouring, oxidation effectiveness is splendid
Etc. good characteristics.
2nd, Copper Foil is processed into the structure of densely covered through hole by the present invention, is then respectively coated successively on the two sides of Copper Foil hydrophilic
Property film and hydrophobic film, when air-conditioning heat exchange produces vapor, vapor run into hydrophilic film just drawout and along
Sheet material flows away downwards, but when vapor is excessive, and hydrophilic film can not be in time by the timely drawout of vapor, now part
Hydrone is contacted by ventilative Copper Foil with hydrophobic film, hydrophobic film by hydrone formation be easy to landing the globule and
Reach remove heat exchanger fin between condensed water purpose, serve unexpected defrosting effect.
3rd, the present invention is by copper borate whisker and T2 copper powders progress mixed smelting, can obtain specific strength, fatigue strength, resistance to
The higher composite of property is ground, using the method for ball milling whisker can be made to be distributed in copper powder more uniformly, institute in the present invention
The ball grinding method used can significantly reduce Ball-milling Time, while reducing the segregation and crack defect of whisker.
4th, embryo material is carried out cold rolling twice and intermediate annealing twice by the present invention, can further eliminate cold work hardening, extensive
The plasticity and cold deformation ability of multiple copper.
Further advantage, target and the feature of the present invention embodies part by following explanation, and part will also be by this
The research and practice of invention and be understood by the person skilled in the art.
Embodiment
With reference to embodiment, the present invention is described in further detail, to make those skilled in the art with reference to specification
Word can be implemented according to this.
It should be noted that experimental method described in following embodiments, unless otherwise specified, is conventional method, institute
Reagent and material are stated, unless otherwise specified, is commercially obtained.
Embodiment 1
A kind of gas permeability copper air-conditioner foil, it is compounded in the hydrophilic material and hydrophobicity on its two sides by Copper Foil and respectively
Material is constituted；
Wherein, the copper foil surface gathers through hole, and its thickness is 0.01mm, the quantity of the through hole up to 5000/
m2, the diameter of the pin hole is less than 0.03mm；
Wherein, the hydrophilic material is eptfe film, and its thickness is 0.01mm；
Wherein, the hydrophobic material is the mixture of porous silica gel and carborundum, the porous silica gel and carborundum
Volume ratio is 1:1.25, the consumption of the porous silica gel is 1g/m2, the fineness of the porous silica gel and carbon dust is between 1250-
Between 2500 mesh.
The preparation method of the gas permeability copper air-conditioner foil, the Copper Foil is by T2 coppers into comprising the following steps：
S1, preparation meet the Copper Foil of thickness, and the Copper Foil is etched, and make the copper of the densely covered through hole of Copper Foil
Paper tinsel, the thickness of the Copper Foil is 0.01mm, and the quantity of the through hole is up to 5000/m2, the diameter of the through hole is less than
0.03mm；
S2, the one side of eptfe film and step the S1 Copper Foil prepared is combined using adhesive, its
In, the thickness of the eptfe film is 0.01mm, and the composite pressure used is 3kg/cm3, combined temp is
80 DEG C, hauling speed is 2m/s, and the consumption of adhesive is 6g/m2；
S3, the another side coating polyethylene alcohol by Copper Foil, are combined with porous silica gel and carborundum, wherein, it is described micro-
The volume ratio of hole silica gel and carborundum is 1:1.25, the consumption of the porous silica gel is 1g/m2, the porous silica gel and carborundum
Fineness be 1250-2500 mesh, the composite pressure used is 8kg/cm3, combined temp is 85 DEG C, and hauling speed is 1m/
S, the consumption of adhesive is 5g/m2。
Preferably, the preparation method of the Copper Foil in the step S1 is：By copper borate whisker and T2 copper powders in mass ratio
For 1:20 carry out mixing and ball milling, by the powder isostatic cool pressing after ball milling into cylindrical blank, by the cylindrical blank in argon gas
Sintered under protective atmosphere, the blank after sintering is pressed again, blank of the blank after multiple pressure after argon atmosphere resintering, resintering
Sheet material is hot extruded into, sheet material carries out Ageing Treatment under argon atmosphere, the sheet material through Wetted constructures is continued into rolling is
It may be adapted to the blank of cold rolling 3.5 ± 0.5mm thickness, by 2 cold rolling calenderings and an etching process, obtain 0.01mm thickness
Surface gather through hole ventilative Copper Foil.
