CN105586738A - Sizing method suitable for weaving at low-humidity environment - Google Patents

Sizing method suitable for weaving at low-humidity environment Download PDF

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Publication number
CN105586738A
CN105586738A CN201510956479.0A CN201510956479A CN105586738A CN 105586738 A CN105586738 A CN 105586738A CN 201510956479 A CN201510956479 A CN 201510956479A CN 105586738 A CN105586738 A CN 105586738A
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China
Prior art keywords
sizing
humidity environment
under low
method under
weaving
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CN105586738B (en
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沈艳琴
武海良
纪德信
黄小根
熊锐
杨明杰
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Xian Polytechnic University
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Xian Polytechnic University
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/04Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/11Starch or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a sizing method suitable for weaving at the low-humidity environment. The method comprises the specific steps that by mass, 28-82% of PVA and 72-18% of modified starch are weighed, wherein the content sum is 100%; a sizing agent is weighed, the size is adjusted, finally obtained mixed size is input into a size vat of a sizing machine, and sizing is carried out on warp yarns in a double soak and press mode. The size formula is simple and only comprises PVA and 100% potato branch etherification starch, burdens can be reduced for sizing workers, management of managers is facilitated, and the sizing method accords with the development tendency of small composition of the formula. Yarns obtained through the size formula and the sizing technology can meet the weaving requirements at the low-humidity environment, the working environment of workers in weaving workshops is greatly improved, the production cost of weaving enterprises is reduced, and the market popularization prospect is good.

