CN105586527A - Anti-corrosion anti-flaming nonferrous metal material and preparation method thereof - Google Patents
Anti-corrosion anti-flaming nonferrous metal material and preparation method thereof Download PDFInfo
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- CN105586527A CN105586527A CN201510629888.XA CN201510629888A CN105586527A CN 105586527 A CN105586527 A CN 105586527A CN 201510629888 A CN201510629888 A CN 201510629888A CN 105586527 A CN105586527 A CN 105586527A
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/03—Making non-ferrous alloys by melting using master alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/10—Alloys containing non-metals
- C22C1/1036—Alloys containing non-metals starting from a melt
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/10—Alloys containing non-metals
- C22C1/1084—Alloys containing non-metals by mechanical alloying (blending, milling)
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
- C22C30/04—Alloys containing less than 50% by weight of each constituent containing tin or lead
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Abstract
The invention discloses an anti-corrosion anti-flaming nonferrous metal material and a preparation method thereof. The anti-corrosion anti-flaming nonferrous metal material is characterized in that the nonferrous metal material comprises, by weight, 20-30 parts of silver-lead master alloy, 12-14 parts of gypsum powder, 6-8 parts of glass fiber, 3-5 parts of quartz, 8-10 parts of borax, 15-20 parts of triethanolamine, 3-5 parts of trisodium phosphate, 3-5 parts of sodium benzoate, 6-8 parts of calcium phytate, 2-4 parts of titanium dioxide, 2-4 parts of copper oxide, 2-4 parts of cobaltous oxide, 0.5-0.7 part of a corrosion inhibitor and 0.6-0.8 part of fire retardant. The silver-lead master alloy enables the nonferrous metal material to have good corrosion resistance; an anti-oxidant solution makes the oxidation resistance of the nonferrous metal material be improved, so that the prepared nonferrous metal material is stable and reliable in fire resistance and free of smoky fire and smoke, has good decorative performance and is convenient to machine and obvious in effects of environmental protection and energy saving; in addition, the corrosion inhibition effect of the corrosion inhibitor on nonferrous metal is better than that of a BTA corrosion inhibitor, and oxidation losses are low; the composite material is made to have certain strength and heat transfer performance by adding the filling materials.
Description
Technical field
The invention belongs to nonferrous materials technical field, be specifically related to a kind of corrosion-resistant fire-retardant nonferrous materials and preparation method thereof.
Background technology
A feature of state's nonferrous metal resource is that grandidierite is many, and the grade having is lower, and not only multiple non-ferrous metal Chang Gongsheng together, and also contains a large amount of non-ferrous metals in some iron ore, as contained a large amount of vanadium, titanium in Panzhihua iron mine; In Baotou Iron Ore, contain a large amount of rare earths and niobium, therefore research is applicable to new technology, new technology, new equipment and the new material of Chinese Resources feature, progressively sets up the nonferrous materials system that is applicable to Chinese situation and be a very important task from now on.
Domestic non-ferrous metal industry concentration degree is low, scale and benefit are poor, resource is disperseed, and is again one of the industry closely of integrating with the world market simultaneously. Change the unfavorable situation of Chinese Enterprise in raw material fluctuation, produce non-ferrous metal synthetic material significant. In metal processing industry, the products such as copper strips, copper wire, Copper Foil, silver strip, filamentary silver are storing and In transit easily plays blackening, blackout, tarnish, even play the problems such as verdigris, and the antioxidant using is not at present that to have little effect be exactly expensive.
In addition, though existing nonferrous materials is the flames of anger mostly, produce cigarette, though solve inflammable difficulty, once but catch fire more difficult putting out. And especially important to the corrosion-resistant treatments of non-ferrous metal.
At present, in order to reach good effect, the corrosion inhibiter of non-ferrous metal mainly adopts BTA, but this chemical substance has huge poison, and operating personnel's health is had to very large infringement. Thereby good, the cheap and fire-retardant nonferrous materials of a kind of corrosion resistance of innovation and creation is a development of demand direction.