Relative air humidity is less than 1% in melting.
The concrete operations of the mixing and ball milling include：Ball milling parameter is ratio of grinding media to material 8:1, steel ball presses sphere diameter from 10mm-80mm
Totally eight kinds of specifications are loaded in mixture, drum's speed of rotation 200r/min, and ball mill working method shuts down 30s, then instead to rotate forward 900s
Turn 900s, shut down 30s, so circulation, Ball-milling Time is 4h.
The concrete operations of 2 cold rolling calenderings include：Once cold rolling is carried out under the conditions of blank temperature is less than 80 DEG C, respectively
Passage uses 25% pass reduction, by the cold rolling calendering of 7 passages, is rolling to 0.4 ± 0.05mm thickness, turns annealing furnace progress the
Intermediate annealing；Cold rolling blank after first time intermediate annealing is subjected to secondary cold-rolling, each passage is processed using 35% passage
Rate, by the cold rolling calendering of 5 passages, is rolling to 0.01mm thickness.
The concrete operations of the etching process step include：Blank by secondary cold-rolling is used and contains 3wt% hydrochloric acid
The aqueous solution as electrolyte, with 80 DEG C of liquid temperature and current density 0.42A/cm2Implemented by direct current etching, this results in
Copper Foil with through hole, the quantity of the through hole is up to 5000/m2, and the diameter of the through hole is less than 0.03mm.
The concrete operations of the annealing steps include：The Copper Foil that process is rolled through paper tinsel is incubated under 350 DEG C of annealing temperature
8h, then it is incubated 10h under 250 DEG C of annealing temperature.
Also need to carry out the operation except grease before the step 2：Alkali cleaning, cleaning step are carried out by alkaline bath at 60 DEG C
The grease of copper foil surface prepared by rapid S1；Wherein alkali lye pH value is 11；After alkali cleaning terminates, enter back into tank and carry out high temperature washing,
The alkali lye that copper rolls up remained on surface is cleaned, and high temperature washing temperature is 50 DEG C, after washing terminates, Copper Foil is dried at 180 DEG C.
Embodiment 2
A kind of gas permeability copper air-conditioner foil, it is compounded in the hydrophilic material and hydrophobicity on its two sides by Copper Foil and respectively
Material is constituted；
Wherein, the copper foil surface gathers through hole, and its thickness is 0.02mm, the quantity of the through hole up to 9000/
m2, the diameter of the pin hole is less than 0.03mm；
Wherein, the hydrophilic material is eptfe film, and its thickness is 0.02mm；
Wherein, the hydrophobic material is the mixture of porous silica gel and carborundum, the porous silica gel and carborundum
Volume ratio is 1:1.25, the consumption of the porous silica gel is 1g/m2, the fineness of the porous silica gel and carbon dust is between 1250-
Between 2500 mesh.