Description

One is suitable for woven sizing method under low-humidity environment
Technical field
The invention belongs to textile warp sizing technical field, be specifically related to one and be suitable for knitting under low-humidity environmentThe sizing method of making.
Background technology
Yarn will be processed into woven fabric must be processed into sizing through knitting front preparatory process, and then sizing is being knittedMake workshop and the weft yarn formation fabric that interweaves. The relative humidity of weaving workshop condition has aobvious to the regain of sizingWork impact, wearability and the brute force of the regain of sizing on sizing has remarkable impact, the wearability of sizing,Brute force has determined weaving efficiency and fabric quality. There is desirable moisture regain in textile mills in order to ensure sizing at presentRate, will weave that workshop relative humidity is made as 74%~80%, temperature is 28~30 DEG C. But human engineeringResearch shows, higher temperature and relative humidity are healthy very unfavorable to workman, weave shop workerBe in for a long time temperature up to 28 DEG C, relative humidity is up in more than 74% working environment, operating efficiencyDecline, workman's working environment is very severe, has a strong impact on the body that normally carries out and endanger worker of productionBody health. Severe working environment has caused the recruitment famine of textile mills; High relative humidity is to fabric manufacture equipmentMaintenance unfavorable; More seriously the environment of high humility increased air-conditioning load, consumed moreEnergy consumption, is unfavorable for energy-saving and emission-reduction, weaves workshop and keeps 80% relative humidity, and dewing expense is equivalent to weaveThe expenditure on power of workshop loom; Or be equivalent to keep 2 times of 65-70% relative humidity dewing expense.
Reducing the relative humidity (to 60% left and right) of weaving workshop has become the modern times and has weaved the new trend in workshop,But the formula of size complexity, the slurry component that adopt in existing sizing process are many, and multicomponent slurry is joinedThe performance of side and the ambiguity Chu of regain, only know that sizing must be under higher relative humidity environmentCould weave with higher efficiency, and to the mechanism of doing like this unclear, cause formula of size more and moreComplexity, weaves workshop relative humidity, temperature is more and more higher, has both increased and has weaved cost like this, worsens againWeave workshop condition. Selecting rational formula of size and slashing technique to prepare can be under low-humidity environmentWoven sizing is technical barrier urgently to be resolved hurrily.
Summary of the invention
The object of this invention is to provide one and be suitable for woven sizing method under low-humidity environment, solved existingHave formula of size complexity in warp thread sizing method, starch yarn must under high relative humidity environment, knitThe problem of making.
The technical solution adopted in the present invention is, one is suitable for woven sizing method under low-humidity environment,Specifically implement according to following steps:
Step 1, takes slurry: take respectively by mass percentage following component: PVA28%~82%,Converted starch 72%~18%, the content sum of above each component is 100%;
Step 2, modulation slurries: the slurry that step 1 is taken and water are made mixed under uniform temperature conditionClose slurries;
Step 3, is input to prepared step 2 mixed serum in warp sizing machine stock tank, and employing pair is soaked twoThe mode of pressing is carried out sizing to warp thread.
Feature of the present invention is also,
In step 1, converted starch is 100% potato side chain etherification starch, and PVA is 1799 types.
In step 2, slurries modulation detailed process is: in mixing cirtern, add suitable quantity of water, stir and will walkRapid 1 slurry taking adds wherein, when in mixing cirtern, temperature rises to 98~115 DEG C, and insulation 30~45min,Test serum viscosity using, viscosity meets the requirements, and has sized mixing, and obtains mixed serum.
In step 3, warp sizing machine is single slash-vat slasher or dual-box slasher.
Feature of the present invention is further,
In slurries modulated process, the funneling viscosimeter test of YT821 type for serum viscosity using, instrument connection is 3Number hole, serum viscosity using meets the requirements while being 6.5~7.0s.
The concentration of step 2 gained mixed serum is 10%~12%.
In step 3, it is 6.5-7.0% that warp sizing machine is set regain, and the speed of a motor vehicle of warp sizing machine is 75m/min,Squeezing roller pressure is 35KN.
The invention has the beneficial effects as follows,
(1) formula of size is single, only includes PVA and potato etherification starch, size mixing easily, and managementConvenient, greatly save storage area, meet the development trend of formula of size " few component ".
(2) take full advantage of the characteristic of PVA and potato etherification starch, and combine rational sizingTechnique, the yarn that this formula of size of process and slashing technique were starched can meet weaving under low-humidity environmentRequirement, has improved the working environment of weaving shop worker greatly; Greatly reduce and weave the negative of workshop air-conditioningLotus, the production cost of enterprise declines, and has good marketing prospect.
Brief description of the drawings
Fig. 1 is the sucting wet curve figure of PVA1799 under different relative humidity;
Fig. 2 is the sucting wet curve figure of 100% potato side chain etherification starch.
Detailed description of the invention
Below in conjunction with the drawings and specific embodiments, the present invention is described in detail.
At present, the slurry that textile mills are generally used has PVA, converted starch and polyacrylic slurry. ThisA little slurries have top performance separately under suitable regain.
The 1799 type PVA that the present invention selects are complete alcoholysis type, a polar functionalities hydroxyl in its structure(-OH), has good hygroscopicity, and Fig. 1 is the moisture absorption of PVA1799 under different relative humidityCurve. From Fig. 1, it can also be seen that, in the time that relative humidity is greater than 74%, PVA hygroscopicity significantly improves,This is because relative humidity water higher than 74% time has enough driving forces to destroy amorphous region, causes moisture absorptionRegain significantly rises.
Starch is the macromolecular compound being formed by connecting by α-Isosorbide-5-Nitrae glucoside key by α-D glucose, belongs to polysaccharideClass material, feature is in molecule, to contain many hydroxyls, has good hygroscopicity, Fig. 2 is 100% horseThe sucting wet curve of bell potato side chain etherification starch. As seen from Figure 2, in the time that relative humidity is greater than 70%,Starch size hygroscopicity significantly improves, and this is because under high humility, the concentration of the outside hydrone of starch sizeHeight, interior molecules concentration is little, the trend that the naturally oriented slurry molecular surface of water adheres to, this trend is with interiorThe increase of outer moist gradient and increasing, the regain of starch size also increases thereupon.
