CN105586144B - A kind of scale up test method of complete water-soluble drawing oil and the model that forms a complete production network - Google Patents
A kind of scale up test method of complete water-soluble drawing oil and the model that forms a complete production network Download PDFInfo
- Publication number
- CN105586144B CN105586144B CN201410648683.1A CN201410648683A CN105586144B CN 105586144 B CN105586144 B CN 105586144B CN 201410648683 A CN201410648683 A CN 201410648683A CN 105586144 B CN105586144 B CN 105586144B
- Authority
- CN
- China
- Prior art keywords
- water
- ethanol amine
- drawing oil
- boric acid
- reaction kettle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses completely water-soluble drawing oil producing method of new generation and mating production models, belong to fine chemistry industry new product field, are related specifically to the production application of the fields such as automobile sheet stamping member.Different application methods are such as：Smearing etc. needs the cooperation of different viscosities.The technology uses the ethanol amine borate of oneself synthesis（A）, ethanolamine fatty acid salt（B）And water（C）Three kinds of substances are amplified compounding, mass ratio A:B:C is 1:1‑0.2：1‑0.1.Its corresponding amplification production Viscosity Model is modified ASTM models, using the viscosity under environment temperature as index, using B and C as regulated variable.Amplification production addition ratio is provided by model calculating in the case where amplifying the condition of production.Drawing oil product cooling, lubricity and anti-extreme pressure compared with existing oil-based products is more preferable, saves stamping parts oil removing process, can be rinsed with tap water, have anti-flammability, safety and environmental protection, the severe of Complex Parts is suitble to stretch application.
Description
Technical field
The present invention relates to scale up test methods and scale-up model that a kind of carbon steel thin plate punching press is finished full water-soluble drawing oil.
Background technology
Drawing oil as a kind of process oil, play the role of during metallic plate punching it is extremely important, have lubrication,
The performances such as anti-extreme pressure, cooling, antirust.Currently, the drawing oil applied in sheet metal mechanical stamping in the market is all oil base production
Product, it the shortcomings that be：Stamping parts product cannot be washed, and high temperature oil removing process is needed；The cooling difference and easy firing of oil-based products；
Anti-extreme pressure and lubricity deficiency etc. are stretched to severe.Complete water-soluble water base drawing oil product is the replacement production of a new generation
Product, it has washing property, high anti-extreme pressure and lubrication, anti-flammability, rust-preventing characteristic completely, environment Wholly-degradable etc.
Advantage.The viscosity of the product is related with material category, mixed proportion and temperature, under conditions of material therefor type is constant, is
Adjusting viscosity is solved with adapting to operating procedure and operating environment by changing mixture ratio method.It is researched and developed for oneself
Complete water-soluble drawing oil eries product carry out production amplification, and develop a mixing Viscosity Model.
Water base drawing oil Viscosity Model can regard Liquid-liquid mixing Viscosity Model as.Now, there are many empirical models and half
Theoretical model is for calculating Liquid-liquid mixing object viscosity, wherein most of is to return to obtain using experimental data. Arrhenius
Model is the classical model for calculating mixture viscosity value, it is suitable for calculating the viscosity number of pure hydrocarbon mixed system,
Lederer increases correction factor on this basis, establishes the Linear Combination Model of new mixing viscosity logarithm.Bingham
New Viscosity Model is proposed based on perfect solution, that is, the inverse for mixing viscosity falls equal to two kinds of substance viscosities of composition mixture
The linear combination of number and mass fraction.Hereafter, Kendall and Monroe establishes the mass fraction of mixture viscosity 1/n powers
Linear Combination Model is recommended to glue for the similar pure hydrocarbon mixed system of environment under low pressure calculating structure by american petroleum research institute
Degree.Cragoe proposes the ln (2000u for calculating high viscosity mixed systemi) the linear combination mould reciprocal with mass fraction
Type.Now, since basic data disunity causes the Viscosity Model obtained can not be general, erect image Centeno et al are pointed out simultaneously
There is no universal universal viscosity model.Although can accurately be calculated without blanket Viscosity Model as water base drawing oil mixes
The viscosity number of system can but re-establish and be used for viscosity calculations for water base drawing oil mixed system model.