Present invention also offers a kind of preparation method of gas permeability copper air-conditioner foil, the Copper Foil by T2 coppers into, including
Following steps：
S1, preparation meet the Copper Foil of thickness, and the Copper Foil is etched, and make the copper of the densely covered through hole of Copper Foil
Paper tinsel, the thickness of the Copper Foil is 0.02mm, and the quantity of the through hole is up to 9000/m2, the diameter of the through hole is less than
0.03mm；
S2, the one side of eptfe film and step the S1 Copper Foil prepared is combined using adhesive, its
In, the thickness of the eptfe film is 0.02mm, and the composite pressure used is 3kg/cm3, combined temp is
80 DEG C, hauling speed is 2m/s, and the consumption of adhesive is 6g/m2；
S3, the another side coating polyethylene alcohol by Copper Foil, are combined with porous silica gel and carborundum, wherein, it is described micro-
The volume ratio of hole silica gel and carborundum is 1:1.25, the consumption of the porous silica gel is 1g/m2, the porous silica gel and carborundum
Fineness be 1250-2500 mesh, the composite pressure used is 8kg/cm3, combined temp is 85 DEG C, and hauling speed is 1m/
S, the consumption of adhesive is 5g/m2。
The preparation method of Copper Foil in the step S1 is：It is 1 in mass ratio by copper borate whisker and T2 copper powders:20 enter
Row mixing and ball milling, by the powder isostatic cool pressing after ball milling into cylindrical blank, by the cylindrical blank in argon atmosphere
Lower sintering, the blank after sintering is pressed again, and blank of the blank after multiple pressure after argon atmosphere resintering, resintering is hot extruded into
Sheet material, sheet material carries out Ageing Treatment under argon atmosphere, and it is cold to may be adapted to that the sheet material through Wetted constructures is continued into rolling
The blank of the 3.5 ± 0.5mm thickness rolled, by 2 cold rolling calenderings and an etching process, the surface for obtaining 0.02mm thickness is close
The ventilative Copper Foil of cloth through hole.
Relative air humidity is less than 1% in melting.
The concrete operations of the mixing and ball milling include：Ball milling parameter is ratio of grinding media to material 8:1, steel ball presses sphere diameter from 10mm-80mm
Totally eight kinds of specifications are loaded in mixture, drum's speed of rotation 200r/min, and ball mill working method shuts down 30s, then instead to rotate forward 900s
Turn 900s, shut down 30s, so circulation, Ball-milling Time is 4h.
The concrete operations of 2 cold rolling calenderings include：Once cold rolling is carried out under the conditions of blank temperature is less than 80 DEG C, respectively
Passage uses 35% pass reduction, by the cold rolling calendering of 6 passages, is rolling to 0.4 ± 0.05mm thickness, turns annealing furnace progress the
Intermediate annealing；Cold rolling blank after first time intermediate annealing is subjected to secondary cold-rolling, each passage is processed using 45% passage
Rate, by the cold rolling calendering of 4 passages, is rolling to 0.02mm thickness.
The concrete operations of the etching process step include：Blank by secondary cold-rolling is used and contains 3wt% hydrochloric acid
The aqueous solution as electrolyte, with 80 DEG C of liquid temperature and current density 0.42A/cm2Implemented by direct current etching, this results in
Copper Foil with through hole, the quantity of the through hole is up to 9000/m2, and the diameter of the through hole is less than 0.03mm.
The concrete operations of the annealing steps include：The Copper Foil that process is rolled through paper tinsel is incubated under 350 DEG C of annealing temperature
8h, then it is incubated 10h under 250 DEG C of annealing temperature.
Also need to carry out the operation except grease before the step 2：Alkali cleaning, cleaning step are carried out by alkaline bath at 60 DEG C
The grease of copper foil surface prepared by rapid S1；Wherein alkali lye pH value is 13；After alkali cleaning terminates, enter back into tank and carry out high temperature washing,
The alkali lye that copper rolls up remained on surface is cleaned, and high temperature washing temperature is 60 DEG C, after washing terminates, Copper Foil is dried at 180 DEG C.
Embodiment 3
A kind of gas permeability copper air-conditioner foil, it is compounded in the hydrophilic material and hydrophobicity on its two sides by Copper Foil and respectively
Material is constituted；
Wherein, the copper foil surface gathers through hole, and its thickness is 0.015mm, the quantity of the through hole up to 6000/
m2, the diameter of the pin hole is less than 0.03mm；
Wherein, the hydrophilic material is eptfe film, and its thickness is 0.015mm；
Wherein, the hydrophobic material is the mixture of porous silica gel and carborundum, the porous silica gel and carborundum
Volume ratio is 1:1.25, the consumption of the porous silica gel is 1g/m2, the fineness of the porous silica gel and carbon dust is between 1250-
Between 2500 mesh.