The slurries that the present invention adopts PVA1799 and 100% potato side chain etherification starch to be mixed, energyEnough realizing woven reason under low humidity (relative humidity 60%) condition is: adopting PVA1799When the slurries of preparing with 100% potato side chain etherification starch carry out starching, too high relative humidity can makeToo much moisture enters into the serous coat on sizing, has reduced the cohesive force of serous coat, causes the brute force of sizingDecline with wearability, meanwhile, farina natural moisture content is than the high 2-3% of cornstarch water content,So adopt the yarn of PVA and potato starch pulp, need to just can not give under high relative humidityThe good resistance to flexibility of serous coat on sizing. And in existing sizing process, mostly select PVA1799, corn to becomeProperty starch and multi-component polymerized polyacrylic slurry make mixed serum, warp thread is carried out to sizing, and surveysThe performance of examination sizing is that 70-74%, sized warp moisture regain are 8.3% slashing strength when above in relative humidityThe highest, wearability is best. This is because polyacrylic slurry is competence exertion under high regain onlyIts effect, and high regain must have the environment of high humility, otherwise sizing will moisture releasing, and sizing can not be protectedHold higher regain, and then impact is weaved.
One of the present invention is suitable for woven sizing method under low-humidity environment, comprises formula of size and sizing workSkill, its formula of size is: be made up of following component by mass percentage: polyvinyl alcohol 28%~82%,Converted starch 72%~18%, the content sum of above each component is 100%; Wherein, converted starch is 100%Potato side chain etherification starch, PVA is 1799 types.
Slashing technique is specifically implemented according to following steps:
Step 1, takes slurry: take respectively by mass percentage following component: PVA28%~82%,Converted starch 72%~18%, the content sum of above each component is 100%; Wherein, converted starch is 100%Potato side chain etherification starch, PVA is 1799 types.
Step 2, modulation slurries: the slurry that step 1 is taken and water are made mixed under uniform temperature conditionClose slurries; Slurries modulation detailed process is: in mixing cirtern, add suitable quantity of water, stir and step 1 is claimedThe slurry of getting adds wherein, and when in mixing cirtern, temperature rises to 98~115 DEG C, insulation 30~45min, surveysExamination serum viscosity using, viscosity meets the requirements, and has sized mixing, and obtains mixed serum; Serum viscosity using YT821The funneling viscosimeter test of type, instrument connection is No. 3 holes, serum viscosity using meets the requirements while being 6.5~7.0s;The concentration of gained mixed serum is 10%~12%.
Step 3, is input to prepared step 2 mixed serum in warp sizing machine stock tank, and employing pair is soaked twoThe mode of pressing is carried out sizing to warp thread. Wherein, warp sizing machine is single slash-vat slasher or dual-box slasher;It is 6.5-7.0% that warp sizing machine is set regain, and the speed of a motor vehicle of warp sizing machine is 75m/min, and squeezing roller pressure is35KN。
Embodiment 1
Fabric specification: MJ60 × 60140 × 12067 〞 1/1 plain weave
Step 1, takes 1799 type PVA25kg and 100% potato side chain etherification starch A11575kg,604L running water is squeezed in mixing cirtern, and turn on agitator, by the PVA taking and converted starch A115Add wherein, setting mixing cirtern temperature is 98 DEG C, when in mixing cirtern, temperature rises to 98 DEG C, and insulation45min, with the k value of slurries in the funneling viscosimeter of YT821 type (No. 3 holes) test mixing cirtern, whenWhen viscosity is 6.8s, slurries have been modulated, and obtain mixed serum;
Step 2, squeezes into step 1 gained mixed serum in the stock tank of Benniger dual-box slasher, establishesDetermining warp sizing machine regain is 6.5%, and the speed of a motor vehicle of warp sizing machine is 75m/min, and squeezing roller pressure is 35KN,Adopt the mode of double-clip-double-nip to carry out starching to JC60 yarn.
Embodiment 2
Fabric specification: MJC60 × JC60200 × 90120 〞 satin weave
Step 1, takes 1799 type PVA37.5kg and 100% potato side chain etherification starch A11562.5kg, squeezes into 684L running water in mixing cirtern, and turn on agitator, by the PVA taking and sex changeStarch A115 adds wherein, and setting mixing cirtern temperature is 115 DEG C, treats that in mixing cirtern, temperature rises to 115 DEG CTime, insulation 30min, with sticking of slurries in the funneling viscosimeter of YT821 type (No. 3 holes) test mixing cirternDegree value, in the time that viscosity is 6.5s, slurries have been modulated, and obtain mixed serum;
Step 2, squeezes into step 1 gained mixed serum in the stock tank of Benniger dual-box slasher, establishesDetermining warp sizing machine regain is 7.0%, and the speed of a motor vehicle of warp sizing machine is 75m/min, and squeezing roller pressure is 35KN,Adopt the mode of double-clip-double-nip to carry out starching to JC60 yarn.
Embodiment 3
Fabric specification: MJC60 × JC60200 × 90120 〞 satin weave
Step 1, takes 1799 type PVA80kg and 100% potato side chain etherification starch A11520kg, squeezes into 822L running water in mixing cirtern, and turn on agitator is formed sediment the PVA taking and sex changePowder A115 adds wherein, and setting mixing cirtern temperature is 105 DEG C, when in mixing cirtern, temperature rises to 105 DEG C,Insulation 38min, with the k value of slurries in the funneling viscosimeter of YT821 type (No. 3 holes) test mixing cirtern,In the time that viscosity is 7s, slurries have been modulated, and obtain mixed serum;
Step 2, squeezes into step 1 gained mixed serum in the stock tank of Benniger dual-box slasher, establishesDetermining warp sizing machine regain is 6.8%, and the speed of a motor vehicle of warp sizing machine is 75m/min, and squeezing roller pressure is 35KN,Adopt the mode of double-clip-double-nip to carry out starching to JC60 yarn.
Comparative example
Choose current factory conventional warp sizing formula of size and slashing technique, its detailed process is:
Fabric specification: MJC60 × JC60200 × 90120 〞 satin weave
Step 1, takes 1799 type PVA37.5kg, maize oxidized starch TRF-S75kg, polypropyleneWintercherry material 25kg, SLMO-962kg, squeeze into 690.5L running water in mixing cirtern, turn on agitator,The PVA taking, converted starch, solid propylene slurry and wax disk(-sc) are added wherein, set mixing cirtern temperatureBe 105 DEG C, when in mixing cirtern, temperature rises to 105 DEG C, insulation 38min, funneling by YT821 typeThe k value of slurries in viscosimeter (No. 3 holes) test mixing cirtern, in the time that viscosity is 7.8 seconds, slurries are adjustedSystem completes, and obtains mixed serum;
Step 2, squeezes into step 1 gained mixed serum in the stock tank of Benniger dual-box slasher, establishesDetermining warp sizing machine regain is 9%, and the speed of a motor vehicle of warp sizing machine is 75m/min, and squeezing roller pressure is 35KN,Adopt the mode of double-clip-double-nip to carry out starching to JC60 yarn.
Embodiment and comparative example under different relative humidity sized warp moisture regain and the performance test results as table 1Show.
Table 1
As can be seen from Table 1, adopt sizing method provided by the invention, when relative humidity is 60%, starchesThe regain of yarn is in the time of 6.5% left and right, and the brute force of sizing and wearability are all best; And comparative example slurryYarn is in relative humidity 70%, sized warp moisture regain 8.7% time, and brute force and the wearability of sizing are best. ByThis is visible, and sizing method of the present invention can be given wearability that warp thread is good and strong under low-humidity environmentPower.
Utilizing the embodiment of the present invention and comparative example method gained yarn, is that 28 DEG C, relative humidity are in temperatureIn 60% environment, weave, it is weaved and the results are shown in Table 2 simultaneously.
Table 2
Weaving efficiency Stop/100,000 latitudes of latitude Menelipsis/100,000 latitude
Embodiment 1 88.8 10.3 5.9
Embodiment 2 87.7 10.8 5.9
Embodiment 3 91.4 9.6 3.3
Comparative example 85.6 10.9 9.8
From table 2, adopt sizing method of the present invention, can under low humidity, complete and weave, and knitMake efficiency high.