Summary of the invention
For problems of the prior art, the object of the present invention is to provide a kind of corrosion-resistant fire-retardant nonferrous materials and preparation method thereof.
The technical scheme that the present invention takes is: a kind of corrosion-resistant fire-retardant nonferrous materials, it is characterized in that, the each component of raw material is composed as follows according to weight portion: argentalium intermediate alloy 20-30 part, land plaster 12-14 part, glass fibre 6-8 part, quartzy 3-5 part, borax 8-10 part, triethanolamine 15-20 part, tertiary sodium phosphate 3-5 part, Sodium Benzoate 3-5 part, phytic acid calcium 6-8 part, titanium dioxide 2-4 part, cupric oxide 2-4 part, cobalt oxide 2-4 part, corrosion inhibiter 0.5-0.7 part, fire retardant 0.6-0.8 part.
Further, described corrosion inhibiter is that Boratex, sodium fluoride and ribonucleoside triphosphote are according to the mixture of weight ratio 3:2:2 composition.
Further, described fire retardant is that diammonium hydrogen phosphate, lauryl sodium sulfate and cobalt aluminate are according to the mixture of weight ratio 2:3:3 composition.
Further, described argentalium intermediate alloy adopts high vacuum electric arc melting method to be molten into the argentalium alloy of leaded mass percent 45-55%.
A preparation method for corrosion-resistant fire-retardant nonferrous materials, is characterized in that, specifically comprises the steps: (1) packing material processed: after land plaster, glass fibre and quartz are mixed, calcining 2-3h adds the mixed 25-35min of borax in batch mixer; (2) argentalium intermediate alloy processed: it is to soak 2-3h in 0.3g/L-0.5g/L liquor argenti nitratis ophthalmicus that lead alloy plate is placed on to concentration, is then placed in heat treatment tank type stove heat treatment 7-8h under 180-220 DEG C of temperature conditions; (3) join oxidation resistance liquid: get triethanolamine, tertiary sodium phosphate, Sodium Benzoate according to percentage by weight, add in the opening reactor of 220 revs/min of rotating speeds and stir; (4) synthetic material processed: will add phytic acid calcium, titanium dioxide, cupric oxide, cobalt oxide in the argentalium intermediate alloy making in above-mentioned steps, through pincers pot or converter high-temperature heating 3h, the packing material and the oxidation resistance liquid that add above-mentioned steps to make, quenching in cold water, put into ball mill, ratio according to 3:5 is watered, defibrination 30-40min.
Beneficial effect of the present invention is: the argentalium intermediate alloy in the present invention is as one of primary raw material, and argentalium intermediate alloy adopts the fusing of high vacuum electric arc melting method can reduce the scaling loss of noble metal and make alloying component even; Silver and the plumbous corrosion resistance that can improve metal, can make nonferrous materials have good corrosion resistance; Oxidation resistance liquid strengthens the antioxygenic property of material.
The synergy of the composition such as land plaster, fire retardant in the present invention, makes the fire protecting performance of the nonferrous materials making reliable and stable, without pyrotechnics, smokeless; And have good ornamental; Be convenient to processing, environmental protection and energy saving successful. Corrosion inhibiter in the present invention has been abandoned traditional BTA, substantially non-toxic, and on the corrosion mitigating effect of non-ferrous metal also than corrosion inhibiter effective that adopts BTA, packing material makes the composite adhesion property that makes good, oxidational losses is low, and adding of packing material makes composite have certain intensity and heat transfer property. Material composition is nontoxic, and antibiotic property is good, has wear-resisting, acid-alkali-corrosive-resisting.
Preparation technology is easy, easy to operate, is easy to industrial implementation.