The preparation method of the gas permeability copper air-conditioner foil, the Copper Foil is by T2 coppers into comprising the following steps：
S1, preparation meet the Copper Foil of thickness, and the Copper Foil is etched, and make the copper of the densely covered through hole of Copper Foil
Paper tinsel, the thickness of the Copper Foil is 0.015mm, and the quantity of the through hole is up to 6000/m2, the diameter of the through hole is less than
0.03mm；
S2, the one side of eptfe film and step the S1 Copper Foil prepared is combined using adhesive, its
In, the thickness of the eptfe film is 0.015mm, and the composite pressure used is 3kg/cm3, combined temp is
80 DEG C, hauling speed is 2m/s, and the consumption of adhesive is 6g/m2；
S3, the another side coating polyethylene alcohol by Copper Foil, are combined with porous silica gel and carborundum, wherein, it is described micro-
The volume ratio of hole silica gel and carborundum is 1:1.25, the consumption of the porous silica gel is 1g/m2, the porous silica gel and carborundum
Fineness be 1250-2500 mesh, the composite pressure used is 8kg/cm3, combined temp is 85 DEG C, and hauling speed is 1m/
S, the consumption of adhesive is 5g/m2。
The preparation method of Copper Foil in the step S1 is：It is 1 in mass ratio by copper borate whisker and T2 copper powders:20 enter
Row mixing and ball milling, by the powder isostatic cool pressing after ball milling into cylindrical blank, by the cylindrical blank in argon atmosphere
Lower sintering, the blank after sintering is pressed again, and blank of the blank after multiple pressure after argon atmosphere resintering, resintering is hot extruded into
Sheet material, sheet material carries out Ageing Treatment under argon atmosphere, and it is cold to may be adapted to that the sheet material through Wetted constructures is continued into rolling
The blank of the 3.5 ± 0.5mm thickness rolled, by 2 cold rolling calenderings and an etching process, obtains the surface of 0.015mm thickness
The ventilative Copper Foil of densely covered through hole.
Relative air humidity is less than 1% in melting.
The concrete operations of the mixing and ball milling include：Ball milling parameter is ratio of grinding media to material 8:1, steel ball presses sphere diameter from 10mm-80mm
Totally eight kinds of specifications are loaded in mixture, drum's speed of rotation 200r/min, and ball mill working method shuts down 30s, then instead to rotate forward 900s
Turn 900s, shut down 30s, so circulation, Ball-milling Time is 4h.
The concrete operations of 2 cold rolling calenderings include：Once cold rolling is carried out under the conditions of blank temperature is less than 80 DEG C, respectively
Passage uses 30% pass reduction, by the cold rolling calendering of 6 passages, is rolling to 0.4 ± 0.05mm thickness, turns annealing furnace progress the
Intermediate annealing；Cold rolling blank after first time intermediate annealing is subjected to secondary cold-rolling, each passage is processed using 40% passage
Rate, by the cold rolling calendering of 5 passages, is rolling to 0.015mm thickness.
The concrete operations of the etching process step include：Blank by secondary cold-rolling is used and contains 3wt% hydrochloric acid
The aqueous solution as electrolyte, with 80 DEG C of liquid temperature and current density 0.42A/cm2Implemented by direct current etching, this results in
Copper Foil with through hole, the quantity of the through hole is up to 6000/m2, and the diameter of the through hole is less than 0.03mm.
The concrete operations of the annealing steps include：The Copper Foil that process is rolled through paper tinsel is incubated under 350 DEG C of annealing temperature
8h, then it is incubated 10h under 250 DEG C of annealing temperature.
Also need to carry out the operation except grease before the step 2：Alkali cleaning, cleaning step are carried out by alkaline bath at 60 DEG C
The grease of copper foil surface prepared by rapid S1；Wherein alkali lye pH value is 11-13；After alkali cleaning terminates, enter back into tank and carry out high-temperature water
Wash, cleaning copper rolls up the alkali lye of remained on surface, high temperature washing temperature is 55 DEG C, after washing terminates, is dried Copper Foil at 180 DEG C
It is dry.
The industrial applicibility of the present invention
1st, the present invention is processed using T2 copper, and T2 copper has good conduction, heat conduction, anti-corrosion and processing characteristics, can weld
Connect and soldering.The impurity of the electrical and thermal conductivity containing reduction is less have after processing it is indeformable, film is easy for colouring, oxidation effectiveness is splendid
Etc. good characteristics.