Claims (7)

1. be suitable for a woven sizing method under low-humidity environment, it is characterized in that, specifically according to belowStep is implemented:
Step 1, takes slurry: take respectively by mass percentage following component: PVA28%~82%,Converted starch 72%~18%, the content sum of above each component is 100%;
Step 2, modulation slurries: the slurry that step 1 is taken and water are made mixed under uniform temperature conditionClose slurries;
Step 3, is input to prepared step 2 mixed serum in warp sizing machine stock tank, and employing pair is soaked twoThe mode of pressing is carried out sizing to warp thread.
2. one according to claim 1 is suitable for woven sizing method under low-humidity environment, its spyLevy and be, in step 1, converted starch is 100% potato side chain etherification starch, and PVA is 1799Type.
3. one according to claim 1 is suitable for woven sizing method under low-humidity environment, its spyLevy and be, in step 2, slurries modulation detailed process is: in mixing cirtern, add suitable quantity of water, stir alsoThe slurry that step 1 is taken adds wherein, when in mixing cirtern, temperature rises to 98~115 DEG C, and insulation30~45min, test serum viscosity using, viscosity meets the requirements, and has sized mixing, and obtains mixed serum.
4. one according to claim 3 is suitable for woven sizing method under low-humidity environment, its spyLevy and be, in slurries modulated process, the funneling viscosimeter test of YT821 type for serum viscosity using, testHole is No. 3 holes, and serum viscosity using meets the requirements while being 6.5~7.0s.
5. one according to claim 3 is suitable for woven sizing method under low-humidity environment, its spyLevy and be, the concentration of step 2 gained mixed serum is 10%~12%.
6. one according to claim 1 is suitable for woven sizing method under low-humidity environment, its spyLevy and be, in step 3, warp sizing machine is single slash-vat slasher or dual-box slasher.
7. one according to claim 6 is suitable for woven sizing method under low-humidity environment, its spyLevy and be, in step 3, it is 6.5-7.0% that warp sizing machine is set regain, and the speed of a motor vehicle of warp sizing machine is 75m/min,Squeezing roller pressure is 35KN.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106958145A (en) * 2017-03-18 2017-07-18 罗凯峰 The formula of size and its sizing technique of starching in low bath raio cheese or warp beam cylinder
CN109457366A (en) * 2018-12-25 2019-03-12 际华三五零九纺织有限公司 It is a kind of different through multi-weft fabric and its production method
CN114293331A (en) * 2021-12-31 2022-04-08 杭州正大纺织有限公司 Preparation process of TR yarn size

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Publication number Priority date Publication date Assignee Title
CN106958145A (en) * 2017-03-18 2017-07-18 罗凯峰 The formula of size and its sizing technique of starching in low bath raio cheese or warp beam cylinder
CN106958145B (en) * 2017-03-18 2019-04-26 罗凯峰 The formula of size and its sizing technique of starching in low bath raio cheese or warp beam cylinder
CN109457366A (en) * 2018-12-25 2019-03-12 际华三五零九纺织有限公司 It is a kind of different through multi-weft fabric and its production method
CN114293331A (en) * 2021-12-31 2022-04-08 杭州正大纺织有限公司 Preparation process of TR yarn size

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