In enlarged experiment, the input amount of raw material increases, and occurs during lab scale without the problem：1. former material
Gelatin phenomenon occurs between material, influences the final molding of water-soluble drawing oil;2. due to mass production, original technique is not most
Excellent method causes to waste；Will be to semi-finished product raw material storing, the stability of material is different, to storage request difference；Pilot scale
Equipment is operationally different from the equipment of lab scale, for how safety needs to set from newly efficiently and reasonably using reaction kettle
It is fixed, so will be from new settings for the technique of water-soluble drawing oil scale up test.
Invention content
Present invention efficiently solves variety of problems of water-soluble drawing oil during scale up test, provide water solubility
Drawing oil producing method and method of viscosity control.
The present invention uses following technical scheme:Water-soluble drawing oil scale up test method and mating production model, it is special
Sign is:M-ASTM models (, ), correct ASTM models undetermined parameter a and b seek use table, repair
The use of positive model.Raw materials ethanol amine, aliphatic acid, boric acid and corresponding proportioning, the charging sequence of 3 kinds of intermediates, ethyl alcohol
Broken fastization of amine boric acid fat, water filling flow velocity and mode.
It is a kind of water solubility drawing oil scale up test match set of model：
Since water-soluble drawing oil viscosity is related with material category, mixed proportion and environment temperature.It is right that this method passes through
The calculated value and measured value of ASTM (Viscosity Model) carry out the linear fit amendment of least square method, obtain M-ASTM models (, ), degree of fitting, which reaches from 0.8600, is increased to 0.9907.M-ASTM models by temperature, and raw material contains
Amount, material category and water-soluble drawing oil viscosity correlation are to together.It thus can be according to the environment temperature used, device requirement
Viscosity, the anti-ratio derived between compounding substance, is accurately controlled the viscosity of water-soluble drawing oil, to meet the use of equipment
It is required that.Fig. 1 is M-ASTM model symbol explanations.
The viscosity number first measured by multiple batches of water base drawing oil, ambient temperature value and mixed proportion value are brought into modified
In ASTM models, undetermined parameter a, b are sought, further according to the amendment ASTM models of obtained determination undetermined parameter.With this model,
Know environment temperature that client uses and its requirement use viscosity after, ingredient proportion, specific Instructing manufacture can be found out.
In order to facilitate use, is looked into The present invention gives Fig. 2 M-ASTM model undetermined parameters and take table.
A kind of scale up test method of water solubility drawing oil：
Water-soluble drawing oil forms using 3 kinds of raw material compoundings：Amine fatty acid salt, ethanol amine boric acid fat and originally
Water.Mass ratio ethanolamine fatty acid salt：Ethanol amine boric acid fat and water are equal to 1：1-0.2：1-0.1 can be adjusted according to different requirements
Save its ratio.
2.1 ethanolamine fatty acid salt production methods：
By ethanol amine：Aliphatic acid is equal to 0.2-1.0:1 mass ratio measures and aliphatic acid is first put into reaction kettle, then throws
Enter ethanol amine, the temperature of reaction kettle is 50-120oC, mixing speed are 60-80 revs/min, react 1-5 hours, obtain ethanol amine fat
Fat hydrochlorate, brown color liquid, solidifies at room temperature.
2.2 ethanol amine boric acid fat production methods：
By ethanol amine:Boric acid is equal to 1-2.4:1 mass ratio measures.Boric acid is first put into reaction kettle, then puts into ethyl alcohol
The temperature of amine, reaction kettle is 70-200oC, mixing speed are 60-80 revs/min, react 3-10 hours, obtain ethanol amine boric acid fat,
Light yellow viscous liquid, at room temperature quickly solidification.When being cooled to room temperature, ethanol amine boric acid fat is taken out, and smashed, diameter is small
In 5 centimetres.Sealed storage.
The compounding of 2.3 water-soluble drawing oils
In 3 kinds of raw material being used in compounding, water can be replaced with tap water, with take with.In compounding using suitable below
Sequence.
The first step：After obtaining ethanolamine fatty acid salt, constant temperature 50-90 is keptoC stops stirring, is put in proportion into ethanol amine
Boric acid fat fragment starts stirring and stirs, 60-80 revs/min, 30-50 minutes.
Second step：Stop stirring, inspection state, burgundy, uniform viscous pasty state is presented in solution.