2nd, Copper Foil is processed into the structure of densely covered through hole by the present invention, is then respectively coated successively on the two sides of Copper Foil hydrophilic
Property film and hydrophobic film, when air-conditioning heat exchange produces vapor, vapor run into hydrophilic film just drawout and along
Sheet material flows away downwards, but when vapor is excessive, and hydrophilic film can not be in time by the timely drawout of vapor, now part
Hydrone is contacted by ventilative Copper Foil with hydrophobic film, hydrophobic film by hydrone formation be easy to landing the globule and
Reach remove heat exchanger fin between condensed water purpose, serve unexpected defrosting effect.
3rd, the present invention is by copper borate whisker and T2 copper powders progress mixed smelting, can obtain specific strength, fatigue strength, resistance to
The higher composite of property is ground, using the method for ball milling whisker can be made to be distributed in copper powder more uniformly, institute in the present invention
The ball grinding method used can significantly reduce Ball-milling Time, while reducing the segregation and crack defect of whisker.
4th, embryo material is carried out cold rolling twice and intermediate annealing twice by the present invention, can further eliminate cold work hardening, extensive
The plasticity and cold deformation ability of multiple copper.
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed
With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art
Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, the present invention is not limited
In specific details and shown here as the embodiment with description.
Claims (9)
1. a kind of gas permeability copper air-conditioner foil, it is characterised in that it is compounded in the hydrophily material on its two sides by Copper Foil and respectively
Material and hydrophobic material composition；
Wherein, the densely covered through hole of the copper foil surface, its thickness is 0.01-0.02mm, and the quantity of the through hole reaches 5000-
9000/m2, the diameter of the through hole is less than 0.03mm；
Wherein, the hydrophilic material is eptfe film, and its thickness is 0.01-0.02mm；
Wherein, the hydrophobic material is the mixture of porous silica gel and carborundum, the volume of the porous silica gel and carborundum
Than for 1:1.25, the consumption of the porous silica gel is 1g/m2, the fineness of the porous silica gel and carborundum is between 1250-
Between 2500 mesh.
2. a kind of preparation method of gas permeability copper air-conditioner foil as claimed in claim 1, it is characterised in that the Copper Foil is by T2
Copper is into comprising the following steps：
S1, preparation meet the Copper Foil of thickness, and the Copper Foil is etched, and make the Copper Foil of the densely covered through hole of Copper Foil, institute
The thickness for stating Copper Foil is 0.01-0.02mm, and the quantity of the through hole reaches 5000-9000/m2, the diameter of the through hole is small
In 0.03mm；
S2, the one side of eptfe film and step the S1 Copper Foil prepared is combined using adhesive, wherein, institute
The thickness for stating eptfe film is 0.01-0.02mm, and the composite pressure used is 3Kg/cm3, combined temp is
80 DEG C, hauling speed is 2m/s, and the consumption of adhesive is 6g/m2；
S3, the another side coating polyethylene alcohol by Copper Foil, are combined with porous silica gel and carborundum, wherein, the microporous silicon
The volume ratio of glue and carborundum is 1:1.25, the consumption of the porous silica gel is 1g/m2, the porous silica gel and carborundum it is thin
Degree is 1250-2500 mesh, and the composite pressure used is 8Kg/cm3, combined temp is 85 DEG C, and hauling speed is 1m/s, is glued
The consumption of mixture is 5g/m2。
3. the preparation method of gas permeability copper air-conditioner foil as claimed in claim 2, it is characterised in that the copper in the step S1
The preparation method of paper tinsel is：It is 1 in mass ratio by copper borate whisker and T2 copper powders:20 carry out mixing and ball milling, by the powder after ball milling
The cylindrical blank is sintered into cylindrical blank, the blank after sintering is answered by last isostatic cool pressing under argon atmosphere
Blank of the blank after argon atmosphere resintering, resintering after pressure, multiple pressure is hot extruded into sheet material, and sheet material is in argon atmosphere
Lower carry out Ageing Treatment, it is the base that may be adapted to cold rolling 3.5 ± 0.5mm thickness that the sheet material through Wetted constructures, which is continued to roll,
Material, by 2 cold rolling calenderings and an etching process, obtains the ventilative copper of the densely covered through hole in surface of 0.01-0.02mm thickness
Paper tinsel.