Detailed description of the invention
1 one kinds of corrosion-resistant fire-retardant nonferrous materials of embodiment, it is characterized in that, the each component of raw material is composed as follows according to weight portion: 20 parts of argentalium intermediate alloys, 12 parts of land plasters, 6 parts, glass fibre, 3 parts, quartz, 8 parts of boraxs, 15 parts of triethanolamines, 3 parts of tertiary sodium phosphates, 3 parts of Sodium Benzoates, 6 parts of phytic acid calcium, 2 parts of titanium dioxide, 2 parts of cupric oxide, 2 parts of cobalt oxides, Boratex, sodium fluoride and ribonucleoside triphosphote are according to 0.5 part of the corrosion inhibiter of weight ratio 3:2:2 composition, diammonium hydrogen phosphate, lauryl sodium sulfate and cobalt aluminate are according to 0.6 part of the fire retardant of weight ratio 2:3:3 composition.
2 one kinds of corrosion-resistant fire-retardant nonferrous materials of embodiment, it is characterized in that, the each component of raw material is composed as follows according to weight portion: 25 parts of argentalium intermediate alloys, 13 parts of land plasters, 7 parts, glass fibre, 4 parts, quartz, 9 parts of boraxs, 18 parts of triethanolamines, 4 parts of tertiary sodium phosphates, 4 parts of Sodium Benzoates, 7 parts of phytic acid calcium, 3 parts of titanium dioxide, 3 parts of cupric oxide, 3 parts of cobalt oxides, Boratex, sodium fluoride and ribonucleoside triphosphote are according to 0.6 part of the corrosion inhibiter of weight ratio 3:2:2 composition, diammonium hydrogen phosphate, lauryl sodium sulfate and cobalt aluminate are according to 0.7 part of the fire retardant of weight ratio 2:3:3 composition.
3 one kinds of corrosion-resistant fire-retardant nonferrous materials of embodiment, it is characterized in that, the each component of raw material is composed as follows according to weight portion: 30 parts of argentalium intermediate alloys, 14 parts of land plasters, 8 parts, glass fibre, 5 parts, quartz, 10 parts of boraxs, 20 parts of triethanolamines, 5 parts of tertiary sodium phosphates, 5 parts of Sodium Benzoates, 8 parts of phytic acid calcium, 4 parts of titanium dioxide, 4 parts of cupric oxide, 4 parts of cobalt oxides, Boratex, sodium fluoride and ribonucleoside triphosphote are according to 0.7 part of the corrosion inhibiter of weight ratio 3:2:2 composition, diammonium hydrogen phosphate, lauryl sodium sulfate and cobalt aluminate are according to 0.8 part of the fire retardant of weight ratio 2:3:3 composition.
A preparation method for corrosion-resistant fire-retardant nonferrous materials, is characterized in that, specifically comprises the steps: (1) packing material processed: after land plaster, glass fibre and quartz are mixed, calcining 2-3h adds the mixed 25-35min of borax in batch mixer; (2) argentalium intermediate alloy processed: it is to soak 2-3h in 0.3g/L-0.5g/L liquor argenti nitratis ophthalmicus that lead alloy plate is placed on to concentration, is then placed in heat treatment tank type stove heat treatment 7-8h under 180-220 DEG C of temperature conditions; (3) join oxidation resistance liquid: get triethanolamine, tertiary sodium phosphate, Sodium Benzoate according to percentage by weight, add in the opening reactor of 220 revs/min of rotating speeds and stir; (4) synthetic material processed: will add phytic acid calcium, titanium dioxide, cupric oxide, cobalt oxide in the argentalium intermediate alloy making in above-mentioned steps, through pincers pot or converter high-temperature heating 3h, the packing material and the oxidation resistance liquid that add above-mentioned steps to make, quenching in cold water, put into ball mill, ratio according to 3:5 is watered, defibrination 30-40min.