Third walks：Start 60-80 revs/min of secondary agitation, for tap water in the form of thread, flow velocity is reaction kettle body per minute
1/10 long-pending flow velocity is injected along the edge of reaction kettle.After water injects, stirring 3-5min, feeding are maintained.
4th step：Product seals, half-light storage.
5th step：Use 30-50oC warm water cleans the equipment such as reaction kettle, then dries.
Through the above scheme, the present invention can bring following advantageous effect：The present invention provides water-soluble drawing oil viscosities
Control method and the model that forms a complete production network.The viscosity that water-soluble drawing oil can effectively be controlled, reaches corresponding equipment requirement.It is excellent
The process of change can be safe, efficiently and reasonably produces water-soluble drawing oil.
Description of the drawings
Attached drawing 1 is M-ASTM model formation symbol descriptions.
Attached drawing 2 is that M-ASTM model undetermined parameters are looked into and take table.
Specific embodiment
This embodiment is merely to illustrate the application method of model of the present invention, and is not limited to the scope of the present invention.In addition understand
For after having read content of this experiment with invention, those skilled in the art can carry out the present invention various changes and repair
Change, these equivalent forms also fall within the scope of the appended claims of the present application.
Embodiment 1
Using the reaction kettle of 150L, the severe of 100 kilograms of production is stretched with water-soluble drawing oil, requirement be
30oC, for viscosity is 1500mpas：
According to equipment requirement is used, use environment temperature 30 is determinedoC and viscosity 1500mpas, as shown in Figure 1, checking in a
=1.61, b=- 0.59, obtains concrete model , , calculate
Ingredient proportion=0.89, the quality of water and ethanol amine boric acid fat and the quality equal to ethanolamine fatty acid salt.Compound mass ratio
For ethanolamine fatty acid salt：Ethanol amine boric acid fat：Water=1：0.89：0.11.So ingredient proportion is determined as ethanolamine fatty acid salt
=50 kilograms, ethanol amine boric acid fat=44.5 kilogram, water=5.5 kilogram.
Embodiment 2
Environment temperature 20oC, 600 mpas of viscosity requirement, moderate elongation is used, as shown in Fig. 2, a=1.84 is checked in, b=-
0.80, obtain concrete model , , calculate ingredient proportion=0.74 and ethanol amine boric acid fat quality and be ethanol amine fat equal to the quality compounding mass ratio of ethanolamine fatty acid salt
Fat hydrochlorate：Ethanol amine boric acid fat：Water=1：0.74：0.26.So ingredient proportion is determined as ethanolamine fatty acid salt=50 kilogram, second
Hydramine boric acid fat=37 kilogram, water=13 kilogram.
Embodiment 3
Environment temperature 10oC, 200 mpas of viscosity requirement, either shallow, which stretches, to be used, as shown in Fig. 2, a=1.31 is checked in, b=-
0.46, obtain concrete model , , calculate ingredient proportion=0.46, the quality of water and ethanol amine boric acid fat and quality compounding mass ratios equal to ethanolamine fatty acid salt are ethanol amine
Fatty acid salt：Ethanol amine boric acid fat：Water=1：0.46：0.52.So ingredient proportion is determined as ethanolamine fatty acid salt=50 kilogram,
Ethanol amine boric acid fat=23 kilogram, water=27 kilogram.
Embodiment 4
Ethanol amine boric acid fat production method：
It is ethanol amine in mass ratio：Boric acid=1.5：1 ratio measures 60 kilograms of ethanol amine, 40 kilograms of boric acid.First by boron
Acid input reaction kettle, then ethanol amine is put into, the temperature of reaction kettle is 90-200oC, mixing speed are 60 revs/min, are reacted 3 hours,
Obtain ethanol amine boric acid fat, light yellow viscous liquid, at room temperature quickly solidification.Being cooled to room temperature is, takes out ethanol amine boric acid fat,
And smashed, diameter is less than 5 centimetres.Sealing, storage.
Embodiment 5
Ethanolamine fatty acid salt production method：
By ethanol amine：Aliphatic acid=0.5：1 ratio measures 50 kilograms of ethanol amine, 100 kilograms of aliphatic acid.First by aliphatic acid
Reaction kettle is put into, then puts into ethanol amine, the temperature of reaction kettle is 120oC, mixing speed are 60 revs/min, react 4 hours, obtain
Ethanolamine fatty acid salt, brown color liquid, solidifies at room temperature.