4. the preparation method of gas permeability copper air-conditioner foil as claimed in claim 3, it is characterised in that relative atmospheric is wet in melting
Degree is less than 1%.
5. the preparation method of gas permeability copper air-conditioner foil as claimed in claim 3, it is characterised in that the tool of the mixing and ball milling
Gymnastics is made to include：Ball milling parameter is ratio of grinding media to material 8:1, by sphere diameter, from 10mm-80mm, totally eight kinds of specifications are loaded in mixture steel ball, ball mill
Rotating speed 200r/min, ball mill working method shuts down 30s to rotate forward 900s, then inverts 900s, shuts down 30s, so circulation,
Ball-milling Time is 4h.
6. the preparation method of gas permeability copper air-conditioner foil as claimed in claim 3, it is characterised in that 2 cold rolling calenderings
Concrete operations include：Once cold rolling is carried out under the conditions of blank temperature is less than 80 DEG C, each passage is processed using 25-35% passages
Rate, by the cold rolling calendering of 6-7 passages, is rolling to 0.4 ± 0.05mm thickness, turns annealing furnace and carries out first time intermediate annealing；By
Cold rolling blank after intermediate annealing carries out secondary cold-rolling, and each passage uses 35-45% pass reductions, by 4-5 passages
Cold rolling calendering, is rolling to 0.01-0.02mm thickness.
7. the preparation method of gas permeability copper air-conditioner foil as claimed in claim 3, it is characterised in that the etching process step
Concrete operations include：To using the aqueous solution for containing 3wt% hydrochloric acid as electrolyte by the blank of secondary cold-rolling, with liquid temperature
80 DEG C and current density 0.42A/cm2Implemented by direct current etching, this results in the Copper Foil with through hole, the insertion
The quantity in hole reaches 5000-9000/m2, the diameter of the through hole is less than 0.03mm.
8. the preparation method of gas permeability copper air-conditioner foil as claimed in claim 6, it is characterised in that the tool of the annealing steps
Gymnastics is made to include：The Copper Foil that process is rolled through paper tinsel is incubated 8h under 350 DEG C of annealing temperature, then under 250 DEG C of annealing temperature
It is incubated 10h.
9. the preparation method of gas permeability copper air-conditioner foil as claimed in claim 2, it is characterised in that before the step S2 also
Need to carry out the operation except grease：Alkali cleaning, the oil of copper foil surface prepared by cleaning step S1 are carried out by alkaline bath at 60 DEG C
Fat；Wherein alkali lye pH value is 11-13；After alkali cleaning terminates, enter back into tank and carry out high temperature washing, cleaning copper rolls up the alkali of remained on surface
Liquid, high temperature washing temperature is 50-60 DEG C, after washing terminates, is dried Copper Foil at 180 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510962967.2A CN105603343B (en) | 2015-12-21 | 2015-12-21 | Gas permeability copper air-conditioner foil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510962967.2A CN105603343B (en) | 2015-12-21 | 2015-12-21 | Gas permeability copper air-conditioner foil and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105603343A CN105603343A (en) | 2016-05-25 |
| CN105603343B true CN105603343B (en) | 2017-07-14 |
Family
ID=55983677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510962967.2A Active CN105603343B (en) | 2015-12-21 | 2015-12-21 | Gas permeability copper air-conditioner foil and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105603343B (en) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2533529B2 (en) * | 1987-04-20 | 1996-09-11 | 日本油脂株式会社 | Amorphous metal-metal composite and method for producing the same |
| JPH0780272B2 (en) * | 1989-12-12 | 1995-08-30 | 住友特殊金属株式会社 | Thermal conductive composite material |
| JP2003324296A (en) * | 2002-04-26 | 2003-11-14 | Fuji Kobunshi Kogyo Kk | Heat sink made of electrolytic corrosion preventing metal |