The above is not limitation of the present invention; be noted that for those skilled in the art; do not departing under the prerequisite of essential scope of the present invention; can also make some variations, remodeling, interpolation or replacement, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (5)
1. a corrosion-resistant fire-retardant nonferrous materials, is characterized in that, the each component of raw material is composed as follows according to weight portion:
Argentalium intermediate alloy 20-30 part, land plaster 12-14 part, glass fibre 6-8 part, quartzy 3-5 part, borax 8-10 part, triethanolamine 15-20 part, tertiary sodium phosphate 3-5 part, Sodium Benzoate 3-5 part, phytic acid calcium 6-8 part, titanium dioxide 2-4 part, cupric oxide 2-4 part, cobalt oxide 2-4 part, corrosion inhibiter 0.5-0.7 part, fire retardant 0.6-0.8 part.
2. the corrosion-resistant fire-retardant nonferrous materials of one according to claim 1, is characterized in that, described corrosion inhibiter is that Boratex, sodium fluoride and ribonucleoside triphosphote are according to the mixture of weight ratio 3:2:2 composition.
3. the corrosion-resistant fire-retardant nonferrous materials of one according to claim 1, is characterized in that, described fire retardant is that diammonium hydrogen phosphate, lauryl sodium sulfate and cobalt aluminate are according to the mixture of weight ratio 2:3:3 composition.
4. the corrosion-resistant fire-retardant nonferrous materials of one according to claim 1, is characterized in that, described argentalium intermediate alloy adopts high vacuum electric arc melting method to be molten into the argentalium alloy of leaded mass percent 45-55%.
5. a preparation method for corrosion-resistant fire-retardant nonferrous materials, is characterized in that, specifically comprises the steps:
(1) packing material processed: after land plaster, glass fibre and quartz are mixed, calcining 2-3h adds the mixed 25-35min of borax in batch mixer;
(2) argentalium intermediate alloy processed: it is to soak 2-3h in 0.3g/L-0.5g/L liquor argenti nitratis ophthalmicus that lead alloy plate is placed on to concentration, is then placed in heat treatment tank type stove heat treatment 7-8h under 180-220 DEG C of temperature conditions;
(3) join oxidation resistance liquid: get triethanolamine, tertiary sodium phosphate, Sodium Benzoate according to percentage by weight, add in the opening reactor of 220 revs/min of rotating speeds and stir;
(4) synthetic material processed: will add phytic acid calcium, titanium dioxide, cupric oxide, cobalt oxide in the argentalium intermediate alloy making in above-mentioned steps, through pincers pot or converter high-temperature heating 3h, the packing material and the oxidation resistance liquid that add above-mentioned steps to make, quenching in cold water, put into ball mill, ratio according to 3:5 is watered, defibrination 30-40min.
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| CN201510629888.XA CN105586527A (en) | 2015-09-29 | 2015-09-29 | Anti-corrosion anti-flaming nonferrous metal material and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11602658B2 (en) | 2020-12-15 | 2023-03-14 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
| US11819722B1 (en) | 2019-06-07 | 2023-11-21 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11975231B2 (en) | 2022-03-31 | 2024-05-07 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| WO2024102391A1 (en) * | 2022-11-09 | 2024-05-16 | Perimeter Solutions Lp | Fire retardant compositions containing a carbonate salt |
-
2015
- 2015-09-29 CN CN201510629888.XA patent/CN105586527A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11819722B1 (en) | 2019-06-07 | 2023-11-21 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11819723B2 (en) | 2019-06-07 | 2023-11-21 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11602658B2 (en) | 2020-12-15 | 2023-03-14 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
| US11628324B2 (en) | 2020-12-15 | 2023-04-18 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11865391B2 (en) | 2020-12-15 | 2024-01-09 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11865392B2 (en) | 2020-12-15 | 2024-01-09 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11883703B2 (en) | 2020-12-15 | 2024-01-30 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
| US11975231B2 (en) | 2022-03-31 | 2024-05-07 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| WO2024102391A1 (en) * | 2022-11-09 | 2024-05-16 | Perimeter Solutions Lp | Fire retardant compositions containing a carbonate salt |
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Application publication date: 20160518 |