Embodiment 6
According to embodiment 4 and embodiment 3, ethanol amine boric acid fat produces completion in advance, and fragmented, and diameter is less than 5 lis
Rice, takes 23 kilograms.After the completion of 50 kg ethanol amine fatty acid salts produce, stop stirring, 23 kg ethanol amine boric acid fat are thrown
Enter in reaction kettle, is put into along edge.Agitating paddle is opened, 60 revs/min, after the 30-50 minutes times of stirring arrive, stops stirring, sees
Examine phenomenon, liquid is burgundy, uniform, and viscous pasty state is again turned on stirring, 60 revs/min, tap water along reaction kettle edge, with
15L/ minutes flow velocitys are added, and after tap water is added, continue stirring 3-5 minutes, stop stirring, take out water-soluble drawing
Oily finished product.In process of production, reaction kettle is always maintained at 90oAfter C constant temperature feedings, constant temperature system is closed, injection is originally
Water, using the waste-heat tap water of reaction kettle, quiet bubble 30 minutes, brush reaction kettle dries.
The present embodiment is the water-soluble drawing oil produced with scale up test method and with set of model.
Claims (7)
1. a kind of water solubility drawing oil, which is characterized in that the drawing oil is compounded using 3 kinds of raw materials, is ethanol amine respectively
Fatty acid salt, ethanol amine boric acid fat and tap water；
The compound proportion of the ethanolamine fatty acid salt and ethanol amine boric acid fat closes
System is using the drawing oil viscosity under environment temperature and application scenario as target component, is adjustable with material category and mixed proportion
Variable carries out the non-thread of least square method after given target variable by calculated value to ASTM Viscosity Models and measured value
Property fitting correct, obtained modified ASTM model formations；
In formula,Water-soluble drawing oil viscosity is represented,Relative viscosity is represented,It represents ethanol amine boric acid fat and accounts for ethanol amine
The mass ratio of borate.
2. a kind of water-soluble drawing oil according to claim 1, which is characterized in that the ethanolamine fatty acid salt:Second
The mass ratio of hydramine boric acid fat and tap water is 1: 1-0. 2 : 1-0. 1.
3. a kind of water-soluble drawing oil according to claim 1, which is characterized in that the ethanolamine fatty acid salt production
Method includes：
Aliphatic acid is first put into reaction kettle, then puts into ethanol amine, the temperature of reaction kettle is 50-120 DEG C, mixing speed 60-80
Rev/min, it reacts 1-5 hours, obtains ethanolamine fatty acid salt, brown color liquid.
4. a kind of water-soluble drawing oil according to claim 3, which is characterized in that the matter of the ethanol amine and aliphatic acid
Amount is than being 0.2-1.0：1.
5. a kind of water-soluble drawing oil according to claim 1, which is characterized in that the production of the ethanol amine boric acid fat
Method includes：
Boric acid is first put into reaction kettle, then puts into ethanol amine, the temperature of reaction kettle is 70-200 DEG C, mixing speed be 60-80 turn/
Point, it reacts 3-10 hours, obtains ethanol amine boric acid fat, light yellow viscous liquid, quickly solidification, takes out ethanol amine boric acid at room temperature
Fat, and smashed, diameter is less than 5 centimetres of sealings, storage.
6. a kind of water-soluble drawing oil according to claim 5, which is characterized in that the quality of the ethanol amine and boric acid
Than for 1-2.4：1.