| JP5734670B2 (en) * | 2011-01-07 | 2015-06-17 | 富士フイルム株式会社 | Composition for forming layer to be plated and method for producing laminate having metal film |
| EP2818578B1 (en) * | 2012-02-24 | 2018-08-22 | JFE Steel Corporation | Metal material surface treatment method, and metal material |
| CN104002515B (en) * | 2013-02-25 | 2016-08-03 | 南亚塑胶工业股份有限公司 | Composite type double sided black Copper Foil and manufacture method thereof |
-
2015
- 2015-12-21 CN CN201510962967.2A patent/CN105603343B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105603343A (en) | 2016-05-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2007121622A1 (en) | A Cu/Al COMPOSITE PIPE AND A MANUFACTURING METHOD THEREOF | |
| CN102294456A (en) | Manufacturing method for oblique rolling of bimetallic compound seamless steel pipe by centrifugal blank | |
| CN106626694A (en) | Metal laminated composite plate and preparation method thereof | |
| CN105603343B (en) | Gas permeability copper air-conditioner foil and preparation method thereof | |
| TWI592475B (en) | Adsorption material and method of manufacturing the same and adsorption heat pump | |
| CN109226264A (en) | A kind of warm rolling method of copper-titanium alloy composite plate | |
| CN103757575B (en) | A kind of method for annealing of aluminium volume | |
| CN102575319A (en) | Copper alloy seamless pipe | |
| CN106222478B (en) | A kind of ternary-alloy sealing material and preparation method thereof | |
| CN105459499B (en) | Gas permeability aluminum air-conditioner foil and preparation method thereof | |
| CN108344321A (en) | A kind of heat exchanger composite fin foil and its manufacturing method | |
| CN108373152A (en) | Conductive graphite paper and preparation method thereof | |
| CN100507432C (en) | Surface treatment process for heat sink of air conditioner | |
| CN1286393A (en) | Built-in plate-fins machine oil cooler made of aluminium | |
| CN105080998A (en) | Method for preparing no-interlayer titanium steel composite plates | |
| KR101574892B1 (en) | Heating tube coated with carbon nano material used for Absorption Refrigerator and evaporator comprising the same | |
| CN102773478A (en) | Sintering method for improving mechanical strength of tantalum block | |
| CN209558943U (en) | Heat exchanger, air conditioner and refrigeration equipment | |
| CN107619920B (en) | A kind of method for shaping of silver-based solder ring plate | |
| CN208635205U (en) | Outdoor location and air-conditioning for air-conditioning | |
| JP2534225B2 (en) | Method for manufacturing vacuum blazing member for heat exchanger assembled by blazing sheet to form internal hollow structure | |
| JP2004044909A (en) | Aluminum fin material for heat exchanger, fin, and fin tube type heat exchanger | |
| CN102899536A (en) | Preparation process of hydrophilic foil of air conditioner | |
| CN105624759B (en) | Ceramic membrane with capillary structure and super dehumidifier wetting property and preparation method thereof | |
| CN114769349B (en) | Preparation method of ultra-wide large-size titanium-coated copper composite profile |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhou Qingfen Inventor before: Deng Shaomin Inventor before: Chen Tiyong Inventor before: Gu Shengjun |
|
| CB03 | Change of inventor or designer information | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170606 Address after: 315012 Zhejiang Province, Ningbo city Haishu District Liyuan Road No. 755 room 1025 Applicant after: Ningbo Polygala cubic Energy Technology Co Ltd Address before: 536000, the Guangxi Zhuang Autonomous Region Beihai Industrial Park, Taiwan road and Jilin Road intersection southeast Applicant before: BEIHAI GUANGLI COLOR PRINTING CO., LTD. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171208 Address after: 536000 Haicheng District Industrial Park, Beihai, the Guangxi Zhuang Autonomous Region Patentee after: Jin Zhixiong Address before: 315012 Zhejiang Province, Ningbo city Haishu District Liyuan Road No. 755 room 1025 Patentee before: Ningbo Polygala cubic Energy Technology Co Ltd |
|
| TR01 | Transfer of patent right |