7. a kind of production method of water-soluble drawing oil according to claim 1, which is characterized in that including：
Lipid is first produced, then reproduction salt intermediate product is re-dubbed drawing oil product, and presses following order:
The first step:After obtaining ethanolamine fatty acid salt, 50-100 DEG C of constant temperature is kept, stops stirring, is put in proportion into ethanol amine boron
Sour fat fragment starts stirring and stirs, 60-80 revs/min, 30-50 minutes；
Second step:Stop stirring, inspection state, burgundy, uniform, viscous pasty state is presented in solution；
Third walks:Start 60-80 revs/min of secondary agitation, for tap water in the form of thread, flow velocity is the 1/ of reaction kettle volume per minute
10 flow velocity is injected along the edge of reaction kettle;After water injects, stirring 3-5min, feeding are maintained；
4th step:Product seals, half-light storage；
5th step:Reaction kettle equipment is cleaned with 30-50 DEG C of warm water, is then dried.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410648683.1A CN105586144B (en) | 2014-11-17 | 2014-11-17 | A kind of scale up test method of complete water-soluble drawing oil and the model that forms a complete production network |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410648683.1A CN105586144B (en) | 2014-11-17 | 2014-11-17 | A kind of scale up test method of complete water-soluble drawing oil and the model that forms a complete production network |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105586144A CN105586144A (en) | 2016-05-18 |
| CN105586144B true CN105586144B (en) | 2018-10-16 |
Family
ID=55926054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410648683.1A Expired - Fee Related CN105586144B (en) | 2014-11-17 | 2014-11-17 | A kind of scale up test method of complete water-soluble drawing oil and the model that forms a complete production network |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105586144B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102206530A (en) * | 2011-05-05 | 2011-10-05 | 重庆大学 | Stainless steel temperature difference drawing mould lubricant |
| CN102660367A (en) * | 2012-04-24 | 2012-09-12 | 长春工业大学 | Producing method of water-soluble drawing oil for stamping carbon steel sheets |
| CN103666660A (en) * | 2012-09-20 | 2014-03-26 | 中国石油化工股份有限公司 | Automobile part drawing oil composition and use thereof |
-
2014
- 2014-11-17 CN CN201410648683.1A patent/CN105586144B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102206530A (en) * | 2011-05-05 | 2011-10-05 | 重庆大学 | Stainless steel temperature difference drawing mould lubricant |
| CN102660367A (en) * | 2012-04-24 | 2012-09-12 | 长春工业大学 | Producing method of water-soluble drawing oil for stamping carbon steel sheets |
| CN103666660A (en) * | 2012-09-20 | 2014-03-26 | 中国石油化工股份有限公司 | Automobile part drawing oil composition and use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105586144A (en) | 2016-05-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103386461B (en) | A kind of microemulsion non-ferrous metal releasing agent and preparation method thereof | |
| CN100571926C (en) | Heat resisting lubricating agent | |
| CN103694068B (en) | A kind of emulsion plant type composite oil phase | |
| CN108641031A (en) | A kind of hindered phenol/styrene-acrylic composite emulsion and preparation method thereof | |
| Rogers | Hansen solubility parameters as a tool in the quest for new edible oleogels | |
| CN104311795A (en) | Preparation method of amino acid modified self-emulsifying waterborne epoxy resin | |
| CN105586144B (en) | A kind of scale up test method of complete water-soluble drawing oil and the model that forms a complete production network | |
| CN106398821A (en) | Preparation method of plant oil-based lubricating oil | |
| CN106087552A (en) | Preparation method of a kind of water-based zinc stearate dispersion liquid and products thereof and application | |
| CN103992196B (en) | A kind of special oil phase of heat-sensitized explosive production line and preparation method thereof | |
| CN104945206B (en) | A kind of heat-sensitized technique Compound oil phase for emulsion explosive and preparation method thereof | |
| CN101671597A (en) | Concentrated liquid state oil-based rust inhibitor and preparation technology thereof | |
| CN109536260A (en) | Environment-friendly type lubricating grease with high lubricating property and preparation method thereof | |
| CN106367186B (en) | One vegetable oil base degradable lubricating oil | |
| CN108410555A (en) | A kind of lathe environment-protective lubricant oil | |
| CN104231233B (en) | Water-soluble self curable epoxy resin and preparation method | |
| CN102994205A (en) | Stretching emulsion of stainless steel product | |
| CN107502106A (en) | A kind of water-borne acrylic coatings and preparation method thereof and application method | |
| CN103468375A (en) | Preparation method for metalware stretching emulsion | |
| CN106190454A (en) | A kind of Digit Control Machine Tool rotating shaft special lube and preparation technology thereof | |
| CN105418828A (en) | Aqueous acrylic acid emulsion and preparation method thereof | |
| CN104560055B (en) | A kind of lysotropic liquid crystal and its production and use | |
| CN105524686B (en) | A kind of lubrication Seal Oil and preparation method thereof for automotive air outlet | |
| CN109609247A (en) | Anhydrous calcium-base grease and preparation method thereof | |
| CN104387287B (en) | A kind of method of acetochlor oil purifying |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20181016 Termination date: 20201117 |